Patent Application
20220190377
The present disclosure relates to fuel cell cartridges, fuel cell modules, and combined cycle power generation systems for solid oxide fuel cells.
Fuel cells which are power generation devices using a power generation method by an electrochemical reaction, and have characteristics such as excellent power generation efficiency and environmental friendliness are known. Among the fuel cells, solid oxide fuel cells (SOFC) generate electric power using hydrogen and carbon monoxide produced by reforming fuels such as city gas, natural gas, and coal gas, using ceramics such as zirconia ceramics as an electrolyte. The solid oxide fuel cell has a high operating temperature of about 700° C. to 1100° C. in order to increase the ionic conductivity, and is known as a versatile and highly efficient high-temperature fuel cell. The solid oxide fuel cell generates electric power by reaction of an oxidant gas with a fuel gas supplied to the inside and the outside of a tubular cell stack (cell tube) having a cathode and an anode, for example.
SOFCs can generate electric power more efficiently by increasing the combined operating pressure with rotating equipment such as gas turbines, micro gas turbines and turbochargers. In such a pressurizing system, the compressed air discharged from a compressor is supplied to the cathode of the SOFC as an oxidized gas. The high-temperature exhaust fuel gas discharged from the SOFC is supplied to a combustor at the inlet of the rotating equipment and is burned. The rotating equipment is rotated with the high-temperature combustion gas generated by the combustor. In this way, power can be recovered.
Patent Literature 1 discloses a fuel cell device that facilitates wiring work by electrically connecting a plurality of cell stacks constituting a fuel cell with a conductive current collecting member. In such a plurality of cell stacks, a temperature distribution that is not negligible occurs during operation, and the internal resistance of each cell stack depends on the temperature. That is, the higher the temperature of the cell stack, the smaller the internal resistance and the easier it is for the current to flow. Therefore, if the current is distributed to the cell stacks so that the voltages of the cell stacks connected in parallel are equal, an imbalance occurs in the current flowing through the cell stacks. Patent Literature 1 proposes a configuration in which a plurality of cell stacks is classified into a high-temperature region and a low-temperature region in order to suppress such a current imbalance, and cell stacks which are electrically connected by divided current collecting member are connected to each other.
In Patent Literature 1, a plurality of cell stacks is classified so as to correspond to a high-temperature region and a low-temperature region determined on the basis of a temperature distribution, and the cell stacks are electrically connected by divided current collecting members. However, depending on the number of cell stacks connected by each current collecting member, the number of cell stacks in the high-temperature region may be equal to or smaller than the number of cell stacks in the low-temperature region, and the current density in the high-temperature region may be higher than the current density in the low-temperature region. This means that the amount of heat generated in the high-temperature region is larger than the amount of heat generated in the low-temperature region, which acts in the direction of promoting the deviation of the temperature distribution. Therefore, in Patent Literature 1, there is a possibility that the temperature distribution between a plurality of cell stacks, which causes a current imbalance, is not sufficiently equalized.
At least one embodiment of the present invention has been made in view of the above circumstances, and an object thereof is to provide a fuel cell cartridge, a fuel cell module, and a combined cycle power generation system capable of equalizing the temperature distribution between a plurality of cell stacks.
(1) In order to solve the above problems, a fuel cell cartridge according to at least one embodiment of the present invention is fuel cell cartridge including a plurality of cell stacks including a plurality of cells forming a solid oxide fuel cell, wherein the cell stack group including the plurality of cell stacks includes: an inner cell stack group arranged in an inner region of a cell arrangement region in which the plurality of cell stacks is arranged; and an outer cell stack group arranged in an outer region located outside the inner region of the cell arrangement region, the inner cell stack group and the outer cell stack group are connected in series with respect to an external load, and a current density of the outer cell stack group is configured to be higher than a current density of the inner cell stack group.
According to the configuration of (1), the cell stack group including a plurality of cell stacks included in the fuel cell cartridge includes an inner cell stack group and an outer cell stack group arranged outside the inner cell stack. The inner cell stack group and the outer cell stack group are connected in series with respect to the external load, and the current density of the outer cell stack group is configured to be higher than the current density of the inner cell stack group during energization. Therefore, the amount of heat generated in the outer cell stack group is relatively larger than that in the inner cell stack group as compared with the case where the current densities of the inner cell stack group and the outer cell stack group are equal to each other. As a result, it is possible to equalize the temperature distribution between the outer cell stack group in which the heat dissipation amount is larger than the inner cell stack group, and the inner cell stack group in which the heat dissipation amount is smaller than the outer cell stack group.
(2) In some embodiments, in the configuration of (1), the plurality of cell stacks have the same conductive area, and the outer cell stack group includes a smaller number of cell stacks than the inner cell stack group.
According to the configuration of (2), the cell stacks constituting the fuel cell cartridge have the same conductive area. By reducing the number of cell stacks included in the outer cell stack group to be smaller than the number of cell stacks included in the inner cell stack group, when the inner cell stack group and the outer cell stack group are connected in series to the external load during energization, the current density of the outer cell stack group can be configured to be higher than the current density of the inner cell stack group.
(3) In some embodiments, in the configuration of (1) or (2), the cell stacks constituting the inner cell stack group and the cell stacks constituting the outer cell stack group are electrically connected by mutually independent current collecting members.
According to the configuration of (3), the cell stacks constituting the inner cell stack group and the outer cell stack group are electrically connected by independent current collecting members. As a result, the above configuration can be realized with an efficient layout without significantly changing the configuration of the conventional fuel cell cartridge in which a large number of cell stacks are arranged.
(4) In some embodiments, in any one of (1) to (3), the outer cell stack group surrounds an entire circumference of the inner cell stack group.
According to the configuration of (4), since the entire circumference of the inner cell stack group is surrounded by the outer cell stack group, the amount of heat dissipation tends to be smaller and the temperature tends to be higher than that of the outer cell stack group. By setting the current density of the outer cell stack group to be higher than that of the inner cell stack group, the temperature distribution can be equalized.
(5) In some embodiments, in any one of (1) to (3), the outer cell stack group is arranged on both sides of the inner cell stack group.
According to the configuration of (5), by adopting a configuration in which the outer cell stack group is arranged on both sides of the inner cell stack group, the temperature distribution can be equalized even when a plurality of the fuel cell cartridges are arranged and expanded.
(6) In some embodiments, in any one of (1) to (5), the inner cell stack group includes a first inner cell stack group and a second inner cell stack group that adjacent to each other, and the first inner cell stack group and the second inner cell stack group are connected in series.
According to the configuration of (6), the inner cell stack group is further subdivided into a first inner cell stack group and a second inner cell stack group adjacent to each other. By connecting the first inner cell stack group and the inner cell stack group in series with each other, the temperature distribution in the inner cell stack group can be further equalized.
(7) In some embodiments, in any one of (1) to (6), the cell stack has a cylindrical horizontal stripe shape in which a plurality of fuel cells are electrically connected in series.
According to the configuration of (7), the above configuration is suitably applicable to a fuel cell cartridge including a cell stack having a cylindrical horizontal stripe shape.
(8) In some embodiments, in any one of (1) to (6), the cell stack has a flat cylindrical horizontal stripe shape.
According to the configuration of (8), the above configuration is suitably applicable to a fuel cell cartridge including a cell stack having a flat cylindrical horizontal stripe shape.
(9) A fuel cell module according to at least one embodiment of the present invention includes the fuel cell cartridge according to any one of (1) to (8).
According to the configuration (9), a fuel cell module capable of generating electric power more efficiently can be realized by equalizing the temperature distribution in the plurality of cell stacks constituting the fuel cell cartridge.
(10) In order to solve the above problems, a combined cycle power generation system according to at least one embodiment of the present invention includes the fuel cell module according to (9) and a gas turbine or turbocharger that generates rotational power using an exhaust fuel gas and an exhaust oxidized gas exhausted from the fuel cell, in which the fuel cell module is supplied with the oxidized gas compressed using the rotational power, and the plurality of cell stacks generates power using the fuel gas and the oxidized gas.
According to the configuration (10), a combined cycle power generation system capable of generating electric power more efficiently can be realized.
According to at least one embodiment of the present invention, it is possible to provide a fuel cell cartridge, a fuel cell module, and a combined cycle power generation system capable of equalizing the temperature distribution among a plurality of cell stacks.
Embodiments of the present invention will now be described in detail with reference to the accompanying drawings. It is intended, however, that unless particularly specified, dimensions, materials, shapes, relative positions and the like of components described in the embodiments shall be interpreted as illustrative only and not limitative of the scope of the present invention.
The fuel gas supply pipe 207 is provided inside the pressure vessel 205 and is connected to the plurality of fuel gas supply branch pipes 207a as well as a fuel supply system (not illustrated) that supplies a predetermined gas composition and a predetermined flow rate of fuel gas G in accordance with the amount of power generated by the fuel cell module 201. The fuel gas supply pipe 207 branches and guides a predetermined flow rate of fuel gas supplied from the fuel supply system (not illustrated) to the plurality of fuel gas supply branch pipes 207a.
The fuel gas supply branch pipe 207a is connected to the plurality of fuel cells cartridges 203 as well as the fuel gas supply pipe 207. The fuel gas supply branch pipe 207a guides the fuel gas supplied from the fuel gas supply pipe 207 to the plurality of fuel cells cartridges 203 at a substantially equal flow rate, and substantially equalizes the power generation performance of the plurality of fuel cells cartridges 203.
The fuel gas exhaust branch pipe 209a is connected to the fuel gas exhaust pipe 209 as well as the plurality of fuel cells cartridges 203. The fuel gas exhaust branch pipe 209a guides the exhaust fuel gas discharged from the fuel cell cartridge 203 to the fuel gas exhaust pipe 209. The fuel gas exhaust pipe 209 is connected to the plurality of fuel gas exhaust branch pipes 209a, and a portion thereof is arranged inside the pressure vessel 205. The fuel gas exhaust pipe 209 guides the exhaust fuel gas led out from the fuel gas exhaust branch pipe 209a at a substantially equal flow rate to a fuel gas discharge system (not illustrated) outside the pressure vessel 205.
The pressure vessel 205 is operated at an internal pressure of 0.1 MPa to about 1 MPa and an internal temperature is operated at atmospheric temperature to about 550° C., and a material having pressure resistance and corrosion resistance to oxidizing agents such as oxygen included in the oxidized gas is used. For example, a stainless steel material such as SUS304 is suitable.
As illustrated in
In the present embodiment, the fuel cell cartridge 203 has a structure in which the fuel gas supply room 217, the fuel gas discharge room 219, the oxidized gas supply room 221, and the oxidized gas discharge room 223 are arranged as illustrated in
The power generation room 215 is a region formed between the upper heat insulation 227a and the lower heat insulation 227b. The power generation room 215 is a region in which the fuel cells 105 of the cell stack 101 are arranged and the fuel gas and the oxidized gas react electrochemically with each other to generate electric power. The temperature in the vicinity of the central portion of the power generation room 215 in the longitudinal direction of the cell stack 101 is in a high temperature atmosphere of about 700° C. to 1100° C. during a normal operation of the fuel cell module 201.
The fuel gas supply room 217 is a region surrounded by an upper casing 229a and the upper tube plate 225a of the fuel cell cartridge 203. The fuel gas supply room 217 is communicated with the fuel gas supply branch pipe 207a (not illustrated) by a fuel gas supply hole 231a provided in the upper casing 229a. One end of the cell stack 101 is arranged in the fuel gas supply room 217 so that the inside of a substrate tube 103 of the cell stack 101 is open to the fuel gas supply room 217. The fuel gas supply room 217 guides the fuel gas supplied from the fuel gas supply branch pipe 207a (not illustrated) through the fuel gas supply hole 231a to the inside of the substrate tubes 103 of the plurality of cell stacks 101 at a substantially uniform flow rate to substantially equalize the power generation performance of the plurality of cell stacks 101.
The fuel gas discharge room 219 is a region surrounded by a lower casing 229b and the lower tube plate 225b of the fuel cell cartridge 203. The fuel gas discharge room 219 is communicated with the fuel gas exhaust branch pipe 209a (not illustrated) by a fuel gas exhaust hole 231b provided in the lower casing 229b. The other end of the cell stack 101 is arranged in the fuel gas discharge room 219 so that the inside of the substrate tube 103 of the cell stack 101 is open to the fuel gas discharge room 219. The fuel gas discharge room 219 aggregates the exhaust fuel gas that has passed through the inside of the substrate tubes 103 of the plurality of cell stacks 101 and has been supplied to the fuel gas discharge room 219, and guides the aggregated exhaust fuel gas to the fuel gas supply branch pipe 209a (not illustrated) through the fuel gas exhaust hole 231b.
A predetermined gas composition and a predetermined flow rate of oxidized gas is branched into oxidized gas supply branch pipes according to the amount of power generated by the fuel cell module 201 and is supplied to the plurality of fuel cells cartridges 203. The oxidized gas supply room 221 is a region surrounded by the lower casing 229b, the lower tube plate 225b, and the lower heat insulation 227b of the fuel cell cartridge 203. The oxidized gas supply room 221 is communicated with the oxidized gas supply branch pipe (not illustrated) by an oxidized gas supply hole 233a provided in the lower casing 229b. The oxidized gas supply room 221 guides a predetermined flow rate of oxidized gas supplied from the oxidized gas supply branch pipe (not illustrated) through the oxidized gas supply hole 233a to the power generation room 215 through an oxidized gas supply gap 235a described later.
The oxidized gas discharge room 223 is a region surrounded by the upper casing 229a, the upper tube plate 225a, and the upper heat insulation 227a of the fuel cell cartridge 203. The oxidized gas discharge room 223 is communicated with the oxidized gas exhaust branch pipe (not illustrated) by an oxidized gas exhaust hole 233b provided in the upper casing 229a. The oxidized gas discharge room 223 guides the exhaust oxidized gas supplied from the power generation room 215 to the oxidized gas discharge room 223 through the oxidized gas exhaust gap 235b, which will be described later, to an oxidized gas exhaust branch pipe (not illustrated) through the oxidized gas exhaust hole 233b.
The upper tube plate 225a is fixed to a side plate of the upper casing 229a between a top plate of the upper casing 229a and the upper insulation 227a so that the upper tube plate 225a, the top plate of the upper casing 229a, and the upper insulation 227a are substantially parallel to each other. The upper tube plate 225a has a plurality of holes corresponding to the number of cell stacks 101 provided in the fuel cell cartridge 203, and the cell stacks 101 are inserted into the holes, respectively. The upper tube plate 225a airtightly supports one set of ends of the plurality of cell stacks 101 with the aid of either one or both of a sealing member and an adhesive member, and isolates the fuel gas supply room 217 and the oxidized gas discharge room 223 from each other.
The lower tube plate 225b is fixed to a side plate of the lower casing 229b between a bottom plate of the lower casing 229b and the lower insulation 227b so that the lower tube plate 225b, the bottom plate of the lower casing 229b, and the lower heat insulation 227b are substantially parallel to each other. The lower tube plate 225b has a plurality of holes corresponding to the number of cell stacks 101 provided in the fuel cell cartridge 203, and the cell stacks 101 are inserted into the holes, respectively. The lower tube plate 225b airtightly supports the other set of ends of the plurality of cell stacks 101 with the aid of either or both of a sealing member and an adhesive member, and isolates the fuel gas discharge room 219 and the oxidized gas supply room 221 from each other.
The upper heat insulation 227a is arranged at the lower end of the upper casing 229a so that the upper heat insulation 227a, the top plate of the upper casing 229a, and the upper tube plate 225a are substantially parallel to each other, and is fixed to the side plate of the upper casing 229a. The upper heat insulation 227a is provided with a plurality of holes corresponding to the number of cell stacks 101 provided in the fuel cell cartridge 203. The diameter of this hole is set to be larger than the outer diameter of the cell stack 101. The upper heat insulation 227a has an oxidized gas exhaust gap 235b formed between the inner surface of the hole and the outer surface of the cell stack 101 inserted through the upper heat insulation 227a.
The upper heat insulation 227a separates the power generation room 215 and the oxidized gas discharge room 223, and suppresses an increase in the temperature of the atmosphere around the upper tube plate 225a to thereby suppress a decrease in strength and an increase in corrosion due to an oxidizing agent included in the oxidized gas. The upper tube plate 225a and the like are made of a metal material having high temperature durability such as Inconel, and prevents the upper tube plate 225a and the like from being exposed to the high temperature in the power generation room 215 and an increase in the temperature difference from the upper casing 229a to thereby prevent thermal deformation. The upper heat insulation 227a guides the exhaust oxidized gas that has passed through the power generation room 215 and has been exposed to the high temperature to the oxidized gas discharge room 223 through the oxidized gas exhaust gap 235b.
According to the present embodiment, due to the structure of the fuel cell cartridge 203 described above, the fuel gas and the oxidized gas flow in opposite directions inside and outside the cell stack 101. As a result, the exhaust oxidized gas exchanges heat with the fuel gas supplied to the power generation room 215 through the inside of the substrate tube 103, and is cooled to a temperature at which the upper tube plate 224a or the like made of a metal material does not deform due to buckling or the like and the cooled exhaust oxidized gas is supplied to the oxidized gas discharge room 223. The fuel gas is heated by heat exchange with the exhaust oxidized gas discharged from the power generation room 215 and is supplied to the power generation room 215. As a result, the fuel gas preheated to a temperature suitable for power generation without using a heater or the like can be supplied to the power generation room 215.
The lower heat insulation 227b is arranged at the upper end of the lower casing 229b so that the lower heat insulation 227b, the bottom plate of the lower casing 229b, and the lower tube plate 225b are substantially parallel to each other, and is fixed to the side plate of the upper casing 229a. The lower heat insulation 227b is provided with a plurality of holes corresponding to the number of cell stacks 101 provided in the fuel cell cartridge 203. The diameter of this hole is set to be larger than the outer diameter of the cell stack 101. The lower heat insulation 227b has an oxidized gas supply gap 235a formed between the inner surface of the hole and the outer surface of the cell stack 101 inserted through the lower heat insulation 227b.
The lower heat insulation 227b separates the power generation room 215 and the oxidized gas supply room 221, and the suppresses an increase in the temperature of the atmosphere around the lower tube plate 225b to thereby suppress a decrease in strength and an increase in corrosion due to an oxidizing agent included in the oxidized gas. The lower tube plate 225b and the like are made of a metal material having high temperature durability such as Inconel, and prevent the lower tube plate 225b and the like from being exposed to the high temperature and an increase in the temperature difference from the lower casing 229b to thereby prevent deformation. The lower heat insulation 227b guides the oxidized gas supplied to the oxidized gas supply room 233 to the power generation room 215 through the oxidized gas supply gap 235a.
According to the present embodiment, due to the structure of the fuel cell cartridge 203 described above, the fuel gas and the oxidized gas flow in opposite direction inside and outside the cell stack 101. As a result, the exhaust fuel gas that has passed through the power generation room 215 through the inside of the substrate tube 103 exchanges heat with the oxidized gas supplied to the power generation room 215, and is cooled to a temperature at which the lower tube plate 225b or the like made of a metal material that does not deform due to buckling or the like and the cooled exhaust fuel gas is discharged to the fuel gas discharge room 219. The oxidized gas is heated by heat exchange with the exhaust fuel gas and is supplied to the power generation room 215. As a result, the oxidized gas heated to the temperature required for power generation without using a heater or the like can be supplied to the power generation room 215.
The DC power generated in the power generation room 215 is led out to the vicinity of the end of the cell stack 101 by a lead film 115 made of Ni/YSZ or the like provided in the plurality of fuel cells 105, and is then collected by a current collecting mechanism of the fuel cell cartridge 203 and is taken out to the outside of each fuel cell cartridge 203. The pieces of electric power led out to the outside of the fuel cell cartridges 203 by the current collecting mechanism, that is, the pieces of electric power generated by the fuel cell cartridges 203, are connected to a predetermined series number and a predetermined parallel number and are led out to the outside of the fuel cell module 201. After that, the electric power is converted to predetermined AC power by an inverter or the like and supplied to a power load. The details of the current collecting mechanism for collecting DC power will be described later.
Next, a cylindrical cell stack of the present embodiment will be described with reference to
The cell stack 101 has the cylindrical substrate tube 103, the plurality of fuel cells 105 formed on the outer circumferential surface of the substrate tube 103, and an interconnector 107 formed between adjacent fuel cells 105. The fuel cell 105 is formed by stacking an anode 109, an electrolyte 111, and a cathode 113. The cell stack 101 has the lead film 115 electrically connected via the interconnector 107 to the cathode 113 of the single fuel cell 105 closest to the end in the axial direction of the substrate tube 103 among the plurality of single fuel cells 105 formed on the outer circumferential surface of the substrate tube 103.
The substrate tube 103 is made of a porous material and contains, for example, CaO-stabilized ZrO2 (CSZ), Y2O3-stabilized ZrO2 (YSZ), or MgAl2O4. The substrate tube 103 supports the fuel cell 105, the interconnector 107, and the lead film 115, and diffuses the fuel gas supplied to the inner circumferential surface of the substrate tube 103 to the anode 109 formed on the outer circumferential surface of the substrate tube 103 through fine pores of the substrate tube 103.
The anode 109 is formed of an oxide of a composite material of Ni and a zirconia-based electrolyte material, and for example, Ni/YSZ is used. In this case, the anode 109, specifically, Ni, which is a component of the anode 109, has a catalytic action on the fuel gas. This catalytic action is to cause a reaction of the fuel gas supplied through the substrate tube 103 (for example, a mixed gas of methane (CH4) and water vapor) to reform it into hydrogen (H2) and carbon monoxide (CO). The anode 109 causes an electrochemical reaction of hydrogen (H2) and carbon monoxide (CO) obtained by reforming and oxygen ions (O2−) supplied via the electrolyte 111 near the interface with the electrolyte 111 to produce water (H2O) and carbon dioxide (CO2). At this time, the fuel cell 105 generates electric power by the electrons emitted from the oxygen ions.
YSZ, which has airtightness that makes it difficult for gas to pass through and high oxygen ion conductivity at high temperature, is mainly used as the electrolyte 111. The electrolyte 111 allows the oxygen ions (O2−) generated at the cathode to move toward the anode.
The cathode 113 is formed of, for example, LaSrMnO3-based oxide or LaCoO3-based oxide. The cathode 113 dissociates oxygen in an oxidized gas such as the supplied air in the vicinity of the interface with the electrolyte 111 to generate oxygen ions (O2−).
The interconnector 107 is formed of a conductive perovskite-type oxide represented by M1-xLxTiO3 (M is an alkaline earth metal element and L is a lanthanoid element) such as SrTiO3 system, and is a dense film in which the fuel gas and the oxidized gas are not mixed. The interconnector 107 has stable electrical conductivity in both an oxidizing atmosphere and a reducing atmosphere. The interconnector 107 electrically connects the cathode 113 of one fuel cell 105 and the anode 109 of the other fuel cell 105 in adjacent fuel cells 105 to connect the adjacent fuel cells 105 in series.
Since the lead film 115 needs to have electron conductivity and a thermal expansion coefficient close to that of other materials constituting the cell stack 101, the lead film 115 is formed of a composite material of Ni such as Ni/YSZ and a zirconia-based electrolyte material. The lead film 115 leads the DC power generated by the plurality of fuel cells 105 connected in series by the interconnector out to the vicinity of the end of the cell stacks 101.
Next, the current collecting mechanism of the fuel cell cartridge 203 will be described.
The fuel cell cartridge 203 includes a plurality of cylindrical cell stacks 101 constituting the fuel cell (in the present embodiment, the fuel cell cartridge 203 is provided with a total of 56 cell stacks 101). Each cell stack 101 has the cathode 113 (positive electrode) and the anode 109 (negative electrode) as described with reference to
As illustrated in
The fuel cell cartridge 203 includes a current collector plate 11 (first positive electrode current collector), a current collector plate 12 (second positive electrode current collector), a current collector plate 21 (first negative electrode current collector), and a current collector plate 22 (second negative electrode current collector). The current collector plate 11 (first positive electrode current collector) is a conductive plate member that electrically connects the positive electrodes of the outer cell stack groups 101B, and is arranged in the outer region A2. The current collector plate 12 (second positive electrode current collector) is a conductive plate member that electrically connects the positive electrodes of the inner cell stack groups 101A, and is arranged in the inner region A1. The current collector plate 21 (first negative electrode current collector) is a conductive plate member that electrically connects the negative electrodes of the inner cell stack groups 101A, and is arranged in the inner region A1. The current collector plate 22 (second negative electrode current collector) is a conductive plate member that electrically connects the negative electrodes of the outer cell stack groups 101B, and is arranged in the outer region A2.
As illustrated in
The arrows illustrated in the path indicate the circulation direction of the current flowing through the path. In the following drawings, the arrows illustrated in the path indicate the circulation direction of the current flowing through the path.
Here, the cell stacks 101 included in the fuel cell cartridge 203 have the same conductive area, and the outer cell stack group 101B includes a smaller number of cell stacks 101 than the inner cell stack group 101A. Therefore, when the inner cell stack group 101A and the outer cell stack group 101B connected in series to an external load are energized, the current density of the outer cell stack group 101B having a small total conductive area is configured to be higher than the current density of the inner cell stack group 101A having a large total conductive area.
On the other hand, in the present embodiment, as described above, since the current density of the outer cell stack group 101B is configured to be higher than the current density of the inner cell stack group 101A, the amount of heat generated in the outer cell stack group 101B is increased relative to the inner cell stack group 101A. As a result, an equalized temperature distribution T as compared with the comparative example is obtained.
In the present embodiment, as illustrated in
This temperature distribution T is equalized while suppressing the maximum temperature Tmax as compared with the maximum temperature Tmax′ of the comparative example. Therefore, as illustrated as the temperature distribution Ta in
Such a configuration can be constructed by electrically connecting the inner cell stack group 101A and the outer cell stack group 101B by independent current collecting members like the above-mentioned current collector plates (the current collector plate 11 (first positive electrode current collector), the current collector plate 12 (second positive electrode current collector), the current collector plate 21 (first negative electrode current collector), and the current collector plate 22 (second negative electrode current collector)). As a result, the above configuration can be realized with an efficient layout without significantly changing the configuration of the conventional fuel cell cartridge in which a large number of cell stacks are arranged.
A path in which current is circulated in the fuel cell cartridge 203 is a parallel combination of two paths, one path illustrated on the left side of
Even when the outer cell stack group 101B is divided and provided on both sides of the inner cell stack group 101A in this way, the temperature distribution can be equalized effectively by setting the current density of the outer cell stack group 101B to be higher than that of the inner cell stack group 101A.
When the plurality of fuel cells cartridges 203 are expanded and arranged, since the contact surface between adjacent fuel cell cartridges 203 is close to a heat insulating state and a temperature gradient is unlikely to occur, there is little need for equalizing the temperature distribution. In such a case, as illustrated in
The outer cell stack groups 101B1 and 101B2 arranged on both sides of the inner cell stack group 101A may include the same number of cell stacks 101, but different numbers of cell stacks 101 may be included in consideration of the balance of the temperature distribution.
As illustrated in
As described above, in the second modification, the temperature distribution can be equalized by further subdividing the inner cell stack group 101A and changing the number of cell stacks included in each cell stack group to perform finer temperature adjustment as compared with the first modification. In this case, as in
In the above-described embodiment, the case where the fuel cell cartridge 203 has the cylindrical cell stack 101 has been described, but the cell stack 101 included in the fuel cell cartridge 203 may have another type.
In such a fuel cell cartridge 303, the inner region A1 and the outer region A2 are defined, and a plurality of cell stacks 101 is classified into an inner cell stack group 101A located in the inner region A1 and an outer cell stack group 101B located in the outer region A2. The inner cell stack group 101A and the outer cell stack group 101B are connected in series to an external load (not illustrated) via a predetermined current collecting system.
Here, the cell stacks 101 included in the fuel cell cartridge 303 have the same conductive area, and the outer cell stack group 101B includes a smaller number of the cell stacks 101 than the inner cell stack group 101A. Therefore, when the inner cell stack group 101A and the outer cell stack group 101B connected in series to the external load are energized, the current density of the outer cell stack group 101B having a small total conductive area is configured to be higher than the current density of the inner cell stack group 101A having a large total conductive area. By setting the current density of the outer cell stack group 101B to be higher than that of the inner cell stack group 101A in this way, the temperature distribution can be effectively equalized.
As described above, according to the above embodiment, since the current density of the outer cell stack is set to be higher than the current density of the inner cell stack, the temperature distribution can be equalized between the outer cell stack having a larger heat dissipation amount than the inner cell stack and the inner cell stack having a smaller heat dissipation amount than the outer cell stack.
The fuel cell module 201 may be applied to a combined cycle power generation system used in combination with a GTCC (gas turbine combined cycle power generation), an MGT (micro gas turbine), or a turbocharger. In such a combined cycle power generation system, exhaust fuel gas and exhaust oxidized gas discharged from the SOFC module are supplied to a combustor (not illustrated) of a gas turbine to generate high-temperature combustion gas, and this combustion gas is adiabatically expanded by the gas turbine to generate rotational power. The compressor is driven with the rotational power and compressed gas is supplied to an oxidized gas supply main pipe 21 of the fuel cell module 10 as oxidized gas. The oxidized gas is a gas containing approximately 15% to 30% of oxygen, and air is typically preferable. However, in addition to air, a mixed gas of combustion exhaust gas and air or a mixed gas of oxygen and air can be used.
At least one embodiment of the present invention can be used for fuel cell cartridges, fuel cell modules, and combined cycle power generation systems of solid oxide fuel cells.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2019-033433 | Feb 2019 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2020/005963 | 2/17/2020 | WO | 00 |
