The present invention relates to a fuel cell device applicable to electronic devices, including a charger, using a fuel cell, for example, a direct methanol fuel cell.
Fuel cells can be classified into various types depending on the type of electrolyte and the like. One known typical fuel cell is a polymer electrolyte fuel cell (PEFC) using a solid polymer electrolyte as electrolyte. The polymer electrolyte fuel cell is suitable for a power supply for driving an electronic device because it can be produced at a lower cost, can be easily smaller, thinner and lighter, and can provide high output density in terms of cell performance. For the polymer electrolyte fuel cell, in addition to a type using hydrogen as fuel, another type has been developed which modifies methanol or natural gas to generate hydrogen to be used as fuel. In recent years, a direct methanol fuel cell (DMFC) has been developed in which methanol as fuel is directly supplied to a fuel cell to generate electricity.
In the direct methanol fuel cell, a membrane and electrode assembly (MEA) into which an electrolyte membrane and a pair of electrodes are integrated and a flat plate-shaped separator having a fuel channel in one surface and an oxidant gas channel in the other surface are alternately stacked on a base plate. Supplying methanol-water solution to the fuel channel and air to the oxidant gas channel causes a power generation reaction on the electrolyte membrane. In the direct methanol fuel cell, water and carbon dioxide are produced as a product and discharged.
An active (forced intake-type) fuel cell in which fuel is supplied to a fuel cell and product of power generation (water, carbon dioxide) is discharged using an auxiliary, such as a pump, has been proposed, and a passive (open-type) fuel cell in which methanol-water solution, air and the like spread naturally and no auxiliary is used has been proposed. Previously, a fuel cell used as a charging cradle for mobile phone has been described in Japanese Patent No. 4005608.
As for a charger, with the widespread use of mobile devices, including mobile phones, notebook computers, portable audio/video devices and mobile terminals, a charger capable of charging secondary cells of a plurality of mobile devices is required. For example, a USB charger having a universal serial bus (USB) terminal may satisfy such a requirement.
As a fuel cell, a thin fuel cell unit has been proposed having a structure in which a plurality of unit cells (fuel cells) are arranged in a plane on a thermoplastic resin sheet and connected in series. For a thin fuel cell, for example, a direct methanol fuel cell, methanol-water solution as fuel is supplied from a fuel cartridge to a fuel electrode (hereinafter referred to as anode electrode). Oxygen (air) is supplied from an opening of an outer housing to an air electrode (hereinafter referred to as cathode electrode). A problem exists that the amount of fuel remaining in the fuel cartridge is not immediately obvious.
In view of the above, it is an object of the present invention to provide a fuel cell device that can obviously indicate the amount of fuel remaining in the fuel cartridge.
In order to solve the above-described problem, the invention is a fuel cell device including:
a housing forming a fuel cell containing space for containing a fuel cell;
a fuel cartridge attachable to and detachable from the housing; and
a light emitting device, placed in the housing, for generating light to illuminate the fuel cartridge.
The fuel cell includes: an anode electrode to which fuel is supplied; a cathode electrode to which air is supplied; a membrane and electrode assembly sandwiched between the anode electrode and the cathode electrode; and an anode plate-shaped member stacked on the anode electrode.
The fuel cell device further includes a secondary cell to be charged by the fuel cell.
The fuel cell device further includes a terminal part, provided in the housing, for extracting power from the fuel cell. The terminal part is a USB port.
The invention is a fuel cell device including:
a cabinet to which a speaker unit is attached;
a supporting part for supporting the cabinet;
a base to which the supporting part is attached;
a fuel cell placed between the cabinet and the base and a fuel container for storing fuel for the fuel cell;
a circuit part contained in the base; and
a wireless receiver for generating input signal for the speaker unit.
A secondary cell is contained in the base.
According to the invention, the light emitting device in the housing illuminates the fuel cartridge. This can facilitate checking of the amount of fuel remaining in the fuel cartridge.
Now, embodiments of the invention are described. The description is performed in the following order.
1. First Embodiment
2. Assembly Process
3. Second Embodiment
4. Variation Example
Note that, although the embodiments described below are specific preferable examples of the invention with various limitations for technical convenience, the scope of the invention is not intended to be limited to these embodiments unless otherwise stated to limit the invention in the following description.
The USB charger 100 includes a USB port 101. A USB device 103 is connected to the USB port 101 via a USB plug 102a, a USB cable 102b and a USB plug 102c. Note that the invention is applicable to any of USB 1.1, USB 2.0 and USB 3.0 standards.
A DC power supply generated by the charger 100 is provided to the USB device 103. The USB device 103 includes a secondary cell, for example, a lithium ion secondary cell, that is charged by the power of the charger 100. Note that, in an example described later, the USB charger 100 includes two USB ports.
The lithium ion secondary cell in the USB device 103 is charged using a CC-CV (constant-current constant-voltage) charging method that is a combination of constant-current charging and constant-voltage charging. For example, when the cell voltage is equal to or less than a set voltage (e.g., 4.2 V), constant-current charging control is performed to perform constant-current charging by a constant current (e.g., 0.5 A per USB port). When the cell voltage (internal electromotive force) is increased by the charging and reaches 4.2 V, the operation is switched to constant-voltage charging control and charging current is gradually decreased. Then, when the charging current reaching a set charging-completion detection value is detected, charging completion is detected.
Such a charging control is performed by a charging control circuit in the USB device 103. The USB charger 100 outputs an output voltage of 5 V from the USB port 101, and the output current is gradually decreased from e.g., 0.5 A as charging progresses.
As shown in
The USB port 101 includes data pins 107a and 107b in addition to the power supply pins. A microcomputer as a controller may be provided in the USB charger 100 to detect whether a device is connected or not, using the data pins 107a and 107b, and to perform communication with the device for authentication.
The DC-DC converter 105 converts the voltage input from the fuel cell V1 to around 5 V approximately equal to the voltage of the secondary cell V2. For example, the fuel cell of the USB charger 100 generates a constant power of 2.5 W. When a little or no load current flows as in the end stage of charging, current is supplied from the fuel cell V1 to a load, and charging current is supplied to the secondary cell V2 by excess power of the fuel cell V1. At the start of the power generation operation of the fuel cell or when load current is momentarily large, the secondary cell V2 outputs power to cover a deficit. Thus, a hybrid configuration of a fuel cell and a secondary cell can respond to a rapid increase in load current, thereby eliminating the need for a larger power supply unit.
Appearance of First Example of USB Charger
As shown in
The housing 1 is made of a metal and contains a fuel cell, a lithium ion secondary cell, a wiring board on which a control circuit and the like are mounted, a light-emitting diode and the like as described later. The bottom surface of the housing 1 is covered with a bottom plate 4. A plurality of air-intake holes 5 are formed in the bottom plate 4 to supply air to the fuel cell. Furthermore, legs 11a, 11b and 11c made of a synthetic resin are provided in order to form a space for air intake under the bottom plate 4.
Two USB ports 6a and 6b are provided in the periphery of the housing 1. Manual switches 7a and 7b are provided near the USB ports 6a and 6b, respectively. Furthermore, a light-emitting diode (LED) 8 and a communication connector 9 are provided on the rear surface of the housing 1. The LED 8 is lit in, for example, green when the fuel cell is in operation, and is lit in, for example, orange when the fuel cell is outputting power. The manual switches 7a and 7b are push button switches for switching whether or not to output power from the USB ports 6a and 6b, respectively. For example, pushing the manual switch 7a causes the power source to output power from the USB port 6a and the LED 8 to be lit in orange. The communication connector 9 is for test purpose.
A plurality of air-discharge holes 10 are formed in the upper portion of the periphery of the housing 1. In
Now, the structure of the housing 1 and the components contained in the housing 1 are described in more detail with reference to
As shown in
As shown in
An attachment mechanism for attaching/detaching the fuel cartridge 2 is provided in the upper portion of the housing 1. On the underside of the attachment mechanism, an LED/switch board on which components related to the LEDs and switches are mounted is placed. A needle for drawing fuel from the fuel cartridge protrudes in the attachment mechanism. In order to supply fuel to the fuel cell, a fuel pump is used.
As shown in
As shown in
A lithium ion secondary cell 121 is attached to the LED/switch board with, for example, a double-stick tape. As shown in
The fuel cell attached to the chassis 132 has a structure shown in
Furthermore, a fuel pump 145 for supplying fuel to the anode electrode is provided with a packing 146 in between. The fuel pump 145, which is, for example, a micropump using a piezoelectric device, supplies fuel to the power generation part 141. For the collector of the cathode plate 142, a perforated metal or mesh made of stainless steel, aluminum or the like is used.
The power generation part 141, packing 146 and fuel pump 145 are stacked and contained in a frame 147. Furthermore, a frame 148 and screws secure the stack. The frame 148 includes attachment tabs 149a, 149b, 149c and 149d at the corners. The frame 147 also includes attachment tabs at positions similar to those of the frame 148. In these tabs, holes through which screws are screwed are formed. Furthermore, a fuel receiver 150 is formed on the fuel pump 145.
As shown in
Thus, when the fuel cell has been attached, the end 112 of the fuel supply tube 111 is connected to the fuel receiver 150 of the fuel pump 145. Furthermore, a wiring harness is connected.
As shown in
Heat Transfer
In the first embodiment of the invention described above, the power generation part 141 is heated up to about 45 C-50 C during power generation operation. The power generation part 141 is secured to the fixed axles 136a-136d with the frames in between. The fixed axles 136a-136d are formed integrated with the housing 1. Thus, the heat of the power generation part 141 is transferred to the housing 1 through the fixed axles 136a-136d. The fixed axles 136a-136d are made of a material having a good heat transferability, such as aluminum.
The heat transferred to the housing 1 heats the air in the space within the housing 1 to cause upward air flow. The heated air is discharged to the outside through the air-discharge holes 10 formed in the upper portion of the housing 1. The upward air flow increases the amount of air taken in through the air-intake holes 5 formed in the bottom plate 4 of the housing 1. The amount of air (oxygen) taken into the power generation part 141 also increases. This can increase the output of the power generation part 141. Furthermore, advantageously, this invention does not use an air intake fan, which does not increase power consumption. Furthermore, discharging the air in the housing 1 to the outside, which can provide heat dissipation effect.
Appearance of Second Example of USB Charger
A second example of the USB charger to which the invention is applied is shown in
Similarly to the above-described first example (see
Appearance of Third Example of USB Charger
A third example of the USB charger to which the invention is applied is shown in
The third example has a portable configuration, whereas the first and second examples have a fixed (stationary) configuration. A power generation part, secondary cell, board and the like are stacked in the housing 1 in the thickness direction of the housing 1. The power generation part is attached in parallel with the front face of the housing 1, and air is supplied to a cathode plate through the air-intake holes 12. An attachment mechanism 13 for attaching a hand carry strap is provided on one side surface of the housing 1. A cartridge lock operation key 14 for locking/unlocking the attachment of the fuel cartridge 2 is provided on the rear surface of the housing 1.
A USB port 6, manual switch 7, LED 8 and communication connector 9 are provided in one side surface of the housing 1. The LED 8 is lit in, for example, green when the fuel cell is in operation, and is lit in, for example, orange when the fuel cell is outputting power. The manual switches 7 is a push button switch for switching whether or not to output power from the USB port 6. The communication connector is for test purpose. Light from an LED provided in the housing 1 works as an illumination for the fuel cartridge 2, which can facilitate checking of the fluid level of the fuel cartridge 2, thus, checking the amount of remaining fuel.
Appearance of Fourth Example of USB Charger
A fourth example of the USB charger to which the invention is applied and which is portable is shown in
In the fourth example, similarly to the third example (see
Appearance of Fifth Example of USB Charger
A fifth example of the USB charger to which the invention is applied and which is portable is shown in
In the fifth example, similarly to the third example (see
Appearance of Sixth Example of USB Charger
A sixth example of the USB charger to which the invention is applied and which is portable is shown in
In the sixth example, similarly to the third example (see
Appearance of Seventh Example of USB Charger
A seventh example of the USB charger to which the invention is applied and which is portable is shown in
In the seventh example, similarly to the third example (see
Appearance of Eighth Example of USB Charger
A eighth example of the USB charger to which the invention is applied and which is portable is shown in
In the eighth example, similarly to the third example (see
Appearance of Ninth Example of USB Charger
A ninth example of the USB charger to which the invention is applied is shown in
In the ninth example, similarly to the third example (see
A second embodiment of the invention are described.
For example, a full-range speaker unit 18 is attached to a cabinet 19. The cabinet 19 is supported by a base 21 with a leg 20 in between. The thickness of the leg 20 is smaller than the depth of the cabinet 19. This forms a space to contain a fuel cartridge 2 in the lower portion of the cabinet 19. The fuel cartridge 2 is cylindrical-shaped. An LED illuminates the fuel cartridge 2 from the bottom, top or side surface of the fuel cartridge 2.
Furthermore, between the top surface of the fuel cartridge 2 and the bottom surface of the cabinet 19, two shelves 22a and 22b for containing a fuel cell protrude forward from the leg 20 at a right angle. Each shelf contains a power generation part of the fuel cell. For example, one shelf contains two power generation parts 141 (see
The base 21 contains a plurality of lithium ion secondary cells. Furthermore, a signal processing board on which a signal processor for generating drive signal for the speaker unit 18 is mounted is placed in the base 21. A plurality of LEDs 23 for indicating the operation state are placed on the front surface of the base 21. A communication connector 24 used for operation check or the like is provided in the right side surface of the base 21. A power-on switch 25 is provided on the left side surface of the base 21.
A step-like portion is formed on the rear side of the cabinet 19, on which a receiving antenna 26 is provided. The receiving antenna 26 receives audio playback signal from an audio signal playback apparatus not shown. The audio signal can be wirelessly transmitted using an existing method, such as FM transmission, millimeter-wave band transmission or the like. Signal received by the receiving antenna 26 is amplified by the signal processor in the base 21 and supplied to the speaker unit.
As described above, containing the lithium ion secondary cells and the signal processing board in the base 21 and placing the fuel cell at a higher level can lower the center of gravity and can prevent heat generated by the fuel cell from affecting the signal processing board. Furthermore, the fuel cartridge can be seen while music is playbacked by the speaker, facilitating checking of the amount of remaining fuel. The speaker according to the invention can be configured to be wireless to eliminate the need for a cable in any of power supplying and signal supplying.
The invention is not intended to be limited to the above-described embodiments, and various changes may be made based on the technical spirit of the invention.
Number | Date | Country | Kind |
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2009-038800 | Feb 2009 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2010/052003 | 2/4/2010 | WO | 00 | 8/17/2011 |