Fuel cell fluid distribution system

Abstract
The dominant fuel cell design is based on using separator plates with flow fields to distribute the reaction gases parallel to the membrane. In our invention the solid electrolyte membrane fuel cell has a multitude of conduits that penetrate the catalyst coated membranes and the porous gas diffusion layers in a perpendicular direction, each conduit separated by an active area. The conduits are distributed in a repeatable parallelogram unit to create a two dimensional pattern. The conduits have appropriately positioned integrated gaskets to provide reactant gases to the anode (fuel) or cathode (oxidant) and to ensure that the anode fuel is prevented from entering the cathode side of the membrane and vice-versa. A separate conduit (in/out) for the water cooling can be added or the water cooling can be integrated to the air exhaust or the hydrogen exhaust to extract the heat from the electrochemical reaction and the reaction water.
Description

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS


FIG. 1, the single cell schematic drawing illustrates the basic concept. The air in, air out, hydrogen in, hydrogen out and water thru feed conduits are indicated. The separator plate (1), in-situ seals (4) and edge seals (3) are illustrated. The cross-section 2-2 is reproduced in FIG. 2.



FIG. 2, the cross-section 2-2 of the single cell to illustrate the main components. In the center is the proton exchange membrane (7) sandwiched between anode (6) and cathode (8) catalyzed layers referred to as a CCM (catalyst coated membrane) (6+7+8). Facing the anode and cathode are the gas diffusion layers (GDL) (5) also known as gas diffusion media or porous gas diffusion media. The function of the GDL is to distribute the reaction gases uniformly over the active area of the membrane and to extract the water and heat from the electrochemical reaction. In this invention, the feed conduits (air in and hydrogen in this illustration) are perpendicular to the CCM and the two GDLsThis assembly is referred to as the MEA (membrane electrode assembly). A separator plate (1), also referred to as bipolar plate (sheet, foil), is inserted to separate each cell. The GDL must have seals (4) to prevent mixing of the reaction gases. In our invention the seals are produced in situ, thus ensuring the necessary gas tightness and simplifying the assembly. The edges are sealed (3) in the same way.



FIG. 3 is a basic fuel cell stack assembly schematic illustration. Multiple cells (9) are combined by stacking, interconnecting individual cells in electrical series. Current collectors (10) are inserted between the stack and the fluid distribution manifolds (11). The bottom end plate (12) is illustrated, the top end plate (13) is partly shown and the necessary connecting rods or other assembly methods to maintain the pressure on the stack are not included in the schematic.



FIG. 4, the basic functionality of the fluid distribution—manifold (11) is illustrated with the bottom end plate (12); (air in, air out, hydrogen in, cooling water in and hydrogen out combined with water out). This basic unit can be modified; geometry, size, spacing and spatial arrangements are variables that can be selected over a wide range of values. This basic unit is for illustrative purpose only, it could be vastly different in size and ratio length/width.



FIG. 5 is representative of a different design where the distribution manifolds and end plates are integrated into a single component. The multiple cells (9) are combined by stacking, interconnecting individual cells in electrical series. The current collectors (10) are inserted between the stack and distribution manifold/end plate integrated component inlet (14) outlet (15). The inlet (14) is an assembly of four plates, namely; a perforated distribution plate with three types of feed conduits that is one type for air, one type for hydrogen and one type for water (14-1), a manifold to feed the hydrogen in the designated conduits (14-2), a separator plate between the hydrogen manifold and the other manifolds, (14-3), and an inlet fluid distribution (14-4) described in FIG. 6. The outlet (15) is an assembly of outlet manifolds for air, hydrogen and water combined (15-2) and a perforated distribution plate (15-1). This design is simpler, lighter and more rigid than the design illustrated in FIGS. 3 and 4.



FIG. 6 is an illustration of the modular end plate with flow distribution (14-4). The face plate (14-4-1) is the connecting plate (interface) for the water-in, air-in and hydrogen-in. The separator plate (14-4-2) is the distribution manifold for water in and hydrogen in, (14-4-3) is a separator plate and allows all fluids thru (water, air, hydrogen). The separator (14-4-4) is the distribution manifold for air in. The last plate of the combination distribution manifolds/end plate is (14-4-5) which seals the manifold.



FIG. 7 is an exploded view of the design illustrated in FIG. 5. A multitude of single cell (9) connected in series with a plurality of conduits with integrated gaskets (seals), the current collectors (10), the flow distribution and end plates combination inlet (14) and outlet (15). The details of the combination fluid distribution manifolds/end plate have been given in FIG. 5 and FIG. 6.





DETAILED DESCRIPTION OF THE INVENTION

In situ seals


One example of a process to make the in situ seals is given as representative of a wide range of alternatives. The catalyst coated membrane and the gas diffusion layers can either be pre-assembled by pressing under a specified set of temperature, time and pressure or the catalyst coated membrane and the gas diffusion layers are handled separately. The conduit's geometry, size and spacing are all variables that can be selected. The choice is determined to some degree by the application, the operating parameters and the auxiliary equipments. The gas diffusion layers are then precisely perforated to match the seal's location. The appropriate sealing material is prepared and injected in the openings (perforations in the GDL) and cured. The gasket material is selected for the compatibility with the membrane and the catalysts and to have the required mechanical, thermal, electrical and viscous properties to provide an adequate seal in reference to gas tightness, mechanical strength durability and reliability. The edge seals can also be done by a number of alternatives. Once the integrated gaskets are formed the assembly CCM+GDL+ separator plates are perforated. The individual cells with the plurality of conduits are then ready for assembly. Again numerous alternatives are possible to align and compress the stack of cells. Current collectors are positioned at each extremity and the manifold—end plate combination completes the stack assembly. Pressure is applied and maintained by mechanical means. Two examples are described as illustrative of the many possibilities can be proposed by a person skilled in the art.


EXAMPLE 1


FIG. 3 and FIG. 4 illustrate a stack assembly with a basic concept of the fluid distribution.


Once the membrane and the porous gas diffusion media have been selected, in the present case Nafion™ membrane and GDL from SGL Carbon Group, the catalyst coated membrane (membrane plus platinum) and the porous gas diffusion media are pressed together according to the recommendation of the manufacturers regarding temperature, pressure and time. The geometry, size and number of conduits are selected based on the operating conditions and the required power per cell and total power. The first step is then to prepare the assembly CCM-GDL for the integrated gaskets on the anode and cathode side of the membrane and to mold the gaskets. The final step prior to assembly is to pierce the gaskets and membrane.


The assembled individual cells are then stacked inserting a separator/bipolar plate between each cell. Current collectors (10) complete the stack, the fluid distribution manifold (11) is then added and finally the end plates (12, 13) and tie-rods (missing from the figure) compress the stack. Fittings for oxygen/air, hydrogen, and water are then attached to the manifold and the stack is ready to be put in operation.


EXAMPLE 2


FIGS. 5, 6 and 7 illustrate a variant of the basic concept. The significant modifications are in the fluid manifold and end plates design.


FIG. 5—The catalyst coated membrane and the porous gas diffusion media, in the present case Ion-Power CCM with Nafion™ membrane, and SGL 34BC GDL, are pressed together according to the recommendation of the manufacturers regarding temperature, pressure and time. The geometry, size and number of conduits are selected based on the operating conditions and the required power per cell and total power. The assembly CCM-GDL is prepared by mechanically making the openings in the GDL for the integrated gaskets on the anode and cathode side of the membrane. A silicone based product with an inert carbon base additive is injected and the gaskets are cured. The final step prior to assembly is to pierce the gaskets together with the CCM and the GDL on the opposite side.


The assembled individual cells (9) are then stacked. Current collectors (10) complete the stack. In this example the combination fluid distribution manifold and end plates (14) are added and the system is compressed by elastic wrapping around the stack, not shown in the figure. Fittings for oxygen/air, hydrogen and water are then attached to the manifold and the stack is ready to be put in operation.


FIG. 6—An exploded view of the combination end plate (structural function) and manifold (fluid distribution) (14-4). This design and variants on the same idea have several advantages over the basic intuitive concept of Example 1:

    • Combine two functions—structural and fluid distribution
    • Lighter than the design with separate components
    • Easier to fabricate and lower cost of the manifold
    • More flexibility in the design
    • More uniform distribution of the fluids


FIG. 7—An illustration of the several components for this example. The number of conduits, 48, is totally arbitrary and only illustrative of the concept of plurality of conduits. The illustrated conduits pattern is a rectangular matrix; however one can easily use other geometries. In this example three separate conduits are used for the inlet and two for the outlet, therefore the cooling conduits must be either combined with the air or hydrogen exhaust, in the illustration air and water are combined.


The core of the fuel cell is the catalyst coated electrolyte membrane (6+7+8), sandwiched between the cathode GDL (5) and the anode GDL (5). Each cathode and anode has integrated gaskets; on cathode side (4) and on anode side (4). These integrated gaskets ensure that the anode fuel is prevented from entering the cathode side of the membrane and the air prevented from entering the anode side. The water cooling conduits in this example are combined with the air exhaust conduits which is also the exhaust for the reaction water. The first and the last cell are connected in series with the current collectors (10). The distributor plates (14-1, 14-2, and 14-3) are inserted between the current collector (10) and the fluid manifold (14-4).

Claims
  • 1. A solid electrolyte membrane fuel cell comprising a plurality of conduits that penetrate the catalyst coated membrane and the porous gas diffusion layers in a perpendicular direction to the catalyst coated membrane plane, the conduits have appropriately positioned integrated gaskets to provide reactant gases to the anode or cathode and to ensure that the anode fuel is prevented from entering the cathode side of the membrane and vice-versa, a water cooling path to extract the heat from the electrochemical reaction, each conduit is fully separated from each other by an active area of the solid electrolyte membrane.
  • 2. The fuel cell of claim 1 wherein the conduits are located so the fuel (hydrogen or hydrogen rich mixture) is distributed in a radial direction in the porous gas diffusion layers from fuel inlet conduits to fuel outlet conduits.
  • 3. The fuel cell of claim 1 wherein the conduits are located so the oxidant (oxygen/air) is distributed in a radial direction in the porous gas diffusion layers from oxidant inlet conduits to oxidant outlet conduits.
  • 4. The fuel cell of claim 1 wherein the conduits are located so the electrochemical reaction by-product water is removed in a radial direction in the porous gas diffusion layers from air/oxygen inlet conduits to air/oxygen outlet conduits.
  • 5. The fuel cell of claim 1 wherein the conduits are located so the oxidant exhaust and cooling fluid are combined in outlet conduits.
  • 6. The fuel cell of claim 1 wherein the conduits are located so the fuel exhaust and cooling fluid are combined in outlet conduits.
  • 7. The fuel cell of claim 1 wherein the gaskets fully isolate the anode flow from the cathode flow; the gaskets are fabricated in situ with a material compatible with the membrane and the catalyst coated layer.
  • 8. The gasket material in claim 1 consisting of silicone based elastomers.
  • 9. The gasket material in claim 1 consisting of silicone based elastomers with inert additives.
  • 10. The gasket material in claim 1 consisting of polyurethane elastomers.
  • 11. The gasket material in claim 1 consisting of polyurethane elastomers with inert additives.
  • 12. The gasket material in claim 1 consisting of thermoset elastomers.
  • 13. The gasket material in claim 1 consisting of thermoset elastomers with inert additives.
  • 14. The inert additives in claim 9 wherein the additives are carbon based.
  • 15. The inert additives in claim 9 wherein the additives are silicon dioxide based.
  • 16. The inert additives in claim 9 wherein the additives are aluminum oxide based.
  • 17. The inert additives in claim 9 wherein the additives are ceramic based.
  • 18. The inert additives in claim 11 wherein the additives are carbon based.
  • 19. The inert additives in claim 111 wherein the additives are silicon dioxide based.
  • 20. The inert additives in claim 11 wherein the additives are aluminum oxide based.
  • 21. The inert additives in claim 11 wherein the additives are ceramic based.
  • 22. The inert additives in claim 13 wherein the additives are carbon based.
  • 23. The inert additives in claim 13 wherein the additives are silicon dioxide based.
  • 24. The inert additives in claim 13 wherein the additives are aluminum oxide based.
  • 25. The inert additives in claim 13 wherein the additives are ceramic based.
  • 26. The porous gas diffusion layers in claim 1 wherein the gas diffusion layer porosity is between 60 and 90 percent.
  • 27. The porous gas diffusion layers in claim 1 wherein the gas diffusion layer average pore size is between 5 and 50 microns.
  • 28. The porous gas diffusion layers in claim 1 wherein the gas diffusion layer thickness is between 50 and 500 microns.
  • 29. The catalyst coated membrane in claim 1 wherein the membrane is perfluorosulfonic acid polymer based.
  • 30. The catalyst coated membrane in claim 1 wherein the membrane is a poly-benzimidazole (PBI) temperature resistant polymer.
  • 31. The catalyst coated membrane in claim 1 wherein the membrane is an engineered hydrocarbon membrane.
  • 32. The catalyst coated membrane in claim 1 wherein the membrane is a sulfonated poly ether ketone (SPEEK).
  • 33. The conduits in claim 1 wherein the conduit geometry provide uniform distribution of the reactants.
  • 34. The conduits in claim 1 wherein the size is between about 1 to 5 mm.
  • 35. The conduits in claim 1 wherein the conduits are distributed in a repeatable parallelogram unit to create a two dimensional pattern.
  • 36. The conduits in claim 1 wherein the combined cross-sectional area of the conduits total between about 10 and 50 percent of the total active area of the fuel cells.
  • 37. The porous gas diffusion layers in claim 1 wherein the material is hydrophobic.
  • 38. The porous gas diffusion layers in claim 1 wherein the material has hydrophobic region in contact with the catalyst coated membrane and has hydrophilic region in contact with the separator plates.
  • 39. A fuel cell stack of two or more fuel cells connected in series, the stack comprising a plurality of fuel cells, a plurality of separator plates between each fuel cell with openings matching the conduits in the individual fuel cells, two fluid distribution manifolds with fluid flows that register with the openings in the separator plates and the conduits in the fuel cells, said fluid distribution manifolds having external ports for the fluids inlets and outlets, two current collectors, two end plates disposed on opposing sides of the said plurality of fuel cells to maintain the stack under compression.
  • 40. The fluid distribution manifold function and end plate mechanical function in claim 39 wherein these two functions are accomplished by separate components.
  • 41. The fluid distribution manifold function and end plate mechanical function in claim 39 wherein these two functions are combined in an integrated component.
  • 42. The separator plates and the bipolar plates in claim 39 wherein the material is both a good electrical conductor to connect electrically the individual cells and a good thermal conductor to extract the heat of reaction in mostly radial direction toward the cooling water circulation conduits.
  • 43. The separator plates material in claim 39 wherein the material is; graphite, flexible graphite, expanded graphite, electrically conductive composites, coated metallic, uncoated metallic.