Aspects of the present disclosure relate generally to a fuel cell stack assembly and a method of operating the same.
U.S. application Ser. No. 11/656,563, filed on Jan. 23, 2007 and published as US published application 2007/0196704 A1 and incorporated herein by reference in its entirety, describes a fuel cell system in which the solid oxide fuel cell (SOFC) stacks are located on a base, as shown in
In this prior art system, the SOFC stacks maintain a compressive load. The compressive load is maintained by upper pressure plate 230, tie rods 222, lower pressure plate 90 and a compression spring assembly located below the lower pressure plate 90. The compression spring assembly applies a load directly to the lower pressure plate 90 and to the upper pressure plate 230 via the tie rods 222. The bores or feed-throughs 224 through the baffles 220 act as heat sinks and thereby decrease the system efficiency.
In an alternative embodiment, the load is transmitted through the base 239 as this is the only zero datum of the system. Penetrations or feed-throughs through the base 239 are used in order to pull the required load from the base 239.
According to various embodiments, provided is a fuel cell stack assembly comprising: a fuel cell stack column; and side baffles disposed on opposing sides of the column. The side baffles have a first coefficient of thermal expansion (CTE) at room temperature, the column has a second CTE at room temperature, and the first CTE is within +/−20%, such as within +/−10% of the second CTE.
According to various embodiments, provided is a fuel cell stack assembly comprising: a fuel cell stack column; and side baffles disposed on opposing sides of the column. The side baffles may comprise first and second baffle plates that are laminated to one another and comprise different ceramic materials.
According to various embodiments, provided is a fuel cell stack assembly comprising: a fuel cell stack column; and side baffles disposed on opposing sides of the column. The side baffles may comprise first, second, and third baffle plates that are laminated to one another, with the second baffle plate being disposed between the first and third baffle plates. At least one of the second baffle plates comprises channels that extend in a direction perpendicular to a stacking direction of fuel cells of the column.
According to various embodiments a fuel cell stack assembly comprising: a fuel cell stack column; an upper block disposed on a first end of the column; a lower block having a laminate structure and disposed on an opposing second end of the column; and side baffles disposed on opposing sides of the column and connected to the compression assembly and the lower block. The lower block may comprise: an inlet manifold extending there through and connected to an inlet of the column; and an outlet manifold extending there through and connected to an outlet of the column.
According to various embodiments, provided is a method of operating a fuel cell stack assembly comprising a fuel cell stack column, side baffles disposed on opposing sides of the column, and at least one channel extending through one of the side baffles, the method comprising at least one of: flowing air through the at least one channel to cool the column; flowing fuel through the at least one channel to the column; electrically bypassing at least one fuel cell of the column using a bypass electrodes disposed in a plurality of the channels which include the at least one channel; and detecting a characteristic of the column using a sensor or electrical lead disposed in at least one channel.
According to various embodiments, provided is a fuel cell stack assembly comprising: a fuel cell stack column; a compression assembly configured to apply pressure to the column; and an upper plate assembly upon which the compression assembly is disposed. The upper plate assembly comprises: a rod plate upon which the compression assembly is disposed; a termination plate disposed between the rod plate and an end plate of the column; an interface seal disposed between the termination plate and the end plate; and a shim disposed between the termination plate and the rod plate.
According to various embodiments, provided is a fuel cell stack assembly comprising: a fuel cell stack column; a compression assembly configured to apply pressure to the column; and an upper plate assembly upon which the compression assembly is disposed. The upper plate assembly comprises: a rod plate upon which the compression assembly is disposed; a termination plate disposed between the rod plate and an end plate of the column; and an interface seal disposed between the termination plate and the end plate.
According to various embodiments, provided is a fuel cell stack assembly comprising: a fuel cell stack column; a compression assembly configured to apply pressure to the column; and an upper plate assembly upon which the compression assembly is disposed. The upper plate assembly comprising: a rod plate upon which the compression assembly is disposed; a termination plate disposed between the rod plate and an end plate of the column, the termination plate comprising 94-96 wt % Cr and 4-6 wt % Fe; and an interface seal disposed between the termination plate and the end plate.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to provide further explanation of the invention as claimed.
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate exemplary embodiments of the invention, and together with the description serve to explain the principles of the invention.
The present disclosure is described more fully hereinafter with reference to the accompanying drawings, in which exemplary embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the exemplary embodiments set forth herein. Rather, these exemplary embodiments are provided so that this disclosure is thorough, and will fully convey the scope of the invention to those skilled in the art. In the drawings, the size and relative sizes of layers and regions may be exaggerated for clarity. Like reference numerals in the drawings denote like elements.
It will be understood that when an element or layer is referred to as being “on” or “connected to” another element or layer, it can be directly on or directly connected to the other element or layer, or intervening elements or layers may be present. In contrast, when an element is referred to as being “directly on” or “directly connected to” another element or layer, there are no intervening elements or layers present. It will be understood that for the purposes of this disclosure, “at least one of X, Y, and Z” can be construed as X only, Y only, Z only, or any combination of two or more items X, Y, and Z (e.g., XYZ, XYY, YZ, ZZ).
The bores or feed-throughs 224 of the system of
An exemplary fuel manifold 204 is described in the U.S. application Ser. No. 11/656,563 noted above. Any number of fuel manifolds 204 may be provided between adjacent end plates of adjacent fuel cells of the fuel cell stacks 14, as desired.
The side baffles 220 connect the upper block 603 of the compression assembly 600 and the lower block 503. The side baffles 220, the compression assembly 600, and the lower block 503 may be collectively referred to as a “stack housing”. The stack housing is configured to apply a compressive load to the column 140. The configuration of the stack housing eliminates costly feed-throughs and resulting tie rod heat sinks and uses the same part (i.e., side baffle 220) for two purposes: to place the load on the stacks 14 and to direct the cathode feed flow stream (e.g., for a ring shaped arrangement of stacks shown in
The side baffles 220 are plate-shaped rather than wedge-shaped and include baffle plates 202 and ceramic inserts 406 configured to connect the baffle plates 202. In particular, the baffle plates 202 include generally circular cutouts 502 in which the inserts 406 are disposed. The inserts 406 do not completely fill the cutouts 502. The inserts 406 are generally bowtie-shaped, but include flat edges 501 rather than fully rounded edges. Thus, an empty space remains in the respective cutouts 502 above or below the inserts 406.
The side baffles 220 and baffle plates 202 have two major surfaces and one or more (e.g., four) edge surfaces. One or more of the edge surfaces may have an area at least 5 times smaller than each of the major surfaces. Alternatively, one or more edge surfaces may have an area at least 4 times or 3 times smaller than at least one of the major surfaces. Preferably, the baffle plates 202 have a constant width or thickness, have a substantially rectangular shape when viewed from the side of the major surface, and have a cross sectional shape which is substantially rectangular. In alternative embodiments, the ceramic side baffles 220 are not rectangular, but may have a wedge shaped cross-section. That is, one of the edge surfaces may be wider than the opposing edge surface. However, unlike the prior art baffles, which completely fill the space between adjacent electrode stacks 14, the side baffles 220 of this embodiment are configured so that there is space between side baffles 220. In other words, the side baffles 220 of this embodiment do not completely fill the space between adjacent columns 140. In other embodiments, wedge-shaped metal baffles may be inserted between adjacent side baffles 220, similar to the configuration shown in
Generally, the side baffles 220 are made from a high-temperature tolerant material, such as alumina or other suitable ceramic. In various embodiments, the side baffles 220 are made from a ceramic matrix composite (CMC). The CMC may include, for example, a matrix of aluminum oxide (e.g., alumina), zirconium oxide or silicon carbide. Other matrix materials may be selected as well. The fibers may be made from alumina, carbon, silicon carbide, or any other suitable material. The lower block 503 and the compression assembly 600 may also be made of the same or similar materials. The selection of particular materials for the compression housing is discussed in detail, below.
Any combination of the matrix and fibers may be used. Additionally, the fibers may be coated with an interfacial layer designed to improve the fatigue properties of the CMC. If desired, the CMC baffles may be made from a unitary piece of CMC material rather than from individual interlocking baffle plates. The CMC material may increase the baffle strength and creep resistance. If the baffles are made from alumina or an alumina fiber/alumina matrix CMC, then this material is a relatively good thermal conductor at typical SOFC operating temperatures (e.g., above 700° C.). If thermal decoupling of neighboring stacks or columns is desired, then the baffles can be made of a thermally insulating ceramic or CMC material.
Other elements of the compression housing, such as the lower block 503 and the compression assembly 600 may also be made of the same or similar materials. For example, the lower block 503 may comprise a ceramic material, such as alumina or CMC, which is separately attached (e.g., by the inserts, dovetails or other implements) to the side baffles 220 and to a system base 239. The use of the ceramic block material minimizes creation of heat sinks and eliminates the problem of linking the ceramic baffles to a metal base, which introduces thermal expansion interface problems. The selection of particular materials for the components of the compression housing is discussed in detail, below.
Referring to
The compression assembly 600 may include a rod plate 607 configured to provide a resilient surface against which the spring 611 can generate a compressive load. Preferably, the rod plate 607 includes retention barriers 608 configured to prevent the spring 611 from sliding off the rod plate 607. When using a leaf spring, the rod plate 607 may also include spring support rods 604. In this configuration, the spring 611 may be placed on top of the spring support rods 604 in an unstressed condition (see also
An upper plate 601 is provided on top of the spring 611, that is, on the opposite side of the spring 611 from the rod plate 607. The upper plate 601 may include a spring tensioner 612, in this embodiment a rod, on the bottom of the upper plate 601. The spring tensioner 612 is preferably located approximately in the center of the upper plate 601. The compression assembly 600 may also be provided with an upper block 603 which may include either cutouts 304 (which accept inserts 406 from baffles as illustrated) or protrusions 303 by which compression assembly 600 may be attached to the side baffles 220.
A temporary tightening mechanism may be attached over or to the compression assembly 600 during the process of connecting the assembly to the baffles 220. In the embodiment of
The compression load applied by the compression assembly 600 may be adjusted via a pressure adjusting mechanism 610. The pressure adjusting mechanism 610 may be, for example, a screw or bolt which may be raised or lowered by rotating. In the embodiment illustrated in
In use, the pressure adjusting mechanism 610 is lowered (and the spring 611 compressed) until the upper block 603 can be connected (e.g., hooked) to the side baffles 220. Once the side baffles 220 are connected via dovetails, inserts or other implements, the pressure adjusting mechanism 610 is loosened to release the bracket 602. The force of the spring 611, previously “held” by the pressure adjusting mechanism 610, is now transferred to the side baffles 220. Adjustment of the compressive force on the stack may be attained by fitting shims (not shown) between the compression assembly 600 and the top of the column of stacks 14 (which sits below the rod plate 607 of the compression assembly 600). More shims create a tighter compression. The pressure adjusting mechanism 610 provides pretension to allow connection of the compression assembly 600 to the side baffles 220. The bracket 602, including mechanism 610 and elements 605, 606 and 609 are then removed from the fuel cell column before the column is placed into an operating mode.
It is also important to note that the spring constant of the compression assembly may be highly non-linear. Further, since the compression assembly is already deflected at 20° C., the additional deflection at 700° C. may apply a substantially higher load to the column 140. Based on modeling, it is calculated that an original load of 350 lbs at room temperature can exceed 1000 lbs, when the column 140 heats up to 650° C. (before the interface seals melt). The opposite scenario is also true, in that the load on the column 140 will be reduced significantly, if the column 140 is cooled from a high temperature. The fundamental reason for this difference is the CTE difference between the column 140 and the side baffles. The increased loading at high temperatures may result in damage to the fuel cell stacks of the column 140 and/or other components of the fuel cell stack assembly.
In order to overcome or reduce the above and/or other problems, the side baffles 220 of the above embodiments may be configured to have a CTE that is substantially the same (within about +/−20%, such as +/−10%) as the CTE of the column 140. According to some embodiments, the CTE of the baffle plates 202 may be within about +/−5% of the CTE of the column 140. The CTE of the side baffles may be altered by altering the composition of one or more components of the side baffles 220. Herein, the CTE of an element refers to a CTE of the element at room temperature.
For example, when the side baffles each include a single baffle plate 202, as shown in the embodiment of
As shown in Table 1, an alumina-titania mixture may be prepared to have a CTE of 9.7, which is substantially the same as the CTE of a column of fuel cell stacks. As such, a side baffle 220 including an alumina-titania mixture expands at substantially the same rate as the column 140, which prevents excessive loading of the column 140 during heating.
Further, zirconia (tetragonal phase), magnesia, and a zirconia-magnesia mixture exhibit CTE's that are slightly higher than 9.7. As such, side baffles 220 including these materials could also prevent excessive loading of the column 140 during heating. While these materials would expand at a higher rate than the column 140, such a difference can be compensated for by a compression assembly, since the spring constant of the compression assembly 600 may be more linear at lower levels of compression. Side baffles 220 can include a mixture of alumina and magnesia, or a mixture of alumina and zirconia, with amount ratios of the mixtures configured such that the side baffles 220 and the column 140 have substantially the same CTE.
The baffle plates 202 and the ceramic inserts 406 of the side baffles 220 may be formed of the same material. However, according to some embodiments, the baffle plates 202 and the ceramic inserts 406 may be formed of different materials that have CTE's that are higher or lower than the CTE of the column 140, so long as the total CTE of the side baffles 220 is similar to the CTE of the column 140.
The baffle plates 202A, 202B are substantially the same size and shape, but have different CTE's. However, the overall CTE of the side baffle 220A may be similar to the CTE of a fuel cell stack column In particular, In particular, the CTE of the side baffle 220A may be within about +/−20%, such as +/−10% of the CTE of the fuel cell column. For example, when the fuel cell stack has a CTE of about 9.7, the side baffle 220A may have a CTE ranging from about 8.7 to about 10.7.
According to some embodiments, the first baffle plates 202A may be formed of alumina, which has a CTE of about 7.2, and the second baffle plates 202B may be formed of tetragonal zirconia, which has a CTE of about 12. Accordingly, the CTE of the side baffle 220A may be about 9.6, i.e., the average of 7.2 and 12. Thus, the side baffle 220A may have a CTE that is substantially the same as the 9.7 CTE of a typical fuel cell stack column. However, according to some embodiments, the CTE of the first side baffle plates 202A may be higher than the CTE of the stack 14, and the CTE of the second side baffle plates 202B may be lower than the CTE of the stack 14, so long as the total CTE of the side baffle 220A is within about +/−20%, such as +/−10% of the CTE of the fuel cell stack column.
While four baffle plates are shown in
Referring to
The first and second baffle plates 202C, 202D may include materials having different CTE's. However, in contrast to the fuel cell stack assembly 200A, the first and second baffle plates 202C, 202D may have different lengths (i.e., heights in the stack stacking direction). As such, that the overall CTE of the side baffle 220B may be set to be substantially the same as the CTE of the fuel cell stack column, by varying the lengths of the first and second baffle plates 202C, 202D. In other words, varying the lengths of the first and second baffle plates 202C, 202D allows for the use of a wider variety of ceramic materials, since varying the length of a baffle plates can change the actual linear expansion of the plate, and thereby compensate for the use of different materials having an average CTE that is not substantially the same as that of a fuel cell stack column. For example, baffle plates having a higher CTE may be made relatively shorter, and/or baffle plates having a lower CTE may be made relatively longer, to compensate for CTE variations. However, the lengths of baffle plates that deviate more from the CTE of the fuel cell stack column can be adjusted in consideration of the CTE of the other baffle plates, such that the CTE of the corresponding side baffle is within +/−20%, such as +/−10% of the CTE of the fuel cell stack column.
In particular, when considering a side baffle including only two baffle plates 202C, 202D, if the first baffle plate 202C is formed of material A having a CTE of 7.2, and the second baffle plate 202D is formed of material B having a CTE of 14, a ratio of the lengths of the first and second baffle plates 202C, 202D would be 14/7.2. As such, a length A of the first baffle plate 202C and a length B of the second baffle plate 202D can be determined using the following Equations 1 and 2:
Accordingly, the total CTE of a side baffle including two baffle plates may be adjusted by adjusting the lengths of the baffle plates included therein, in view of the materials used to form the baffle plates. Further, the present disclosure is applicable to side baffles that include fewer or additional baffle plates. For example, in the side baffle 220B, the total lengths of baffle plates 202C can be used as the length A, and the total length of the baffle plates 202D can be used as length B, in Equation 1. Equations 1 and 2 can be expanded to include additional components and/or materials, such as a third type of baffle plate. It should also be noted that the CTE of any ceramic inserts used to connect baffle plates should also be accounted for in determining the CTE of a side baffle.
Conventionally, fuel cell stack assemblies may be disposed in close proximity to one another, to reduce space requirements. In addition, ceramic components are pressed to a particular design thickness, limiting the functionality thereof to providing structural and dielectric characteristics.
In view of such drawbacks, various embodiments of the above-described ceramic components may be formed of multiple bonded (laminated) layers, which can have internal features/flow paths that are beneficial for improving dielectric strength, providing flow channels, temperature control, and instrumentation insertion. With regard to dielectric strength, ceramic components formed of layers of different materials can be prepared. For example, layers of ceramic components that are disposed relatively close to a fuel cell stack column may include materials having a higher dielectric strength, such as different ceramic compositions, different purities of alumina, and CMCs, than layers disposed further from the stack.
Ceramic components may also include layers of different thermal conductivity to manage the thermal profile of the fuel cell stack column. Further, layers can be configured provide space for instrumentation, such as probes, stress detectors, thermocouples, voltage detectors, bypass conductors, and the like.
For example, the third plate 806, which is closest to the fuel cell stack column 140, may have a higher dielectric strength than the first and second plates 802, 804 disposed further from the fuel cell stack column 140. The first plate 802 and or the second plate 804 may have higher strength and/or rigidity than the third plate 806. As such, each plate may be configured to impart specific features to the side baffle 820. For example, one of the plates 802, 804, 806 may be formed of a material having a relatively higher thermal conductivity than other plate(s). However, the present disclosure is not limited to the specific compositions and/or characteristics, which may be altered according to specific applications and requirements.
With regard to flow channels, ceramic components, such as side baffles, having a laminate structure can be configured such that certain layers form an internal manifold or channel(s). Such a structure may be used to deliver fuel to a fuel cell stack column, which can eliminate or simplify existing fuel rails 214. Further, such an internal manifold could also be configured to direct air into and/or around the fuel cell stack column to improve temperature change characteristics of the fuel cell stack column. Accordingly, such structures may operate as air and/or fuel manifolds.
Manifolds or channels may be formed in a laminate ceramic component by forming holes in individual ceramic layers, and then connecting the layers such that the holes are aligned to form a manifold or channel. In the alternative, one of the layers may be formed of ceramic strips, with areas between the strips forming a manifold or channel(s), in conjunction with other layers disposed on opposing sides of the strips.
Referring to
The channels 808 may be equally spaced apart. However, according to some embodiments, the second plate 804 may include a higher density of the channels 808 in areas that receive more heat. For example, the second plate 804 may include more channels 808 in areas adjacent to the center of the fuel cell stack column 140 than at areas adjacent to ends (e.g., top and bottom) of the fuel cell stack column 140, which tend to be cooler than the center of the stack column 140. According to some embodiments, the second plate 804 may be formed of ceramic strips that at least partially define the channels 808.
According to some embodiments, a method of providing air to the stack assembly 900 is provided. In particular, air is blown horizontally into the stack assembly (i.e., into the page) into an open face of the stack column 140 and into channels 808. A portion of the air fed into the stack 14 is used as an oxidizer in an electrochemical power generation reaction, while a portion of the air is fed through the channels 808 to cool the stack column 140.
The fuel cell stack assembly 1000 may also include a fuel channel 810 that extends through the side baffle 820 and lower block 503. In some embodiments, the fuel channel 810 may also optionally extend through the upper block 603. An opening 822 of the fuel channel 810 may be connected to a fuel source 818. The fuel source 818 may be a natural gas pipeline, a fuel storage vessel, such as hydrogen or hydrocarbon fuel tank, or any other suitable source of fuel. The fuel channel 810 may be configured to reform a fuel e.g., to act as a fuel reformer or pre-reformer. For example, the fuel channel 810 may include a fuel reformation catalyst. The catalyst may be any suitable catalyst, such as a nickel/rhodium, for example. Suitable catalysts are disclosed in U.S. Pat. Nos. 8,563,180 and 8,057,944, which are incorporated herein, in their entireties, by reference. The catalyst may be coated on the inner surface of the fuel channel 810 or may be disposed within the fuel channel 810.
The fuel channel 810 may be connected to the inlet manifold 812. The inlet manifold 812 may be connected to a fuel inlet 824 of the fuel cell stack column 140. In particular, the fuel channel 810 may extend through an inner layer of the lower block 503. However, in other embodiments, the fuel channel may extend to a lower surface of the lower block 503. The lower block 503 may also include a fuel outlet 826 of the fuel cell stack column 140.
Referring to
According to an alternative embodiment, rather than embedding the bypass electrodes 830 into the side baffle 820, the side baffle may contain openings (e.g., vertically stacked, horizontally extending through holes) which expose the side edges of the respective interconnects in the fuel cell stack column 140. If a defective fuel cell is detected in the stack, then the electrically connected bypass electrodes 830 are inserted into openings in the side baffles 820. The bypass electrodes 830 are connected by a connector 834 and contact the respective side edges of the interconnects located above and below the defective fuel cell in the stack.
The side baffles 820 may also include sensors 832. The sensors 832 may extend through a side baffle 820 and contact the fuel cell stack column 140. The sensors 832 may be imbedded in channels in a side baffle 820. The sensors 832 may be temperature sensors (thermocouples), pressure sensors, electrical sensors, e.g., lead wires for a current or voltage sensor, or the like.
Referring to
The rod plate 607 includes grooves 714 in which the support rods 604 are disposed. The rod plate 607 may also include a thermocouple slot 709. A thermocouple may be inserted into the slot 709 to measure column temperature. The rod plate 607 may be formed of alumina or a similar ceramic material. The rod plate 607 may have a thickness of at least 1 mm. For example, the rod plate 607 may have a thickness ranging from about 1 mm to about 5 mm, or about 2 mm to about 4 mm, such as a thickness of about 3 mm.
The support rods 604 are configured to support the spring 611. The spring 611 is configured to apply pressure to the column, via the support rods 604, the rod plate 607, and the termination plate 27. The interface seal 712 is an annular seal disposed between the end plate 716 and the termination plate 27, and is configured to prevent fuel in a fuel riser opening in the end plate 716 from flowing between the end plate 716 and the termination plate 27. The interface seal 712 may be formed of a glassy material. The interface seal 712 may flow at a temperature of at least 650° C., such as a temperature ranging from 675° C. to 725° C., or 685° C. to 715° C. For example, the interface seal may flow at a temperature of about 700° C.
Due to the nature of materials used in the stack assembly 1200, the load during first heat up of the stack increases to as high as 850 lbs, until the interface seal 712 disposed around a fuel riser opening in the end plate 716 flows and spreads out before setting. This load increases the bending stresses of rod plate 607, which may cause it to break. This results in disturbing the load distribution in the stack, which may lead to a loss of contact between the end plate 716 and the termination plate 27, leading to a loss or flickering of column voltage and/or a fuel leak at the top of the column.
Referring to
Referring to
Referring to
The shim 720 may be formed of a ceramic or cermet material. The shim 720 may have a thickness of at least about 10 mm. For example, the shim 720 may have a thickness ranging from about 10 mm to about 40 mm, from about 12 mm to about 20 mm, or from about 14 mm to about 16 mm. The shim 720 may have a thickness of about 15 mm, according to some embodiments. The shim 720 may be configured to support the rod plate 607, such that the bending stress (shown by arrows) applied to the rod plate 607 is reduced.
Referring to
Referring to
Referring to
The termination plate 27 may be made of 446 stainless steel (SS 446) or a Cr/Fe alloy. SS 446 may include by weight, 73% Fe, 23.0%-27.0% Cr, 1.5% Mn, 1.0% Si, 0.25% Ni, 0.20% Ni, 0.20% C, 0.04% P, and 0.03% S. The Cr/Fe alloy may include, by weight, about 94-96% Cr and about 4-6% Fe, such as 95 wt % Cr and 5 wt % Fe, which may be the same material as used in end plates and interconnects in the column 140. However, the present inventors determined that using the Cr/Fe alloy results in a reduction in stress applied to the thermocouple slot 709 and reduced bending of termination plate 27 and rod plate 607, 607A.
As shown in
Any one or more features from any one or more embodiments may be used in any suitable combination with any one or more features from one or more of the other embodiments. Although the foregoing refers to particular preferred embodiments, it will be understood that the invention is not so limited. It will occur to those of ordinary skill in the art that various modifications may be made to the disclosed embodiments and that such modifications are intended to be within the scope of the invention. All of the publications, patent applications and patents cited herein are incorporated herein by reference in their entirety.
Number | Date | Country | |
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62109227 | Jan 2015 | US |
Number | Date | Country | |
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Parent | 16245663 | Jan 2019 | US |
Child | 17655681 | US | |
Parent | 15008726 | Jan 2016 | US |
Child | 16245663 | US |