1. Technical Field
The present invention relates to a fuel cell stack having a structure of a stacked plurality of fuel-cell single cells.
2. Related Art
A fuel cell stack of this kind is disclosed in Patent Document 1 titled “fuel cell stack structure”. The fuel cell stack structure disclosed in Patent Document 1 includes a plurality of multi-cell modules each of which is formed by stacking a plurality of cells, wherein the plurality of multi-cell modules are arranged in series in the stacking direction, and bead gaskets seal the interface between the plurality of multi-cell modules.
Patent Document 1: Japanese Patent Unexamined Publication No. 2005-190706
However, in such fuel cell stacks as described above, since a dissimilar member such as a bead gasket is interposed between multi-cell modules, a dimensional error or the like may cause insufficient load transfer in the stacking direction. This may cause uneven power generation performance between cells (fuel-cell single cells) or the like.
A fuel cell stack according to one or more embodiments of the present invention includes two or more cell modules and a novel sealing plate interposed between the cell modules and that can adequately transfer a load in the stacking direction.
A fuel cell stack according to one or more embodiments of the present invention includes: at least two cell modules, each of which is constituted by an integrally-stacked plurality of fuel-cell single cells; and a sealing plate interposed between the cell modules. The sealing plate includes a sealing member disposed at the edge part thereof to seal the interfaces between the sealing plate and the edge parts of the cell modules. The fuel cell stack further includes a member contacting structure that transfers a load in the stacking direction disposed in a sealed inner area between the cell modules and the sealing plate, and each of the plurality of fuel-cell single cells includes a membrane electrode assembly and a pair of separators that sandwich the membrane electrode assembly, wherein the member contacting structure allows the outermost separators of the adjacent cell modules to face each other so as to transfer a load in the stacking direction and includes protrusions formed in the sealed inner area of the cell modules and a thin portion formed in the sealing plate that allows the protrusions of the cell modules on both sides thereof to contact with each other.
With the above-described configuration, the fuel cell stack according to one or more embodiments of the present invention, which includes the two or more cell modules and the sealing plate interposed between the cell modules, can adequately transfer a load in the stacking direction. This can equalize the surface pressure and the contact resistance acting on each of the fuel-cell single cells and can also equalize the power generation performance of each of the fuel-cell single cells.
Embodiments of the present invention will be described below with reference to the drawings. In embodiments of the invention, numerous specific details are set forth in order to provide a more thorough understanding of the invention. However, it will be apparent to one of ordinary skill in the art that the invention may be practiced without these specific details. In other instances, well-known features have not been described in detail to avoid obscuring the invention.
A fuel cell stack FS of
The fuel cell stack FS further includes end plates 56A, 56B disposed respectively in both ends of the cell modules M in the stacking direction, fastening plates 57A, 57B disposed on both surfaces corresponding to the long sides of the fuel-cell single cells C (the upper and lower surfaces in FIGS. 1(A)-1(B)), and reinforcing plates 58A, 58B disposed on both surfaces corresponding to the short sides. The fastening plates 57A, 57B and the reinforcing plates 58A, 58B are coupled to both end plates 56A, 56B by bolts (not shown).
As described above, the fuel cell stack FS has a case-integrated structure as illustrated in
The membrane electrode assembly 1, which is generally referred to as an MEA (membrane electrode assembly), includes an electrolyte layer of a solid polymer that is to interposed between a cathode layer and an anode layer, although they are not shown in detail in the figure. The membrane electrode assembly 1 is integrally formed with an outer resin frame (not shown). A manifold hole or the like may be formed in the frame to supply or discharge reaction gas.
As illustrated in
As illustrated in
The manifold holes H1 to H3 on the left in
Although not shown in the figure, sealing members are disposed between the frame of the membrane electrode assembly 1 and the separators 2 and around the manifold holes H1 to H6. The sealing members, which also serve as an adhesive as described below, air-tightly join the membrane electrode assembly 1 with the separators 2. In this regard, the sealing members disposed in the edge part of the frame of the membrane electrode assembly 1 and the separators 2 provide air-tightness of the gas channels GC, GA. Further, the sealing members disposed around the manifold holes H1 to H6 have openings, for supplying fluids to respective interlayer gaps, at suitable locations, while providing air-tightness.
A predetermined number of above-described fuel-cell single cells C are stacked to form a cell module M. In this regard, two adjacent fuel-cell single cells C form a channel F for cooling fluid (e.g. water) therebetween, and two adjacent cell modules M also form a channel F for cooling fluid therebetween. That is, the sealing plate P is disposed between the cell modules M, i.e. in the channel F for cooling fluid.
The sealing plate P is formed as a separate piece from the above-described fuel-cell single cells C. As illustrated in
The plate base 50 is molded from a single electrically-conductive metal plate. The plate base 50 is formed in substantially the same shape and size as the above-described fuel-cell single cells C in the plan view. Since the plate base 50 is constituted by the electrically-conductive metal plate, it can provide stable electrical connection over time.
In the sealing plate P, sealing members 51 are formed around each of the manifold holes H1 to H6. Further, an outer sealing member 52 is formed along the outermost edge of the plate base 50, and an inner sealing member 53 is formed along the inner side of the outer sealing member 52 with a predetermined distance. These sealing members are individually formed all over the periphery in an endless shape. The sealing members 51 around the manifold holes H1 to H6 are disposed independently from each other.
The sealing plate P keeps back rainwater from the outside by means of the outer sealing member 52 and prevents a leak of the cooling fluid flowing through the channel F between the cell modules M by means of the inner sealing member 53. The sealing plate P also provides electrical insulation. Further, the sealing plate P is configured to be easily detachable by peeling the sealing members 51 to 53 from the cell modules M.
As described above, the fuel cell stack FS includes the two or more cell modules M, each of which is constituted by the integrally stacked plurality of fuel-cell single cells C, and the sealing plate P interposed between the cell modules M. The sealing plate P further includes the outer and inner sealing member 53, 53 that seals the interfaces between the sealing plate P and the edge parts of the cell modules M.
That is, in the fuel cell stack FS, the sealing plate P, i.e. a dissimilar member, is interposed between the cell modules M constituted by the fuel-cell single cells C. In order to improve a load transfer in the stacking direction, the fuel cell stack FS is provided with a member contacting structure that transfers a load in the stacking direction, which disposed in a sealed inner area between the cell modules M and the sealing plate P.
In the fuel cell stack FS according to the embodiment of
The above-described apexes of the corrugation of the separators 2 are used as the protrusions 11 formed on the cell modules M. Accordingly, the protrusions 11 can be formed by setting the height of the apexes of the corrugation to a level higher than a regular level at least in the separators 2 that are located on the outer side of the outermost fuel-cell single cells C of each cell module M.
Alternatively, the protrusions 11 can be formed by setting the height of the apexes of the corrugation in a center area to a level slightly higher than the regular level in at least one of the separators 2 of each fuel-cell single cell C, and the single cells C that include such a separator 2 are stacked. When such fuel-cell single cells C are stacked, since the excess height of the corrugation apexes of each separator 2 are accumulated, the resultant cell module M has a curved shape in which the center part is swelled as illustrated in
The opening 12 of the sealing plate P is formed in an area inside the above-described outer and inner sealing member 52, 53. The opening 12 has such a size that can receive the protrusions 11 of the cell modules M from both sides to allow the protrusions 11 of the cell modules M on both sides to contact with each other in the opening 12. Accordingly, the height of the protrusions 11 of each cell module M is approximately a half of the thickness of the sealing plate P.
In the fuel cell stack FS that includes the two or more cell modules M and the sealing plate P interposed between the cell modules M, the protrusions 11 of adjacent two cell modules M are in contact with each other through the member contacting structure, i.e. the opening 12 of the sealing plate P. This can improve a load transfer in the stacking direction even if there is a dimensional error or the like between the components.
That is, the fuel cell stack FS, in which a dissimilar member (the sealing plate P) is interposed between the cell modules M, can adequately transfer a load in the stacking direction. This can equalize the surface pressure and the contact resistance of the fuel-cell single cells C, which can eventually equalize the power generation performance of the fuel-cell single cells C.
As a result of the above-described improvement in load transfer and equalization of the surface pressure and the contact resistance, the surface pressure acting on the outer and inner sealing members 52 and 53 of the sealing plate P also becomes sufficient and uniform. Accordingly, the fuel cell stack FS can have improved sealing performance of the sealing plate P.
Further, since the fuel cell stack FS is configured such that the sealing plate P is easily detachable from the cell modules M, if there is a defect in one of the fuel-cell single cells C, it is possible to exchange only the cell module M that includes the faulty fuel-cell single cell C. Therefore, it is advantageous that the other fuel-cell single cells C and cell modules M can be further used continuously.
In the illustrated fuel cell stack FS, a member contacting structure, that transfer a load in the stacking direction, includes protrusions 11 formed within a sealed inner area of cell modules M and an opening 12 formed in a sealing plate P to allow the protrusions 11 of the cell modules M on both sides thereof to contact with each other. Further, in one or more embodiments, the protrusions 11 are constituted by convex surfaces formed by the curved cell modules M as illustrated by the virtual lines in
In the fuel cell stack FS according to one or more embodiments, each fuel-cell single cell C includes sealing members S having a sealing function and a contacting function. The sealing members S are disposed between a frame of a membrane electrode assembly 1 and separators 2 at the edge part as previously described. Since heat is generated during power generation, a thermosetting adhesive is used for the sealing members S.
The frame of the membrane electrode assembly 1 is made of resin while the separators 2 are made of metal. When such dissimilar materials are joined with each other by using a thermosetting adhesive, the adhesive contracts after curing. Accordingly, the fuel-cell single cells C swells in the center part due to the contraction of the outer edge. Therefore, when a plurality of such fuel-cell single cells C are stacked to form a cell module M, the deformation of each fuel-cell single cells C are accumulated. As a result, as illustrated in
As with one or more of the above embodiments, in the fuel cell stack FS that includes the cell modules M and the sealing plate P interposed between the cell module M, the protrusions 11 of adjacent two cell modules M are in contact with each other through the opening 12 of the sealing plate P. This can improve a load transfer in the stacking direction even if there is a dimensional error or the like between the components.
Further, the equalized surface pressure and contact resistance of each of the fuel-cell single cells C enables equalization of the power generating function of the fuel-cell single cells C. In addition, the surface pressure acting on the outer and inner sealing members 52 and 53 of the sealing plate P also becomes sufficient and uniform. This can improve the sealing performance of the sealing plate P.
Ideally, if fuel-cell single cells C of the above-described cell modules M were flat and have uniform thickness, the surface pressure distribution would be uniform when they are stacked. However, as described above, since the resin frame of the membrane electrode assembly 1 and the metal separators 2 are joined with each other by using the thermosetting adhesive, the fuel-cell single cells C have a swelled center part.
In one or more embodiments of the present invention, the convex surfaces of the cell modules M due to the swelled fuel-cell single cells C and the sealing plate P interposed between the cell modules M are ably utilized to provide the member contacting structure that is composed of the convex surfaces as the protrusions 11 and the opening 12 of the separator 2. Then, the member contacting structure improves load transfer in the stacking direction and allows a sufficient and uniform surface pressure to be applied on the inner and outer sealing member 52, 53 of the sealing plate P.
Each of the fuel cell stacks FS illustrated in
The fuel cell stack FS of
As with one or more of the above embodiments, the above-described fuel stacks FS can adequately transfer a load in the stacked direction even if there is a dimensional error or the like between the components. As a result, the equalized surface pressure and contact resistance of each of the fuel-cell single cells C enables equalization of the to power generating performance of the fuel-cell single cells C. The sealing performance of the sealing plate P can also be improved. Furthermore, the opening 12 or the thin portion 13 formed in the sealing plate P produces reduced weight of the sealing plate P and the high yield of the sealing plate P with respect to the material thereof. They can also improve the flow of cooling fluid.
The fuel cell stack FS of
The fuel cell stack FS of
The spacers 14, 15 can be formed at the same time as forming sealing members 51 to 53 in the sealing plate P. For example, the sealing members 51 to 53 and the spacers 14, 15 may be formed simultaneously with a rubber material by injection molding on the sealing plate P.
As with one or more of the above embodiments, the above-described fuel cell stacks FS can adequately transfer a load in the stacked direction even if there is a dimensional error or the like between the components. As a result, the equalized surface pressure and contact resistance of each of the fuel-cell single cells C enables equalization of the power generating performance of the fuel-cell single cells C. The sealing performance of the sealing plate P can also be improved. Furthermore, the spacers 14, 15 increase the flexibility of adjustment for further improving load transfer. Use of an elastic material for the spacers 14, 15 produces improved load transfer and capability of absorbing a deformation in the stacking direction.
Furthermore, the fuel cell stacks FS illustrated in
The configuration of the fuel cell stack is not limited to the above-described embodiments. Detail of the configuration may be suitably changed, and the configurations of the above-described embodiments may be suitably combined with each other without departing from the gist of the present invention.
While the invention has been described with respect to a limited number of embodiments, those skilled in the art, having benefit of this disclosure, will appreciate that other embodiments can be devised which do not depart from the scope of the invention as disclosed herein. Accordingly, the scope of the invention should be limited only by the attached claims.
Number | Date | Country | Kind |
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2012-255838 | Nov 2012 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2013/079958 | 11/6/2013 | WO | 00 |