Patent Application
20140335433
The present invention relates to a fuel cell.
A polymer electrolyte fuel cell (hereinafter simply called “fuel cell”) has a membrane electrode assembly which includes electrodes placed on both surfaces of an electrolyte membrane having good proton conductivity in the wet state, as a power generation element (e.g., Patent Literature 1). A fuel cell mounted on a fuel cell vehicle may fall into a high temperature state that has an extremely high operating temperature, when the operation of the fuel cell is continued in an environment of remarkably high ambient temperature (for example, temperature of about 40° C.) or when high load operation is continued for a long time period, for example, during hill climbing or during acceleration. The fuel cell in the high temperature state may have the reduced proton conductivity in the electrolyte membrane. This may lead to degradation of the power generation performance and deterioration of the controllability of the fuel cell, for example, by making it difficult to output a desired electric power. This problem is not limited to the fuel cell vehicle but is commonly found in fuel cell systems including fuel cells.
An object of the invention is to provide a technology of improving the controllability of a fuel cell.
The invention may be implemented by any of the following aspects and embodiments, in order to solve at least part of the above problems.
There is provided a fuel cell system, comprising: a fuel cell; and a controller that controls a voltage of the fuel cell. The controller sets a processing condition to change a power generation characteristic of the fuel cell expressed as a relationship between electric current and voltage, based on a target voltage which is a target value of voltage relative to a predetermined electric current of the fuel cell. The controller performs a temporary voltage drop process under the processing condition, wherein the temporary voltage drop process temporarily drops the voltage of the fuel cell based on the power generation characteristic of the fuel cell, so as to cause a temporary increase in electric current of the fuel cell and change the power generation characteristic of the fuel cell.
Even when the power generation performance of the fuel cell is degraded, for example, in the high temperature state, this fuel cell system performs the temporary voltage drop process under the adequate processing condition, thus changing the power generation characteristic of the fuel cell and raising the voltage of the fuel cell to the target voltage. This accordingly improves the controllability of voltage control of the fuel cell.
There is provided the fuel cell system according to Aspect 1, wherein the controller obtains in advance a relationship between an amount of voltage increase, which is an increased amount of the voltage relative to the predetermined electric current of the fuel cell by a change of the power generation characteristic when the temporary voltage drop process is performed, and the processing condition of the temporary voltage drop process. The controller uses the relationship and sets the processing condition, based on a target voltage increase amount, which is a difference between a present voltage relative to the predetermined electric current and the target voltage.
This fuel cell system uses the relationship between the amount of voltage increased by the temporary voltage drop process and the processing condition of the temporary voltage drop process and thereby adequately sets the processing condition to raise the voltage of the fuel cell to the target voltage.
There is provided the fuel cell system according to Aspect 2, wherein the processing condition is at least one of; a minimum voltage in the temporary voltage drop process; a retention period when the minimum voltage is maintained in the temporary voltage drop process; and a voltage rise rate for recovery of voltage in the temporary voltage drop process.
This fuel cell system adequately sets the minimum voltage in the temporary voltage process, the period when the minimum voltage is maintained and the voltage rise rate (current drop rate) for recovery of voltage as the processing condition of the temporary voltage drop process according to the increase amount of target voltage.
There is provided the fuel cell system according to either Aspect 2 or Aspect 3, further comprising an operating state detector that detects an operating state of the fuel cell immediately before execution of the temporary voltage drop process. The controller obtains in advance a relationship among the amount of voltage increase, which is the increased amount of the voltage relative to the predetermined electric current of the fuel cell by the change of the power generation characteristic when the temporary voltage drop process is performed, the operating state of the fuel cell and the processing condition of the temporary voltage drop process. The controller uses the relationship and sets the processing condition, based on the operating state of the fuel cell and the target voltage.
This fuel cell system adequately sets the processing condition of the temporary voltage drop process according to the increase amount of target voltage and the operating state of the fuel cell.
There is provided the fuel cell system according to Aspect 4, wherein the operating state of the fuel cell immediately before execution of the temporary voltage drop process is at least one of; an accumulated time of a period when the fuel cell is in a high temperature state having higher temperature than a predetermined temperature; and a catalyst utilization rate indicating a state of a catalyst supported on an electrode of the fuel cell.
This fuel cell system adequately sets the processing condition of the temporary voltage drop process according to the increase amount of target voltage, the accumulated time of the period when the fuel cell is in the high temperature state and/or the catalyst utilization rate of the fuel cell.
There is provided the fuel cell system according to any one of Aspects 2 to 5, further comprising a voltage measurement unit that measures the voltage of the fuel cell. The controller corrects the relationship, in order to reduce a difference between an observed value of voltage of the fuel cell after execution of the temporary voltage drop process and the target voltage.
This fuel cell system sets the more adequate processing condition to achieve a desired voltage increase in the temporary voltage drop process.
There is provided the fuel cell system according to any one of Aspects 1 to 6, further comprising a secondary battery that is controlled by the controller to be charged and discharged and assists an output electric power of the fuel cell in the temporary voltage drop process. The controller specifies in advance a lower limit value of a state of charge of the secondary battery, which is a threshold value to limit discharging of the secondary battery, and manages the state of charge of the secondary battery not to make the state of charge of the secondary battery lower than the lower limit value. The controller reduces the lower limit value during execution of the temporary voltage drop process, so as to relieve a condition of limiting discharging of the secondary battery.
This fuel cell system ensures compensation of electric power by the secondary battery during execution of the temporary voltage drop process.
There is provided a control method of a fuel cell system, comprising:
(a) a computer setting a processing condition to change a power generation characteristic of a fuel cell expressed as a relationship between electric current and voltage, based on a target voltage which is a target value of voltage relative to a predetermined electric current of the fuel cell, and
(b) the computer performing a temporary voltage drop process under the processing condition set based on the target voltage, wherein the temporary voltage drop process temporarily drops a voltage of the fuel cell based on the power generation characteristic of the fuel cell, so as to cause a temporary increase in electric current of the fuel cell and change the power generation characteristic of the fuel cell.
Even when the power generation performance of the fuel cell is degraded, for example, in the high temperature state, this control method performs the temporary voltage drop process under the adequate processing condition, thus changing the power generation characteristic of the fuel cell and raising the voltage of the fuel cell to the target voltage. This accordingly improves the controllability of voltage control of the fuel cell.
The invention may be implemented by any of various aspects: for example, a fuel cell system and a vehicle equipped with the fuel cell system. The invention may also be implemented by any of other aspects, such as a control method of a fuel cell system, a control device and a program that cause the control method to be performed and a non-transitory storage medium in which the program is stored.
The fuel cell 10 is a polymer electrolyte fuel cell that receives supplies of hydrogen (anode gas) and the air (cathode gas) as reactive gases and generates electricity. The fuel cell 10 has a stack structure formed by stacking a plurality of power generation elements 11 called unit cells. Each of the power generation elements 11 includes a membrane electrode assembly (not shown) as a power generating body provided by placing electrodes on both surfaces of an electrolyte membrane and two separators (not shown) placed across the membrane electrode assembly.
The electrolyte membrane may be made of a solid polymer thin film having good proton conductivity in the wet state. The electrodes may be made of conductive particles having a catalyst for accelerating an electricity generating reaction supported thereon. The catalyst may be, for example, platinum (Pt), and the conductive particles may be, for example, carbon (C) particles.
The controller 20 is implemented by a microcomputer including a central processing unit and a main storage unit. The controller 20 receives a request of power output and controls the respective components described below in response to this request to cause the fuel cell 10 to generate electricity.
The cathode gas supply structure 30 includes a cathode gas piping 31, an air compressor 32, an air flow meter 33, an on-off valve 34 and a humidifier 35. The cathode gas piping 31 is provided as a piping connected to the cathode side of the fuel cell 10. The air compressor 32 is connected with the fuel cell 10 via the cathode gas piping 31 to supply the outside air taken in and compressed as the cathode gas to the fuel cell 10.
The air flow meter 33 is located in the upstream of the air compressor 32 to measure the amount of the outside air taken in by the air compressor 32 and send the measurement value to the controller 20. The controller 20 actuates the air compressor 32 based on this measurement value and thereby controls the supply amount of the air to the fuel cell 10.
The on-off valve 34 is provided between the air compressor 32 and the fuel cell 10 and is opened and closed according to the flow of the air supply through the cathode gas piping 31. More specifically, the on-off valve 34 is normally in the closed position and is opened when the air having a specified pressure is supplied from the air compressor 32 to the cathode gas piping 31.
The humidifier 35 humidifies the high-pressure air fed from the air compressor 32. The controller 20 controls the humidifying amount of the air supplied to the fuel cell 10 by the humidifier 35 and adjusts the wet state inside the fuel cell 10, in order to maintain the electrolyte membrane in the wet state and achieve the good proton conductivity. The humidifier 35 is connected with a cathode off-gas piping 41 to use the moisture in an off-gas for humidifying the high-pressure air.
The cathode gas discharge structure 40 includes the cathode off-gas piping 41, a pressure regulator 43 and a pressure measurement unit 44. The cathode off-gas piping 41 is provided as a piping connected to the cathode side of the fuel cell 10 to discharge a cathode off-gas out of the fuel cell system 100. The pressure regulator 43 regulates the pressure of the cathode off-gas in the cathode off-gas piping 41 (back pressure on the cathode side of the fuel cell 10). The pressure measurement unit 44 is provided in the upstream of the pressure regulator 43 to measure the pressure of the cathode off-gas and send the measurement value to the controller 20. The controller 20 adjusts the valve opening of the pressure regulator 43, based on the measurement value of the pressure measurement unit 44.
The anode gas supply structure 50 includes an anode gas piping 51, a hydrogen tank 52, an on-off valve 53, a regulator 54, a hydrogen supply device 55 and a pressure measurement unit 56. The hydrogen tank 52 is connected with the anodes of the fuel cell 10 via the anode gas piping 51 to supply hydrogen filled in the tank to the fuel cell 10. The fuel cell system 100 may include a reforming unit that reforms a hydrocarbon fuel to produce hydrogen, in place of the hydrogen tank 52, as the hydrogen supply source.
The on-off valve 53, the regulator 54, the hydrogen supply device 55 and the pressure measurement unit 56 are provided on the anode gas piping 51 in this order from the upstream side (hydrogen tank 52-side). The on-off valve 53 is opened and closed in response to a command from the controller 20 to control the inflow of hydrogen from the hydrogen tank 52 to the upstream side of the hydrogen supply device 55. The regulator 54 is provided as a pressure reducing valve to regulate the pressure of hydrogen on the upstream side of the hydrogen supply device 55, and the valve opening of the regulator 54 is controlled by the controller 20.
The hydrogen supply device 55 may be, for example, an injector that is an electromagnetically-driven on-off valve. The pressure measurement unit 56 measures the pressure of hydrogen on the downstream side of the hydrogen supply device 55 and sends the measurement value to the controller 20. The controller 20 controls the hydrogen supply device 55 based on the measurement value of the pressure measurement unit 56, so as to control the amount of hydrogen supplied to the fuel cell 10.
The anode gas circulation and discharge structure 60 includes an anode off-gas piping 61, a gas liquid separator 62, an anode gas circulation piping 63, a hydrogen circulation pump 64, an anode water discharge piping 65, a drain valve 66 and a pressure measurement unit 67. The anode off-gas piping 61 is provided as a piping that connects an outlet of the anodes of the fuel cell 10 with the gas liquid separator 62 to introduce an anode off-gas including unreacted gases (for example, hydrogen and nitrogen) that have not been used for the electricity generating reaction, to the gas liquid separator 62.
The gas liquid separator 62 is connected with the anode gas circulation piping 63 and the anode water discharge piping 65. The gas liquid separator 62 separates a gas component included in the anode off-gas from a fluid and introduces the gas component to the anode gas circulation piping 63 while introducing the fluid to the anode water discharge piping 65.
The anode gas circulation piping 63 is connected with the anode gas piping 51 at a position in the downstream of the hydrogen supply device 55. The hydrogen circulation pump 64 is provided on the anode gas circulation piping 63. Hydrogen included in the gas component separated by the gas liquid separator 62 is fed to the anode gas piping 51 by this hydrogen circulation pump 64. The fuel cell system 100 circulates hydrogen included in the anode off-gas and resupplies the hydrogen to the fuel cell 10 in this manner, thus improving the use efficiency of hydrogen.
The anode water discharge piping 65 is provided as a piping to discharge the fluid separated by the gas liquid separator 62 out of the fuel cell system 100. The drain valve 66 is provided on the anode water discharge piping 65 and is opened and closed in response to a command from the controller 20. The controller 20 normally closes the drain valve 66 during operation of the fuel cell system 100 and opens the drain valve 66 at a predetermined water discharge timing or at a discharge timing of an inert gas included in the anode off-gas.
The pressure measurement unit 67 of the anode gas circulation and discharge structure 60 is provided on the anode off-gas piping 61. The pressure measurement unit 67 measures the pressure of the anode off-gas (back pressure on the anode side of the fuel cell 10) in the vicinity of an outlet of a hydrogen manifold of the fuel cell 10 and sends the measurement result to the controller 20.
The cooling medium supply structure 70 includes a cooling medium piping 71, a radiator 72, a three-way valve 73, a cooling medium circulation pump 75 and two cooling medium temperature measurement units 76a and 76b. The cooling medium piping 71 is provided as a piping to circulate a cooling medium for cooling the fuel cell 10 and includes an upstream-side pipe 71a, a downstream-side pipe 71b and a bypass pipe 71c.
The upstream-side pipe 71a connects an outlet manifold for the cooling medium provided in the fuel cell 10 with an inlet of the radiator 72. The downstream-side pipe 71b connects an inlet manifold for the cooling medium provided in the fuel cell 10 with an outlet of the radiator 72. The bypass pipe 71c has one end connected with the upstream-side pipe 71a via the three-way valve 73 and the other end connected with the downstream-side pipe 71b. The controller 20 controls opening and closing of the three-way valve 73 to adjust the amount of inflow of the cooling medium to the bypass pipe 71c and thereby control the amount of inflow of the cooling medium to the radiator 72.
The radiator 72 is provided on the cooling medium piping 71. The radiator 72 exchanges heat between the cooling medium flowing through the cooling medium piping 71 and the outside air, so as to cool down the cooling medium. The cooling medium circulation pump 75 is provided on the downstream side (cooling medium inlet side of the fuel cell 10) of the connecting position of the bypass pipe 71c in the downstream-side pipe 71b and is actuated in response to a command of the controller 20.
The two cooling medium temperature measurement units 76a and 76b are respectively provided on the upstream-side pipe 71a and the downstream-side pipe 71b and send the respective measurement values to the controller 20. The controller 20 determines the operating temperature of the fuel cell 10 from a difference between the measurement values of the respective cooling medium temperature measurement units 76a and 76b. The controller 20 controls the rotation speed of the cooling medium circulation pump 75 based on the determined operating temperature of the fuel cell 10 and thereby adjusts the operating temperature of the fuel cell 10.
The fuel cell system 100 further includes an ambient temperature sensor 101 and a vehicle speed sensor 102 to obtain vehicle information of the fuel cell vehicle. The ambient temperature sensor 101 detects the temperature outside of the fuel cell vehicle and sends the detection value to the controller 20. The vehicle speed sensor 102 detects the current speed of the fuel cell vehicle and sends the detection value to the controller 20. The controller 20 appropriately uses the information obtained from these sensors for output control of the fuel cell 10.
The fuel cell 10 is connected with the DC/AC inverter 83 via a direct current line DCL, and the DC/AC inverter 83 is connected with a motor 200 as a driving force source of the fuel cell vehicle. The secondary battery 81 is connected to the direct current line DCL via the DC/DC converter 82.
The secondary battery 81 serves as an auxiliary power source of the fuel cell 10. The secondary battery 81 may be, for example, a lithium ion battery. The controller 20 controls the DC/DC converter 82 to control the electric current and the voltage of the fuel cell 10 and charging and discharging of the secondary battery 81, so as to vary and adjust the voltage level of the direct current line DCL.
The SOC detector 94 is connected to the secondary battery 81. The SOC detector 94 detects the SOC (state of charge) as the charging state of the secondary battery 81 and sends the detection value to the controller 20. The SOC of the secondary battery 81 herein denotes the ratio of the remaining charge (amount of accumulated power) of the secondary battery 81 to the charging capacity of the secondary battery 81. The SOC detector 94 measures the temperature, the electric power and the electric current of the secondary battery 81 to detect the SOC of the secondary battery 81.
The controller 20 controls charging and discharging of the secondary battery 81 based on the detection value of the SOC detector 94, such that the SOC of the secondary battery 81 is maintained in a specified range. More specifically, when the SOC of the secondary battery 81 obtained from the SOC detector 94 is lower than a predetermined lower limit value, the controller 20 controls the secondary battery 81 to be charged with electric power output from the fuel cell 10. When the SOC of the secondary battery 81 is higher than a predetermined upper limit value, on the other hand, the controller 20 controls the secondary battery 81 to be discharged.
The DC/AC inverter 83 converts the direct current power obtained from the fuel cell 10 and the secondary battery 81 into alternating current power and supplies the alternating current power to the motor 200. When regenerative electric power is generated by the motor 200, the DC/AC inverter 83 converts the regenerative electric power to direct current power. The regenerative electric power converted to the direct current power is accumulated in the secondary battery 81 via the DC/DC converter 82.
The cell voltage measurement unit 91 is connected with the respective power generation elements 11 of the fuel cell 10 to measure the voltage of each power generation element 11 (cell voltage). The cell voltage measurement unit 91 sends the measurement results to the controller 20. The controller 20 obtains a voltage output from the fuel cell 10, based on the measurement results of the cell voltage measurement unit 91.
The current measurement unit 92 is connected with the direct current line DCL to measure the electric current value output from the fuel cell 10 and sends the measurement value to the controller 20. When there are differences between the observed values and target values (control values) of the cell voltage and the electric current, the controller 20 performs feedback control to correct the control values, in order to reduce the differences.
The impedance measurement unit 93 is connected with the fuel cell 10. The impedance measurement unit 93 measures the impedance of the entire fuel cell 10 by application of alternating current to the fuel cell 10 and sends the measurement result to the controller 20. The controller 20 manages the wet state of the electrolyte membranes of the fuel cell 10, based on the measurement result of the impedance measurement unit 93. The open-close switch 95 is provided on the direct current line DCL and controls the electrical connections between the fuel cell 10 and the motor 200 and between the secondary battery 81 and the motor 200, in response to a command of the controller 20.
The controller 20 stores in advance information indicating the power generation characteristics of the fuel cell 10, such as the I-V characteristic and the I-P characteristic as control information for controlling the fuel cell 10. The I-V characteristic and the I-P characteristic of the fuel cell 10 vary depending on the operating condition of the fuel cell 10, for example, the operating temperature. It is accordingly preferable that the controller 20 has the control information with respect to each operating condition.
The controller 20 obtains a target current It to be output from the fuel cell 10 responding to a requested power Pt, based on the I-P characteristic of the fuel cell 10. The controller 20 also obtains a target voltage Vt of the fuel cell 10 to output the target current It, based on the I-V characteristic of the fuel cell 10. The controller 20 controls the DC/DC converter 82 to set the voltage of the direct current line DCL to the target voltage Vt, so as to control the fuel cell 10 and the secondary battery 81 to output the requested power Pt.
At step S20 (
When the fuel cell 10 is not in the high-temperature state, the controller 20 continues the control of the ordinary operation (step S10). When the fuel cell 10 is in the high-temperature state, the controller 20 starts high-temperature operation (step S25). The controller 20 performs control to suppress an increase in operating temperature of the fuel cell 10 and suppress drying of the electrolyte membranes, as the high-temperature operation. More specifically, the controller 20 performs control to increase the supply flow rate of the cooling medium to the fuel cell 10 and control to increase the degree of humidification of the reactive gas. Like during the ordinary operation, the output control of the fuel cell 10 is also performed during high-temperature operation. It is, however, known that the power generation performance of the fuel cell 10 degrades with an increase in operating temperature.
In general, the I-V characteristic of the fuel cell is likely to change in a falling direction of the curved graph representing the I-V characteristic with an increase in operating temperature of the fuel cell. The fuel cell has a decreasing power generation efficiency with a fall of the graph representing the I-V characteristic and falls into the power generation state that is likely to generate heat. In the power generation state that the graph representing the I-V characteristic has a remarkable fall, drying of the electrolyte membranes and oxidation of the catalyst are accelerated. The fuel cell then falls into a critical state (shown by the broken line) having difficulty in increasing the electric current according to the power generation characteristic to increase the electric power. Application of an additional load to the fuel cell in this state may lead to irreversible degradation of the fuel cell.
In the fuel cell system 100 of the embodiment, the controller 20 accordingly determines whether the fuel cell 10 is in the critical state that has remarkable degradation of the power generation performance at a specified timing during the high-temperature operation (step S30 in
When it is determined that the power generation state of the fuel cell 10 is not the critical state, the controller 20 continues the control of the high-temperature operation (step S25). When the operating temperature of the fuel cell 10 decreases during the high-temperature operation and the fuel cell 10 is recovered from the high-temperature state, the operation control of the fuel cell 10 is returned to ordinary operation (shown by broken line arrow).
When it is determined at step S30 that the power generation state of the fuel cell 10 is the critical state, on the other hand, the controller 20 starts degradation avoidance operation to avoid degradation of the fuel cell 10 (step S40). This degradation avoidance operation restricts the output control of the fuel cell 10. Specifically, the controller 20 limits the output power of the fuel cell 10 to a predetermined limiting value. More specifically, the controller 20 limits the voltage of the fuel cell 10 to a predetermined limiting voltage Vlim and limits the electric current of the fuel cell 10 to a predetermined limiting current Ilim. During this degradation avoidance operation, the secondary battery 81 compensates for a shortage to the requested power.
Even during this degradation avoidance operation, in some cases, there may be a request that needs to further increase the voltage of the fuel cell 10, for example, there may be a need for electric power that exceeds the electric power compensable by the secondary battery 81. There may also be a need to further increase the voltage of the fuel cell 10, in response to an internal request of the fuel cell system.
When detecting a request that needs to increase the voltage of the fuel cell 10 during the degradation avoidance operation (step S50), the fuel cell system 100 of the embodiment does not regard the request as an invalid request but starts power generation characteristic recovery operation (step S60). This power generation characteristic recovery operation repeatedly performs a temporary voltage drop process described below at predetermined cycles and a predetermined number of times, so as to temporarily improve the power generation performance of the fuel cell 10.
The experiment increased the electric current of the fuel cell from I1 to I2, temporarily kept the electric current at I2 and again decreased to I1 in a period between a time t1 and a time t2 (
The reason of incompatibility between the electric current and the voltage of the fuel cell after the temporary increase in electric current as shown in
As described above, the temporary voltage drop process that temporarily decreases the voltage of the fuel cell to temporarily increase the electric current based on the power generation characteristic of the fuel cell (I-V characteristic) recovers the power generation characteristic of the fuel cell and improves the power generation performance of the fuel cell. The improvement in power generation performance by the recovery change of the power generation characteristic is, however, only temporary. The voltage of the fuel cell gradually decreases with elapse of time even when the electric current is kept constant. In order to achieve desired improvement of the power generation performance, it is accordingly preferable to repeatedly perform the temporary voltage drop process.
It is assumed here that the controller 20 detects a request to increase the voltage of the fuel cell 10 to the target voltage Vt, while the fuel cell 10 outputs the limiting voltage Vlim and the limiting current Ilim during the degradation avoidance operation (steps S40 and S50 in
The controller 20 decreases the voltage of the fuel cell 10 from the limiting voltage Vlim to Vc and increases the electric current from Ilim to Ic (time t1a). The controller 20 keeps the voltage at the decreased voltage Vc for a predetermined time period and increases the voltage to a higher voltage Vp than the original limiting voltage Vlim in order to return the electric current to the original limiting current Ilim (time t1b).
In the description hereinafter, the difference between the increased voltage Vp after the temporary voltage drop process and the original voltage Vlim before execution of the temporary voltage drop process, i.e., the amount of voltage increase by the temporary voltage drop process is called “amount of voltage increase ΔV” (ΔV=Vp−Vlim). The fuel cell system 100 of the embodiment sets the increased voltage Vp based on the target voltage Vt, sets a target value of the amount of voltage increase ΔV (target increase amount ΔV) and specifies the processing condition of the temporary voltage drop process to achieve the target increase amount ΔV as described in detail later.
The “increased voltage Vp” described above corresponds to the “target voltage” in the claims, and the “target increase amount ΔV” corresponds to the “target amount of voltage increase” in the claims.
In a period between the time t1b and a time t2a, the controller 20 controls the electric current output from the fuel cell 10 to be kept at Ilim. As described above, however, the improvement in power generation performance of the fuel cell 10 is only temporary, so that the controller 20 gradually decreases the voltage from Vp at a predetermined rate. After that, the controller 20 repeats the temporary voltage drop process similar to that performed in the period between the time t1a and the time t1b at predetermined cycles T and a predetermined number of times, in order to make the time average voltage of the fuel cell 10 equal to the target value Vt.
The fuel cell system 100 of the embodiment repeatedly performs the temporary voltage drop process to temporarily decrease the voltage as described above during the power generation characteristic recovery operation, so as to further increase the voltage of the fuel cell 10 from the limiting voltage Vlim. The power generation characteristic recovery process is specifically performed by the following procedure.
At step S110, the controller 20 specifies a dropped voltage Vc which is a minimum voltage of the fuel cell 10 (target value of voltage drop) in the temporary voltage drop process, based on the target increase amount ΔV, as the processing condition of the temporary voltage drop process. More specifically, the controller 20 obtains the dropped voltage Vc as described below.
By this experiment, the inventors of the present invention have found that there is a linear relationship between the amount of voltage drop in the temporary voltage drop process and the amount of voltage increase by the temporary voltage drop process, such that the amount of voltage increase increases at a substantially fixed rate with an increase in amount of voltage drop. It has also been found that the linear relationship is substantially constant, irrespective of the value of electric current of the fuel cell.
The controller 20 stores in advance a map representing the relationship between the amount of voltage drop and the amount of voltage increase similar to
At step S120, the temporary voltage drop process is performed repeatedly at predetermined cycles T and a predetermined number of times to temporarily decrease the voltage of the fuel cell 10 to the dropped voltage Vc specified at step S110 for a specific fixed period. This increases the voltage of the fuel cell 10 from the limiting voltage Vlim as described in
At step S130, the controller 20 determines whether an appropriate amount of voltage increase is obtained by the temporary voltage drop process. More specifically, the controller 20 measures the increased voltage of the fuel cell 10, calculates a difference between the target increase amount ΔV as the target value and an actual amount of voltage increase, and determines whether the difference is in a predetermined allowable range (for example, about ±10%).
When the difference is out of the allowable range, the controller 20 corrects the map described in
When the appropriate value is obtained as the target increase amount ΔV in the temporary voltage drop process at step S120 or after correction of the map at step S130 is completed, the controller 20 terminates the power generation characteristic recovery operation. The controller 20 then performs the degradation avoidance operation until there is another need to increase the voltage of the fuel cell 10 (step S40). The controller 20 returns the operation control to the high-temperature operation of step S25 when the power generation performance of the fuel cell 10 is recovered from the critical state during the degradation avoidance operation, and returns the operation control to the ordinary operation when the fuel cell 10 is not hot in the high-temperature state (flow shown by the broken line arrows).
As described above, even after the fuel cell 10 falls into the high-temperature state to have degradation of the power generation performance to the critical range, the fuel cell system 100 of the embodiment performs the power generation characteristic recovery operation to reach the voltage of the fuel cell 10 to the target voltage. This improves the controllability of the fuel cell 10 in the high temperature state. The power generation characteristic recovery operation specifies the processing condition of the temporary voltage drop process according to the target voltage, thus enabling the voltage of the fuel cell 10 to be adequately controlled. Additionally, the power generation characteristic recovery operation feeds back the actual amount of voltage increase by the temporary voltage drop process to the map for specifying the processing condition. This further improves the controllability of the fuel cell 10.
In the power generation characteristic recovery operation of the second embodiment, after obtaining the target increase amount ΔV at step S110, the controller 20 specifies a voltage rise rate Vry as a recovery rate of voltage in the temporary voltage drop process, based on the target increase amount ΔV (step S111). The controller 20 uses a relationship between an increase rate of voltage (voltage rise rate) for recovery of voltage in the temporary voltage drop process and an amount of voltage increase described below, in order to obtain the specified value of the voltage rise rate Vrv.
As shown by these graphs, the lower decrease rate of the current density when decreasing from Ihigh to Ilow, i.e., the higher voltage rise rate, leads to the higher voltage value after the change. The inventors of the present invention have accordingly found that the temporary voltage drop process increases the amount of voltage increase with an increase in recovery rate of the voltage. In other words, the inventors of the present invention have found that the temporary voltage drop process increases the degree of improvement in performance of the fuel cell with an increase in voltage rise rate. In the fuel cell system of the second embodiment, the controller 20 uses a map described below to specify the processing condition of the temporary voltage drop process.
The controller 20 refers to this map to obtain the voltage rise rate Vry against the target increase amount ΔV (step S111). The controller 20 then performs the temporary voltage drop process to decrease the voltage of the fuel cell 10 to a predetermined dropped voltage Vc, keep the voltage of the fuel cell 10 at the dropped voltage Vc for a predetermined time period and recover the voltage of the fuel cell at the voltage rise rate Vry (step S120). The fuel cell system 100 of the second embodiment may adjust the execution interval of the temporary voltage drop process (time interval between a voltage increase and a subsequent voltage drop) according to the voltage rise rate Vrv, in order to perform the temporary voltage drop process at the predetermined cycles T.
As described above, the fuel cell system of the second embodiment refers to the relationship obtained in advance and specifies a voltage rise rate as one processing condition of the temporary voltage drop process based on a desired amount of voltage increase, so as to achieve desired recovery of power generation characteristics of the fuel cell 10. This improves the controllability of the fuel cell 10 during high load operation. It may be construed that the fuel cell system of the second embodiment refers to the relationship obtained in advance and specifies a current decrease rate in the temporary voltage drop process, based on a desired amount of voltage increase.
When detecting that the fuel cell 10 is in the high temperature state during ordinary operation, the controller 20 starts measurement of the accumulated time when the fuel cell 10 is in the high temperature state (hereinafter referred to as “high temperature duration time”) and starts high-temperature operation (steps S24 and S25). This high temperature duration time is used to specify the processing condition of the temporary voltage drop process during power generation characteristic recovery operation. The high temperature measurement time may be reset when a predetermined time has elapsed after the operating temperature of the fuel cell 10 decreases to cause the fuel cell 10 not to be in the high temperature state.
In the power generation characteristic recovery operation (
Under the fixed condition of the temporary voltage drop process, the amount of voltage increase by the temporary voltage drop process increases with an increase in high temperature duration time. The increase rate in amount of voltage increase is reduced with an increase in high temperature duration time. The amount of voltage increase is converged to a maximum value when the high temperature duration time exceeds a predetermined value.
The inventors of the present invention have found that this relationship between the high temperature duration time and the amount of voltage increase is obtainable with respect to each dropped voltage as the minimum voltage in the temporary voltage process. The fuel cell system of the third embodiment refers to maps showing the relationship among the high temperature duration time, the amount of voltage increase and the dropped voltage and specifies the dropped voltage Vc as the processing condition of the temporary voltage drop process, based on the high temperature duration time Td and the target increase amount ΔV.
At step S112, the controller 20 selects a map suitable to determine the target increase amount ΔV against the high temperature duration time Td obtained at step S105 and obtains the dropped voltage Vc corresponding to the selected map. This dropped voltage Vc is specified as the processing condition of the temporary voltage drop process. The maps of
As described above, the fuel cell system of the third embodiment specifies the adequate processing condition of the temporary voltage drop process, based on the high temperature duration time Td immediately before execution of the temporary voltage drop process in addition to the target increase amount ΔV. This accordingly improves the controllability of the fuel cell 10 during high load operation.
The above third embodiment specifies the dropped cell voltage Vc as the processing condition of the temporary voltage drop process, based on the target increase amount ΔV and the high temperature duration time Td. As shown in the graphs of
The fuel cell system of the fourth embodiment performs power generation characteristic recovery operation described below, upon determination that the fuel cell 10 falls into the critical state during the high temperature state and upon a request of voltage increase given to the fuel cell 10. Like step S100 described in the first embodiment (
At step S210, the controller 20 obtains a present cathode potential φi of the fuel cell 10. The cathode potential φi is obtained by Equation (1) given below using a present cell voltage Vci of the fuel cell 10, a cell resistance R of the fuel cell 10 obtained from the measurement value of the impedance measurement unit 93 and a present current density I of the fuel cell 10:
φi=Vci+I×R (1)
At step S220, the controller 20 refers to this map and obtains the present catalyst utilization rate φi against the present cathode potential φi (shown by the broken line arrows). At step S230, the controller 20 substitutes the present catalyst utilization rate φi, the target increase amount ΔV, the cell resistance R and a present operating temperature T of the fuel cell 10 into Tafel equation-based Equation (2) given below and obtains a target catalyst utilization rate φt as a target value of catalyst utilization rate after the temporary voltage drop process:
ΔV=(R×T/α×F)×ln(φt/φi) (2)
wherein α represents a transfer coefficient of cathode reaction and is generally a value between 0.5 and 1.0, and F represents Faraday constant.
At step S240, the controller 20 refers to the map described in
Vc=φ
t
−I×R (3)
At step S260, the controller 20 repeatedly performs the temporary voltage drop process to maintain the dropped voltage Vc obtained at step S250 for a predetermined time period, at predetermined cycles T and a predetermined number of times. At step S270, the controller 20 measures an actual amount of voltage increase of the fuel cell 10 in the temporary voltage drop process and calculates a difference from the target increase amount ΔV as the target value. When the difference is out of a predetermined allowable range (for example, about ±10%), the controller 20 corrects the map described in
As described above, the fuel cell system of the fourth embodiment specifies the dropped voltage Vc as the processing condition of the temporary voltage drop process, based on the target increase amount ΔV obtainable from the target voltage and the catalyst utilization rate φi indicating the operating state of the fuel cell 10 immediately before execution of the temporary voltage drop process. One of the reasons for recovery of the power generation characteristics of the fuel cell 10 by the temporary voltage drop process is that the temporary current increase reduces the oxide layer of the catalyst and improves the catalyst utilization rate. Accordingly, setting the processing condition of the temporary voltage drop process based on the catalyst utilization rate more directly controls the degree of improvement in power generation performance of the fuel cell 10, thus ensuring output control of the fuel cell 10 with high accuracy.
In the course of the temporary voltage drop process, in some cases, the shortage of the output of the fuel cell 10 may be compensated by the output of the secondary battery 81. As described above, however, the SOC of the secondary battery 81 has a predetermined lower limit value. In the state that the SOC of the secondary battery 81 is remarkably low, compensation by the secondary battery 81 may be difficult in the course of the temporary voltage drop process. After setting the processing condition of the temporary voltage drop process at step S110, the fuel cell system of the fifth embodiment accordingly performs a preparation process to ensure compensation by the secondary battery 81 during repeated execution of the temporary voltage drop process (step S115).
Upon determination that the compensation of output by the secondary battery 81 is needed, the controller 20 detects the present SOC of the secondary battery 81 (step S310). Upon determination that no compensation of output by the secondary battery 81 is needed, on the contrary, the controller 20 returns to the power generation characteristic recovery operation and repeatedly performs the temporary voltage drop process at the predetermined cycles T and a predetermined number of times (step S120 in
At step S320 (
As the process flow of and after step S330 (
Upon determination that the SOC of the secondary battery 81 becomes lower than the lower limit value when the secondary battery 81 compensates for the shortage of electric power, the controller 20 resets the lower limit value to a smaller value and determines whether the shortage of electric power is compensable by the secondary battery 81 (step S330). In other words, the controller 20 resets the lower limit value of the SOC of the secondary battery 81 to a second lower limit value which is smaller than the initial setting of the lower limit value and determines whether the SOC of the secondary battery 81 becomes lower than the second lower limit value when the secondary battery 81 compensates for the shortage of electric power in the temporary voltage drop process.
Upon determination that the shortage of electric power in the temporary voltage drop process is compensable by changing the lower limit value of the SOC of the secondary battery 81, the controller 20 changes the lower limit value of the SOC of the secondary battery 81 to the second lower limit value (step S340). The lower limit value of the SOC of the secondary battery 81 is set to prevent degradation of the secondary battery 81 due to the insufficient state of charge. The load applied to the secondary battery 81 is reduced by improvement in power generation performance of the fuel cell 10. The fuel cell system of the fourth embodiment dares to temporarily reduce the limitation of the SOC of the secondary battery 81, so as to ensure execution of the temporary voltage drop process.
Upon determination that the shortage of electric power in the temporary voltage drop process is not compensable by changing the lower limit value of the SOC of the secondary battery 81, on the other hand, the controller 20 changes the processing condition of the temporary voltage drop process (step S350). More specifically, the controller 20 makes a correction to increase the value of the dropped voltage Vc, in order to reduce the shortage of electric power during execution of the temporary voltage drop process. After changing the lower limit value of the SOC or after changing the dropped voltage Vc, the controller 20 returns to the power generation characteristic recovery operation and starts execution of the temporary voltage drop process (step S120 in
As described above, the fuel cell system of the fifth embodiment makes preparations to enable the secondary battery 81 to compensate for the electric power, so as to ensure execution of the temporary voltage drop process. Accordingly, this certainly improves the power generation performance of the fuel cell 10 during high load operation.
The present invention is not limited to the embodiments or aspects described above but may be implemented by various other aspects within the scope of the invention. Some examples of possible modifications are given below.
In each of the embodiments described above, the fuel cell system is mounted on the fuel cell vehicle. The fuel cell system of each of the embodiments may, however, not be necessarily mounted on the fuel cell vehicle. The fuel cell system may be mounted on another device or system as the power supply source to supply electric power responding to an external request.
In each of the embodiments described above, the controller 20 sets the dropped voltage Vc, the voltage rise rate Vry or the lower voltage retention period as the processing condition of the temporary voltage drop process, based on the target increase amount ΔV. The target increase amount ΔV is unequivocally related to the increased voltage Vp after execution of the temporary voltage drop process, so that this is construed that the processing condition is set, based on the increased voltage Vp which is the target voltage after execution of the temporary voltage drop process. Accordingly, the controller 20 may use a map specified in advance to represent the relationship between the increased voltage Vp and the processing condition of the temporary voltage drop process, instead of the map described in the above embodiment. The controller 20 may also use a relationship between the target voltage Vt and the processing condition of the temporary voltage drop process, which is specified in advance, and set the processing condition of the temporary voltage drop process based on the target voltage Vt.
The controller 20 may set another processing condition as the processing condition of the temporary voltage drop process. For example, the controller 20 may set the cycle T of repeatedly performing the temporary voltage drop process, based on the increased voltage Vp or the target increase amount ΔV. The controller 20 may set a plurality of processing conditions, based on the increased voltage Vp or the target increase amount ΔV. For example, the controller 20 may set both the dropped voltage Vc and the voltage rise rate Vrv, based on the increased voltage Vp or the target increase amount ΔV.
The third embodiment describes above detects the high temperature duration time Td as the operating state of the fuel cell 10 immediately before execution of the temporary voltage drop process and specifies the processing condition of the temporary voltage drop process, based on the target increase amount ΔV and the high temperature duration time Td. The operating state of the fuel cell 10 detected for determining the processing condition of the temporary voltage drop process may, however be another element. Concrete examples include:
cell voltage
impedance
current density
stoichiometric ratio of reactive gas; and
inlet pressure or outlet pressure (back pressure).
The “stoichiometric ratio” herein means a ratio of an actual supply amount of cathode gas to a theoretically required amount of cathode gas for a certain amount of power generation of the fuel cell (theoretical consumption of cathode gas). The “inlet pressure” means a pressure on the supply side of the reactive gas of the fuel cell 10. The “outlet pressure” means a pressure on the discharge side of the reactive gas of the fuel cell 10.
The processing condition of the temporary voltage drop process may be specified, based on at least one of the increased voltage Vp as the target voltage after execution of the temporary voltage drop process and the above elements of the operating state of the fuel cell 10. The processing condition of the temporary voltage drop process may be specified, for example, based on the combination of the increased voltage Vp, the high temperature duration time Td and the cell voltage or may be specified, based on a combination of more multidimensional elements.
Each of the embodiments described above starts the high-temperature operation (step S25) after detecting the high temperature state of the fuel cell 10 and starts the power generation characteristic recovery operation (step S60) during execution of the degradation avoidance operation of the fuel cell 10 (step S40). Detection of the high temperature state of the fuel cell 10 may, however, be omitted, and the high-temperature operation and the degradation avoidance operation may also be omitted. The controller 20 may perform the power generation characteristic recovery operation, for example, upon detection of drying of the electrolyte membranes of the fuel cell 10 or degradation of the power generation performance.
In each of the embodiments described above, in order to specify the processing condition of the temporary voltage drop process, the controller 20 uses the map representing the relationship between the target increase amount ΔV and the processing condition of the temporary voltage drop process or the map representing the relationship among the target increase amount ΔV, the operating state of the fuel cell 10 and the processing condition of the temporary voltage drop process. The controller 20 may, however, not necessarily use these maps but may use a predetermined relationship such as mathematical expressions or functions and set the processing condition of the temporary voltage drop process based on the target increase amount ΔV or the operating state of the fuel cell 10. The controller 20 may not necessarily use the relationship expressed by any of these maps and mathematical expressions. The controller 20 may set the processing condition of the temporary voltage drop process, based on at least the increased voltage Vp which is the target voltage after execution of the temporary voltage drop process (including a value unequivocally determinable from the increased voltage Vp).
Each of the embodiments described above controls the electric current after execution of the temporary voltage drop process to be equal to the electric current immediately before the start of voltage drop. The electric current after execution of the temporary voltage drop process may alternatively be controlled to be different from the electric current immediately before the start of voltage drop.
In the fifth embodiment described above, the controller 20 reduces the lower limit value of the SOC of the secondary battery 81 at step S340. The controller 20 may alternatively cancel the limitation of the SOC of the secondary battery 81 at step S340.
Each of the embodiments described above corrects the map based on the observed value of the voltage of the fuel cell 10 and the target increase amount ΔV, after execution of the temporary voltage drop process. The map correction process may, however, be omitted.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2011-259040 | Nov 2011 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2012/007266 | 11/13/2012 | WO | 00 | 5/23/2014 |
