This application is related to control of a fuel cell vehicle having a differential pressure flow meter to measure humidity at the cathode inlet of a fuel cell stack.
Fuel cell vehicles harness a chemical reaction between hydrogen and oxygen to generate electricity, and generally operate more efficiently when the oxygen and hydrogen reactants are pressurized. For the air (oxygen) supply system, this may be accomplished with an air compressor upstream of the fuel cell stack and a throttle valve downstream of the stack operated to control the pressure differential across the stack using sensors to measure the air flow and air pressure within the system. A Fuel Cell Control Unit (FCCU) or other vehicle controller(s) determines the target air flow rate and pressure to provide a requested electric power output, and controls the compressor, throttle valve, and/or other actuators accordingly.
Humidity within the fuel cell stack may affect both performance and longevity of the fuel cells within the stack. Fuel cell systems may include a humidifier to selectively increase the humidity of the ambient air supplied to the fuel cell stack by the air compressor. Various strategies have been developed to measure or infer the humidity including use of an HFR (high frequency resistance) device or a UEGO (universal exhaust gas oxygen) sensor, for example. While suitable for some applications, UEGO sensors were originally developed for relatively warmer engine exhaust gas temperatures and relatively smaller variations in oxygen content such that they may involve more challenging calibration protocols for desired performance in fuel cell applications.
In various embodiments, a vehicle includes a fuel cell stack having a cathode inlet, a humidifier having an airflow outlet fluidly coupled to the cathode inlet of the fuel cell stack, a mass airflow sensor disposed within an intake airflow upstream of the cathode inlet of the fuel cell stack and upstream of the airflow outlet of the humidifier, and a differential pressure airflow sensor positioned between the airflow outlet of the humidifier and the cathode inlet of the fuel cell stack. The vehicle may also include a controller programmed to operate at least one of the humidifier and the fuel cell stack in response to relative humidity of airflow into the cathode inlet of the fuel cell stack based on a differential pressure signal from the differential pressure airflow sensor. The controller may be further programmed to operate at least one of the humidifier and the fuel cell stack in response to the relative humidity indicated by airflow measured by the mass airflow sensor, airflow measured by the differential pressure airflow sensor, and mass fraction of airflow measured by the differential pressure sensor. The controller may be further programmed to operate at least one of the humidifier and the fuel cell stack in response to mass of water vapor in the intake airflow downstream of the humidifier indicated by differential pressure measured by the differential pressure airflow sensor. The controller may be further programmed to operate at least one of the humidifier and the fuel cell stack in response to a dewpoint temperature of the intake airflow downstream of the humidifier using the mass of water vapor and pressure of the intake airflow at the cathode inlet of the fuel cell stack.
In one or more embodiments, the vehicle may include a temperature sensor and a pressure sensor disposed in the intake airflow between the humidifier and the cathode inlet of the fuel cell stack. The vehicle may also include a humidifier bypass valve disposed upstream of the humidifier, the humidifier bypass valve controlled by the controller in response to the relative humidity of airflow at the cathode inlet of the fuel cell stack as indicated by the mass airflow sensor and the differential pressure airflow sensor. The vehicle may also include an air compressor having an outlet fluidly connected to the cathode inlet of the fuel cell stack upstream of the mass airflow sensor and the humidifier.
Embodiments may include a differential pressure airflow sensor comprising a cone-shaped airflow diverter disposed within a conduit fluidly coupling airflow from the humidifier to the cathode inlet of the fuel cell stack, and further disposed between a first pressure sampling port in the conduit positioned upstream of an apex of the diverter and a second pressure sampling port in the conduit positioned downstream of a base of the diverter. A transducer may be coupled to the first and second pressure sampling ports and provide a signal corresponding to the differential pressure. In various other embodiments, the differential pressure airflow sensor comprises a pitot tube.
Embodiments may also include a differential pressure airflow sensor comprising a conduit fluidly coupling airflow from the humidifier to the cathode inlet of the fuel cell stack and including a frustoconical section having an upstream diameter larger than a downstream diameter, a first pressure sampling port upstream of the frustoconical section, and a second pressure sampling port downstream of the frustoconical section. A transducer may be coupled to the first and second pressure sampling ports and provide a signal corresponding to the differential pressure.
Embodiments may also include a method for controlling a fuel cell vehicle, comprising, by a controller: controlling at least one of a humidifier and a fuel cell stack responsive to relative humidity of airflow at a cathode inlet of the fuel cell stack, the relative humidity indicated by signals from a differential pressure flow sensor positioned downstream of the humidifier and upstream of the cathode inlet of the fuel cell stack. The method may include controlling the humidifier by controlling airflow through the humidifier. Controlling airflow through the humidifier may include operating a bypass valve to direct at least some intake airflow to the cathode inlet of the fuel cell stack bypassing the humidifier. In one or more embodiments, the relative humidity may be indicated using signals from a mass airflow sensor positioned upstream of the humidifier in combination with the signals from the differential pressure flow sensor. The relative humidity may further be based on temperature and pressure of airflow at the cathode inlet of the fuel cell stack.
In one or more embodiments, a fuel cell system includes an air compressor having an inlet fluidly coupled to ambient, a humidifier fluidly coupled to an outlet of the air compressor, a mass airflow sensor disposed downstream of the air compressor and upstream of the humidifier, a fuel cell stack having a cathode inlet fluidly coupled to an outlet of the humidifier, a differential pressure flow sensor disposed downstream of the humidifier and upstream of the cathode inlet of the fuel cell stack, and a controller programmed to control at least one of the air compressor and the fuel cell stack in response to humidity of airflow to the cathode inlet of the fuel cell stack as indicated by signals from at least the mass airflow sensor and the differential pressure flow sensor. The fuel cell system may include a bypass valve positioned downstream of the compressor and upstream of the fuel cell stack, the bypass valve operated by the controller to reduce airflow through the humidifier in response to humidity of the airflow to the cathode inlet exceeding a corresponding threshold. The differential pressure flow sensor may include a conduit fluidly coupling airflow from the humidifier to the cathode inlet of the fuel cell stack and including a frustoconical section having an upstream diameter larger than a downstream diameter, a first pressure sampling port upstream of the frustoconical section, a second pressure sampling port downstream of the frustoconical section, and a differential pressure transducer coupled to the first and second pressure sampling ports. The controller may be further programmed to adjust speed of the air compressor in response to the humidity of the airflow to the cathode inlet.
Fuel cell systems having a differential pressure flow sensor according to the present disclosure may have one or more advantages. For example, the disclosed differential pressure flow sensors are simple in construction and do not require active control by a vehicle controller (such as needed for use of a UEGO sensor). The differential pressure sensor may be implemented in a short section of molded piping or conduit having a frustoconical section of reducing diameter with pressure sample ports upstream and downstream of the frustoconical section connected to an associated differential pressure transducer with no significant pressure loss over a wide range of operating pressures and humidity. The differential pressure flow sensors require less complex calibration protocols and may use zero differential pressure as a data point indicating zero flow rate.
As required, detailed representative examples of the claimed subject matter are disclosed herein; however, it is to be understood that the disclosed examples are merely representative and may be implemented in various and alternative forms. The figures are not necessarily to scale; some features may be exaggerated or minimized to show details of particular components. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art to variously employ the claimed subject matter.
Fuel cell stacks typically include hundreds of individual fuel cells. A single conventional fuel cell consists of a membrane electrode assembly (MEA) and two flow-field plates which deliver about 0.5 to 1 V during operation. Individual fuel cells are stacked to form the fuel cell stack, and arranged such that a collective supply manifold for fluid feeds is provided to openings of the cathode, anode, and coolant fields. Similar to batteries, the fuel cell slack achieves higher voltage and power output when compared with an individual cell.
One type of fuel cell stack conventionally used in vehicles is the proton exchange membrane (PEM) fuel cell which includes membrane-electrode interfaces, where the membrane may be a solid polymer membrane electrolyte positioned between an anode and cathode. The anode and cathode are connected to respective current collectors, with openings for gas distribution for the reactants entering and exiting the fuel cell. The cells are operated in a humidified state to maintain performance. Water is produced on the cathode side of the membrane at the catalyst layer. Therefore, water vapor has an easier path to move away from the membrane, through the gas diffusion layer, to the cathode flow field. Thus, the overall hydration level of the membrane is strongly influenced by the cathode flow stream, which has a stronger mechanism for dehydrating the membrane because of higher flow rates on the cathode side. If the PEM is not adequately humidified, the conductivity of the protons in the membrane decreases which can affect cell performance. Furthermore, as the level of membrane hydration decreases, the internal resistance may increase, reducing the output voltage and corresponding power. Additionally, low humidity can cause the PEM to dry out which may result in degradation of the membrane over time. On the other hand, excess humidity also can cause issues in performance by inhibiting the reactants from diffusing to the catalyst sites. This result is caused by Hooding of the electrodes and gas channels if the water removal is insufficient, reducing the PEM's efficiency and power.
As such, control of the cathode inlet hydration level has a strong influence on the overall hydration level of the stack membranes, and the humidity level at the cathode side inlet into a PEM fuel cell stack is important for overall operation of the fuel cell stack. Thus, a humidity sensor is typically provided at the cathode inlet to measure the humidity level. Controlling the water balance for the PEM requires accurate water vapor measurements at temperatures approaching 100° ° C. and pressures up to 3 bar absolute, often at or near saturation levels. Non-industrial humidity sensing technologies typically cannot meet the demands under such harsh environments. The present disclosure uses a differential pressure sensor flow meter in combination with various other sensors commonly used in fuel cell systems, such as a mass airflow sensor, temperature, pressure, etc. to provide an indication of relative humidity of the airflow at the cathode inlet.
Fuel supply from a hydrogen storage tank system 215 is enabled by controller 270 with the supply pressure to the fuel cell stack 212 controlled by a pressure control device 217 that may be controlled by controller 270. The pressure control device 217 takes input from a pressure sensor 218 at the inlet of the fuel cell stack anode 220 to control the hydrogen fuel pressure to the stack 212. An air compressor 222 controlled by controller 270 increases the ambient pressure of air filtered by air filter 223 based on signals from mass airflow sensor (MAF) 225, pressure sensor 227, temperature sensor 229, and/or differential pressure flow sensor 224 to control the pressure, temperature, and humidity of airflow entering the cathode inlet of the fuel cell stack cathode 226. Outlet airflow from compressor 222 may pass through bypass valve 260 before passing through humidifier 232 to supply cathode 226 with air (oxygen). Bypass valve 260 is controlled by controller 270 to selectively allow at least a portion of the airflow from compressor 222 to bypass humidifier 232 to control humidity of the airflow entering the cathode inlet.
The system is generally controlled such that the pressure on either side of the fuel cell membrane (not shown) between anode 220 and cathode 226 is maintained within a certain tolerance, for example around 600 mbar. The tolerance may vary depending upon the fuel cell stack design. Any overpressure or under pressure may result in system shut down to protect the fuel cell stack membrane.
As previously described, for efficient power generation, the fuel cell stack 212 may require humidified gases. Anode gas humidity may be maintained by recirculating the anode gas mixture from the fuel cell stack outlet using a blower 228 to mix feed gas from the hydrogen storage tank system 215 with the recirculated hydrogen. Cathode gas (air) humidity is maintained by controlling humidifier 232, such as by controlling airflow through humidifier 232 using bypass valve 260 and/or controlling water flow to humidifier 232, for example.
At the anode side of the fuel cell stack outlet, a water knock-out 236 and purge/drain valve 240 are provided to remove water from the anode outlet. This removed water is passed to exhaust system 242 of the vehicle 214. At the cathode side of the fuel cell stack outlet, a back pressure throttle valve 244 fluidly connects the humidifier 232 and the exhaust system 242. Position of throttle valve 244 and compressor 222 are controlled by controller 270 to maintain a desired cathode subsystem pressure. A throttle valve position signal may be used by controller 270 to determine when the throttle valve 244 is with a predetermined range of a wide-open throttle (WOT) position and/or at WOT position.
where P1 represents pressure, u1 represents airflow velocity, and A1 represents area of the opening surrounding the diverter 310 within the conduit 312 at the first pressure sampling port, and P2 represents pressure, u2 represents airflow velocity, and A2 represents area of the opening surrounding the diverter 310 within the conduit at the second pressure sampling port.
where P1 represents pressure, u1 represents airflow velocity, and A1 represents area within the conduit 512 at the first pressure sampling port 520, and P2 represents pressure, u2 represents airflow velocity, and A2 represents area within the conduit 512 at the second pressure sampling port 522.
The density for a mixed gas (such as humidified air containing air and water vapor) can be calculated using the individual fraction or partial pressure in addition to the temperature and sum of partial pressures. Representative equations based on the universal gas law are generally known by those of skill in the art and are provided below for convenience without detailed explanation:
Using the above, the differential pressure between the sampling ports of the differential pressure flow sensor may be determined based on the following:
Using Equation (1) assuming values for the partial fraction of the water vapor of dry air in the first case, and no air in the second case provides:
The mass flow rate from the differential pressure sensor may then be used to determine the dew point temperature (and associated relative humidity) based on the following:
The processes, methods, or algorithms disclosed herein can be deliverable to/implemented by a processing device, processor, controller, or computer, which can include any existing programmable electronic control unit or dedicated electronic control unit. Similarly, the processes, methods, or algorithms can be stored as data and instructions executable by a controller or computer in many forms including, but not limited to, information permanently stored on non-writable storage media such as ROM devices and information alterably stored on writeable storage media such as RAM devices, FLASH devices, MRAM devices and other non-transitory optical media. Alternatively, the processes, methods, or algorithms can be embodied in whole or in part using suitable hardware components, such as Application Specific Integrated Circuits (ASICs), Field-Programmable Gate Arrays (FPGAs), state machines, controllers, or any other hardware components or devices, or a combination of hardware, software, and firmware components.
As illustrated in
While representative examples are described above, it is not intended that these examples describe all possible forms or implementations of the claimed subject matter. The words used in the specification are words of description rather than limitation, and it is understood that various changes may be made without departing from scope of the claims. Additionally, the features of various implementing examples may be combined with one or more features from other examples to form further examples or embodiments of the claimed subject matter whether or not the particular combination of features is explicitly illustrated or described in detail. Although one or more examples or features may have been described as providing advantages over other examples or prior art implementations with respect to one or more desired characteristics, those of ordinary skill in the art recognize that one or more features or characteristics can be compromised to achieve desired overall system attributes, which depend on the specific application and implementation. As such, examples described as less desirable than others or prior art implementations with respect to one or more characteristics are not outside the scope of the disclosure and may be desirable for particular applications.