The present invention relates to degasification of liquids, and more particularly, to removal of gas from a liquid through a flow perturbation element within a fluid channel.
Liquid fuel is often utilized in vehicles, such as aircraft, as a coolant for various systems. The presence of dissolved oxygen in hydrocarbon liquid fuels may be objectionable because the oxygen supports oxidation reactions that yield undesirable by-products. Dissolution of air in liquid fuel results in an approximately 70 ppm oxygen concentration at equilibrium saturation conditions. When aerated fuel is heated between approximately 300° F. and 850° F. the dissolved oxygen initiates free radical reactions of the fuel resulting in deposits commonly referred to as “coke” or “coking.” Coke may be detrimental to the fuel lines and may inhibit combustion. The formation of such deposits may impair the normal functioning of a fuel system, either with respect to an intended heat exchange function or the efficient injection of fuel.
One example Fuel Stabilization Unit (FSU) available for use in aircraft to remove oxygen from the liquid fuel includes a planar fuel channel that receives oxygen-saturated fuel. The fuel channel is lined with an oxygen permeable membrane to remove oxygen from the liquid fuel. An oxygen pressure gradient across the oxygen permeable membrane draws the oxygen from the liquid fuel to produce oxygen-depleted liquid fuel. Although effective, it is desirable to further reduce the size and weight of the FSU while achieving similar or improved oxygen removal.
Accordingly, it is desirable to provide a compact and lightweight fuel system for degassing liquids, such as liquid fuel.
One embodiment fuel system according to the present invention includes a flow perturbation element within a fuel channel. The flow perturbation element includes a shaped gas permeable surface for removing dissolved gas from passing fuel efficiently. A gas permeable membrane is coated on the gas permeable surface and allows the dissolved gas to be transported out of passing fuel into a gas-removal channel. The gas permeable surfaces on the flow perturbation elements provide “active” surface, which allows the fuel channel to be both compact and efficient.
One embodiment fuel system according to the present invention includes a fuel passage that defines an axis. A first gas permeable membrane includes a first distal section and a first proximal section that is relatively nearer to the axis than the first distal section. A second flow perturbation element includes a second gas-removal channel in communication with a second gas permeable membrane. The second gas permeable membrane includes a second distal section and a second proximal section that is relatively nearer to the axis than the second distal section.
One embodiment fuel system includes a fuel channel for receiving fuel having dissolved gas therein. A porous flow perturbation element defines a non-planar flow passage through the fuel channel. A gas permeable membrane is in communication with the fuel channel. A gas-removal channel adjacent the porous flow perturbation element receives the dissolved gas from the fuel through the gas permeable membrane and porous flow perturbation element.
One embodiment fuel system according to the present invention includes a fuel channel having a flow passage between elongated channel walls for receiving fuel having dissolved gas therein. A porous flow perturbation element extends from one of the elongated channel walls into the flow passage. A gas permeable membrane is in communication with the fuel channel. A gas-removal channel adjacent the porous flow perturbation element receives the dissolved gas from the fuel through the gas permeable membrane and porous flow perturbation element.
One embodiment method includes coating a gas permeable membrane adjacent a non-planar fuel channel substrate to produce a non-planar fuel channel flow perturbation element.
The above examples are not intended to be limiting. Additional examples are described below.
The various features and advantages of this invention will become apparent to those skilled in the art from the following detailed description. The drawings that accompany the detailed description can be briefly described as follows:
One form of the ECD 12 is a gas turbine engine, such as in aircraft. Typically, the fuel also serves as a coolant for one or more sub-systems in the aircraft and becomes heated as it is delivered to fuel injectors immediately prior to combustion.
A heat exchange section 18 represents a system through which the fuel passes in a heat exchange relationship. It should be understood that the heat exchange section 18 may be directly associated with the ECD 12 and/or distributed elsewhere in the larger system 10. The heat exchange system 18 may alternatively or additionally include a multiple of heat exchangers distributed throughout the system.
As generally understood, fuel F stored in the reservoir 16 normally contains dissolved oxygen, possibly at a saturation level of 70 ppm. A fuel pump 20 draws the fuel F from the reservoir 16. The fuel pump 20 communicates with the reservoir 16 via a fuel reservoir conduit 22 and a valve 24 to a fuel inlet 26 of the deoxygenator system 14. The pressure applied by the fuel pump 20 assists in circulating the fuel F through the deoxygenator system 14 and other portions of the fuel system 10. As the fuel F passes through the deoxygenator system 14, oxygen is selectively removed into a vacuum or sweep gas system 28. The sweep gas S can be any gas that is essentially free of oxygen.
The deoxygenated fuel Fd flows from a fuel outlet 30 of the deoxygenation system 14 via a deoxygenated fuel conduit 32, to the heat exchange system 18 and to the ECD 12. A portion of the deoxygenated fuel may be recirculated, as represented by recirculation conduit 33 to either the deoxygenation system 14 and/or the reservoir 16. It should be understood that although a particular component arrangement is disclosed in the illustrated embodiment, other arrangements will benefit from the invention.
Referring to
The oxygen permeable membrane 36 allows dissolved oxygen (and other gases) to diffuse through angstrom-size openings, such as voids or pores, but excludes the larger fuel molecules. Alternatively, or in conjunction with the angstrom-size openings, the oxygen permeable membrane 36 utilizes a solution-diffusion mechanism to dissolve and diffuse oxygen through the membrane, while excluding the fuel.
The family of Teflon AF, which is an amorphous copolymer of perfluoro-2,2-dimethyl-1,3-dioxole (PDD) often identified under the trademark “Teflon AF” registered to E. I. DuPont de Nemours of Wilmington, Del., and the family of Hyflon AD, which is a copolymer of 2,2,4-trifluoro-5-trifluoromethoxy-1,3-dioxole (TTD) registered to Solvay Solexis, Milan, Italy have proven to provide effective results as oxygen permeable membranes for fuel deoxygenation. The Teflon AF 2400 and/or Teflon AF 1600 material is believed to use a solution-diffusion mechanism. Given this description, one of ordinary skill in the art will recognize other types of fluoropolymers or other polymer materials to meet their particular needs as an oxygen permeable membrane.
The inlet 26 of the fuel deoxygenator system 14 receives oxygen-rich fuel and an outlet 30 discharges oxygen-depleted fuel. A vacuum port 29 is in communication with the fuel channel 38 for creating an oxygen partial pressure gradient within the fuel channel 38 through the membrane to extract dissolved oxygen and other dissolved gases.
The specific quantity of fuel channels 38 is determined by application-specific requirements, such as fuel type, fuel temperature, and mass flow demand from the engine. Further, different fuels containing different amounts of dissolved oxygen may require different amounts of deoxygenation to remove a desired amount of dissolved oxygen.
Referring to
A backing layer 74, such as porous polyetherimide or other porous material, can be located between the porous support 42 and the oxygen permeable membrane 36. In one example, the backing layer 74 is about 2 mil thick, however, the thickness can be varied depending on the needs of the particular design.
The backing layer 74 can be deposited onto the porous support 42 using a known phase inversion method. In a further example, the backing layer 74 can be deposited using a phase inversion technique disclosed by R. W. Baker, “Membrane Technology and Applications”, Second Edition, John Wiley & Sons, Ltd., p. 96-103.
The flow perturbation elements 55 include gas permeable surfaces 66 through which oxygen is drawn (i.e., “active” surfaces). Pores 70 (shown schematically) of the porous support 42 form a gas permeation passage 68 (i.e. pore 70 network) with the angstrom-size openings of the oxygen permeable membrane 36 and porous backing layer 74 to fluidly connect the fuel channel 38 and the gas-removal channel 40. The backing layer 74 provides a bridge for oxygen transport between the oxygen permeable membrane 36 and the porous support 42. In other words, the porosity of the backing layer 74 provides passages for oxygen to move from the oxygen permeable membrane 36 to the porous support 42. The reason why the backing layer 74 may be needed is that for resistance reduction purposes, the pore size in the porous support 42 sometimes is too big for the oxygen permeable membrane 36 to be coated on directly. If the pore size is fine enough while flow resistance is still at a desired level, the oxygen permeable membrane 36 can be coated on directly on to the porous support 42 without the backing layer 74. The oxygen permeable membrane 36 is coated on the gas permeable surfaces 66 to prevent fuel from passing into the passages 68 and allow dissolved oxygen to be transported from the fuel channel 38 into the gas permeation passages 68 and then into the gas-removal channel 40.
Fuel flowing through the fuel channel 38 is in contact with the oxygen permeable membrane 36. Vacuum via the vacuum port 29 creates an oxygen partial pressure differential (i.e., an oxygen concentration differential) across the oxygen permeable membrane 36 which causes transfer of oxygen dissolved within the fuel through the oxygen permeable membrane 36, porous backing layer 74, and porous support 42, and out of the deoxygenator system 14 through the gas-removal channel 40. Alternatively, the same oxygen partial pressure differential can be created by sweep gas which constantly removes the oxygen in the gas-removal channel 40.
The porous support 42 is fabricated in a known manner by molding, casting, sintering, or other method from a porous polymer, metal foam, porous ceramic, ceramic foam, or polymer foam for example. One example polymer foam includes open cell polyurethane. In a further example, the porous support 42 is resistant to liquid fuel so as not to significantly degrade and has a relatively high porosity to provide uniform vacuum distribution and enable efficient oxygen removal without significant oxygen partial pressure build-up. In some examples, the porous support 42 and the gas-removal channel 40 can be combined as one part.
In the illustrated example, the flow elements 55 are integrated to provide the fuel channel 38 with intricate multi-dimensional flow characteristics. In other words, the flow perturbation elements 55 extend into the flow of fuel through the fuel channel 38 (
Utilizing gas permeable surfaces 66 on the flow perturbation elements 55 in combination with the oxygen permeable membrane 36 and the backing layer 74 provides the benefit of greater oxygen removal efficiency compared to conventional planar fuel channels without “active” flow perturbation elements 55. Therefore, the fuel deoxygenator system 14 can be made more compact for the same performance or be made to remove more oxygen with the same size.
In one example, the configuration of the fuel channel 38 is designed to maximize oxygen exposure to the oxygen permeable membrane 36 to increase the amount of dissolved oxygen removed from the fuel. In one example, this is accomplished by increasing the surface area of the oxygen permeable membrane 36. In another example, this is accomplished by exposing active oxygen permeable membrane 36 area to the flow region where oxygen concentration is relatively high. In a further example, this is accomplished by providing mixing and/or optimal fuel flow patterns through the fuel channel 38. In one example, the fuel channels 38 are small enough to provide desired oxygen contact with the oxygen permeable membrane 36 and large enough so as not to undesirably restrict fuel flow.
The flow perturbation elements 55 enhance deoxygenation by increasing the efficiency due to higher surface-to-volume ratio and by perturbing the flow near the membrane 36 surface, thus enhancing oxygen transport from the bulk of the fuel directly to the surface of the membrane. The flow perturbation elements 55 of the deoxygenator system 14 therefore enhance contact between oxygen and the oxygen permeable membrane 36 to increase mass transport of dissolved oxygen.
Each flow perturbation element 55 defines a forward surface F and an aft surface A. The forward surface F faces a direction approximately opposite to the fuel flow direction and the aft surface A faces in a direction with the fuel flow direction.
In the illustrated example, the forward surface F includes a curved section 50a and a planar section 50b, and the aft surface A includes a planar section 52. The planar section 50b and planar section 52 define a first flow perturbation element thickness T1. and the curved section 50a and the planar section 52 define a second flow perturbation element thickness T2. In this example, the thickness T1 is greater than the thickness T2. Utilizing a flow perturbation element 55 having a relatively thicker base facilitates ejection from a mold during manufacturing of the porous support 42 (e.g., injection molding).
As shown in the embodiment of
The flow perturbation elements 55 in the illustrated example define troughs sections 76a, 76b, and 76c and peak sections 78a, 78b, and 78c in the respective fuel channels 38a, 38b, and 38c. The trough sections 76a, 76b, and 76c are located farther from the respective central axes A than the peak sections 78a, 78b, and 78c.
In the illustrated embodiment, the trough sections 76a of fuel channel 38a correspond to the peak sections 78b of fuel channel 38b. That is, the trough sections 76a are aligned along an axial direction along the axes A with the peak sections 78b. The trough sections 76b of fuel channel 38b correspond to the peak sections 78c of fuel channel 38c. In other words, each fuel channel 38a, 38b, and 38c is symmetric relative to a plane along its respective axis A.
The flow perturbation elements 55 include corners 79 to provide a smooth transition between the trough sections 76a, 76b, 76c and the peak sections 78a, 78b, and 78c. This provides the benefit of eliminating relatively sharp bends in the oxygen permeable membranes 36a, 36b, and 36c. In one example, the corners 79 are rounded to a radius of curvature such as about 0.015 inches.
In the illustrated embodiment, structural members 80 support the oxygen permeable membranes 36a, 36b, and 36c and define the gas-removal channels 40. In one example shown in
Optionally, the backing layer 74 (
In the above examples, the oxygen permeable membrane 36 is coated adjacent the backing layer 74, the support structure 80, or other substrate. In one example of making the oxygen permeable membrane, the oxygen permeable membrane 36 is prefabricated with or without the backing layer 74 in flat or pre-shaped form and then formed to a shape of the support structure 80, or other substrate. In another example, the oxygen permeable membrane 36 is coated in situ adjacent the backing layer 74, support structure 80, or other substrate. If the pore size in support structure 80 is fine enough while flow resistance is still at proper level, the oxygen permeable membrane 36 can be coated on directly on to the porous support 42 without the backing layer 74. A flow channel does not have to have the same type or size of the flow perturbation elements 55. Given this description, one of ordinary skill in the art will recognize that different types and sizes of the flow perturbation elements 55 can be used to adjust the performance.
The oxygen permeable membrane is formed, for example, by spray coating, electro-spray coating (e.g., wherein electrical field is used to direct the spray to desired areas), brush coating, solution cast coating, vapor deposition coating, plasma coating, or solventless vapor coating. These methods are applicable to forming the gas permeable membrane 36 by prefabrication and are thought to be applicable to in situ formation of the gas permeable membrane 36.
In one prefabrication example, the oxygen permeable membrane 36 is prefabricated in a known manner and shape-formed onto the support structure 80 which allows gas to flow within, or other substrate. A vacuum or pressure is used to conform the prefabricated oxygen permeable membrane 36 with or without the backing layer 74 to the non-planar shape of the support structure 80, or other substrate. Optionally, heat is used to form the oxygen permeable membrane 36 to the non-planar shape of the support structure 80, or other substrate. In a further example, the backing layer 74 (
In one example of in situ formation, the oxygen permeable membrane 36 is formed adjacent the backing layer 74, support structure 80, or other substrate. This eliminates additional steps associated with conforming the oxygen permeable membrane 36 with the shape of the support structure 80, or other substrate.
One example in situ coating method includes solventless vapor coating. In solventless vapor coating, a desired amount of precursor materials, such as monomers for the formation of amorphous fluoropolymer, is vaporized. The vaporized monomers are deposited onto the flow perturbation element 55 to form a green coating. The term “green” refers generally to a coating that is not fully developed. Here the green coating is not yet fully developed because the monomers have not yet been polymerized.
The porous support 42 and green coating are then heated at a selected temperature in an inert atmosphere to polymerize the green coating and thereby form the oxygen permeable membrane 36. The selected temperature depends on the selected type of polymer, and is generally known for polytetrafluoroethylene. The disclosed vapor deposition process provides a uniform thin membrane on the non-planar shape of the porous support 42 as in
Alternatively, a plasma coating method is utilized to coat the oxygen permeable membrane 36 on a non-planar surface. Plasma coating includes introducing precursor materials, such as monomers, into a plasma generator. A plasma generated in the plasma generator bombards the monomers with electrons. Impact between the electrons and monomers fragments thereby activates the monomers. The activated fragments are coated onto the non-planar shape and polymerize to form the oxygen permeable membrane 36. Similar to the vapor deposition process, plasma coating is thought to provide a uniform thin membrane having a thickness between about 100 nm and 2 μm on the non-planar shape.
Alternatively to vapor or plasma coating, solution casting has been used to form planar membranes and is thought to be applicable to fabricating the oxygen permeable membrane 36 on a non-planar surface. In one example of solution casting, precursor materials are mixed in solution with a solvent. The permeable surfaces 66 (
In another example, coating of the oxygen permeable membrane 36 is accomplished by chemical vapor deposition (CVD) as described by Sharangpani and Singh (Rev. Sci. Instrum. 68 (3), March 1997). In a further example, coating of the oxygen permeable membrane 36 is accomplished by laser ablation as described by Blanchet (Appl. Phys. Lett. 62 (5), 1 Feb. 1993).
The foregoing description is exemplary rather than defined by the limitations within. Many modifications and variations of the present invention are possible in light of the above teachings. One of ordinary skill in the art would recognize that certain modifications would come within the scope of this invention. It is, therefore, to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described. For that reason the following claims should be studied to determine the true scope and content of this invention.