1. Field of the Inventions
The present inventions are related to fuel cartridges that may be used, for example, in combination with fuel cells.
2. Background
Many devices are fueled by fuel that is stored in a fuel cartridge. Although the present inventions are not limited to fuel cartridges that are used in conjunction with any particular type of device, fuel cells are one example of a device that may consume fuel stored in a fuel cartridge, and the present inventions are discussed in the context of fuel cells for illustrative purposes only. Fuel cells convert fuel and oxidant into electricity and a reaction product. Fuel cells that employ hydrogen as the fuel and oxygen as the oxidant, for example, produce water and/or water vapor as the reaction product. Fuel cartridges used in conjunction with fuel cells typically store pressurized gaseous fuel or a fuel containing substance, such as a chemical compound, that releases the gaseous fuel in the presence of water or a catalyst.
The inventors herein have determined that conventional fuel cartridges, especially those used in conjunction with fuel cells, are susceptible to improvement. More specifically, the inventors herein have determined that it can be undesirable to store large amounts of gaseous fuel (such as hydrogen) in a fuel cartridge because such storage can raise safety concerns and provide less than optimal energy density. The inventors herein have also determined that, in those instances where fuel containing substances are stored in a fuel cartridge, conventional apparatus for causing the gaseous fuel to be released do not provide precise control over the process. This lack of control can lead to the release of more fuel than is required by the fuel cell, which also raises safety concerns. Thus, the inventors herein have determined that it would be desirable to provide fuel cartridges that facilitate precise control over the conditions associated with the release of gaseous fuel from the fuel containing substance.
Detailed description of preferred embodiments of the inventions will be made with reference to the accompanying drawings.
The following is a detailed description of the best presently known modes of carrying out the inventions. This description is not to be taken in a limiting sense, but is made merely for the purpose of illustrating the general principles of the inventions. Additionally, although the inventions herein are discussed in the context of fuel cells and host devices powered by fuel cells, the fuel cartridges described herein are not limited solely to use with fuel cells. With respect to fuel cells, the present inventions are applicable to a wide range of fuel cell technologies, including those presently being developed or yet to be developed. Thus, although various exemplary fuel cartridges are described below with reference to a proton exchange membrane (PEM) fuel cell, other types of fuel cells, such as solid oxide fuel cells, are equally applicable to the present inventions. It should also be noted that detailed discussions of fuel cell structures, the structures of other fuel consuming devices, and the internal operating components of host devices powered thereby that are not pertinent to the present inventions have been omitted for the sake of simplicity.
As illustrated for example in
There are a variety of advantages associated with such fuel cartridges and the fuel consuming systems that employ them. For example, the present inventions facilitate the storage of gaseous fuel in a non-gaseous state. This provides increased safety and energy density as compared to fuel cartridges that store fuel in a gaseous state. The present inventions also allow the release of fuel from a fuel containing substance 106 to be precisely controlled by simply controlling the actuation of the heaters 108. For example, individual heaters 108 may be actuated at predetermined intervals as long an fuel is being drawn from the cartridge 100. Alternatively, the host device may be used to calculate the amount of fuel required to, for example, power a fuel cell based on operating parameters such as current draw or voltage and actuate individual heaters 108 accordingly.
The fuel storage areas 104, which in the exemplary implementation are formed in a plate 116 positioned within the housing 102, may be of any suitable size, shape and number. The precision at which the cartridge 100 can produce gaseous fuel will increase with the number of fuel storage areas 104 (for a given overall volume of fuel containing substance 106 within the cartridge). Preferably, the density of the fuel storage areas 104 will be maximized by employing a shape that facilitates the minimization of the space between the fuel storage areas. Although the present inventions are not limited to any particular shape, the exemplary fuel storage areas 104 are hexagon-shaped and positioned in the array illustrated in
Although the present inventions are not limited to any particular fuel or fuel containing substance, one type of fuel containing substance is fuel containing chemical compounds that are used to provide hydrogen (the fuel used in the exemplary PEM fuel cell). Sodium borohydride, for example, is a stable compound in a solution or gel that will readily form hydrogen in the presence of heat, as illustrated by the following chemical equation: NaBH4+2H2O→4H2+NaBO2. The solution should also contain a sufficient concentration of sodium hydroxide to prevent the formation of any appreciable amount of hydrogen during storage. Other exemplary fuel containing substances include borane hydrozene complexes and metal hydrides.
One end of each of the fuel storage areas 104 in the exemplary fuel cartridge 100 will be open so that the gaseous fuel can escape into the open region 110 from the fuel storage areas when the fuel containing substance 106 is heated. As such, the fuel containing substance 106 should be relatively viscous, i.e. viscous enough to remain in the fuel storage areas 104 without substantial leakage regardless of the orientation of the fuel cartridge 100. Suitably viscous fuel containing substances include gels and viscous solutions containing up to 40% sodium borohydride by weight, 0.1 to 15% gelling agent (such as a polyethylene amine of molecular weigh 2000 to 20000) by weight, and 0-10% aqueous sodium hydroxide by weight. This substance, which has an energy density of about 4000 watt-hour/kilogram, will form hydrogen when heated to about 110° C. to 150° C. Depending on the fuel containing substance employed, heating temperatures may range from 80° C. to 500° C.
During manufacture, the viscous fuel containing substance 106 may, for example, be pressed into the fuel storage areas 104. Any excess fuel containing substance 106 may then be scraped off of the surfaces of the plate 116.
As illustrated for example in
The exemplary heaters 108 are preferably resistors that may be selectively actuated, by driving current through the selected resistor(s), to generate heat that is applied to the fuel containing substance 106 in selected fuel storage areas 104. Other suitable heaters include, for example, tubes in a heat exchanger through which a heat transfer fluid flows. The storage areas 104, heaters 108 and plate 116 are respectively configured such that the actuation of a particular heater will only cause the fuel containing substance 106 associated with that heater to emit gaseous fuel and will not substantially heat the fuel containing substance (i.e. apply enough heat to cause the release of fuel) associated with other heaters. As illustrated for example in
It should be noted that the present inventions are not limited to any particular heater system. For example, resistors and/or other heater devices, may be controlled by way of an addressing system such as those disclosed in the ink jet printer context in commonly assigned U.S. Pat. Nos. 5,644,342 and 6,007,186, which are assigned to the Hewlett-Packard Company and incorporated herein by reference.
Referring more specifically to
The exemplary fuel cartridge 100 also includes an electrical connector 134 (
The size of the exemplary fuel cartridge 100 would, of course, vary in accordance with factors such as the size of the host device and the desired amount of fuel containing substance to be stored. Although the present inventions are not limited to any particular size, the exemplary fuel cartridge 100, which produces hydrogen from a sodium borohydride based fuel containing substance and is suitable for use in a notebook computer, carries about 100 milliliter (ml) of the fuel containing substance. Here, the housing 102 could, for example, be about 100 mm in length, about 50 mm wide and about 5 mm thick (with approximately 3 mm of the overall thickness being the plate 116 and approximately 0.5 mm being the open region 110). It is contemplated that, depending on the application and type of fuel containing substance, the size of the cartridge may be varied to accommodate from less than 10 ml of fuel containing substance for a small low power host device to 100 ml or more for a larger high power host device. Of course, these volumes may be increased or decreased as needed.
The exemplary fuel cartridge 100 and the portion of the host device that receives the fuel cartridge will preferably have corresponding shapes and a mechanical keying apparatus (not shown), such as a rail and slot arrangement, to prevent the fuel cartridge from being inserted improperly and, in many instances, prevent the wrong type of fuel cartridge from being connected the host device. A suitable locking device, such as a latch (not shown), may also be provided to hold the fuel cartridge in place. A relatively small fuel cartridge 100 (as compared to the host device) could be inserted into the host device, while relatively large fuel cartridges could be mounted on the exterior.
Although the present inventions are not limited to any particular arrangement for the connection of the fuel cartridge to the host device, the preferred arrangement is a self-sealing connector arrangement that prevents leakage. With such a self-sealing arrangement, seals will be maintained at the fuel cartridge connector 114 and the host device connector 116 when the two are connected to, and disconnected from, one another as the fuel cartridge is received by, and removed from, the host device. Once the sealed connection is made, fuel will be allowed to flow from the open region 110 to a fuel cell or other fuel consuming device under the conditions described below. Preferably, the connection will occur automatically when the fuel cartridge 100 is received by (e.g. inserted into or connected to) the host device to connect the fuel cartridge to the associated fuel consuming device.
One example of a self-sealing connector arrangement that may be used in conjunction with the present inventions is illustrated in
In the exemplary implementation illustrated in
When the fuel cartridge connector 112 is inserted into the host device connector 114 (
Although the present inventions are not limited to use with any particular host device, the fuel cell powered notebook computer 200 illustrated in
The exemplary notebook computer 200 is, with respect to many of the structural and operating components, substantially similar to conventional portable computers such as the Hewlett-Packard Omnibook 6000 notebook PC. More specifically, the exemplary portable computer 200 includes structural components such as a main housing 202 and a display housing 204 that is pivotably connected to the main housing by a hinge 206. The main housing 202 includes a module bay for optional modules such as the illustrated CD-ROM drive module 208, a 3.5 inch disk drive module, or a ZIP drive module. The exemplary main housing 202 is also provided with a user interface 210 that allows the user to interact with the computer 200. The user interface 210 includes a keyboard 212, a touch pad 214, a first pair of right/left click buttons 216 and a second pair of right/left click buttons 218. Each of these elements operates in conventional fashion to control the operations of the computer 200 and application programs running thereon. In addition to supporting a display 220, the display housing 204 also acts as a lid to cover the user interface 210 when in the closed position. To that end, a conventional latch arrangement (not shown) may be provided to lock the free end of the display housing 204 to the main housing 202 and maintain the display housing in the closed position.
The operating components of the exemplary computer 200 illustrated in
The exemplary notebook computer 200 also includes a fuel cell system 232, or other fuel consuming/power generating device, that is connected to various electrical loads within the computer. The exemplary fuel cell system 232 is a fuel cell stack consisting of a plurality of cells. Although the present inventions are not limited to any particular type of fuel cell system, the exemplary fuel cells are PEM fuel cells, which include an anode and a cathode separated by a PEM. Gaseous fuel, such as hydrogen, is supplied to the anode and oxygen supplied to the cathode. In the illustrated embodiment, oxygen may be supplied to the fuel cell stack by drawing ambient air into the stack through a vent in the housing 202. A fan may be provided to facilitate this process. The bi-product (water vapor and nitrogen in the exemplary embodiment) is carried away from the fuel cell system 232 by a manifold and vented out of the housing 202. The notebook computer 200 or other host device should also include a battery 234 to provide power prior to the initial transfer of fuel to the fuel cell system 232. Such power would be used to, for example, power the system processor prior to the production of power by the fuel cell system 232.
During operation of the exemplary computer 200, the heaters 108 in the exemplary fuel cartridge 100 will be selectively actuated by connecting them to a voltage source and ground within the computer, by way of the connectors 134 and 142, in order to provide fuel for the fuel cell system 232. The open region 110 may be filled with a small amount of pressurized fuel (such as hydrogen gas) during the fuel cartridge manufacturing process. This fuel, which will flow under pressure to the fuel cell system 232 when the connectors 112 and 114 mate, may be used to fuel the fuel cell system prior to actuation of the heaters 108. Alternatively, one or more of the heaters will have to be actuated, when the cartridge 100 is initially connected to the computer 200 or the first time the computer is used after the initial connection, in order to create a sufficient amount of pressurized fuel to fuel the fuel cell system 232. Actuation of the heaters 108 may be controlled by the system processor 222 (or a separate controller) along with the other components and subsystems (sometimes referred to as “balance of plant” components and systems) that control of the exemplary PEM fuel cell system. A feedback loop is one exemplary method of controlling the production of fuel within the fuel cartridge 100. Such control would include the rate of fuel production in addition to whether or not fuel is being produced at all.
The present inventions have also have application in the area of electrochemical cell devices, such as fuel cells and batteries, which may be used to power devices that consume electrical power (e.g. notebook computers, personal digital assistants, digital cameras, portable telephones and games). As illustrated for example in
The fuel cartridge 100′ is substantially similar to the cartridge 100 described above in that it includes a plurality of fuel storage areas 104 that respectively store a quantity of a fuel containing substance 106 and a plurality of heaters 108 to heat the fuel containing substance (not shown in
Another exemplary electrochemical cell device in accordance with a present invention is generally represented by reference numeral 308 in
It should also be noted that the primary difference between fuel cells and batteries is simply that all of the fuel that will be consumed by a battery is initially present in the battery, whereas fuel cells have a replenishable fuel supply. Thus, the exemplary electrochemical cell devices 300 and 308 could also be referred to as “fuel cells” in those instances where the associated fuel cartridge 100′ is replaceable, or as a “batteries” in those instances where the associated fuel cartridge 100′ is not replaceable.
Although the present inventions have been described in terms of the preferred embodiments above, numerous modifications and/or additions to the above-described preferred embodiments would be readily apparent to one skilled in the art. By way of example, but not limitation, the various components of the exemplary fuel cartridges described above may be interchanged. Fuel cartridges in accordance with the present inventions may also include a fuel cell bi-product reservoir to store bi-product from the operation of the fuel cell in those instances where it is not practicable to vent the bi-product out of the host device. It is intended that the scope of the present inventions extend to all such modifications and/or additions.
Number | Name | Date | Kind |
---|---|---|---|
1416938 | Bowman | May 1922 | A |
3450500 | Setzer et al. | Jun 1969 | A |
4193978 | Muller et al. | Mar 1980 | A |
4225320 | Gell | Sep 1980 | A |
4354822 | Madsen et al. | Oct 1982 | A |
4493878 | Horiba et al. | Jan 1985 | A |
4499864 | Lovercheck | Feb 1985 | A |
4866250 | Pasbrig | Sep 1989 | A |
5432023 | Yamada et al. | Jul 1995 | A |
5504471 | Lund | Apr 1996 | A |
5644342 | Argyres | Jul 1997 | A |
5673939 | Bees et al. | Oct 1997 | A |
5789093 | Malhi | Aug 1998 | A |
5795668 | Banerjee | Aug 1998 | A |
5797269 | Nishimura et al. | Aug 1998 | A |
5804329 | Amendola | Sep 1998 | A |
5812156 | Bullock et al. | Sep 1998 | A |
5939033 | Kendall et al. | Aug 1999 | A |
5962155 | Kuranaka et al. | Oct 1999 | A |
5976725 | Gamo et al. | Nov 1999 | A |
6007186 | Erni | Dec 1999 | A |
6015209 | Barinaga et al. | Jan 2000 | A |
6039430 | Helterline et al. | Mar 2000 | A |
6054228 | Cisar et al. | Apr 2000 | A |
6057051 | Uchida et al. | May 2000 | A |
6089687 | Helterline | Jul 2000 | A |
6113208 | Benjamin et al. | Sep 2000 | A |
6129861 | Meusinger et al. | Oct 2000 | A |
6198250 | Gartstein et al. | Mar 2001 | B1 |
6268077 | Kelley et al. | Jul 2001 | B1 |
6294276 | Ogino | Sep 2001 | B1 |
6530233 | Nakamura et al. | Mar 2003 | B1 |
6534033 | Amendola et al. | Mar 2003 | B1 |
6713201 | Bullock et al. | Mar 2004 | B2 |
6724194 | Barton | Apr 2004 | B1 |
6828049 | Bullock et al. | Dec 2004 | B2 |
6887546 | Leban | May 2005 | B2 |
20010045364 | Hockaday et al. | Nov 2001 | A1 |
20010052433 | Harris et al. | Dec 2001 | A1 |
20020018925 | Celemin | Feb 2002 | A1 |
20020127447 | Edlund et al. | Sep 2002 | A1 |
20030008186 | Dickman et al. | Jan 2003 | A1 |
20030022041 | Barton et al. | Jan 2003 | A1 |
20030022042 | Wells et al. | Jan 2003 | A1 |
20030051785 | Gauthier et al. | Mar 2003 | A1 |
20030082426 | Bullock et al. | May 2003 | A1 |
20030082427 | Prasad et al. | May 2003 | A1 |
20030124408 | Hojo et al. | Jul 2003 | A1 |
20030129464 | Becerra et al. | Jul 2003 | A1 |
20030136453 | Johnson | Jul 2003 | A1 |
20030138676 | Leban | Jul 2003 | A1 |
20030138679 | Prasad et al. | Jul 2003 | A1 |
20040009121 | Jensen et al. | Jan 2004 | A1 |
20050079128 | de Vos et al. | Apr 2005 | A1 |
Number | Date | Country |
---|---|---|
2728109 | Jan 1978 | DE |
0 940 260 | Sep 1999 | EP |
1 253 522 | Oct 2002 | EP |
1 353 393 | Oct 2002 | EP |
1249427 | Oct 2002 | EP |
1 306 918 | May 2003 | EP |
1396472 | Mar 2004 | EP |
1568374 | May 1980 | GB |
2283235 | May 1995 | GB |
09-213359 | Aug 1997 | JP |
10-321248 | Dec 1998 | JP |
2001-185184 | Jul 2001 | JP |
2001-295996 | Oct 2001 | JP |
2001-313047 | Nov 2001 | JP |
WO-9820282 | May 1998 | WO |
WO 9820282 | May 1998 | WO |
WO-0024076 | Oct 1998 | WO |
WO 0035032 | Jun 2000 | WO |
WO0179012 | Oct 2001 | WO |
WO-03043112 | May 2003 | WO |
WO-04001883 | Dec 2003 | WO |
Number | Date | Country | |
---|---|---|---|
20040076861 A1 | Apr 2004 | US |