The present application is a continuation of International Application No. PCT/JP2004/004260 filed on Mar. 26, 2004, and further the present application claims priority to Japanese Patent Application No. P2003-124480 filed in the Japan Patent Office on Apr. 28, 2003, the entire contents of which being incorporated herein by reference.
This invention relates to a functional device, its manufacturing method, functional system and functional material, and more particularly, to integration of a bottom-up system and a top-down system.
Conventional mainstream functional devices are those manufactured by a top-down approach based upon micro-fabrication, as represented by semiconductor integrated circuits. Especially regarding semiconductor devices, huge semiconductor electronics industry has been established, via inventions of transistors by Bardeen, et al. and inventions of semiconductor integrated circuits by Noyce et al and/or Kilby, et al.
On the other hand, the top-down approach begins to see delimitation in various points. As a technique that breaks the limit, a bottom-up approach by self-organization, etc. has been remarked and studied actively.
Both cell systems and neuron systems have been reported to continuously expand and grow by autonomous dispersion at individual sites (R. R. Llinas, The Biology of the Brain, p. 94, W.H. Freeman & Company, NY, 1989). This is classified to bottom-up systems.
In bottom-up systems, individual portions independently build structures according to local rules or interactions that lead to autonomous decentralized systems. It has been demonstrated by using cellular automaton that there are four different types of structure-building schemes (constant, periodically laminated (nested), functionally structured, and random) with respect to time (S. Wolfram, A New Kind of Science, pp. 51-81, Wolfram Media Inc., IL, USA, 2002).
Also with respect to time, especially, based upon the concept of time projection the Inventor, et al. reported an improvement of a time projection chamber (TPC) as an elementary particle detector using secondary electrons continuously moving with time (electrons generated along trajectories of elementary particles), based on constancy of the drift velocity (P. Nemethy, P. Oddone, N. Toge, and A. Ishibashi, Nuclear Instruments and Methods 212 (1983) 273-280).
Useful and interesting physical phenomena have been observed, such as surface strengthening effect by plasmon excitation observed in a nanospace formed by metal interfaces, especially in a local space between a two-dimensional sample plane and an opposed probe (Futamata, et al., Spectroscopical Society of Japan, Lecture Symposium 2002 Spring “The Forefront of Microscopic Vibration Spectroscopy” Lecture Papers, pp. 20-23).
It has also been reported that resolution of a one-atomic layer in the growth direction is obtained in growth of a semiconductor using metal organic chemical vapor deposition (MOCVD) (A. Ishibashi, MOCVD-grown Atomic Layer Superlattices, Spectroscopy of Semiconductor Microstructures, eds. G. Fasol, A. Fasolino, P. Lugli, Plenum Press, NY, 1989).
In electrochemical growth as well, details of the growth mechanism have been known (Shiro Haruyama, Electrochemistry for Surface Engineers, p. 112, Maruzen, Tokyo, 2001).
In the field of electrochemistry, it has been known that polymeric electrolyte can be deposited on a work by immersing the work and a counter electrode into water containing neutralized polymeric electrolyte and applying d.c. current across the work and the counter electrode (edited by Tsuguo Yamaoka, “New Development of Practical Polymeric Resist Materials, Their Applications as Photopolymers”, Chapter 6, CMC Shuppan, 1996).
Also reported has been a structure inserting a molecular element at a crossing point of approximately 40 nm wide metal wires put crosswise (Y. Chen, D. A. A. Ohlberg, X. Li, D. R. Stewart, R. S. Williams, J. O. Jeppesen, K. A. Nielsen, J. F. Stoddart, D. L. Olynick, and E. Anderson, Nanoscale Molecular Switch Devices Fabricated by Imprint Lithography, Appl. Phys. Lett. 82 (2003) 1610).
Further, as another example of bottom-up schemes, there have been proposed a method of building structures by self-organized progressive hierarchical acquisition (SOPHIA) and a method of growing neurons (Japanese Patent Laid-open Publication No. JP2000-216499, Pamphlet of International Publication No. WO02/35616). In addition, there is gene-governed expression of configurations (gene-derived structures) universal to life and biological systems. On the other hand, as other examples of the top-down systems, there are MEMS systems (micro electromechanical systems), microchemical reactors, and building of structures by human brains (brain-derived structures) as homo faber, in general (for example, Takeshi Yoro, “Yuinoron”, Seidosha, 1989).
The present invention provides in an embodiment a functional device having a high property to make the union of bottom-up systems represented by living matters and top-down systems represented by silicon LSI, as well as a manufacturing thereof and a functional system using the functional device.
The present invention provides in another embodiment a functional material suitable for use as the functional device enjoying the best use of advantages of bottom-up systems and top-down systems.
The Inventor has been engaged in earnest studies to solve the above problems involved in the conventional techniques. Summary of the studies is shown below.
As widely known, two-dimensional patterning by photolithography is often used in the manufacture of semiconductor devices by the top-down approach.
We can analyse the situation in the 3-dimensional(3D) coordinates, i.e., time axis, space(or structure)axis, and the variation axis(or development-rate-axis) as shown in
In two-dimensional patterning, for example, configuration of a structure is determined by photo-lithography through batch exposure of a photoresist using a photo mask. Therefore, upon building a structure, there is no exchange of information in lateral directions among the in-plane structures. More specifically, causality mainly exists, thanks to the photo-mask, in interaction in the vertical direction relative to a plane (we can call this out-of-plane causality) and not in the in-plane direction. In the two-dimensional patterning, block structures are produced under a global rule provided by photo-lithography as shown in
Thus, the top-down systems are characterized as an anisotropic (directional) structures which time is projected (or woven into) discontinuously to, and is anisotropic in space-wise. Let a system be expressed by ↑ when having time continuous projectivity or spatial isotropy, and let a system be expressed by ↓ when having time discontinuous projectivity or spatial anisotropy. Then the top-down system can be characterized by (time projectivity, spatial directionality)=(↓,↑) i.e., the system is discontinuous in time-wise and anisotropic in space-wise. In other words, since in a top-down system the time is discontinuously projected and there exists the spatial anisotropy in general, it is well-approximated as (time projectivity, spatial directionality)=(↓,↑).
On the other hand, another stream whose importance has been remarked recently is so-called bottom-up systems. The systems include self-organized systems, for example, composed of inorganic substances, such as those represented by semiconductor quantum dots. Growth of cells and neuron systems as shown in FIG. 2A is another example of bottom-up systems in culture of cells of biosystems. In
As shown in
Thus, as shown in
In general, living matters or life forms adequately combine the bottom-up property based upon the body systemizing property governed by genes and the top-down property based upon governability by brains to realize their integration as a whole. More specifically, the living matters integrate the bottom-up capability in formation of body tissues and the top-down capability by brains by attaching neuron system to cells in the growth of individuals from fertilized eggs through the long course of evolution.
That is, as shown in
On the other hand, to operate systems effectively, control systems must effect information transfer and controls with much smaller “volumes” than controlled systems. Biosystems can be regarded to attach neuron systems, which are 1+α (where 1<α<1) fractal-dimensional strings, to three-dimensional cell systems. The dimension of transfer and control systems must be always smaller than the dimension of cell systems. The neuron systems are distributed in a three-dimensional development in living matters.
Thus, the living matters integrate different kinds of three-dimensional bottom-up systems called cell systems by so-called minimum set-up through bottom-up, self-similar, lower-dimensional structures called neuron systems to which the lapsed time from generation of fertilize eggs is projected continuously.
In an artificial system other than the aforementioned living matters, there is a TPC shown in
This TPC is explained here in greater detail. As shown in
In the sector 26, states between the sense wires 26a and the pads 26c are read out. That is, a kind of information read is conducted, and it can be regarded as local addressing. The same operation takes place even when wires are placed in a close crossing relation, for example, instead of the pads 26c.
Silicon LSI demonstrating a development along a road map represented by the Moore's law is one of representative of so-called top-down devices and systems, and its limits in size, operation power (environmental temperature) and investment to manufacturing facilities are being talked about. However, while no fundamental solutions are found, the device is anticipated to encounter such limits in a near future.
Bottom-up schemes are being remarked as the antithesis of top-down schemes, but their most serious difficulty is impossibility of or severe difficulty in individual addressing.
In nanoscale, both a function derived from living matters and a function not derived from living matters can be reduced to a common interactive mechanism (ultimately to an electromagnetic interaction). Therefore, nanotechnologies making remarkable progress contains latent importance of integrating non-living matters and living matters, but they have not yet been brought into full-scale practical unification or union.
Manufacturing methods of microstructures on the extension of conventional techniques include those using EUV or electron beam lithography and so-called bottom-up schemes using molecules, for example. However, there are no devices and systems that can couple them and try to find out synergy by the coupling. This is because, according to the above-introduced notation regarding the time-wise and space-wise characteristics, the bottom-up systems expressed by (time projectivity, spatial directionality)=(↑,↑) and the top-down systems expressed by (time projectivity, spatial directionality)=(↓,↓) have opposite natures, ↑ versus ↓, and it is difficult to find a contact point between them when just straightforwardly put side-by-side, just like incompatibility of oil and water.
Coupling of the nanoscale world and the macroscopic world is the barrier that engineers must break through to couple new effects or functions that will be obtained in future in the field of nanotechnologies to existing silicon-based IT infrastructures and educing synergies. However, it is believed that no one could make satisfactory success in coupling them.
Bottom-up material systems expected to exhibit high potency through nanotechnologies have no scheme enabling individual addressing in such nanoscale, and they have not been brought into systematic practical use.
In artificial bottom-up systems, no one made success in providing a control line accompanying the main body of a bottom-up system, which corresponds to neurons connecting the brain and body tissues. This might have made it difficult heretofore to couple the top-down and bottom-up systems.
The above-explained TPC is a system similar to the neuron system of a living matter in that it has time continuously projected and partly satisfying its feature of growing with time to distribute its structure in a three-dimensional development and making access. It has two important features, namely, continuous time projectivity based upon a constant drift velocity of electrons and three-dimensional access to the entire system, based on signal amplification at crossing points of thin conductive structures. However, since this TPC contains gas inside, it has not been made up as a complete solid device.
As already explained, for the conventional manufacture of two-dimensional structures such as semiconductor integrated circuits (such as memory devices) in the group of top-down systems, patterning by photo-lithography through batch exposure as shown in
Further, useful and interesting physical phenomena have been observed, such as surface enhancement effect by plasmon excitation observed in a local space between a two-dimensional sample plane and an opposed probe (Futamata, et al., Spectroscopical Society of Japan, Lecture Symposium 2002 Spring “The Forefront of Microscopic Vibration Spectroscopy” Lecture Papers, pp. 20-23). There are no systems arranging nanostructures capable of taking charge of such physical phenomena in multiply parallel throughout the bulk size of mm˜cm. That is, there are no substances forming nano-discrete bulk-sized structures having dense architectures of nanoscale and enabling individual access.
The above problems can be solved by preparing a coupling intermediate layer or a coupling platform having a nature corresponding to the nature of soap that couples oil and water (amphiphilic property) or a neuron system that couples a cell system and a brain system, and more particularly, by making a configuration in which a bottom-up system and a top-down system are coupled by an artificial neuron-equivalent system.
More specifically, the problems can be solved by inserting a system having the nature of (time projectivity, spatial directionality)=(↑,↓) as the third structure between a bottom-up system of (time projectivity, spatial directionality)=(↑,↑) and a top-down system of (time projectivity, spatial directionality)=(↓,↓). For this purpose, an accompanying line corresponding to a neuron system is provided in an artificial bottom-up system. Alternatively, a self-organized system is grown near an accompanying system prepared beforehand.
As shown in
The one-dimensional superlattice 31 grown in this manner is processed into thin pieces. Its significance lies in the following points.
Further, as shown in
While the bottom-up system shown in
Moreover, as shown in
Furthermore, as already explained, although two-dimensional structures in the category of the top-down systems, such as semiconductor integrated circuits, which rely on patterning by batch exposure, are required to satisfy a good resolution in both x and y directions, and the accuracy remains several nm even in the current maximum resolution, the portion of the third structure can have the resolution of an atomic layer because it is formed by the technique that projects time to space as manifested in vacuum deposition technique. Therefore, even when the bottom-up portion is composed of units of a molecular level size, individual access to them is possible in the present invention.
As a technique for overcoming the limit of resolution in the conventional lithography, the use of self-organization is being examined. For example, in two-dimensional memory using quantum dots and simple molecules made by self-organization, layout with accuracy in the order of several angstroms is possible. However, there are no ways to independently access to these self-organized microstructures. Trial to external access by metal wire, for example, which is made by lithography, will not satisfy the requirement of resolution as already explained.
That is, conventional lithography used in top-down systems cannot attain resolution in the order of one atomic layer, and independent access is impossible by the use of bottom-up systems alone (even though resolution might be acceptable). However, by using a structure prepared by forming a block structure controlled in growth rate of one-dimensional superlattice and projecting time to space, then processing it into thin pieces and minimizing the freedom of directionality, like the aforementioned superlattice thin piece 33, it is possible to complementarily couple top-down systems and bottom-up systems and thereby accomplish both resolution in the order of inter-atomic spacing and independent one-to-one access. As already reviewed, the Inventor formerly reported that resolution of one atomic layer can be obtained in the growth direction in growth of AlAs/GaAs two-atomic layer superlattice by MOCVD method as shown in
As already discussed, growth mechanism by MOCVD essentially comprises surface diffusion and kink growth like electrochemical growth mechanism shown in
Therefore, the above method can form a fine, discrete and dense repeated structure, such as a repeated structure of metal or other conductor strips and dielectric elements, with atomic layer accuracy.
In the case of forming the third structure in form of such a repeated structure of conductor strips and dielectric elements, it is desirable that the conductor strips 41, 42 intersect to oppose their knife edges to each other and make a very small area at the intersection (edge-to-edge configuration) as shown in
In case of
(∂2/∂x2+∂2/∂y2∂2/∂z2)φ(x,y,z)=0 (1)
When the space is divided to meshes (distance Δ) and expressed by a differential equation, for the potential φ(i,j,k), calculation progresses as follows.
∂φ(i,j,k)/∂x=(φ(i,j,k)−φ(i−1,j,k))/Δ
∂φ(i,j,k)/∂y=(φ(i,j,k)−φ(i,j−1,k))/Δ
∂φ(i,j,k)/∂z=(φ(i,j,k)−φ(i,j,k−1))/Δ
For example, regarding x, calculation progresses as follows.
∂2φ/∂x2=((φ′(i+1,j,k)−φ′(i,j,k))/Δ
=(φ(i+1,j,k)−φ(i,j,k)/Δ−(i,j,k)−φ(i−1,j,k))/Δ)/Δ
=(φ(i+1,j,k)+φ(i−1,j,k)/−2φ(i,j,k))/Δ2
Similarly, when ∂2φ/∂y2 and ∂2φ/∂z2 are calculated and introduced for substitution into Equation (1), it is rewritten to:
0=(φ(i+1,j,k)+φ(i−1,j,k)−2φ(i,j,k))/Δ2
+(φ(i,j+1,k)+φ(i,j−1,k)−2φ(i,j,k))/Δ2
+(φ(i,j,k+1)+φ(i,j,k−1)−2φ(i,j,k))/Δ2
From the above, solution of the Laplace equation is obtained by revolving the following recurrence formula.
φ(i,j,k)=(φ(i+1,j,k)+(φ(i−1,j,k)
+(φ(i,j+1,k)+φ(i i,j−1,k)+φ(i,j,k+1)+φ(i,j,k−1))/6 (2)
By progressing the calculation by using Equation (2) and introducing the boundary conditions for the configuration of
Similarly, calculation is conducted for the case of
By comparison between
As shown in
Further, in the structure shown in
As a result, in the third structure mentioned above, the sites that will induce surface enhancement effect can be aligned in super-densely parallel. One of the greatest merits of this configuration lies in using no movable portions, absolutely unlike a configuration with densely parallel surface probes making a structure with an array of a number of heads of surface probe microscopes. In addition, by using thin superlattice pieces as thin as 1˜100 μm, it is possible to make the conductor strips 41, 42 extremely narrow and to maintain both high conductivity of the conductor strips 41, 42 and surface evenness of the thin pieces.
For example, if a piece of bottom-up substance is provided at the pseudo zero-dimensional space 45 at the intersection between the conductor strips 41, 42 shown in
Conductor strips/ribbons 41, 42, and conductor lines in general, use electrons as the medium. Therefore, interaction is transmitted very quickly. On the other hand, the speed of changes in the bottom-up region, and more particularly, the speed of the change in configuration of atoms (such as changes in position of functional groups) are considerably slow because of a large inertial mass. Usually, there is a difference by one or more orders of magnitudes (in general, by several orders of magnitudes) between the speeds of those both. Therefore, the structure shown in
Interaction of atomic groups and molecular groups normally propagates like ripples through nearest neighbor groups in nearest neighbor interaction. In the system of
The present invention has been made through the study explained above, and it is supported by the foregoing study and embodiments of the invention explained hereafter.
According to the first aspect of the invention, there is provided a functional device comprising: a first structure formed by local interaction; an anisotropic second structure formed by a predetermined global rule in which time is projected in the structure discontinuously; and a third structure having an anisotropic configuration and coupling or uniting the first and second structures.
According to the second aspect of the invention, there is provided a method of manufacturing a functional device including a first structure and a second structure which are coupled or united via a third structure, comprising:
forming the third structure to have an anisotropic configuration;
forming the second structure to have an anisotropic configuration in which time is projected discontinuously according to a predetermined global rule; and
forming the first structure by local interaction.
According to the third aspect of the invention, there is provided a functional system using a functional device which includes: a first structure formed by local interaction with in-plane causality; an anisotropic second structure formed by a predetermined global rule with out-of-plane causality in which time is projected in the structure discontinuously; and a third structure having an anisotropic configuration and coupling the first and second structures.
In the first, second and third aspects of the invention, the first structure, for example, is formed by autonomous dispersion type interaction, the second structure is formed according to a predetermined global design rule, and the third structure comprises a flat plane or a spherical plane having a periodically laminated anisotropic configuration, i.e. having alternating heterolayers. Alternatively, the first structure is made of autonomous decentralized system, the second structure is formed according to a predetermined global design rule, and the third structure comprises a plurality of planes stacked in a crossing relation, each having a periodically laminated anisotropic configuration or alternating heterolayers and projecting time continuously in the in-plane direction.
According to the fourth aspect of the invention, there is provided a functional device comprising: an isotropic first structure in which time is projected in the structure continuously; an anisotropic second structure in which time is projected in the structure discontinuously; and a third structure having a periodically laminated anisotropic configuration or alternating heterolayers and coupling the first and second structures.
According to the fifth aspect of the invention, there is provided a method of manufacturing a functional device including a first structure and a second structure which are coupled via a third structure, comprising:
forming the third structure to have a periodically laminated anisotropic configuration;
forming the second structure to have an anisotropic configuration in which time is projected in the configuration discontinuously; and
forming the first structure to have an isotropic configuration in which time is projected in the configuration continuously.
According to the sixth aspect of the invention, there is provided a functional system using a functional device which includes: an isotropic first structure in which time is projected in the structure continuously; an anisotropic second structure in which time is projected in the structure discontinuously; and a third structure having a periodically laminated anisotropic configuration or alternating heterolayers and coupling the first and second structures.
In the fourth, fifth and sixth aspects of the invention, the third structure, for example, comprises a plurality of planes stacked in a crossing relation, each having a periodically laminated anisotropic configuration and projecting time continuously in the in-plane direction.
According to the seventh aspect of the invention, there is provided a functional device comprising: an isotropic first structure in which time is projected in the structure continuously; an anisotropic second structure in which time is projected in the structure discontinuously; and an anisotropic third structure in which time is projected in the structure continuously and coupling the first and second structures.
According to the eighth aspect of the invention, there is provided a method of manufacturing a functional device including a first structure and a second structure which are coupled via a third structure, comprising:
forming the third structure to have an anisotropic configuration in which time is projected in the configuration continuously;
forming the second structure to have an anisotropic configuration in which time is projected in the configuration discontinuously; and
forming the first structure to have an isotropic configuration in which time is projected in the configuration continuously.
According to the ninth aspect of the invention, there is provided a functional system using a functional device which includes: an isotropic first structure in which time is projected in the structure continuously; an anisotropic second structure in which time is projected in the structure discontinuously; and an anisotropic third structure in which time is projected in the structure continuously, coupling the first and second structures.
In the seventh, eighth and ninth aspects of the invention, the third structure, for example, is composed of at least two anisotropic two-dimensional structures in which time is projected continuously in the in-plane direction, and thereby recovers pseudo isotropy.
According to the tenth aspect of the invention, there is provided a functional device comprising: a first structure formed by a bottom-up process; an anisotropic second structure formed by a top-down process and projecting time discontinuously; and a periodically laminated anisotropic third structure coupling the first and second structures.
According to the eleventh aspect of the invention, there is provided a method of manufacturing a functional device including a first structure and a second structure which are coupled via a third structure, comprising:
forming the third structure to have alternative heterolayers;
forming the second structure to have an anisotropic configuration in which time is projected in the configuration discontinuously by a top-down process; and
forming the first structure by a bottom-up process.
According to the twelfth aspect of the invention, there is provided a functional system using a functional device which includes a first structure formed by a bottom-up process; an anisotropic second structure formed by a top-down process in which time is projected in the structure discontinuously; and alternatingly heterolayered third structure coupling the first and second structures.
In the tenth, eleventh and twelfth aspects of the invention, the first structure, for example, is formed by a bottom-up process relying on self-organization, the second structure is an integrated circuit (such as semiconductor integrated circuits and/or micro chemical channels circuits) formed by a top-down process, and the third structure is composed of a plurality of anisotropic two-dimensional structures in which time is projected in the structure continuously in the in-plane direction, and thereby recovers pseudo isotropy.
According to the thirteenth aspect of the invention, there is provided a functional device comprising: a first structure having self-similarity or a fractal structure; a second structure in form of an integrated circuit formed by a top-down process; and a third structure having alternatingly heterolayered anisotropic configuration and coupling the first and second structures.
According to the fourteenth aspect of the invention, there is provided a method of manufacturing a functional device including a first structure and a second structure that are coupled via a third structure, comprising:
forming the third structure to have a periodically laminated anisotropic configuration;
forming the second structure to have an integrated circuit by a top-down process; and
forming the first structure to have self-similarity or a fractal structure.
According to the fifteenth aspect of the invention, there is provided a functional system using a functional device which includes: a first structure having self-similarity or a fractal structure; a second structure in form of an integrated circuit formed by a top-down process; and a third structure having an alternatingly heterolayered anisotropic configuration and coupling the first and second structures.
In the thirteenth, fourteenth and fifteenth aspects of the invention, the third structure, for example, comprises a plurality of planes stacked in a crossing relation, each having an alternatingly heterolayered anisotropic configuration and projecting time continuously in the in-plane direction. The integrated circuit may be a semiconductor integrated circuit, for example.
In the first to fifteenth aspects of the invention, the third structure may have a configuration laminating at least two thin pieces each having an alternatingly heterolayered configuration of conductive layers, each having a thickness in the range from 0.2 nm to 60 nm, more preferably in the range from 0.2 nm to 30 nm, and typically in the order of 1˜10 nm, and dielectric layers, each having a thickness in the range from 0.2 nm to 50 μm, typically in the range from 0.2 nm to 600 nm, and more typically in the order of 10˜100 nm, such that the layers cross each other.
The anisotropic structures may have either a single spatial frequency or a plurality of spatial frequencies. Further, each anisotropic structure is a system of substance including different kinds of carriers that are different in characteristic time for propagation of interaction by at least one digit, for example, and take charge of a plurality of interactions or physical phenomena different in nature from each other, and serving as a host concerning a remarked interaction or physical phenomenon, in which a second host substance corresponding to carriers (such as atoms or molecules) characterized in slow interaction or physical phenomenon is dispersed discrete by a first host substance corresponding to carriers (such as electrons) characterized in quick interaction time or physical phenomenon time in the order of 1 nm to 100 nm scale (for example, from 0.2 nm to 600 nm). In this case, at least one portion of the first host substance, for example, coupled to an arbitrary position inside the entire system exists on a one-dimensional line or curve encircling the system, or it is exposed.
In case of using a repetitive lamination of conductive layers and dielectric layers as the third structure, dielectric layers in contact with conductive layers at opposite ends may be either identical or different in nature.
In a typical example, a second structure in form of an integrated circuit (like a semiconductor integrated circuit) manufactured by a top-down process couples to a combination of a first structure and a third structure with a linear or curved one-dimensional structure existing along an edge of the combination as an interface region.
According to the sixteenth aspect of the invention, there is provided a functional material made by stacking at least three layers of third structures defined in the first, fourth, seventh, tenth and thirteenth aspects of the invention.
According to the seventeenth aspect of the invention, there is provided a functional material made by stacking at least two layers of laminations each including a first structure and a third structure defined in the first, fourth, seventh, tenth and thirteenth aspects of the invention.
According to the eighteenth aspect of the invention, there is provided a functional device comprising a structure made by stacking at least two thin pieces each being a periodical lamination or alternating heterolayers of strip-shaped conductive layers and dielectric layers such that the layers cross each other and edges of the conductive layers are opposed to each other.
According to the nineteenth aspect of the invention, there is provided a functional material comprising a structure made by stacking at least two thin pieces each being a periodical lamination of strip-shaped conductive layers and dielectric layers such that the layers cross each other and edges of the conductive layers are opposed to each other.
According to the twentieth aspect of the invention, there is provided a functional device comprising a lamination of at least two thin pieces each having a periodically laminated configuration of conductive layers, each having a thickness in the range from 0.2 nm to 60 nm, and dielectric layers, each having a thickness larger than the thickness of each said conductive layer, such that the layers cross each other and edges of the conductive layers are opposed to each other.
According to the twenty-first aspect of the invention, there is provided a functional material comprising a lamination of at least two thin pieces each having a periodically laminated configuration of conductive layers, each having a thickness in the range from 0.2 nm to 60 nm, and dielectric layers, each having a thickness larger than the thickness of each said conductive layer, such that the layers cross each other and edges of the conductive layers are opposed to each other.
In the twentieth and twenty-first aspects of the invention, thickness of each conductive layer is preferably in the range from 0.2 nm to 30 nm, and thickness of each dielectric layer is generally in the range from 0.2 nm to 200 μm and typically in the range from 0.2 nm to 50 μm.
According to the twenty-second aspect of the invention, there is provided a functional device comprising an anisotropic structure which is a system of substance including different kinds of carriers which are different in characteristic time for propagation of interaction by at least one digit, for example, and take charge of a plurality of interactions or physical phenomena different in nature from each other, and serving as a host concerning a remarked interaction or physical phenomenon, in whcih a second host substance characterized in slow interaction or physical phenomenon is dispersed discrete by a first host substance characterized in quick interaction time or physical phenomenon time in the order of 1 nm to 100 nm scale to make a bulk size.
According to the twenty-third aspect of the invention, there is provided a method of manufacturing a functional device including an anisotropic structure which is a system of substance including different kinds of carriers which are different in characteristic time for propagation of interaction by at least one order of magnitudes, for example, and take charge of a plurality of interactions or physical phenomena different in nature from each other, and serving as a host concerning a remarked interaction or physical phenomenon, in which a second host substance characterized in slow interaction or physical phenomenon is dispersed discrete by a first host substance characterized in quick interaction time or physical phenomenon time in the order of 1 nm to 100 nm scale to make a bulk size.
According to the twenty-fourth aspect of the invention, there is provided a functional system using a functional device including an anisotropic structure which is a system of substance including different kinds of carriers which are different in characteristic time for propagation of interaction by at least one order of magnitudes, for example, and take charge of a plurality of interactions or physical phenomena different in nature from each other, and serving as a host concerning a remarked interaction or physical phenomenon, in which a second host substance characterized in slow interaction or physical phenomenon is dispersed discrete by a first host substance characterized in quick interaction time or physical phenomenon time in the order of 1 nm to 100 nm scale to make a bulk size.
In the sixteenth to twenty-fourth aspects of the invention, the description made in conjunction with the first to fifteenth aspects of the invention is also applicable to the extent consistent with their natures.
According to the invention having the configuration summarized above, it is possible to easily integrate a top-down system and a bottom-up system, which have been difficult to integrate heretofore, by coupling a first structure formed by local interaction and a second structure formed according to a predetermined global rule with a third structure having an anisotropic configuration.
Additional features and advantages are described herein, and will be apparent from, the following Detailed Description and the figures.
Embodiments of the invention will now be explained below with reference to the drawings.
First explained is the first embodiment.
In the first embodiment, a superlattice thin piece or slice (we call this nano-baumkuchen (NBK)) is formed by electrochemical growth.
To have a superlattice thin piece to grow in the growth apparatus, the electrodes 56, 57 are biased alternately to V1=+V2 and Vr=−V1 as shown in
As the metal of the electrodeposited metal strip/ribbon 62, gold (Au), platinum (Pt) or copper (Cu) may be used, for example. For deposition of Au, a plating bath containing KAu(CN), (NH4)2HPO4, K2HPO4, or the like, is used. For deposition of Cu, a plating bath containing CuSO4.5H2O, H2SO4, thiourea, or the like, is used. For deposition of Pt, a plating bath containing (NH4)2PtCl, NaHPO4.12H2O, or the like, is used.
For growth of the electrodeposited organic strip/ribbon 61 difficult to dissolve into solvents, organic ions, for example, are used as the active agent (edited by Tsuguo Yamaoka, “New Development of Practical Polymeric Resist Materials, Their Applications as Photopolymers”, Chapter 6, CMC Shuppan, 1996).
By using approximately constant growth rate for growth of the electrodeposited organic strip/ribbon 61 difficult to dissolve into solvents and the electrodeposited metal strip/ribbon 62, time interval can be projected to the structure, and as shown in
Next prepared are two cutouts as shown by the rectangular solid line in
If the superlattice thin pieces/slices 71, 72 each include N electrodeposited metal strips/ribbons 62, the electrodeposited metal films 62 of the superlattice thin piece/slice 71 and the electrodeposited metal strips/ribbons 62 of the superlattice thin piece/slice 72 makes N2 intersections in total in
At N2 intersections made by the electrodeposited metal strips/ribbons 62 of the superlattice thin piece/slice 71 and the electrodeposited metal strips/ribbons 62 of the superlattice thin piece/slice 72, bottom-up structures having desired functions are built. For this purpose, quantum dots may be grown by self-organization or self-assembly on the superlattice thin piece/slice 71, for example, used as a substrate, and the other superlattice thin piece/slice 72 may be superposed thereon. Alternatively, a functional material layer (such as inorganic molecules or organic molecules) may be inserted between the superlattice thin pieces/slices 71, 72, and energy may be injected by applying a current between the electrodeposited metal strips/ribbons 62 that are opposed transversely. Thereby, a self-organized critical phenomenon arises, and as a result, a structure having a bottom-up structure between the superlattice thin pieces/slices 71, 72 can be obtained.
In the case where bottom-up structures to be built at N2 intersections of the superlattice thin pieces/slices 71, 72 are made finally by injection and dissipation of energy, these bottom-up structures can be formed automatically in self-alignment with the individual intersections without the need of positioning for alignment. In this case, the electrodeposited metal strips/ribbons 62 of the superlattice thin piece/slice 71 and those of the superlattice thin piece/slice 72 need not intersect at right angles, and it is the only requirement that they connect to edges. These bottom-up structures may be simple memory devices, for example, or bottom-up devices having acquired sophisticated functions by self-organization (SOPHIA) mentioned above. Dimension of the mesh structure by the electrodeposited metal strips/ribbons 62 of the superlattice thin pieces/slices 71, 72 is between 1 and the dimension 2 of the bottom-up system (plane system in this case), and here is established a relation equivalent to the (fractal) dimension of living neuron systems being smaller than the dimension of cell systems. The source material as the basis for forming the bottom-up structures may be introduced by intercalation or by sandwiching, for example. It is also possible to sharpen the knife-edges of the electrodeposited metal films 62 by electrolytic etching before the intercalation/sandwiching. Thereby, it is possible to enhance the surface strengthening effect and compose the bottom-up structures built at intersections of the electrodeposited metal strips/ribbons 62 of the superlattice thin pieces/slices 71, 72 from fewer atomic groups (molecular groups).
A functional device is made by connecting the above-explained two-dimensional structure including bottom-up structures sandwiched by the superlattice thin pieces/slices 71, 72 to a silicon LSI. That is, as shown in
Connection between the electrodeposited metal strips/ribbons 62 of the superlattice thin pieces/slices 71, 72 and the connection pad 83 or the wiring connector 85 may be made by N junctions per one side. Ratio between the number of junctions and the number of intersections of the superlattice thin pieces/slices 71, 72 for building the bottom-up structures are scaled by 1/N. Therefore, contrary to conventional techniques inviting the positional alignment error N2, the embodiment of the invention can reduce the positional alignment error as the value of N increases, or in other words, as the degree of integration increases, and can therefore improve the production yield of devices than conventional techniques. Especially, as shown in
The top-down system comprising LSIs 87 represented by silicon LSIs has a spatially anisotropic structure in which time is projected in the structure discontinuously as explained before, i.e. the structure characterized by (time projectivity, spatial directionality)=(↓,↓) according to the foregoing notation. Further, since the bottom-up structure sandwiched between the superlattice thin pieces/slices 71, 72 is formed as an autonomous decentralized system, time is continuously projected in the structure. Therefore, it has no particular orientation in general, and has, to good approximation an isotropic configuration. Thus, the configuration is characterized by (time projectivity, spatial directionality)=(↑,↑). Therefore, these both structures, even when directly positioned side by side, exhibit the relation of (↑,↑) (↓,↓), and the arrows flip. Therefore, these structures do not couple directly. In contrast, the said two-dimensional structure 82 has an anisotropic configuration with time being continuously projected in the growth direction, that is, the configuration characterized by (time projectivity, spatial directionality)=(↑,↓). In the functional device shown in
Thus, the first embodiment makes it possible to easily realize a functional device having sophisticated functions capable of making the best use of advantages of a bottom-up system and a top-down system represented by silicon LSI. This functional device can exhibit various functions depending upon a combination of functions assigned to the bottom-up system and functions assigned to silicon LSI.
Next explained is the second embodiment of the invention. This embodiment uses quantum dots as the bottom-up structures.
As shown in
The structure shown in
Moreover, the configuration of
The outer circumferential portion 81a of the substrate 81 is the region for locating top-down LSIs. However, they need not be provided all around, and may be provided locally.
Where appropriate, a multi-layered structure may be used, and top-down LSIs can be provided on and under the entire surface including the central portion of the substrate 81.
The frame portion 81b around the two-dimensional structure 82 connects to the electrodeposited metal strips/ribbons 62 extending in parallel in the x and y directions and accessing to N2 intersections of the two-dimensional structure 82 with the same configuration as that of
In the other respects, the second embodiment is identical to the first embodiment within the extent not contradict to its nature.
The second embodiment ensures the same advantages as those of the first embodiment as well.
Next explained is the third embodiment of the invention.
As shown in
In the other respects, the third embodiment is identical to the first and second embodiments within the extent not contradict to its nature.
The third embodiment ensures the same advantages as those of the first and second embodiments as well.
Next explained is the fourth embodiment of the invention.
In the fourth embodiment, as shown in
With this growth apparatus, growth is done as explained below, for example.
An electrically conductive organic resist (not shown) is first coated on side surfaces of the electrode portions 101a of the shaft 101 and the electrode portions 102a of the shaft 102 before hand. Here is used an organic resist that dissolves into a solvent used for dissolving the resin plated 104 through 113 easy to dissolve into solvents. After that, in the same manner as the first embodiment, a periodically laminated structure is formed by alternate lateral growth on side surfaces of the electrode portions 101a via an electrically conductive organic resist in the space between the support plate 103 and the resin plate 104 easy to dissolve into solvents both mounted on the shaft 101, the space between the resin plates 105, 106 and the space between the resin plates 107, 108. Similarly, also in the space between the resin plates 109, 110 easy to dissolve into solvents, both mounted on the shaft 102, the space between the resin plates 111, 112 and the space between the resin plate 113 and the support plate 114, a periodically laminated structure is formed by lateral growth on side surfaces of the electrode portions 102a via a electrically conductive organic resist. The periodically laminated alternatingly heterolayered structure grown on side surfaces of the electrode portions 101a may be either identical to or different from the periodically laminated structure grown on side surfaces of the electrode portions 102a. Subsequently, the electrolytic solution 54 is discharged from the electrolytic bath 51, and a predetermined solvent is introduced to dissolve the electrically conductive organic resist coated on the resin plates 104 through 113 and side surfaces of the electrode portions 101a, 102a. As a result, individual disk-shaped superlattice thin pieces 115 formed by lateral growth on side surfaces of the electrode portions 101a and individual disk-shaped superlattice thin pieces 116 formed by lateral growth on side surfaces of the electrode portions 102a sink down and accumulate alternately. In this manner, a laminated structure composed of alternate accumulation of superlattice thin pieces is obtained.
After that, the laminated structure is taken out from the electrolytic bath, and portions shown by solid-line rectangles in
In the other aspects, the fourth embodiment is identical to the first embodiment, and their explanation is omitted here.
The fourth embodiment has an additional advantage that the functional device is significantly enhanced in functionality and degree of integration by using superlattice thin-piece three-dimensional laminations to form the functional device, in addition to the same advantages as those of the first embodiment.
Next explained is the fifth embodiment of the invention.
Once the resin base film 123 with the metal film is wound up onto the take-up roller 125, it makes a spiral structure in which the resin base film 123 and the metal film are laminated alternately. This spiral heterolayered structure is approximately equivalent to the concentrical structure shown in
The fifth embodiment has the same advantages as those of the first embodiment.
Next explained is the sixth embodiment of the invention.
In the sixth embodiment, superlattice thin pieces/slices 71, 72 are made by the imprinting method shown in
In the other respect, the sixth embodiment is identical to the first embodiment to the extent not contradict to its nature.
The sixth embodiment has the same advantages as those of the first embodiment.
Heretofore, some embodiments have been explained specifically. However, these embodiments should not be construed to limit the invention, but the invention contemplates various changes and modifications based on the technical concept of the invention.
For example, numerical values, materials, configurations, locations, and so on, are not but mere examples, and any other appropriate numerical values, materials, configurations, locations, and so on, may be employed, if necessary.
Further, as the layer sandwiched by superlattice thin pieces, giant magnetoresistance materials of the ferroelectric system or the PrCaMnO system are usable in addition to π electron conjugate organic molecular materials and biomolecular materials.
The concentrical structure itself can be made by other methods than the methods explained as the first to sixth embodiments. For example, it is possible to alternately form different substances on side surfaces by vacuum evaporation while rotating a rotation axis or alternately grow different substances on a columnar substrate by MOCVD, for example.
As materials for forming the concentrical structure, other materials than those used in the first to six embodiments may be used as well. As the dielectric material, inorganic substances such as oxides and organic substances such as polyethylene and polycarbonate may be used.
To bind (↑,↑) and (↓,↓) a structure having the property (↓,↑), i.e. a structure with discontinuous projection of time and isotropic spatial configuration, may be used in lieu of a structure having the property (↑,↓) already explained.
Brain-derived structures that make a category of top-down structures include tangible objects and intangible objects. The former are physical architectures including hardware having three-dimensional existence whereas the latter includes intellectual architectures such as intellectual academic systems, database, software, and so on. Gene-derived structures forming a category of bottom-up structures include not only structures of cell or tissue levels but also organs such as skeletons and internal organs.
Coupling and integration of a bottom-up system and a top-down system are not limited only to hardware in narrow sense, but applicable to various aspects where flows of two incompatible systems rejecting their direct coupling. For example, by carefully examining properties of both systems and identifying and extracting individual sets of incompatible properties (↑,↑) and (↓,↓) an intermediate layer (buffering strategy) having the property (↑,↓) can be inserted between them (if necessary, the operation can be repeated in mode of recurring formula and iteratively. Thereby, the invention can be used to function as a quasi-software scheme (a scheme on a business model or a service model) for matching between movements indwelling in and springing up from users or a mass of consumers (of a hierarchical bottom), such as build-up of markets, consumption trends, etc) and rules or planning of business operations and administrations (of the hierarchical top) given downward from the top according to a predetermined plans.
Further, the concept of the invention can be extended to N component systems like (x1,x2, . . . , xN), and coupling of a plurality of components such as xi and xj is possible. In addition, xi need not be two values of ↑,↓, and may be a many-valued (discrete) parameter.
As described above, according to the present invention, it is possible to realize a sophisticated functional device that can make the best use of advantages of a bottom-up system represented by a living matter and a top-down system represented by silicon LSI. That is, it is possible to realize a sophisticated functional device providing an artificial information transmission and control system corresponding to an associated neuron system between a bottom-up system corresponding to cells and a top-down system.
Furthermore, by using a structure that projects time continuously, it is possible to produce an artificial neuron system equivalent having the extreme resolution (control on the order of atomic layer). This in turn enables supermultiple parallel arrangement of nanostructures/zero-dimensional structures, which can perform surface strengthening effect, for example, over a bulk size.
Moreover, by creating a nanoscale discrete bulk-size system and coupling an LSI system formed on a silicon substrate and an autonomously dispersed system located closely, for example, a platform connecting a bottom-up system and a top-down system can be realized.
Further, by creating a nanoscale discrete bulk size system and obtaining a global size of two-dimensional to three-dimensional nanostructures appearing in the system and addressable locally and individually, a sophisticated platform that couples a microscopic world and a macroscopic world can be obtained. Furthermore, by synergetically coupling almost all nanoscale parallel new functional elements, which have no forms at present but will acquire forms, to existing ULSI systems, epoch-making increase of functions will be possible.
Moreover, the present invention makes it possible to realize a flexible functional device having the degree of integration 10˜160 Gbits/cm2 (0.1˜1 Tb/inch2). For example, a ubiquitous information device in which the surface of a substance directly becomes functional devices can be realized. In this case, since the core portion of the functional device can be formed by lithography, the functional device can be manufactured at a low cost. If the number of elements is N, although conventional techniques needed positional alignment for N2, the present invention needs positional alignment of 4N only, and alleviates the difficulty of positional alignment by 1/N as compared with the conventional difficulty. Moreover, this effect is enhanced with increase of the recording capacity.
In addition, the invention can provide a system of discrete substances represented by cellular automaton governed by difference equations, instead of a system of substances governed by differential equations.
This system of substances can demonstrate modulated dimensions, connectivity, spontaneous break of symmetry, or self-organized critical phenomenon concerning a remarked nature, for example.
Nanotechnologies are expected to develop almost ad infinitum. However, matrix structures supporting nanotechnologies have a cutoff in terms of inter-atomic distance (endless miniaturization is not possible). Therefore, it is important to foresee their “point of convergence” (with certain accuracy), set the limit value and coupling with existing ULSI systems in straight sights from the present moment to start conquering from the viewpoint of preceding the era and acquiring expected fruits of future nanotechnologies that are figureless currently.
It should be understood that various changes and modifications to the presently preferred embodiments described herein will be apparent to those skilled in the art. Such changes and modifications can be made without departing from the spirit and scope of the present subject matter and without diminishing its intended advantages. It is therefore intended that such changes and modifications be covered by the appended claims.
Number | Date | Country | Kind |
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2003/124480 | Apr 2003 | JP | national |
Number | Date | Country | |
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Parent | PCT/JP04/04260 | Mar 2004 | US |
Child | 11247125 | Oct 2005 | US |