Claims
- 1. A compound having the following formula wherein:(a) X1 is N; X2, X3, and X4 are CR″, where R″ is independently H, halogen, cyano, hydroxy, C1-C3 alkyl, C1-C3 haloalkyl, cyclopropyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, substituted or unsubstituted aryl, C1-C3 NHC(O)alkyl, NHC(O)H, C1-C3 haloalkylthio, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 alkynyl, CC2-C4 haloalkynyl or nitro; (b) Z is O, S or NORZ in which RZ is H or C1-C3 alkyl; (c) A is where *=point of attachment in which Q1, Q2 are each O or S, W is O, CH2, CHR6, or a bond, R1 is C1-C8 alkyl, C2-C8 alkenyl, C2-C8 alkynyl, C3-C8 cycloalkyl, unsubstituted or substituted aryl, or unsubstituted or substituted heteroaryl, R2 is H, C1-C3 alkyl, C2-C5 alkenyl or C2-C5 alkynyl, R3 is H, R1, OR1, OC(O)OR1 or OC(O)NR1R6, R4 and R5 are independently H, C1-C6 alkyl, or C2-C6 alkenyl, provided that the sum of carbons for R4 plus R5 is six or less, and further provided that R4 and R5 may be joined into a C3-C6 ring, R6 and R7 are independently H, C1-C6 alkyl, C3-C6 cycoalkyl, C2-C5 alkenyl or C2-C5 alkynyl provided that at least one of R6 and R7 is H; with the proviso that the following compounds are excluded wherein R1 is C1-C8 alkyl, C2-C8 alkenyl, C2-C8 alkynyl, or C3-C8 cycloalkyl, R3 is H, R1, OR1, OC(O)OR1, or OC(O)NR1R6, R6 is H, C1-C6 alkyl, C1-C6 cycloalkyl, C2-C5 alkenyl, or C2-C5 alkynyl, and M is H, C(O)R8, or SO2R9 where R8 is H, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C3-C6 cycloalkyl, alkoxyalkyl, haloalkyl, alkoxyalkenyl, haloalkenyl, alkoxyalkynyl, haloalkynyl, substituted and unsubstituted arylalkyl, substituted and unsubstituted arylalkenyl, substituted and unsubstituted arylalkynyl, substituted and unsubstituted aryl, substituted and unsubstituted heteroaryl, C1-C6 alkoxy, C3-C6 cycloalkoxy, C1-C6 haloalkoxy, C2-C6 alkenyloxy, C2-C6 haloalkenyloxy, C2-C6 alkynyloxy, C2-C6 haloalkynyloxy, C1-C6 thioalkoxy, substituted and unsubstituted arylalkoxy, substituted and unsubstituted arylalkenyloxy, substituted and unsubstituted arylalkyloxy, substituted and unsubstituted boxy, substituted and unsubstituted heteroaryloxy, amino unsubstituted or substituted with one or two C1-C6 alkyl groups, and R9 is C1-C6 alkyl, C2-C6 alkenyl, C3-C6 alkynyl, C3-C6 cycloalkyl, aryl, or heteroaryl; (d) M is Si(t-Bu)Me2, Si(Ph)Me2, SiEt3, SiMe3, C(Z)R8, SO2R9 where R8 is H, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C3-C6 cycloalkyl, alkoxyalkyl, haloalkyl, alkoxyalkenyl, haloalkenyl, alkoxyalkynyl, haloalkynyl, substituted and unsubstituted arylalkyl, substituted and unsubstituted arylalkenyl, substituted and unsubstituted arylalkynyl, substituted and unsubstituted aryl, substituted and unsubstituted heteroaryl, C1-C6 alkoxy, C3-C6 cycloalkoxy, C1-C6 haloalkoxy, C2-C6 alkenyloxy, C2-C6 haloalkenyloxy, C2-C6 alkylyloxy, C2-C6 haloalkynyloxy, C1-C6 thioalkoxy, substituted and unsubstituted arylalkoxy, substituted and unsubstituted arylalkenyloxy, substituted and unsubstituted arylalkynyloxy, substituted and unsubstituted aryloxy, substituted and unsubstituted heteroaryloxy, amino unsubstituted or substituted with one or two C1-C6 alkyl groups, and R9 is C1-C6 alkyl, C2-C6 alkelyl, C3-C6 alkynyl, C3-C6 cycloalkyl, substituted or unsubstituted aryl, or substituted or unsubstituted heteroaryl.
- 2. A composition comprising a compound according to claim 1 and a phytologically acceptable carrier.
- 3. A composition comprising a compound according to claim 1 and at least one other compound selected from insecticides, fungicides, herbicides, nematocides, miticides, arthropodocides and bactericides.
- 4. A method for the control or prevention of fungal infestation, which method comprises applying to the locus of the fungus or the locus in which the infestation is to be controlled or prevented, a fungicidally effective amount of the compound of claim 1.
- 5. A composition comprising a hydrate, salt or complex of the compound according to claim 1.
- 6. A compound of Formula I: wherein:(a) X1 is N; X2, X3, and X4 are CR″, where R″ is independently H, halogen, cyano, hydroxy, C1-C3 alkyl, C1-C3 haloalkyl, cyclopropyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, substituted or unsubstituted aryl, C1-C3 NHC(O)alkyl, NHC(O)H, C1-C3 haloalkylthio, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 alkynyl, C2-C4 haloalkynyl or nitro; (b) Z is O, S or NORZ in which RZ is H or C1-C3 alkyl; (c) A is a C3-C14 cycloalkyl, containing 0-3 heteroatoms and 0-2 unsaturations, which may be unsubstituted or substituted with halogen, hydroxy, C1-C6 alkyl, C1-C6 haloalkyl, cyano, nitro, aroyl, substituted or unsubstituted aryloxy, substituted or unsubstituted heteroaryloxy, C1-C6 alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted heteroarylthio, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C8 aryloxy, substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, C1-C6 acyl, substituted or unsubstituted carboaryloxy, substituted or unsubstituted carboheteroaryloxy, C1-C6 carboalkoxy or amido unsubstituted or substituted with one or two C1-C6 alkyl groups; (d) M is Si(t-Bu)Me2, Si(Ph)Me2, SiEt3, SiMe3, C(Z)R8, SO2R9 where R8 is H, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C3-C6 cycloalkyl, alkoxyalkyl, haloalkyl, alkoxyalkenyl, haloalkenyl, alkoxyalkynyl, haloalkynyl, substituted and unsubstituted arylalkyl, substituted and unsubstituted arylalkenyl, substituted and unsubstituted arylalkynyl, substituted and unsubstituted aryl, substituted and unsubstituted heteroaryl, C1-C6 alkoxy, C3-C6 cycloalkoxy, C1-C6 haloalkoxy, C2-C6 alkenyloxy, C2-C6 haloalkenyloxy, C2-C6 alkynyloxy, C2-C6 haloalkynyloxy, C1-C6 thioalkoxy, substituted and unsubstituted arylalkoxy, substituted and unsubstituted arylalkenyloxy, substituted and unsubstituted arylalkynyloxy, substituted and unsubstituted aryloxy, substituted and unsubstituted heteroaryloxy, amino unsubstituted or substituted with one or two C1-C6 alkyl groups, and R5 is C1-C6 alkyl, C2-C6 alkenyl, C3-C6 alkynyl, C3-C6 cycloalkyl, substituted or unsubstituted aryl, or substituted or unsubstituted heteroaryl.
- 7. A composition comprising a compound according to claim 6 and a phytologically acceptable carrier.
- 8. A composition comprising a compound according to claim 6 and at least one other compound selected from insecticides, fungicides, herbicides, nematocides, miticides, arthropodocides, bactericides.
- 9. A method for the control or prevention of fungal infestation, which method comprises applying to the locus of the fungus or the locus in which the infestation is to be controlled or prevented, a fungicidally effective amount of the compound of claim 6.
- 10. A composition comprising a hydrate, salt or complex of the compound according to claim 6.
- 11. A compound of Formula I: wherein:(a) X1 is N; X2, X3, and X4 are CR″, where R″ is independently H, halogen, cyano, hydroxy, C1-C3 alkyl, C1-C3 haloalkyl, cyclopropyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, substituted or unsubstituted aryl, C1-C3 NHC(O)alkyl, NHC(O)H, C1-C3 haloalkylthio, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 alkynyl, C2-C4 haloalkynyl or nitro; (b) Z is O, S or NORZ in which RZ is H or C1-C3 alkyl; (c) A is a C6-C14 bi- or tricyclic ring system, containing 0-3 heteroatoms and 0-2 unsaturations, which may be unsubstituted or substituted with halogen, hydroxy, C1-C6 alkyl, C1-C6 haloalkyl, cyano, nitro, aroyl, substituted or unsubstituted aryloxy, substituted or unsubstituted heteroaryloxy, C1-C6 alkylthio, substituted or unsubstituted arylthio, substituted or unsubstituted heteroarylthio, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C8 acyloxy, aryl, heteroaryl, C1-C6 acyl, carboaryloxy, carboheteroaryloxy, C1-C6 carboalkoxy or amido unsubstituted or substituted with one or two C1-C6 alkyl groups; and (d) M is Si(t-Bu)Me2, Si(Ph)Me2, SiEt3, SiMe3, C(Z)R8, SO2R9 where R8 is H, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C3-C6 cycloalkyl, alkoxyalkyl, haloalkyl, alkoxyalkenyl, haloalkenyl, alkoxyalkynyl, haloalkynyl, substituted and unsubstituted arylalkyl, substituted and unsubstituted arylalkenyl, substituted and unsubstituted arylalkynyl, substituted and unsubstituted aryl, substituted and unsubstituted heteroaryl, C1-C6 alkoxy, C3-C6 cycloalkoxy, C1-C6 haloalkoxy, C2-C6 alkenyloxy, C2-C6 haloalkenyloxy, C2-C6 alkynyloxy, C2-C6 haloalkynyloxy, C1-C6 thioalkoxy, substituted and unsubstituted arylalkoxy, substituted and unsubstituted arylalkenyloxy, substituted and unsubstituted arylalkynyloxy, substituted and unsubstituted aryloxy, substituted and unsubstituted heteroaryloxy, amino unsubstituted or substituted with one or two C1-C6 alkyl groups, and R9 is C1-C6 alkyl, C2-C6 alkenyl, C3-C6 alkynyl, C3-C6 cycloalkyl, substituted or unsubstituted aryl, or substituted or unsubstituted heteroaryl.
- 12. A composition comprising a compound according to claim 11 and a phytologically acceptable carrier.
- 13. A composition comprising a compound according to claim 11 and at least one other compound selected from insecticides, fungicides, herbicides, nematocides, miticides, arthropodocides, bactericides.
- 14. A method for the control or prevention of fungal infestation, which method comprises applying to the locus of the fungus or the locus in which the infestation is to be controlled or prevented, a fungicidally effective amount of the compound of claim 11.
- 15. A composition comprising a hydrate, salt or complex of the compound according to claim 11.
PRIORITY CLAIM
This application claims benefit to Provisional Application 60/144,646 Jul. 20, 1999.
This application is a Divisional of prior application Ser. No. 09/632,930 filed on Aug. 4, 2000 under Examiner S. Patel, Group Art No. 1624 now U.S. Pat. No. 6,355,660. This U.S. Patent claims a priority from provisional applications 60/149,977 and 60/150,248 which were filed in the U.S. Patent and Trademark Office on Aug. 20, 1999 and Aug. 23, 1999 respectively, the entire disclosures of which are hereby incorporated by reference.
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Provisional Applications (3)
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Number |
Date |
Country |
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60/150248 |
Aug 1999 |
US |
|
60/149977 |
Aug 1999 |
US |
|
60/144646 |
Jul 1999 |
US |