The present application claims the benefit of priority from the Chinese Patent Application No. 201910574042.9, filed on 28 Jun. 2019, the disclosure of which is hereby incorporated by reference in its entirety.
The present application relates to the technical field of electrochemical devices, and more particularly, to a furcated tab, an electrode assembly and a battery.
The following descriptions and examples, though included in this section, are not to be considered as conventional technologies.
Lithium ion batteries have advantages such as high energy density, high operating voltage, low self-discharge rate, small size and light weight, and have wide application in the field of consumer electronics. However, with the rapid development of electric vehicles and mobile electronic devices, people pay more and more attention to the safety of battery. It is hoped not only that there will be no safety hazards during normal use, but also that even if the battery is damaged by severe impact, puncture, etc., the battery will not burn or explode.
A tab is a metal conductor that is electrically connected to a current collector in a lithium ion battery to direct electrical energy to an external circuit. Currently, the current collector used in lithium ion batteries is a metal foil (copper foil, aluminum foil, nickel foil, etc.) current collector or a composite current collector. Compared with a metal foil current collector, the composite current collector has many advantages, such as improved the safety of battery and reduction of battery weight. However, in the process of using such a composite current collector, there are some problems: since the upper and lower metal layers of the composite current collector are not connected together, current conduction on only one side is realized after the composite current collector is welded with the existing tabs, while the opposite side welded with the existing tabs remains electronically insulated; therefore only half of the battery capacity is exerted.
Therefore, it is necessary to improve the structure of existing tabs such that the tabs can be used for a conventional metal foil (copper foil, aluminum foil, nickel foil, etc.) current collector lithium ion battery while the condition that the composite current collector lithium ion battery can exert full battery capacity is ensured.
One of the objectives of the present application is to provide a furcated tab, an electrode assembly and a battery, which would improve the structures of the furcated tab, electrode assembly and battery in the prior art, and effectively solve many problems in the prior art.
Some embodiments of the present application provide a furcated tab, the furcated tab includes a first furcated portion and a second furcated portion. The first furcated portion includes a first end, and the second furcated portion includes a second end. The second end is electrically connected to the first end.
The embodiments of the present application provide a furcated tab by changing the structure of the existing tab, which effectively solves the problem where a lithium ion battery does not exert full battery capacity thereof due to the presence of a non-metal layer when the existing tab is applied to a composite current collector. Meanwhile, the furcated tab provided by the embodiments of the present application can also be used in a lithium ion battery using a common monolithic metal current collector. In the latter case, the furcated tab provided by the embodiments of the present application not only simply replaces the existing tab, but also has the advantages of simplifying the process flow and increasing the energy density in a multi-tab battery.
According to some embodiments of the present application, the first end and the second end form an integrated structure.
According to some embodiments of the present application, the furcated tab further includes a sealing member. The sealing member is connected to the first end and the second end.
According to some embodiments of the present application, the first furcated portion further includes an extending portion extending outward from the first end. The furcated tab further includes a sealing member. The sealing member is connected to the extending portion of the first end. The first end of the first furcated portion is electrically connected to the second end of the second furcated portion by welding.
According to some embodiments of the present application, the furcated tab further includes a third furcated portion provided with a third end. The third end is electrically connected to the first end or the second end.
Some embodiments of the present application further provide an electrode assembly, the electrode assembly includes the furcated tab and a first current collector. The first furcated portion and the second furcated portion of the furcated tab are both electrically connected to the first current collector.
According to some embodiments of the present application, the first current collector includes a first metal layer, a second metal layer, and a non-metal layer located between the first metal layer and the second metal layer. The first furcated portion is electrically connected to the first metal layer, and the second furcated portion is electrically connected to the second metal layer.
According to some embodiments of the present application, the furcated tab further includes a first electrode. The first electrode further includes a first film and the first current collector. The first film is located on both sides of the first current collector. The first film includes a first blank region and a second blank region, a first portion of the first current collector and a second portion of the first current collector are respectively exposed by the first blank region and the second blank region. The first blank region and the second blank region refer to regions of the film where no film material exists. The first furcated portion is electrically connected to the first current collector of the first blank region, and the second furcated portion is electrically connected to the first current collector of the second blank region.
According to some embodiments of the present application, the first electrode includes a film region and an uncovered foil region. The uncovered foil region exposes the first current collector. The first furcated portion and the second furcated portion are respectively electrically connected to the first metal layer and the second metal layer of the first current collector at the uncovered foil region.
According to some embodiments of the present application, the first current collector is a monolithic metal current collector. The first furcated portion is electrically connected to a first surface of the monolithic metal current collector, and the second furcated portion is electrically connected to a second surface, opposite to the first surface, of the monolithic metal current collector.
Some embodiments of the present application further provide a battery, the battery includes a battery case and the electrode assembly.
The following will briefly illustrate the accompanying drawings necessary to describe the embodiments of the present application or the existing technology so as to facilitate the description of the embodiments of the present application. Obviously, the accompanying drawings described below are only part of the embodiments of the present application. For those skilled in the art, accompanying drawings of other embodiments can still be obtained according to the structures illustrated in the accompanying drawings without any creative effort.
The embodiments of the present application will be described in detail below. Throughout the specification, the same or similar components and components having the same or similar functions are denoted by similar reference numerals. The embodiments described herein with respect to the accompanying drawings are illustrative and graphical, and are used for providing a basic understanding on the present application. The embodiments of the present application should not be construed as limiting the present application.
As shown in
As shown in
It should be understood that the first end 404 of the first furcated portion 402a and the second end 406 of the second furcated portion 402b are interchangeably adjusted. For example, the position of the extending portion 407 can be disposed to extend outward from the first end 404 without extending outward from the second end 406 shown in
According to other embodiments of the present application, the electrical connection manner of the furcated tabs 10, 30 and 40 shown in
It should be understood that although the furcated tabs shown in
It should be understood that although
An example that the furcated tab of the embodiments of the present application is connected to the electrode of the electrode assembly will be described below by way of some preferred embodiments.
As shown in
As shown in
It should be understood that although
It should be understood that the first end 804 of the first furcated portion 802a and the third end 806 of the third furcated portion 802c are interchangeably adjusted. For example, the position of the extending portion 807 is changed to be disposed to extend outward from the first end 804 without extending outward from the third end 806 shown in
Although the specific types of the current collectors 514, 514a and 514b are not explicitly indicated in
It can also be seen from
In addition, those skilled in the art will also appreciate that although the above-mentioned
In
The furcated tab provided by the embodiments of the present invention may be used for both a common monolithic metal current collector and a composite current collector. When used in a common monolithic metal current collector, the furcated tab not only simply replaces the existing tab, but also has the advantages of simplifying the process flow and increasing the energy density. When used in a composite current collector, the furcated tab solves the problem that the composite current collector lithium ion battery only exerts half of the battery capacity.
Only comparative examples, embodiments, test methods and test results of the electrode assembly according to the embodiments of the present invention when the composite current collector is used will be described below. The test methods of the electrode assembly using a common monolithic metal current collector are similar, and will not be described here.
Preparation of cathode plate: a composite current collector (12μ polyethylene terephthalate (PET)+double-sided 1μ Al) was used as a cathode current collector, and an active material of lithium cobalt oxide was uniformly coated on the front and back sides of the current collector. After the cathode plate was dried, slitting and cutting were performed, so that the cathode plate had a width of 79 mm and a total length of 889 mm, and the uncovered foil regions on the two sides of the head had a length of 43 mm. In the uncovered foil regions, a common negative electrode tab was ultrasonically welded to a position 25 mm from the film region to obtain the cathode plate.
Preparation of anode plate: common copper foil was used as an anode current collector, an active material of graphite was uniformly coated on the current collector, dried and cold-pressed, and slitting and cutting were performed to obtain the anode plate with a width of 81 mm and a total length of 805 mm. The uncovered foil regions on the two sides had a total length of 57.5 mm. In the uncovered foil region, a common positive electrode tab was welded to a position 46.5 mm from the film to obtain the anode plate.
Preparation of electrode assembly: a separator was placed between the corresponding cathode plate and anode plate, and the electrode assembly was formed by winding. The electrode assembly was subjected to electrolyte injection, packaging and formation to form the electrode assembly of the comparative example.
In the comparative example above, the existing tab and composite current collector were used to prepare the electrode assembly.
The following embodiments 1-3 are the cases where the furcated tab provided by the embodiments of the present application is electrically connected to the uncovered foil region of the electrode (for example, as shown in
Preparation of cathode plate: a composite current collector (12μ polyethylene terephthalate (PET)+double-sided 1μ Al) was used as a cathode current collector, and an active material of lithium cobalt oxide was uniformly coated on the front and back sides of the current collector. After the cathode plate was dried, slitting and cutting were performed, so that the cathode plate had a width of 79 mm and a total length of 889 mm, and the uncovered foil regions on the two sides of the head had a length of 43 mm. In the uncovered foil region, an integrated up-and-down furcated tab was ultrasonically welded to a position 25 mm from the film region to obtain the cathode plate.
Preparation of anode plate: same as the anode plate used in the comparative example.
Preparation of electrode assembly: a separator was placed between the corresponding cathode plate and anode plate, and the electrode assembly was formed by winding. The dry electrode assembly was subjected to electrolyte injection, packaging and formation to form the electrode assembly of Embodiment 1.
In Embodiment 1 above, the composite current collector and the furcated tab 10 in
Preparation of cathode plate: a composite current collector (12μ polyethylene terephthalate (PET)+double-sided 1μ Al) was used as a cathode current collector, and an active material of lithium cobalt oxide was uniformly coated on the front and back sides of the current collector. After the cathode plate was dried, slitting and cutting were performed, so that the cathode plate had a width of 79 mm and a total length of 889 mm, and the uncovered foil regions on the two sides of the head had a length of 43 mm. In the uncovered foil region, an integrated left-and-right furcated tab was ultrasonically welded to a position 25 mm from the film region to obtain the cathode plate.
Preparation of anode plate: same as the anode plate used in the comparative example.
Preparation of electrode assembly: a separator was placed between the corresponding cathode plate and anode plate, and the electrode assembly was formed by winding. The electrode assembly was subjected to electrolyte injection, packaging and formation to form the electrode assembly of Embodiment 2.
In Embodiment 2 above, the composite current collector and the furcated tab 30 in
Preparation of cathode plate: a composite current collector (12μ polyethylene terephthalate (PET)+double-sided 1μ Al) was used as a cathode current collector, and an active material of lithium cobalt oxide was uniformly coated on the front and back sides of the current collector. After the cathode plate was dried, slitting and cutting were performed, so that the cathode plate had a width of 79 mm and a total length of 889 mm, and the uncovered foil regions on the two sides of the head had a length of 43 mm. In the uncovered foil region, an integrated long-and-short furcated tab was ultrasonically welded to a position 25 mm from the film region to obtain the cathode plate.
Preparation of anode plate: same as the anode plate used in the comparative example.
Preparation of electrode assembly: a separator was placed between the corresponding cathode plate and anode plate, and the electrode assembly was formed by winding. The electrode assembly was subjected to electrolyte injection, packaging and formation to form the electrode assembly of Embodiment 3.
In Embodiment 3 above, the composite current collector and the furcated tab 40 in
The following embodiments 4-6 are the cases where the furcated tab provided by the embodiments of the present application is electrically connected to the film region of the electrode (for example, as shown in
Preparation of cathode plate: a composite current collector (12μ polyethylene terephthalate (PET)+double-sided 1μ Al) was used as a cathode current collector, and an active material of lithium cobalt oxide was uniformly coated on the front and back sides of the current collector. After the cathode plate was dried, slitting and cutting were performed, so that the cathode plate had a width of 79 mm and a total length of 889 mm, and the uncovered foil region on the two sides of the head had a length of 43 mm. In the film region, a region was laser-cleaned at a position 414 mm from the edge of the film region, and an integrated up-and-down furcated tab was ultrasonically welded thereon to obtain the cathode plate.
Preparation of anode plate: common copper foil was used as an anode current collector, an active material of graphite was uniformly coated on the current collector, dried and cold-pressed, and slitting and cutting were performed to obtain the anode plate with a width of 81 mm and a total length of 805 mm. The uncovered foil regions on the two sides had a total length of 57.5 mm. In the film region, a region was laser-cleaned at a position 332 mm from the edge of the film region, and a common positive electrode tab was ultrasonically welded thereon to obtain the anode plate.
Preparation of electrode assembly: a separator was placed between the corresponding cathode plate and anode plate, and the electrode assembly was formed by winding. The electrode assembly was subjected to electrolyte injection, packaging and formation to form the electrode assembly of Embodiment 4.
In Embodiment 4 above, the composite current collector and the furcated tab 10 in
Preparation of cathode plate: a composite current collector (12μ polyethylene terephthalate (PET)+double-sided 1μ Al) was used as a cathode current collector, and an active material of lithium cobalt oxide was uniformly coated on the front and back sides of the current collector. After the cathode plate was dried, slitting and cutting were performed, so that the cathode plate had a width of 79 mm and a total length of 889 mm, and the uncovered foil regions on the two sides of the head had a length of 43 mm. In the film region, a region was laser-cleaned at a position 414 mm from the edge of the film region, and an integrated left-and-right furcated tab was ultrasonically welded thereon to obtain the cathode plate.
Preparation of anode plate: common copper foil was used as an anode current collector, an active material of graphite was uniformly coated on the current collector, dried and cold-pressed, and slitting and cutting were performed to obtain the anode plate with a width of 81 mm and a total length of 805 mm. The uncovered foil regions on the two sides had a total length of 57.5 mm. In the film region, a region was laser-cleaned at a position 332 mm from the edge of the film region, and a common positive electrode tab was ultrasonically welded thereon to obtain the anode plate.
Preparation of electrode assembly: a separator was placed between the corresponding cathode plate and anode plate, and the electrode assembly was formed by winding. The electrode assembly was subjected to electrolyte injection, packaging and formation to form the electrode assembly of Embodiment 5.
In Embodiment 5 above, the composite current collector and the furcated tab 30 in
Preparation of cathode plate: a composite current collector (12μ polyethylene terephthalate (PET)+double-sided 1μ Al) was used as a cathode current collector, and an active material of lithium cobalt oxide was uniformly coated on the front and back sides of the current collector. After the cathode plate was dried, slitting and cutting were performed, so that the cathode plate had a width of 79 mm and a total length of 889 mm, and the uncovered foil region on the two sides of the head had a length of 43 mm. In the film region, a region was laser-cleaned at a position 414 mm from the edge of the film region, and an integrated long-and-short furcated tab was ultrasonically welded thereon to obtain the cathode plate.
Preparation of anode plate: common copper foil was used as an anode current collector, an active material of graphite was uniformly coated on the current collector, dried and cold-pressed, and slitting and cutting were performed to obtain the anode plate with a width of 81 mm and a total length of 805 mm. The uncovered foil region on the two sides had a total length of 57.5 mm. In the film region, a region was laser-cleaned at a position 332 mm from the edge of the film region, and a common positive electrode tab was ultrasonically welded thereon to obtain the anode plate.
Preparation of electrode assembly: a separator was placed between the corresponding cathode plate and anode plate, and the electrode assembly was formed by winding. The electrode assembly was subjected to electrolyte injection, packaging and formation to form the electrode assembly of Embodiment 6.
In Embodiment 6 above, the composite current collector and the furcated tab 40 in
The capacity of the electrode assemblies and the resistance of the cathode current collector obtained in the comparative example and Embodiments 1-6 above were measured below.
The specific test and measurement methods are as follows:
1. The electrode assembly was charged with a current of 0.2C to a fully charged state and to 0.02C at constant voltage (CV) to obtain the capacity of the electrode assembly.
2. The resistance of the cathode current collector was calculated by Ohm's law.
The test results are shown in Table 1 below.
It can be seen from Table 1 that, for the electrode assembly of the comparative example and the electrode assemblies of Embodiments 1-6 provided with the same composite current collector, the electrode assemblies using the furcated tabs provided by the embodiments of the present application exert more than double the capacity of the electrode assembly using the existing tab. In addition, it can also be seen from Table 1 that the electrode assemblies provided in Embodiments 1-6 have a resistance of the cathode current collector resistance which is only half of a resistance of the cathode current collector provided in comparative example.
The above description summarizes the features of several embodiments, which enables those of ordinary skill in the art to understand the various aspects of the present application. Those of ordinary skill in the art can readily use the present application as a basis for designing or modifying other compositions to achieve the same objectives and/or the same advantages as the embodiments herein. It is also to be understood by those of ordinary skill in the art that these equal examples do not depart from the spirit and scope of the present application, and it is possible to make various changes, substitutions and modifications to the present application without departing from the spirit and scope of the present application. Although the methods disclosed herein have been described with reference to the specific operations that are performed in a specific order, it should be understood that these operations can be combined, subdivided, or reordered to form an equivalent method without departing from the teachings of the present application. Therefore, unless otherwise specifically indicated herein, the order and grouping of operations shall not be construed as any limitation on the present application.
Number | Date | Country | Kind |
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201910574042.9 | Jun 2019 | CN | national |