Patent Grant
10458707
The present invention relates to furnace flue gas tunnels and related methods.
Fired heaters or furnaces, herein used interchangeably, are common elements of industrial plants. With reference to the reformer furnace R illustrated in
Furnaces include reformers, steam crackers, other reactors, and non-reactive heaters employing burners or other oxidative methods of generating heat and creating flue gas. As used herein, flue gas encompasses any combination of combustion products or effluent gas.
Whether the radiant section F is used for reacting components or merely for heating, the flue gas is gathered in a series of longitudinal tunnels 1 including opposite outside row tunnels 2 and one or more inside row tunnels 4, and passed through transition section 6 to convection section 8, which is a heat recovery section dominated by convective heat transfer where additional heat is often recovered from the flue gas.
With reference to some additional details shown in
The tunnels 1 may include a pair of side walls 16 in each inside tunnel, or a side wall 18 in the case of an outside tunnel, and an outer wall 20 against the firebox wall 22 in the case of the outside row tunnels 2, which are erected from the furnace floor 24 using insulating firebricks transitioning to regular firebrick secured with mortar up to a roof or lid 26, sometimes called coffin covers, often made from large refractory slabs with large expansion gaps created at regular intervals to account for thermal expansion.
The tunnels 1 have flow channels for the flue gas which are normally of uniform width, height and cross-sectional area between the open end 12 and closed end 14. To balance the amount of flue gas entering the tunnels 1 at various points along their length, the number of openings or ports 10 per interval is decreased relative to the pressure drop through the ports 10, which due to the velocity of the flue gas in the tunnels 1, usually means that the number of holes is decreased relative to the distance of the interval from the closed end 14 of the tunnel 1, or stated another way, increased relative to the distance of the interval from the exit end 12 of the tunnel. The ports 10 are formed as the walls 16, 18 are constructed by leaving out half blocks in regular patterns. Since the outside row tunnels 2 generally receive flue gas from the outside row of burners from one side only, these tunnels are usually sized to receive only a fraction of the flue gas passing through the inside row tunnels 4, e.g., 65%. An example applying the industry standard design principles for flue gas tunnels is presented in Table 1.
From this example, it is seen that the use of uniform opening sizes only allows a rough approximation of the desired opening area in each interval. Furthermore, because of the high temperature and thermal stresses, the tunnels 1 are usually constructed with pilasters in the walls at regular intervals 28, which do not allow the placement of openings using conventional block construction techniques. The placement of ports 10 in the industry standard tunnel design thus usually results in a very uneven, fluctuating entry or mass flow rate of flue gas along the various intervals, as shown in
Other efforts to make the flow of flue gas into the tunnels more uniform have included angled slots in the lid of the tunnel and an increasing cross-sectional area of the tunnel to maintain a uniform velocity of flue gas in the tunnel, as described in US 2007/0234974 A1.
Additional design parameters and issues are described in BD Energy Systems Steam Methane Reformer Advanced Training Course Handbook, Part 2—Critical Design Features, Chapter 4—Radiant Section (2015), a copy of which is appended hereto and made a part hereof in its entirety.
Recently, stackable, interlocking refractory blocks made with mullite and/or alumina resistant to high temperature creep, have been made available to the industry, such as those described in US 2006/0242914 A1; or those described in J. Quntiliana et al., “Improving Flue Gas Tunnel Reliability, Nitrogen+Syngas, No. 336, p. 59 (July-August 2015), and WO 2015/188030, e.g., the STABLOX™ flue gas tunnel system commercialized by Blasch Precision Ceramics (Albany, N.Y.). The use of these tunnel systems has facilitated a more versatile location of the ports 10, as well as a more stable and quicker tunnel wall construction. Even so, optimizing the industry standard tunnel design for more precise placement of uniformly sized ports 10, still results in a significant variation in flue gas mass flow rates, e.g., as seen in the example of
The industry would benefit from improved flue gas tunnel designs and operations that avoid or lessen the extent of drawbacks associated with the fluctuation of flue gas flow into and/or within the flue gas tunnels.
In one or more embodiments of the invention, the entry of the flue gas into the tunnel(s) of a furnace is controlled by providing a uniform or regular spacing of entry ports along a tunnel structure, such as a wall(s) and/or roof, and varying the flow conductivity among the entry ports. In some embodiments the flow conductivity is controlled by the size of a passage through the port, e.g., diameter, which may be provided either as through bores of varying diameter or otherwise integrally formed in the structure, or as inserts having bores of varying diameter which are placed in ports having a uniform size. In some embodiments, by matching the flow conductivity and pressure drop through the individual ports (or groups or intervals) to the desired mass flow, the flue gas can be distributed as desired to different locations or regions of the tunnel, e.g., to achieve an essentially evenly distributed mass flow into the tunnel at longitudinal intervals, such as by increasing the diameter of the passages from smallest in the interval near the open or exit end of the tunnel to largest in the interval farthest from the open end, e.g., adjacent a closed end of the tunnel, especially where the tunnel has a uniform cross-sectional area.
In an embodiment of the invention, a furnace tunnel, defining a flow channel for flue gas from a firebox to pass to an open end of the tunnel, comprises a longitudinal refractory structure separating the flow channel from the firebox, a plurality of ports formed in the refractory structure for the flue gas to enter the flow channel from the firebox, a regular spacing pattern of the ports along the length of the refractory structure, and a passage through each of the respective ports providing relatively varied flow conductivities to control flue gas entry into the flow channel.
In another embodiment, a furnace comprises a firebox, and one or more tunnels defining a flow channel for flue gas from a firebox to pass to an open end of the tunnel, and comprising a longitudinal refractory structure separating the flow channel from the firebox, a plurality of ports formed in the refractory structure for the flue gas to enter the flow channel from the firebox, a regular spacing pattern of the ports along the length of the refractory structure, and a passage through each of the respective ports providing relatively varied flow conductivities to control flue gas entry into the flow channel.
In other embodiments of the invention, a furnace tunnel assembly system comprises a plurality of interlocking refractory blocks adapted to form a longitudinal wall of a flue gas flow channel in a firebox, at least some of the blocks comprising ports formed for the flue gas to enter the flow channel from the firebox, and respective flow passages for the ports, wherein at least some of the ports comprise passages having a relatively different flow conductivity than at least some of the other passages.
In other embodiments, a method comprises stacking refractory blocks to form a longitudinal wall of a furnace tunnel, providing a uniform density of ports in successive intervals in the wall between open and closed ends of the tunnel, and providing flow passages of varying relative flow conductivity through the ports.
In other embodiments, a method comprises passing flue gas from a firebox through a longitudinal refractory structure of a tunnel, positioning passages in respective ports evenly distributed along the length of the refractory structure to admit the flue gas into a flow channel in the tunnel, and controlling relative flow rates of the flue gas through the ports by providing some of the passages with a different flow conductivity relative to the other passages, e.g., different cross-sectional areas or diameters.
In other embodiments, a flue gas tunnel comprises a longitudinal wall extending along a flow channel from a closed end of the tunnel to an open end of the tunnel; a plurality of ports of uniform profile formed in the wall for the flue gas to enter the flow channel and arranged in columns from a near column adjacent the open end to a far column adjacent the closed end and a plurality of intermediate columns between the near and far columns, wherein each of the columns has the same number of ports; a like plurality of inserts having a profile matching the respective ports and received therein; orifices formed in the respective inserts; a plurality of sets of the inserts, each set having a different orifice diameter with respect to the other sets, each set of inserts comprising orifices of uniform diameter within the set; wherein each column comprises a plurality of inserts selected from one or more of the sets of inserts, such that an overall cross-sectional flow area through the orifices of each column increases from the near column to the far column.
In other embodiments, a flue gas tunnel disposed in a fired heater comprises a floor, two side walls, a roof, and one or two open ends through which flue gas may exit, optionally through a respective transition section(s), into a respective convection section(s) which may be a common convection section or separate convection sections. At least one side all comprises a plurality of passages of varying cross-sectional areas.
In some embodiments, a plurality of any of the flue gas tunnels described herein are disposed in a steam-methane reformer firebox, the tunnels having an open end through which flue gas may exit into a common convection section or separate convection sections, or through a transition section and into the common convection section. In some embodiments, the plurality of tunnels comprises outer tunnels having one wall with the ports and/or passages formed therein, and inner tunnels between the outer tunnels, the inner tunnels having a pair of opposing side walls with the ports and/or passages formed therein.
In some embodiments, the ports in the refractory structure are equipped with directional flow diverters to promote mixing of the flue gas in the tunnel with a reactant introduced into the tunnel, e.g., a reducing agent to promote selective non-catalytic reduction of the NOx components.
The following definitions are applicable herein:
Adapted to—made suitable for a use or purpose; modified.
Adjacent—next to or adjoining.
Block (brick)—a large solid or hollow piece of hard material, especially rock, stone, concrete, refractory, or wood, typically rectangular with flat surfaces on each side.
Channel—a passage or duct for fluid.
Columns—a vertical or upright arrangement of items.
Closed—having or forming a boundary or barrier.
Control—determine the behavior or supervise the running of.
Cross-sectional area—the extent or measurement of a surface or shape that is or would be exposed by making a straight cut through something, especially at right angles to an axis.
Diameter—a straight line passing from side to side through the center of a body or figure, especially a circle or sphere; the radius is half the diameter.
Different—not the same as another or each other; unlike in nature, form, or quality.
Disposing—putting or arranging in a particular place or way. Used synonymously with placing and positioning.
Dividing—physically or, for the purposes of design, conceptually separating into parts.
Each—used to refer to every one of two or more things, regarded and identified separately.
Embodiments—non-limiting tangible or visible forms of an idea or quality according to the present disclosure or invention.
End—the furthest or most extreme part or point of something.
Enter—come or go into.
Entry—the act of going or coming in.
Far—at, to, or by a great distance (used to indicate the extent to which one thing is distant from another).
Firebox—the chamber of a furnace or boiler in which fuel is burned.
Floor—the lower inside surface of a hollow structure.
Flow—to issue or move in a stream.
Flow conductivity—a measure of how easily a given fluid moves through a channel, passage or orifice at a given pressure drop; the inverse of flow resistivity; the value of K in the equation Q/A=−K*(dp/dx) where Q/A is the superficial or Darcy's velocity (where Q is the volumetric flowrate of the fluid and A is the geometric cross-sectional area of the flow passage or medium), and dp/dx is the pressure change per unit length of the flow passage. For circular orifices the flow conductivity is proportional to the cross-sectional flow area or diameter squared. If the relative flow conductivity of two passages is different depending on the fluid properties and/or flow conditions, the relative flow conductivities are determined using the fluid and conditions actually present, or if the fluid and conditions are not specified, using a flue gas comprised of 1.7 mol % O2, 7.8 mol % CO2, 20 mol % H2O, and 70.5 mol % N2 at entry conditions of 101.2 kPa and 1050° C. (1904° F.), and a pressure drop of 100 Pa (0.4 in. water).
Flue gas—the mixture of gases resulting from combustion and other reactions in a furnace.
Furnace—a structure or apparatus in which heat may be generated at very high temperatures.
Hydraulic diameter—DH=4A/P, where DH is the hydraulic diameter, A is the cross sectional area and P is the wetted perimeter of a channel, duct, or passage.
Essentially imperforate—having no significant openings or apertures.
Insert—a thing that is placed or fit into another thing.
Interlocking—engaging with each other by overlapping or by fitting together projections and recesses.
Intermediate—coming between two things in time, place, order, character, etc.
Interval—a space between two objects, points or units.
Length—measurement or extent of something along its greatest dimension.
Longitudinal—running or along the length of a body; pertaining or extending along the long axis of a body.
Near—located a short distance away.
Open—allowing access, passage, or a view through an empty space; not closed or blocked up.
Pass—move or cause to move in a specified direction.
Passage—a path, channel, or duct through, over, or along which something may pass.
Plate—a thin, flat sheet or strip of metal or other material, typically one used to join or strengthen things or forming part of a machine; a panel.
Plurality—two or more.
Port—an aperture or opening.
Refractory—a substance or material that is resistant to heat.
Regular—arranged in or constituting a constant or definite pattern, especially with the same space between individual instances.
Respective—belonging or relating separately to each of two or more people or things.
Roof or lid—a structure forming an upper cover.
Rows—a number of things in a more or less straight line
Separate—divide or cause to divide into constituent or distinct elements.
Set—a group or collection of similar things.
Size—the relative extent of something.
Spacing—the arranging of the distance between things.
Spacing pattern—a regular arrangement of the distance between things.
Square pattern—a pattern in which joining the centers of four adjacent items forms a square.
Structure—a building or other object constructed from several parts.
Successive—following one another or following others.
Through—moving or lying in one side and out the other.
Triangular pattern—a pattern in which joining the centers of three adjacent items forms an oblique triangle (without a right angle).
Tunnel—a covered passageway, e.g., a structure physically defining a flow channel for flue gas to exit from a furnace.
Uniform—of the same form, manner, degree or character.
Upright—vertical or erect.
Varied—incorporating a number of different types or elements; showing variation or variety.
Wall—a structure enclosing or shutting off a space.
In some embodiments of the invention, a furnace tunnel defines a flow channel for flue gas from a firebox to pass to an open end of the tunnel, e.g., a tunnel having a constant or uniform cross-sectional flow area. In some embodiments, the tunnel comprises a longitudinal refractory structure separating the flow channel from the firebox, a plurality of ports formed in the refractory structure for the flue gas to enter the flow channel from the firebox, a regular spacing pattern of the ports along the length of the refractory structure, and a passage through each of the respective ports providing relatively varied flow conductivities to control flue gas entry into the flow channel.
In some embodiments, the refractory structure comprises at least one upright wall and a roof, e.g., with the ports in the wall(s) and an essentially imperforate roof. In some embodiments, the flow channel can have an essentially uniform cross-sectional flow area.
In some embodiments, the refractory structure comprises blocks, e.g., interlocking and/or stackable blocks. In some embodiments, the ports are integrally formed in the blocks, e.g., by casting or boring, and perforated inserts are received in the ports. In some embodiments, the perforations, e.g., orifices, define cross-sectional flow areas through the respective passages. In some embodiments, the ports have a uniform profile and/or the inserts have a profile matching the respective ports. In some embodiments, the perforations in some of the inserts have a cross-sectional flow area that is greater with respect to the perforations of some of the other inserts. In some embodiments, the perforated inserts comprise sets of a plurality of the inserts, wherein the perforations within each set of inserts have a uniform cross-sectional flow area that differs with respect to the other one or more sets of inserts.
In some embodiments, the ports are disposed in a plurality of intervals comprising a near interval adjacent to the open end, a far interval spaced away from the open end, e.g., adjacent to a closed end of the tunnel, and a plurality of intermediate intervals between the near and far intervals. In some embodiments, the passages through the ports provide the far interval with an overall flue gas flow conductivity relatively greater than the overall flue gas flow conductivity of the near interval. In some embodiments, the overall flue gas flow conductivities of the respective intermediate intervals increase successively from the near interval to the far interval. In some embodiments, the passages through the ports provide the far interval with an overall cross sectional flow area greater than the overall cross sectional flow area of the near interval, and/or the overall cross sectional flow area of the respective intermediate intervals increase successively from the near interval to the far interval.
In some embodiments, each of the near, far and intermediate intervals have the same number of ports. In some embodiments, the ports have a uniform profile and receive perforated inserts having a matching profile. In some embodiments, the perforated inserts comprise one or more sets of the inserts having a uniform perforation diameter. In some embodiments, the far interval has an overall cross sectional flow area greater than the overall cross sectional flow area of the near interval, and/or the overall cross sectional flow area of the respective intermediate intervals increases successively from the near interval to the far interval. In some embodiments, the inserts in each interval comprise inserts from a single set of inserts or from a plurality of different sets.
In some embodiments according to the present invention, a flue gas tunnel comprises a longitudinal wall extending along a flow channel from a closed end of the tunnel to an open end of the tunnel; a plurality of ports of uniform profile formed in the wall for the flue gas to enter the flow channel, and arranged in columns from a near column adjacent the open end to a far column adjacent the closed end and a plurality of intermediate columns between the near and far columns, wherein each of the columns has the same number of ports; a like plurality of inserts having a profile matching the respective ports and received therein; orifices formed in the respective inserts; a plurality of sets of the inserts, each set having a different orifice diameter with respect to the other sets, each set of inserts comprising orifices of uniform diameter within the set; wherein each column comprises a plurality of inserts selected from one or more of the sets of inserts, such that an overall cross-sectional flow area through the orifices of each column increases from the near column to the far column.
In some embodiments, the wall comprises interlocking blocks, the ports are arranged in regular rows and columns, and/or the ports are arranged in a triangular pattern or a square pattern. In some embodiments, the tunnel further comprises single ones of the inserts having a different orifice diameter than the sets of the inserts in the ports of one or more of the columns.
In some embodiments of the invention, a furnace tunnel defines a flow channel for flue gas from a firebox to pass to an open end of the tunnel, and comprises a longitudinal refractory structure separating the flow channel from the firebox, a plurality of ports formed in the refractory structure for the flue gas to enter the flow channel from the firebox, a regular spacing pattern of the ports along the refractory structure, and respective passages through the ports having a varied flow conductivity to control flue gas entry into the flow channel.
In some embodiments according to the present invention, a furnace comprises a firebox and the furnace tunnel of any one or combination of embodiments described herein.
In some embodiments according to the present invention, a furnace tunnel assembly system comprises a plurality of interlocking refractory blocks adapted to form a longitudinal wall of a flue gas flow channel in a firebox. In some embodiments, at least some of the blocks comprise ports formed for the flue gas to enter the flow channel from the firebox, and there are respective flow passages for the ports. In some embodiments, at least some of the ports comprise passages having a relatively different flow conductivity than at least some of the other passages.
In some embodiments of the assembly system, the flow passages comprise openings defined by the profiles of the respective ports, e.g., bores through the blocks, and the different flow conductivities correspond to different cross-sectional areas of the openings, e.g., diameters of the bores.
In some embodiments of the assembly system, the flow passages comprise one or more perforations or orifices formed in respective inserts receivable in the ports, e.g., where the different flow conductivities correspond to different cross-sectional areas of the perforations and/or diameters of the orifices.
In some embodiments, the assembly system comprises a plurality of sets of the port openings or inserts having different perforation or orifice sizes, from which the appropriate or most nearly appropriate size can be selected for a particular port location, or combination of sizes for the ports in a particular interval. For example, the system can comprise a plurality of sets of the inserts, wherein the inserts within each set have respective orifices of the same size, and wherein each set has different orifice sizes than the other sets. In this manner the port openings (e.g., in prefabricated blocks) or inserts can be manufactured in an array of different sizes, an inventory thereof transported to the assembly site, and the appropriate size selected from the inventory for a particular port location. In one non-limiting example, the inventory of port openings and/or inserts can have “standard” sizes to facilitate assembly, e.g., a smallest diameter of from 12.7 mm (0.5 in.) to 19.1 mm (0.75 in.), incremented by 3.17 mm (0.125 in.) up to 31.8 (1.25 in.) to 44.4 mm (1.75 in.), and then incremented by 6.35 mm (0.25 in.) up to a largest diameter of from 63.5 mm (2.5 in.) or 76.2 mm (3 in.). In this manner the wall may be constructed with standard size blocks and/or inserts, selecting the ones with the appropriate opening sizes for the location or interval of the wall.
In some embodiments, the assembly system comprises a kit or essentially complete inventory of component parts for the furnace tunnel assembly, and/or a plurality of the component parts partially pre-assembled into one or more modules.
In some embodiments according to the present invention, a method comprises assembling a furnace tunnel from the blocks and/or inserts of any one or combination of embodiments of the furnace tunnel assembly system described herein.
In some embodiments according to the present invention, a method comprises stacking refractory blocks to form a longitudinal wall of a furnace tunnel, providing a uniform density of ports in successive intervals in the wall between open and closed ends of the tunnel, and providing flow passages of varying relative flow conductivity through the respective ports. In some embodiments, the method further comprises placing perforated inserts in the ports, wherein the flow passages comprise one or more orifices formed in respective inserts which are adapted to be received in the ports, and or wherein the different flow conductivities correspond to different diameters of the orifices. In some embodiments, the method further comprises varying cross-sectional areas of the passages to regulate entry of flue gas from a firebox into the tunnel, e.g., such that a mass flow of the flue gas from the firebox is uniformly distributed through each interval.
In some embodiments according to the present invention, a method comprises passing flue gas from a firebox through a longitudinal refractory structure of a tunnel, positioning passages in respective ports evenly distributed along the length of the refractory structure to admit the flue gas into a flow channel in the tunnel, and controlling relative flow rates of the flue gas through the ports by providing some of the passages with a different flow conductivity relative to the other passages.
In some embodiments, the method further comprises dividing (for design purposes) the length of the refractory structure into a plurality of regular intervals having the same number of ports, wherein the overall flow conductivity of some of the intervals is different relative to the other intervals, e.g., wherein the overall flow conductivity of successive intervals increases from a near interval adjacent to an open end of the tunnel to a far interval adjacent a closed end of the tunnel. In some embodiments, the method alternatively or additionally comprises evenly distributing a mass flow rate of the flue gas entering the tunnel among the intervals, e.g., such that the mass flow rate of the flue gas through each interval is no more than 2% greater or less than an overall average of the mass flow rate through the intervals.
In some embodiments, the method further comprises placing inserts in respective ports, the inserts comprising the respective passages. In some embodiments, the inserts and ports have matching profiles. In some embodiments the inserts comprise sets of perforated inserts, wherein the perforations within each set of inserts have a uniform cross-sectional flow area, e.g., diameter, that differs with respect to the other one or more sets of inserts.
In some embodiments, the method further comprises dividing (for design purposes) the length of the refractory structure into a plurality of regular intervals having the same number of ports, wherein the intervals comprise a near interval adjacent to an open end of the tunnel, a far interval spaced away from the open end, and a plurality of intermediate intervals between the near and far intervals, wherein the perforations in the inserts provide the far interval with an overall cross sectional flow area relatively greater than the overall cross sectional flow area of the near interval, and wherein the overall cross sectional flow area of the respective intermediate intervals increase successively from the near interval to the far interval. In some embodiments, the inserts in each interval comprise inserts from a single set of inserts or from a plurality of different sets.
With reference to
By providing the ports 102 in a regular spacing pattern as shown in
In the embodiments of
The openings 310 in these embodiments, however, are of a uniform size or diameter or profile, whereas inserts 316 have a generally planar portion or plate 318 with a matching outside diameter or other profile for receipt in the ports 300, and variably sized flow passages 320 are formed as circular orifices in each of the inserts 316. The inserts can be made from a heat-resistant material such as a refractory ceramic, for example, alumina, mullite, or a combination thereof, and can be secured in the ports 300 by means of a matching and optionally interlocking profile and/or with refractory mortar or cement. The orifices 320 are arranged in size such that the diameters increase from a smallest diameter in the near interval 308, to a larger diameter in intermediate interval 306, and to a largest diameter in interval 304. These embodiments allow the same blocks 312, 314 to be used to facilitate constructing the wall 302 without concern for the proper placement of the blocks 312, which all have the same size ports 300, whereas the inserts 316 are preferably prefabricated, e.g., predrilled or precast, with the desired size(s) of orifices 320, for placement in the ports 300 before, or preferably during or after the construction of the wall 302.
In some embodiments, the inserts 316 are provided in sets of standard sizes of the orifices 320, e.g., a smallest diameter of 12.7 mm (0.5 in.) or 19.1 mm (0.75 in.) incremented by 3.17 mm (0.125 in.) up to 31.8 (1.25 in.)—44.4 mm (1.75 in.), and then incremented by 6.35 mm (0.25 in.) up to a largest diameter of 63.5 mm (2.5 in.) or 76.2 mm (3 in.). For example, in some embodiments, the inserts 316 may have the following standard diameters for the passage 320:
In the embodiments of
In the embodiments of
In the embodiments of
In the embodiments of
As in
With reference to
In the arrangement shown in
As a further alternative demonstrating another circulating effect by changing the direction of the diverters 850, e.g., they can be pointed horizontally or at an angle toward the closed end 854 to promote back mixing. A back-mixing entry configuration (not shown) of the flow diverters 850 may include accommodation for the effect of any velocity pressure or venturi translation into the pressure drop calculations for flue gas entry into the ports 800.
In some aspects, the disclosure herein relates generally to furnace flue gas tunnels and related methods according to the following Embodiments, among others:
A furnace tunnel defining a flow channel for flue gas from a firebox to pass to an open end of the tunnel, comprising:
The furnace tunnel of Embodiment 1 wherein the refractory structure comprises at least one upright wall and a roof.
The furnace tunnel of Embodiment 1 or Embodiment 2 wherein the refractory structure comprises at least one upright wall comprising the ports and an essentially imperforate roof.
Embodiment 4 The furnace tunnel of any one of Embodiments 1-3 wherein the refractory structure comprises interlocking blocks.
The furnace tunnel of any one of Embodiments 1-4 wherein the refractory structure comprises blocks, wherein the ports are integrally formed in the blocks, and wherein perforated inserts are received in the ports, wherein the perforations define cross-sectional flow areas through the respective passages.
The furnace tunnel of any one of Embodiments 1-5 wherein the ports have a uniform profile and receive perforated inserts having a matching profile, and wherein the perforations in some of the inserts have a cross-sectional flow area that is greater with respect to the perforations of some of the other inserts.
The furnace tunnel of any one of Embodiments 1-6 wherein the ports have a uniform profile and receive perforated inserts having a matching profile, wherein the perforated inserts comprise sets of a plurality of the inserts, wherein the perforations within each set of inserts have a uniform cross-sectional flow area that differs with respect to the other one or more sets of inserts.
The furnace tunnel of any one of Embodiments 1-7 wherein the ports are disposed in a plurality of intervals comprising a near interval adjacent to the open end, a far interval spaced away from the open end, and a plurality of intermediate intervals between the near and far intervals, wherein the passages through the ports provide the far interval with an overall flue gas flow conductivity relatively greater than the overall flue gas flow conductivity of the near interval, and wherein the overall flue gas flow conductivities of the respective intermediate intervals increase successively from the near interval to the far interval.
The furnace tunnel of any one of Embodiments 1-8 wherein the ports are disposed in a plurality of intervals comprising a near interval adjacent to the open end, a far interval spaced away from the open end, and a plurality of intermediate intervals between the near and far intervals, wherein the passages through the ports provide the far interval with an overall cross sectional flow area greater than the overall cross sectional flow area of the near interval, and wherein the overall cross sectional flow area of the respective intermediate intervals increase successively from the near interval to the far interval.
The furnace tunnel of any one of Embodiments 1-9, wherein:
The furnace tunnel of any one of Embodiments 1-10 wherein the inserts in each interval comprise inserts from a single set of inserts or from a plurality of different sets.
A furnace comprising a firebox and the furnace tunnel of any one of Embodiments 1-11.
A furnace tunnel assembly system comprising:
The furnace tunnel assembly system of Embodiment 13 wherein the flow passages comprise bores through the blocks and the different flow conductivities correspond to different diameters of the bores.
The furnace tunnel assembly system of Embodiment 13 or Embodiment 14 wherein the flow passages comprise orifices formed in respective inserts receivable in the ports, wherein the different flow conductivities correspond to different diameters of the orifices.
The furnace tunnel assembly system of and one of Embodiments 13-15, further comprising a plurality of sets of the inserts, wherein the inserts within each set have respective orifices of the same size, and wherein each set has different orifice sizes than the other sets.
A method comprising assembling a furnace tunnel from the blocks and or inserts of the furnace tunnel assembly system of any one of Embodiments 13 to 16.
A method comprising:
The method of Embodiment 18 further comprising placing perforated inserts in the ports, wherein the flow passages comprise one or more orifices formed in respective inserts receivable in the ports, wherein the different flow conductivities correspond to different diameters of the orifices.
The method of Embodiment 18 or Embodiment 19 further comprising varying cross-sectional areas of the passages to regulate entry of flue gas from a firebox into the tunnel such that a mass flow of the flue gas from the firebox is uniformly distributed through each interval.
A method comprising:
The method of Embodiment 21, further comprising dividing the length of the refractory structure into a plurality of regular intervals having the same number of ports, wherein the overall flow conductivity of some of the intervals is different relative to the other intervals.
The method of Embodiment 21 or Embodiment 22 further comprising dividing the length of the refractory structure into a plurality of regular intervals having the same number of ports, wherein the overall flow conductivity of successive intervals increases from a near interval adjacent to an open end of the tunnel to a far interval adjacent a closed end of the tunnel.
The method of any one of Embodiments 21-23, further comprising dividing the length of the refractory structure into a plurality of regular intervals having the same number of ports, and evenly distributing a mass flow rate of the flue gas entering the tunnel among the intervals such that the mass flow rate of the flue gas through each interval is no more than 2% greater or less than an overall average of the mass flow rate through the intervals.
The method of any one of Embodiments 21-24, further comprising placing inserts in respective ports, the inserts comprising the respective passages.
The method of any one of Embodiments 21-25 wherein the inserts and ports have matching profiles.
The method of any one of Embodiments 21-26, wherein the inserts comprise sets of perforated inserts, wherein the perforations within each set of inserts have a uniform cross-sectional flow area that differs with respect to the other one or more sets of inserts.
The method of any one of Embodiments 21-27, further comprising dividing the length of the refractory structure into a plurality of regular intervals having the same number of ports, wherein the intervals comprise a near interval adjacent to an open end of the tunnel, a far interval spaced away from the open end, and a plurality of intermediate intervals between the near and far intervals, wherein the perforations in the inserts provide the far interval with an overall cross sectional flow area relatively greater than the overall cross sectional flow area of the near interval, and wherein the overall cross sectional flow area of the respective intermediate intervals increase successively from the near interval to the far interval.
The method of any one of Embodiments 21-28, wherein the inserts in each interval comprise inserts from a single set of inserts or from a plurality of different sets.
A flue gas tunnel comprising:
The flue gas tunnel of Embodiment 30, wherein the wall comprises interlocking blocks.
The flue gas tunnel of Embodiment 30 or Embodiment 31, wherein the ports are arranged in regular rows and columns.
The flue gas tunnel of any one of Embodiments 30-32, wherein the ports are arranged in a triangular pattern or a square pattern.
The flue gas tunnel of any one of Embodiments 30-33, further comprising single ones of the inserts having a different orifice diameter than the sets of the inserts in the ports of one or more of the columns.
The furnace tunnel of any one of Embodiments 1-11, further comprising one or more directional flow diverters fitted in the ports to promote flue gas circulation in the tunnel.
The furnace tunnel assembly system of any one of Embodiments 13-16, further comprising one or more directional flow diverters for the ports to promote flue gas circulation in the tunnel.
The flue gas tunnel of any one of Embodiments 30-34, further comprising one or more directional flow diverters fitted in the ports to promote flue gas circulation in the tunnel.
A furnace tunnel defining a flow channel for flue gas from a firebox to pass to an open end of the tunnel, comprising:
The furnace tunnel of Embodiment 38, further comprising a spray nozzle to introduce a reducing agent.
The furnace tunnel of Embodiment 39, wherein the reducing agent comprises ammonia or urea solution.
The furnace tunnel of Embodiment 38 or Embodiment 39, wherein the spray nozzle is located at a closed end of the tunnel.
The furnace tunnel of any one of Embodiments 38-41, wherein the flow diverters comprise inserts in the ports having a diverter on an outlet end.
The furnace tunnel of Embodiment 42, wherein the diverter is hemispherical.
The furnace tunnel of Embodiment 42 or Embodiment 43, wherein the inserts have a profile matching a profile of the ports.
The furnace tunnel of any one of Embodiments 42-44, wherein the inserts are provided with orifices to control flue gas entry into the tunnel.
The furnace tunnel of any one of Embodiments 42-45, wherein the inserts comprise a refractory material.
The furnace tunnel of any one of Embodiments 38-46, wherein the refractory structure comprises first and second opposing walls on either side of the flow channel.
The furnace tunnel of Embodiment 47, wherein the flow diverters direct the flow down on the first wall and up on the second wall to effect a circular circulation pattern.
The furnace tunnel of Embodiment 47, wherein the flow diverters direct the flow on both of the first wall and the second wall in the same direction up or down to effect a counterclockwise-clockwise mixed flow pattern.
The furnace tunnel of Embodiment 47, wherein the flow diverters are pointed horizontally or at an angle toward a closed end of the tunnel.
A furnace tunnel defining a flow channel for flue gas from a firebox to pass to an open end of the tunnel, comprising:
The furnace tunnel of any one of Embodiments 38-51, further comprising a passage through each of the respective ports providing relatively varied flow conductivities to control flue gas entry into the flow channel.
A method, comprising:
The method of Embodiment 53 or Embodiment 62, further comprising introducing a reducing agent into the tunnel to lower NOx emissions.
The method of Embodiment 54, wherein the reducing agent comprises ammonia or urea solution.
The method of Embodiment 54 or Embodiment 55, comprising introducing the reducing agent at a closed end of the tunnel.
The method of any one of Embodiments 53-56 or 62, comprising providing orifices in the directional flow diverters to control flue gas entry into the tunnel.
method of any one of Embodiments 53-57 or 62, wherein the directional flow diverters effect a circular circulation pattern in the tunnel.
The method of any one of Embodiments 53-57 or 62, wherein the directional flow diverters effect a counterclockwise-clockwise mixed flow pattern.
The method of any one of Embodiments 53-57 or 62, wherein the directional flow diverters promote back mixing in the tunnel.
The method of any one of Embodiments 53-60, further comprising controlling relative flow rates of the flue gas through the ports by providing some of the passages with a different flow conductivity relative to the other passages.
The method of any one of Embodiments 21-29, further comprising fitting directional flow diverters in the ports to promote flue gas circulation in the tunnel.
The intervals are labeled 1 to 56 at the top of the wall 900, where interval 1 is near the closed end 906 and interval 56 is near the open end 908. The size of the orifices used in each block is indicated schematically in
In this example, the overall flue gas flow conductivity of each interval is adjusted by adjusting the cross-sectional flow area using orifices from 1 or 2 sets of the available orifice sizes in each column, e.g., interval 1 uses 10 (5 in each wall of the interior tunnel) of the inserts with the “A” orifices, interval 2 uses 8 A's and 2 B's, and so on. The smaller orifices in each interval are placed ascending in the lower rows to direct less of the flue gas to the lower rows, corresponding to the temperature-sensitive lower ends of the reactor tubes.
Although only a few exemplary embodiments have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the example embodiments without materially departing from this disclosure. For example, any embodiments specifically described may be used in any combination or permutation with any other specific embodiments described herein. Accordingly, all such modifications are intended to be included within the scope of this disclosure as defined in the following claims. In the claims, means-plus-function clauses are intended to cover the structures described herein as performing the recited function and not only structural equivalents, but also equivalent structures. Thus, although a nail and a screw may not be structural equivalents in that a nail employs a cylindrical surface to secure wooden parts together, whereas a screw employs a helical surface, in the environment of fastening wooden parts, a nail and a screw may be equivalent structures. It is the express intention of the applicant not to invoke 35 U.S.C. § 112(f) for any limitations of any of the claims herein, except for those in which the claim expressly uses the words ‘means for’ or ‘step for’ together with an associated function without the recitation of structure.
This application is a nonprovisional of and claims priority benefit of U.S. 62/233,931 filed Sep. 28, 2015.
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| PCT/US2016/053876 | 9/27/2016 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
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| WO2017/058744 | 4/6/2017 | WO | A |
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| 20180216887 A1 | Aug 2018 | US |
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