This application claims priority to Japanese Patent Application No. 2007-230161 filed on Sep. 5, 2007. The entire disclosure of Japanese Patent Application No. 2007-230161 is hereby incorporated herein by reference.
1. Field of the Invention
The present invention generally relates to a gas physical quantity detecting device for detecting a physical quantity of a gas.
2. Background Information
In conventional technology, a pressure sensor device can be provided to detect gas pressure in a pipe. In one type of pressure sensor device, a filter with an oil impregnated metal mesh or non-woven fabric is provided in an inlet of a sensor element chamber to prevent liquid water or contaminants from entering into the sensor element chamber. One example of this type of pressure sensor device is disclosed in Japanese Laid-Open Patent Publication No. 11-30535 (see, paragraphs 0054 to 0056).
It has been discovered that with a conventional pressure sensor device, as discussed above, water vapor enters into the sensor element chamber through the filter when the device is in a high humidity and high temperature environment. If the ambient temperature decreases, then water condensation (dew) will occur inside the sensor element chamber. Dew or water that has condensed inside the sensor element chamber tends to adhere to the sensor element or form a liquid film on the filter surface due to surface tension. When this occurs, the gas targeted for pressure detection can not reach the sensor element in an effective manner and the gas pressure can not be detected accurately.
The present invention was conceived in view of the problem just described. One object of the present invention is to provide a gas physical quantity detecting device that can detect a physical quantity of a gas accurately without the occurrence of poor detection results caused by water condensation. Another object of the present invention to provide a fuel cell system and a vehicle in which the gas physical quantity detecting device is employed.
In view of the above, a gas physical quantity detecting device is provided that basically comprises a detection element, a detection element chamber and a filter. The detection element is configured to detect a physical quantity of a gas flowing through a gas flow passage. The detection element chamber contains the detection element and configured to supply gas from inside the gas flow passage to the detection element. The filter is arranged between the gas flow passage and the detection element chamber. The filter has a predetermined thickness with the filter being made of a non-hydrophobic material.
Referring now to the attached drawings which form a part of this original disclosure:
Selected embodiments of the present invention will now be explained with reference to the drawings. It will be apparent to those skilled in the art from this disclosure that the following descriptions of the embodiments of the present invention are provided for illustration only and not for the purpose of limiting the invention as defined by the appended claims and their equivalents.
Referring initially to
The gas physical quantity detecting device 1 is mounted around an opening 3 in the gas pipe 2 by a sensor mounting part 4 of the gas physical quantity detecting device 1. The sensor mounting part 4 is a tubular member that is formed around the opening 3 in the gas pipe 2. In this embodiment, an O-ring 5 is arranged between the gas physical quantity detecting device 1 and the sensor mounting part 4 to provide an airtight seal and prevent gas from leaking between the gas physical quantity detecting device 1 and the sensor mounting part 4.
The gas physical quantity detecting device 1 further includes a filter 6 disposed in a bottom portion of the sensor mounting part 4, a detection element chamber 7 defined by an interior of a tubular sensor enclosure 8, an element cover 9 and an electrical wiring harness 10. The element cover 9 is arranged in an upper portion of the inside of the detection element chamber 7 and contains inside a resistance temperature sensor S. The electrical wiring harness 10 receives and transmits a detection signal from the resistance temperature sensor, and supplies electric power to the resistance temperature sensor S. The resistance temperature sensor S detects a concentration of gas that passes from the gas pipe 2 to the resistance temperature sensor S through the opening 3, the filter 6, and the detection element chamber 7. The concentration is detected based on a temperature change of the resistance temperature sensor S. Although in this embodiment a resistance temperature sensor is provided inside the element cover 9 to detect a concentration of the gas, it is also acceptable to change the sensor configuration inside the element cover 9 so as to detect a temperature, pressure or other physical quantity. In this embodiment, the element cover 9 is provided with a small opening 21 for introducing the gas to the resistance temperature sensor S.
The filter 6 is made by interweaving non-hydrophobic fibers in a non-uniform manner such that the filter 6 of non-hydrophobic fibers has a three-dimensional form. In other words, the filter 6 has continuous passageways for gas to pass through the filter 6 from the gas pipe 2 to the detection element chamber 7. However, theses continuous passageways of the filter 6 are non-linear passageways. If the gas of which a physical quantity is being detected contains hydrogen, then it is preferable for the fiber material to be one of the following stainless steels: SUS316 (a stainless steel 18% Cr, 12% Ni, 2% Mo, 0.08% or less of C added thereto), SUS316L (a stainless steel having 18% Cr, 12% Ni, 2% Mo, 0.03% or less of C added thereto), or SUS304 (a stainless steel containing 18% Cr and 8% Ni). By using one of these fiber materials, the filter 6 can be prevented from degrading due to exposure to hydrogen and the filter 6 can be used continuously while exposed to hydrogen without being replaced.
With the gas physical quantity detecting device 1, as described above, if liquid water is contained in the gas flowing through the gas pipe 2, the liquid water will be blocked by the filter 6 and prevented from entering into the detection element chamber 7. As a result, liquid water can be prevented from adhering to the element cover 9 and causing a poor detection result to occur. Additionally, liquid water is prevented from clogging the filter 6 and inhibiting the exchange of gas between the gas pipe 2 and the detection element chamber 7. As a result, the physical quantity of the gas can be detected accurately.
Meanwhile, if water vapor is contained in the gas flowing through the gas pipe 2, the water vapor will pass through the filter 6 and enter the detection element chamber 7. Consequently, there is the possibility that water vapor inside the detection element chamber 7 will condense and cause condensed water (dew) to exist inside the detection element chamber 7. However, since the filter 6 is made by interweaving a non-hydrophobic fiber(s) in a non-uniform manner such that the non-hydrophobic fiber(s) has a three-dimensional form, the surface of the filter 6 is not a flat plane but, instead, has fine indentations and protrusions. The internal structure of the filter 6 is such that there are continuous air voids whose sizes change as they interconnect. These air voids form a plurality of paths through which gas can flow. Thus, an air layer occupies a larger portion of the surface of the filter 6 than in the conventional technology.
In general, the surface tension of water is determined by a contact angle of the water with a surface. In the case of the filter 6, the non-hydrophobic fiber(s) forms many contact surfaces with water droplets in the filter 6. In other words, the non-linear passageways of the filter 6 forms many contact surfaces with water droplets in the filter 6. When water is spread over a plurality of objects (i.e., fibers), the overall contact angle is calculated as a sum of the individual contact angles weighted based on surface area. Since the contact angle of water with respect to air is 0, the contact angle of water with respect to the filter 6 that is occupied by an air layer to a large degree is smaller than the contact angle with respect to a conventional filter. Consequently, a liquid film does not form on the surface of the filter due to surface tension and condensed water infiltrates to the interior of the filter 6 by capillary action. Although a similar effect can be obtained by applying a hydrophilic treatment to the filter, it is necessary to raise the temperature or apply some other process in order to activate the hydrophilic treatment, which causes the cost to increase.
Since the internal structure of the filter 6 is such that there are continuous air voids whose sizes change as they interconnect, any condensed water that is absorbed into the filter 6 gathers in places where the surface tension is strong and leaves places that are not filled with liquid water. Additionally, since gas is constantly entering and exiting the upper and lower surfaces of the filter 6, a situation in which all of the gas paths inside the filter 6 become clogged does not occur. Even if water condenses inside the detection element chamber 7, a situation in which gas is blocked to the inside of the detection element chamber 7 does not occur and a physical quantity of the gas can be detected accurately.
It is preferable for the sizes of the air voids existing on a surface of the filter 6 facing toward the detection element chamber 7 to be smaller than a maximum flame extinguishing diameter (approximately 0.8 mm at atmospheric pressure) of a hydrogen flame at a pressure of a gas flowing inside the gas pipe 2. Thus constructed, even if a spark occurs inside the detection element chamber 7 while the device is being used in a hydrogen atmosphere, the flame will not spread to the gas pipe 2 side and the flame can be suppressed inside the detection element chamber 7.
In order that condensed water occurring inside the detection element chamber 7 will not form a liquid film on an internal wall surface 8a of the sensor enclosure 8, a hydrophilic treatment is applied to the internal wall surface 8a or the roughness of the internal wall surface 8a is made to be larger than the roughness of the surface of the element cover 9. When such a constituent feature is adopted, even if water condensation occurs inside the detection element chamber 7, liquid droplets will not adhere to the internal wall surface 8a. Additionally, since the roughened internal wall surface 8a of the detection element chamber 7 serves as a water condensation kernel, condensed water does not develop on the surface of the element cover 9. Therefore, poor detection results caused by liquid water adhered to the element cover 9 can be prevented. A similar technical effect can be obtained by applying a water repellant treatment to the internal wall surface 8a because doing so will prevent liquid droplets from adhering to the internal surface 8a.
Variation of the filter 6 of
In the filter shown in
In the filter 6″ shown in
In the filter 6′″ shown in
In the filter 6″″ shown in
Referring now to
As shown in
In this second embodiment, the inner tubular member 8b is provided inside on the internal wall of the sensor enclosure 8. The inner tubular member 8b extends to a bottom portion of the sensor mounting part 4. Thus, the inner tubular member 8b forms the detection element chamber 7. The first filter section 6a is arranged in a bottom portion of the inner tubular member 8b. The second filter section 6b is arranged on an internal wall surface of the inner tubular member 8b and extends along the entire area of the internal wall surface of the inner tubular member 8b. Although in this embodiment the first filter section 6a is arranged at least partially inside the detection element chamber 7, it is acceptable for the filter to be arranged outside the detection element chamber 7 (as shown in
The first filter section 6a is made of the same material as the filter 6 of the first embodiment as discussed above. The first filter section 6a is configured and arranged such that a surface thereof that is nearer to the gas pipe 2 protrudes into the gas pipe 2 through the opening 3. By configuring the first filter section 6a such that the surface thereof facing the gas pipe 2 protrudes into the gas pipe 2, moisture absorbed by the first filter section 6a can be carried away by gas flowing through the gas pipe 2. As a result, liquid water inside the detection element chamber 7 can be discharged in an effective manner.
The second filter section 6b is made of the same material as the filter 6 of the first embodiment as discussed above, and is provided on the internal wall surface of the inner tubular member 8b. Providing the second filter section 6b enables condensed water inside the detection element chamber 7 to be absorbed at the side wall portions in addition to the bottom portion of the detection element chamber 7. As a result, liquid water can be prevented from adhering to a detection element cover 9a and a reference element cover 9b, which are described later. Since the first filter section 6a serves as a kernel for water condensation, condensation of water on the surfaces of the element cover 9a and the reference element cover 9b can be prevented. The second fiber density of the second filter section 6b, which is disposed in a peripheral section, is smaller than the first fiber density of the first filter section 6a, which is disposed in a middle section, similar to
The detection element cover 9a and the reference element cover 9b are arranged inside the detection element chamber 7. The detection element cover 9a contains a resistance temperature sensor S1 for gas detection inside. The detection element cover 9a has a narrow hole 21. The reference element cover 9b contains a reference resistance temperature sensor S2 and a reference (comparative) gas. The reference element cover 9b is sealed. Together, the sensors S1 and S2 form a thermal conductivity hydrogen sensor that detects a hydrogen concentration based on a temperature change of the gas detection resistance temperature sensor S1 (which changes in accordance with the hydrogen concentration of the gas) while compensating based on a temperature change of the reference resistance temperature sensor S2. With this configuration, the hydrogen concentration can be detected accurately even if the hydrogen concentration is high, there is no oxygen present, and water vapor exists.
When the thermal conductivity hydrogen sensor (S1 and S2) is used, if there is a flow of gas inside the detection element cover 9a, then the detection value will be affected because the temperature of the gas detection resistance temperature sensor S1 will change due to the heat transfer coefficient in addition to the thermal conductivity. Therefore, it is preferable to take such measures as making the thickness of the first filter section 6a ten (10) mm or larger and making the diameter of the gas pipe 2 larger at the position where the gas physical quantity detecting device 1′ is mounted than at other positions in order to suppress the occurrence of gas flow inside the detection element cover 9a.
When the first filter section 6a has absorbed liquid water, there is the possibility that liquid water will be splashed from the first filter section 6a toward the detection element chamber 7 if the flow rate of gas inside the gas pipe 2 increases abruptly. Therefore, it is preferable for a gap of several millimeters to be provided between the first filter section 6a and the detection element cover 9a. By providing such a gap, splashed water can be prevented from adhering to the surface of the detection element cover 9a.
It is preferable to apply a water repellent treatment to the surfaces of both the detection element cover 9a and the reference element cover 9b. By applying a water repellent treatment to both surfaces, liquid droplets can be prevented from adhering to the surfaces of the detection element cover 9a and the reference element cover 9b even when liquid water absorbed by the first filter section 6a is splashed onto the surfaces of the detection element cover 9a and the reference element cover 9b or when water condenses on the surfaces of the detection element cover 9a and the reference element cover 9b. As a result, poor detection results can be prevented.
It is preferable for a gap to be provided between the detection element cover 9a and the reference element cover 9b. By providing a gap, even if liquid droplets adhere to the surface of either the detection element cover 9a or the reference element cover 9b, a situation in which poor detection results occur due to the formation of a liquid film spanning between the detection element cover 9a and the reference element cover 9b can be prevented.
It is preferable to provide a gap between the internal wall of the detection element chamber 7 and both the detection element cover 9a and the reference element cover 9b. By providing such a gap, even if liquid droplets adhere to the internal wall of the detection element chamber 7 and to the surface of either the detection element cover 9a or the reference element cover 9b, a situation in which poor detection results occur due to the formation of a liquid film spanning between the internal wall of the detection element chamber 7, the detection element cover 9a, and the reference element cover 9b can be prevented.
The gas physical quantity detecting devices 1 and 1′ (including the filter variations of
Three examples 1 to 3 in which one of the gas physical quantity detecting devices 1 and 1′ (including the filter variations of
Referring now to
Fuel electrode: H2→2H++2e− (1)
Oxidant electrode: ½O2+2H++2e−→H2O (2)
Overall: H2+½O2→H2O (3)
The hydrogen pressure reducing valve 34 serves to reduce the pressure of the high pressure hydrogen inside the hydrogen tank 31 to a pressure that is well suited to the operating conditions of the fuel cell tank 32. The hydrogen supply pipe 33 serves to deliver the hydrogen to the fuel electrode of the fuel cell stack 32.
A hydrogen circulation pipe 35 and a circulation pump 36 are provided on an outlet side of the fuel electrode and serve to circulate gas discharged from the fuel electrode to the hydrogen supply pipe 33. A hydrogen discharge pipe 37 extends from the hydrogen circulation pipe 35 to discharge gas from the fuel electrode to the outside. A hydrogen discharge on-off valve 38 opens and closes the hydrogen discharge pipe 37.
The fuel cell system also has a compressor 39 and an air supply pipe 40. The compressor 39 serves to supply compressed air to the oxidant electrode of the fuel cell stack 32 through the air supply pipe 40. An air discharge pipe 41 extends from the air discharge pipe 41 to discharge air from the oxidant electrode to the outside. An air discharge on-off valve 42 opens and closes the air discharge pipe 41.
In this fuel cell system, one of the gas physical quantity detecting devices 1 and 1′ (including the filter variations of
Although one of the gas physical quantity detecting devices 1 and 1′ (including the filter variations of
Meanwhile, if the detection device is provided in the hydrogen supply pipe 33, then the detection error will be larger than when the detection device 1 is provided on the upstream side of the circulation pump 36 because a high hydrogen concentration will be detected at all times and the gas flow rate is higher in the hydrogen supply pipe 33. As a result, it is preferable for the gas physical quantity detecting devices 1 and 1′ (including the filter variations of
Referring now to
Referring now to
While only selected embodiments have been chosen to illustrate the present invention, it will be apparent to those skilled in the art from this disclosure that various changes and modifications can be made herein without departing from the scope of the invention as defined in the appended claims. For example, the size, shape, location or orientation of the various components can be changed as needed and/or desired. Components that are shown directly connected or contacting each other can have intermediate structures disposed between them. The functions of one element can be performed by two, and vice versa. The structures and functions of one embodiment can be adopted in another embodiment. It is not necessary for all advantages to be present in a particular embodiment at the same time. Every feature which is unique from the prior art, alone or in combination with other features, also should be considered a separate description of further inventions by the applicant, including the structural and/or functional concepts embodied by such feature(s). Thus, the foregoing descriptions of the embodiments according to the present invention are provided for illustration only, and not for the purpose of limiting the invention as defined by the appended claims and their equivalents.
Number | Date | Country | Kind |
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2007-230161 | Sep 2007 | JP | national |