Gas sensor with a seal and method of making

Information

  • Patent Grant
  • 9557197
  • Patent Number
    9,557,197
  • Date Filed
    Friday, June 6, 2014
    10 years ago
  • Date Issued
    Tuesday, January 31, 2017
    7 years ago
Abstract
A gas sensor includes a metallic shell with a shell aperture extending therethrough along an axis; a metallic glass holder metallurgically sealed to the shell in order to prevent gases from passing between the glass holder and the shell, the glass holder including a glass holder aperture extending axially therethrough; a ceramic sensing element extending through the shell aperture and through the glass holder aperture; and a glass seal which seals between the sensing element and the glass holder in order to prevent gases from passing between the sensing element and the glass holder. A method of making the gas sensor is also provided.
Description
TECHNICAL FIELD OF INVENTION

The present invention relates to a gas sensor, more particularly to such a gas sensor which includes a ceramic sensing element mounted in a metallic shell, even more particularly to an arrangement for sealing the sensing element to the shell, and still even more particularly to such a gas sensor for sensing exhaust constituents produced by an internal combustion engine.


BACKGROUND OF INVENTION

Gas sensors are known for determining composition concentrations in hot gases, for example, combustion exhaust gases produced by an internal combustion engine. A typical gas sensor includes a ceramic sensing element which includes electrodes at a sensing end thereof that are exposed to the gas being sensed while an opposing terminal end of the sensing element is fluidly isolated from the sensing end. The sensing element is commonly mounted in a metallic shell, and consequently, the sensing element must be sealed with respect to the shell in order to fluidly isolate the terminal end of the sensing element from the sensing end of the sensing element.


Various arrangements are currently used to seal the sensing element with respect to the shell in order to fluidly isolate the terminal end of the sensing element from the sensing end of the sensing element. In U.S. Pat. No. 5,238,551 to Katsu et al., talc that has been compressed between ceramic supports is used to form this seal. However, such a talc seal may not be effective under all conditions that the gas sensor may experience. In U.S. Pat. No. 6,477,887 to Ozawa et al., the sealing arrangement includes a glass seal which seals between the sensing element and an insulator while a mechanical seal is compressed to seal between the insulator and the shell. While this sealing arrangement may be effective, the mechanical seal requires an additional part which adds cost and complexity to the process.


What is needed is a gas sensor which minimizes or eliminates one or more of the shortcomings as set forth above.


SUMMARY OF THE INVENTION

Briefly described, a gas sensor is proved which includes a metallic shell with a shell aperture extending therethrough along an axis; a metallic glass holder metallurgically sealed to the shell in order to prevent gases from passing between the glass holder and the shell, the glass holder including a glass holder aperture extending axially therethrough; a ceramic sensing element extending through the shell aperture and through the glass holder aperture; and a glass seal which seals between the sensing element and the glass holder in order to prevent gases from passing between the sensing element and the glass holder. The glass seal between glass holder and the sensing element together with the metallurgical seal between the glass holder and the shell provides a robust sealing arrangement while minimizing components and simplifying manufacturing processes.


A method of making a gas sensor is also provide where the method includes providing a metallic shell with a shell aperture extending therethrough along an axis; providing a metallic glass holder including a glass holder aperture extending axially therethrough; positioning a ceramic sensing element through the shell aperture and through the glass holder aperture; metallurgically sealing the glass holder to the shell in order to prevent gases from passing between the glass holder and the shell; and providing a glass seal which seals between the sensing element and the glass holder in order to prevent gases from passing between the sensing element and the glass holder.


Further features and advantages of the invention will appear more clearly on a reading of the following detailed description of the preferred embodiment of the invention, which is given by way of non-limiting example only and with reference to the accompanying drawings.





BRIEF DESCRIPTION OF DRAWINGS

This invention will be further described with reference to the accompanying drawings in which:



FIG. 1 is an axial cross-sectional view of a gas sensor in accordance with the present invention;



FIG. 2 is an enlarged axial cross-sectional view of a glass holder and a shell of the gas sensor in accordance with the present invention prior to projection welding the glass holder to the shell;



FIG. 3 is a variation of FIG. 2;



FIG. 4 is an enlarged axial cross-sectional view showing a portion of the gas sensor and a glass preform that is used to form a glass seal in the gas sensor in accordance with the present invention;



FIG. 5 is an enlarged axial cross-sectional view of an upper shield and a shell of the gas sensor in accordance with the present invention prior to projection welding the upper shield to the shell; and



FIG. 6 is a variation of FIG. 5.





DETAILED DESCRIPTION OF INVENTION

In accordance with a preferred embodiment of this invention and referring to FIG. 1, a gas sensor 10 is shown which generally includes a sensing subassembly 12 and an electrical harness subassembly 14. Gas sensor 10 is arranged to sense constituents of hot gases, by way of non-limiting example only, oxygen concentration levels of exhaust gases in an exhaust conduit (not shown) of an internal combustion engine (not shown).


Sensing subassembly 12 includes a metallic shell 16 which may be made of, for example only, 400 series stainless steel and which extends along a shell axis 18 from a shell first end 20 that is distal from electrical harness subassembly 14 to a shell second end 22 that is proximal to electrical harness subassembly 14.


A shell aperture 24 extends axially through shell 16 from shell first end 20 to shell second end 22 such that shell aperture 24 is centered about shell axis 18. Shell aperture 24 includes a shell aperture first section 26 which extends part way into shell 16 from shell first end 20 and a shell aperture second section 28 which extends from shell aperture first section 26 to shell second end 22. Shell aperture first section 26 is larger in diameter than shell aperture second section 28, consequently, a shell shoulder 30 is defined where shell aperture first section 26 meets shell aperture second section 28 such that shell shoulder 30 is substantially perpendicular to shell axis 18.


A shell flange 32 extends radially outward from shell 16. Shell flange 32 may aid in mounting gas sensor 10 to the exhaust conduit and may also aid in attaching electrical harness subassembly 14 to shell 16 as will be described in greater detail later. The outer perimeter of shell 16 between shell first end 20 and shell flange 32 may be provided with external threads 34 which may be used to mate with corresponding internal threads (not shown) of the exhaust conduit for mounting gas sensor 10 to the exhaust conduit. The outer perimeter of shell flange 32 may be a hex-shape in order to facilitate engagement by a tool that is used to rotate shell 16 when mating external threads 34 with the internal threads of the exhaust conduit. The side of shell flange 32 that is proximal to shell second end 22 defines a shell attaching surface 38 that lies in a plane that is substantially perpendicular to shell axis 18. A shell extension 40 may extend axially away from shell flange 32 to shell second end 22. Shell extension 40 is cylindrical and centered about shell axis 18, thereby defining an external diameter 42.


Sensing subassembly 12 also includes a ceramic sensing element 44 which extends along a sensing element axis 46 from a sensing element sensing end 48 to a sensing element terminal end 50. As shown in FIG. 1, sensing element axis 46 is coincident with shell axis 18; however, sensing element axis 46 may not be coincident with shell axis 18 due to manufacturing tolerances and variations. Sensing element 44 may be any cross-sectional shape (as sectioned perpendicular to sensing element axis 46), however, may preferably be rectangular in cross-sectional shape. Sensing element sensing end 48 is exposed, in use, to the gas being sensed while sensing element terminal end 50 is fluidly isolated from the gas being sensed as will be described in greater detail later. Sensing element terminal end 50 may be fluidly isolated from sensing element sensing end 48 in order for sensing element terminal end 50 to be exposed to an air reference zone. Sensing element 44 may be, by way of non-limiting example only, a sensing element as described in U.S. Pat. No. 7,827,848 to Kuisell et al., the disclosure of which is incorporated herein by reference in its entirety. Sensing element 44 is rigidly fixed to shell 16 at a first axial location of sensing element 44 as will be describe in greater detail in the paragraphs that follow.


In order to fluidly isolate sensing element terminal end 50 from sensing element sensing end 48 and to rigidly fix sensing element 44 to shell 16, sensing subassembly 12 includes a metallic glass holder 52 and a glass seal 54. Glass holder 52 is cylindrical and extends axially from a glass holder first end 56 to a glass holder second end 58. A glass holder aperture 60 extends axially through glass holder 52 and includes a glass holder aperture first section 62 which extends part way into glass holder 52 from glass holder first end 56 and a glass holder aperture second section 64 which extends from glass holder aperture first section 62 to glass holder second end 58. Glass holder aperture first section 62 is larger in cross-sectional area (as sectioned perpendicular to shell axis 18) than the cross-sectional area of glass holder aperture second section 64 (as sectioned perpendicular to shell axis 18), consequently, a glass holder shoulder 65 is defined where glass holder aperture first section 62 meets glass holder aperture second section 64. Glass holder aperture first section 62 may be cylindrical while glass holder aperture second section 64 may be shaped to match the cross-sectional shape of sensing element 44. Glass holder aperture second section 64 is sized to surround sensing element 44 sufficiently close to accommodate the forming of glass seal 54 as will be described in greater detail later.


Glass holder 52 may be sized to fit within shell aperture first section 26 in a slip fit interface such that glass holder 52 can be inserted into shell aperture first section 26 substantially uninhibited while substantially preventing radial movement of glass holder 52 within shell aperture first section 26. In order to prevent gases from migrating past shell aperture first section 26 between metallic glass holder 52 and shell aperture first section 26, glass holder 52 is metallurgically sealed to shell 16. As shown in the figures, glass holder 52 is metallurgically sealed to shell 16 at an axial interface between glass holder 52 and shell shoulder 30. In a preferred embodiment, glass holder 52 is metallurgically sealed to shell 16 by welding, and even more preferably by projection welding as will be described in greater detail in the paragraphs that follow.


Referring now to FIGS. 2 and 3, in order to facilitate projection welding glass holder 52 to shell 16, either glass holder 52 or shell 16 includes a projection. As shown in FIG. 2, glass holder 52 (shown prior to being projection welded to shell 16) is provided with a projection 66 which is annular in shape and which comes to a point 68. Also as shown in FIG. 2, projection 66 may be defined at glass holder second end 58. Since projection 66 and glass holder aperture first section 62 are formed on opposite sides of glass holder 52, such an arrangement may be particularly conducive of manufacturing glass holder 52 by powder metal process or metal injection molding where powder metal is shaped in a mold and subsequently sintered in order to bind the particles of metal together. However, if glass holder 52 is desired to be made by machining from solid stock, projection 66 may be moved to glass holder first end 56 which allows projection 66 to be formed on the same side of glass holder 52 as glass holder aperture first section 62 which may be more desirable when machining glass holder 52 from solid stock. If projection 66 is formed on the same side of glass holder 52 as glass holder aperture first section 62, then glass holder 52 needs to be oriented in shell aperture first section 26 such that that glass holder first end 56 faces shell shoulder 30. Alternatively, as shown in FIG. 3, projection 66 is omitted from glass holder 52 and shell shoulder 30 is provided with a projection 70 which is annular in shape and which comes to a point 72.


In order to complete the projection weld between glass holder 52 and shell 16, a first welding electrode 74 is applied to shell 16 while a second welding electrode 76 is applied to glass holder 52 and projection 66 is place in contact with shell shoulder 30 (FIG. 2) or projection 70 is brought into contact with glass holder 52 (FIG. 3). Next, an electric current is passed between first welding electrode 74 and second welding electrode 76, consequently passing the electric current through shell 16 and glass holder 52. A compressive force is applied to projection 66 or projection 70 simultaneously with the passing of electric current through shell 16 and glass holder 52. The compressive force may be applied to projection 66 or projection 70 through one or both of first welding electrode 74 and second welding electrode 76 as represented by arrows F1. The electric current produces heat at projection 66 or projection 70 and the compressive force collapses projection 66 or projection 70, thereby metallurgically sealing glass holder 52 to shell 16. Projection 66 or projection 70 may be collapsed by about 80% of the original height (in the direction of shell axis 18).


Now with reference to FIGS. 1 and 4, in order to form glass seal 54, a glass preform 78 is provided which includes a glass preform aperture 80 extending therethrough. Glass preform 78 is sized to be received within glass holder aperture first section 62 and glass preform aperture 80 is sized to receive sensing element 44 therethrough. Preferably, sensing element 44 is inserted into glass preform aperture 80 and then glass preform 78 is disposed in glass holder aperture first section 62 such that sensing element 44 extends through glass holder aperture second section 64, however, it should now be understood that sensing element 44 may first be disposed within glass holder aperture second section 64 and then glass preform 78 may next be disposed within glass holder aperture first section 62 such that sensing element 44 extends through glass preform aperture 80. After sensing element 44 is positioned at the desired axial position relative to shell 16, glass preform 78 is heated to a sufficiently high temperature to allow glass preform 78 to become molten glass and flow and conform to sensing element 44, glass holder aperture first section 62, and glass holder shoulder 65. Glass preform 78 may be heated, by way of non-limiting example only, by an induction heating coil (not shown) that radially surrounds shell 16. It should be noted that the clearance between sensing element 44 and glass holder aperture second section 64 is sufficiently small in order to prevent glass preform 78 from escaping between sensing element 44 and glass holder aperture second section 64 when glass preform 78 is heated to allow it to flow. After allowing the molten glass to cool, thereby forming glass seal 54, glass seal 54 forms a hermetic seal with glass holder 52 and sensing element 44. The material of glass seal 54 is selected to be compatible with the high temperature environment that glass seal 54 will be exposed to in use. Glass seal 54 preferably has a coefficient of thermal expansion that is less than the coefficient of thermal expansion of glass holder 52.


Again with reference to FIG. 1, sensing subassembly 12 also includes a lower shield 82 which protects sensing element 44 from damage during installation of gas sensor 10 to the exhaust conduit and from damage during operation due high exhaust gas velocities and particulate that may be present in the exhaust gas. Lower shield 82 is made of metal, preferably stainless steel, and may be made, for example, by deep drawing. Lower shield 82 includes a plurality of lower shield louvers 84 therethrough in order to allow the gas to be sensed to be communicated to sensing element sensing end 48. Lower shield 82 may be attached to shell first end 20, for example, by crimping or welding.


Electrical harness subassembly 14 includes an upper shield 86; a plurality of electrical terminals 88 each having a corresponding wire 90 extending therefrom and providing electrical communication between sensing element 44 and an electronic device (not shown), for example only, an electronic control unit of a motor vehicle; a connector body 92; a retainer 94; and a sealing member 96.


Upper shield 86 may be made of, for example only, 400 series stainless steel which extends along an upper shield axis 98 from an upper shield first end 100 that is proximal to shell 16 to an upper shield second end 102 that is distal from shell 16.


An upper shield aperture 104 extends axially through upper shield 86 from upper shield first end 100 to upper shield second end 102 such that upper shield aperture 104 is centered about upper shield axis 98. Upper shield aperture 104 includes an upper shield aperture first section 106 which extends part way into upper shield 86 from upper shield first end 100 and an upper shield aperture second section 108 which extends from upper shield aperture first section 106 to upper shield second end 102. Upper shield aperture first section 106 is larger in diameter than upper shield aperture 104, consequently an upper shield shoulder 110 is defined where upper shield aperture first section 106 meets upper shield aperture 104. Upper shield aperture first section 106 defines an internal diameter 112 that radially surrounds shell extension 40 such that internal diameter 112 is larger than external diameter 42, the importance of which will be made readily apparent later.


An upper shield flange 114 extends radially outward from upper shield 86 at upper shield first end 100. The side of upper shield flange 114 that faces toward shell 16 defines an upper shield attaching surface 116 that is substantially perpendicular to upper shield axis 98. Upper shield flange 114 is used to attach electrical harness subassembly 14 to shell 16 as will be described in greater detail later.


Connector body 92 is made of an electrically insulative material, for example ceramic, and includes a connector body aperture 118 that extends through connector body 92 in the same general direction as upper shield axis 98. Connector body 92 is configured to hold electrical terminals 88 such that electrical terminals 88 extend into connector body aperture 118.


Retainer 94 may be made of metal and radially surrounds connector body 92. Retainer 94 grips the outer perimeter of connector body 92 and has features which are elastically deformed when retainer 94 and connector body 92 are inserted into upper shield aperture first section 106 until retainer 94 reaches upper shield shoulder 110. Consequently, retainer 94 prevents movement of connector body 92 within upper shield 86. It should be noted that retainer 94 may hold connector body 92 in such a way that connector body aperture 118 and electrical terminals 88 may not be centered about shell axis 18 or upper shield axis 98.


Sealing member 96 is preferably made from an elastomeric material and is disposed within upper shield aperture second section 108. Wires 90 pass through sealing member 96 such that each wire 90 is individually sealed with sealing member 96. Upper shield 86 may be radially crimped around sealing member 96, thereby allowing sealing member 96 to prevent intrusion of water and other contaminants from entering upper shield 86.


Sensing element terminal end 50 is received within connector body aperture 118 such that sensing element terminal end 50 elastically displaces electrical terminals 88 in order to provide reliable electrical contact with mating terminals (not shown) on sensing element 44. In this way, sensing element 44 is laterally supported by upper shield 86 at a second axial location of sensing element 44 that is axially apart from the axial location where sensing element 44 is rigidly fixed to shell 16.


Due to manufacturing tolerances and variations, shell axis 18, sensing element axis 46, and upper shield axis 98 may not always be coincident to one another. Consequently, if upper shield 86 is fixed to shell 16 in a concentric relationship such that shell axis 18 is coincident with upper shield axis 98, stress may be placed laterally on sensing element 44. In order to minimize or eliminate lateral stress on sensing element 44, upper shield 86 is attached to shell 16 using upper shield attaching surface 116 and shell attaching surface 38. Since upper shield attaching surface 116 is substantially perpendicular to upper shield axis 98 and shell attaching surface 38 is substantially perpendicular to shell axis 18, misalignment between upper shield axis 98 and shell axis 18 is accommodated while still allowing upper shield attaching surface 116 and shell attaching surface 38 to be joined together as will be described below. As described previously, internal diameter 112 of upper shield aperture first section 106 is larger than external diameter 42 of shell extension 40. This relationship accommodates the necessary misalignment between upper shield axis 98 and shell axis 18. Of course, the magnitude of allowable misalignment between upper shield axis 98 and shell axis 18 is determined by the difference in size between internal diameter 112 of upper shield aperture first section 106 and external diameter 42 of shell extension 40. Consequently, the difference in size between internal diameter 112 of upper shield aperture first section 106 and external diameter 42 of shell extension 40 is preferably designed to accommodate the maximum amount of misalignment between upper shield axis 98 and shell axis 18 that would be necessary to allow insertion of sensing element 44 into connector body aperture 118 while applying no lateral stress or an acceptable magnitude of lateral stress to sensing element 44.


Referring now to FIGS. 5 and 6, a method will now be describe for attaching upper shield 86 to shell 16. Prior to attaching upper shield 86 to shell 16; sensing element 44 is already rigidly fixed to shell 16 as described above. Also prior to attaching upper shield 86 to shell 16, electrical terminals 88, wires 90, connector body 92, retainer 94, and sealing member 96 are positioned within upper shield 86 as described above. Next, sensing element terminal end 50 is inserted into connector body aperture 118, thereby elastically displacing electrical terminals 88 and making electrical contact between electrical terminals 88 and sensing element 44. Sensing element terminal end 50 is inserted into connector body aperture 118 until upper shield attaching surface 116 contacts shell attaching surface 38. The relative position of upper shield axis 98 and shell axis 18 is allowed to be determined by sensing element 44 and electrical terminals 88, thereby preventing excessive lateral stress from being applied to sensing element 44 by upper shield 86 which now laterally supports sensing element 44. After sensing element 44 and electrical terminals 88 determine the relative position of upper shield axis 98 and shell axis 18, upper shield 86 is attached to shell 16 at an interface formed between upper shield attaching surface 116 and shell attaching surface 38, for example, by metallurgical bonding. Projection welding may be used in a preferred embodiment of attaching upper shield 86 to shell 16 at an interface formed between upper shield attaching surface 116 and shell attaching surface 38. As shown in FIG. 5 upper shield attaching surface 116 is further defined by an annular projection 120 which extends axially from upper shield flange 114 toward shell attaching surface 38 and comes to a point 122. Alternatively, as shown in FIG. 6, projection 120 is omitted from upper shield flange 114 and shell attaching surface 38 is further defined by an annular projection 124 which extends axially from shell flange 32 toward upper shield 86 and comes to a point 126.


In order to complete the projection weld between upper shield 86 and shell 16, a third welding electrode 128 is applied to shell 16 while a fourth welding electrode 130 is applied to upper shield 86 and projection 120 is placed in contact with shell attaching surface 38 (FIG. 5) or projection 124 is brought into contact with upper shield attaching surface 116 (FIG. 6). Next, an electric current is passed between third welding electrode 128 and fourth welding electrode 130, consequently the electric current passes through shell 16 and upper shield 86. A compressive force is applied to projection 120 or projection 124 simultaneously with the passing of electric current through shell 16 and upper shield 86. The compressive force may be applied to projection 120 or projection 124 through one or both of third welding electrode 128 and fourth welding electrode 130 as represented by arrows F2. The electric current produces heat at projection 120 or projection 124 and the compressive force collapses projection 120 or projection 124, thereby metallurgically boding upper shield 86 to shell 16. Projection 120 or projection 124 may be collapsed by about 80% of the original height (in the direction of upper shield axis 98).


While this invention has been described in terms of preferred embodiments thereof, it is not intended to be so limited, but rather only to the extent set forth in the claims that follow.

Claims
  • 1. A method of making a gas sensor, said method comprising: providing a metallic shell with a shell aperture extending therethrough along an axis;providing a metallic glass holder including a glass holder aperture extending axially therethrough;positioning a ceramic sensing element through said shell aperture and through said glass holder aperture;metallurgically sealing said glass holder to said shell in order to prevent gases from passing between said glass holder and said shell; andproviding a glass seal which seals between said sensing element and said glass holder in order to prevent gases from passing between said sensing element and said glass holder;wherein one of said shell and said glass holder includes an annular projection extending axially therefrom and said step of metallurgically sealing said glass holder to said shell comprises:placing said projection in contact with a) said shell if said glass holder includes said projection or b) said glass holder if said shell includes said projection; andpassing an electric current through said shell and said glass holder and simultaneously applying a compressive force to said projection, thereby creating heat at said projection and collapsing said projection in order to metallurgically seal said glass holder to said shell.
  • 2. A method as in claim 1 wherein: said glass holder includes said projection;said shell extends from a shell first end to a shell second end;said shell aperture includes a shell aperture first section extending from said shell first end part way into said shell and a shell aperture second section extending from said shell aperture first section to said shell second end such that a shell shoulder is formed where said shell aperture first section meets said shell aperture second section; andsaid step of placing said projection includes placing said projection in contact with said shell shoulder.
  • 3. A method as in claim 2 wherein: said glass holder extends from a glass holder first end to a glass holder second end;said glass holder aperture includes a glass holder aperture first section extending from said glass holder first end part way into said glass holder and a glass holder aperture second section extending from said glass holder aperture first section to said glass holder second end; andsaid projection is located on said glass holder second end.
  • 4. A method as in claim 3 wherein said glass holder aperture first section is larger in cross-sectional area than said glass holder aperture second section.
  • 5. A method of making a gas sensor, said method comprising: providing a metallic shell with a shell aperture extending therethrough along an axis;providing a metallic glass holder including a glass holder aperture extending axially therethrough;positioning a ceramic sensing element through said shell aperture and through said glass holder aperture;metallurgically sealing said glass holder to said shell in order to prevent gases from passing between said glass holder and said shell; andproviding a glass seal which seals between said sensing element and said glass holder in order to prevent gases from passing between said sensing element and said glass holder;wherein said step of metallurgically sealing said glass holder to said shell is performed prior to said steps of positioning said sensing element and providing said glass seal.
  • 6. A method of making a gas sensor, said method comprising: providing a metallic shell with a shell aperture extending therethrough along an axis;providing a metallic glass holder including a glass holder aperture extending axially therethrough;positioning a ceramic sensing element through said shell aperture and through said glass holder aperture;metallurgically sealing said glass holder to said shell in order to prevent gases from passing between said glass holder and said shell; andproviding a glass seal which seals between said sensing element and said glass holder in order to prevent gases from passing between said sensing element and said glass holder;wherein said step of providing said glass seal comprises:providing a glass preform with a glass preform aperture therethrough;positioning said sensing element in said glass preform aperture;heating said glass preform to melt said glass preform to create molten glass; andcooling said molten glass to form said glass seal.
  • 7. A method as in claim 6 wherein: said glass holder extends from a glass holder first end to a glass holder second end;said glass holder aperture includes a glass holder aperture first section extending from said glass holder first end part way into said glass holder and a glass holder aperture second section extending from said glass holder aperture first section to said glass holder second end; andsaid step of providing said glass seal further comprises positioning said glass preform in said glass holder aperture first section.
US Referenced Citations (8)
Number Name Date Kind
5238551 Katsu Aug 1993 A
6477887 Ozawa et al. Nov 2002 B1
6550309 Noda Apr 2003 B1
7341650 Matsuo Mar 2008 B2
7454949 Geier Nov 2008 B2
7497109 Satou Mar 2009 B2
7811434 Mizutani Oct 2010 B2
7827848 Kuisell et al. Nov 2010 B2
Related Publications (1)
Number Date Country
20150354996 A1 Dec 2015 US