The present invention relates generally to systems and methods for cooling or liquefying gases and, more particularly, to a system and method for removing selected components from such gases.
Natural gas is often liquefied under pressure for storage, use and transport. The reduction in volume that results from liquefaction permits containers of more practical and economical design to be used.
Natural gas is typically obtained from underground reservoirs via drilling or similar operations. The resulting natural gas streams, while primarily methane, may contain components such as heavy hydrocarbons (including, for example, butane, ethane, pentane and propane, benzenes, xylenes, heptanes, octanes and heavier components), carbon dioxide, hydrogen, nitrogen and water.
Liquefaction is typically accomplished by chilling the natural gas through indirect heat exchange by one or more refrigeration cycles in one or more heat exchangers. If components such as heavy hydrocarbons are present in a gas stream during liquefaction, such components may freeze and impair operation of the liquefaction heat exchanger. It also may be desirable to recover components as products. In addition, liquid natural gas of higher purity produces less greenhouse gases such as carbon dioxide when it is burned as a fuel.
There are several aspects of the present subject matter which may be embodied separately or together in the methods, devices and systems described and claimed below. These aspects may be employed alone or in combination with other aspects of the subject matter described herein, and the description of these aspects together is not intended to preclude the use of these aspects separately or the claiming of such aspects separately or in different combinations as set forth in the claims appended hereto
In one aspect, a system for removing selected components from a gas stream includes a heat exchanger having a first cooling passage configured to receive a feed gas stream and to provide a cooled feed gas stream. An expander is configured to receive at least a portion of the cooled feed gas stream. A separation device is configured to receive an expanded fluid stream from the expander and to separate the expanded fluid stream into a liquid stream containing selected components and a purified vapor stream having a purified vapor temperature. A compressor is configured to receive the purified vapor stream at approximately the purified vapor temperature and to produce a compressed vapor stream that is returned to the heat exchanger.
In another aspect, a system for liquefying a feed gas includes a heat exchanger having a first cooling passage and a second cooling passage. The first cooling passage is configured to receive a feed gas stream so that a cooled feed gas stream is formed. A mixed refrigerant compression system is in communication with the heat exchanger and configured to cool the first and second cooling passages. A liquefied gas outlet line is connected to an outlet of the second cooling passage. An expander is configured to receive at least a portion of the cooled feed gas stream from the first cooling passage. A separation device is configured to receive an expanded fluid stream from the expander and to separate the expanded fluid stream into a liquid stream containing selected components and a purified vapor stream having a purified vapor temperature. A compressor is configured to receive the purified vapor stream at approximately the purified vapor temperature and to produce a compressed vapor stream. The second cooling passage is configured to receive and liquefy the compressed vapor stream.
In still another aspect, a process is provided for removing selected components from a gas stream and includes the steps of cooling a feed gas stream to provide a cooled feed gas stream, expanding the cooled feed gas stream to provide an expanded gas stream, separating the expanded gas stream into a liquid stream containing selected components and a purified vapor stream having a purified vapor temperature; and compressing the purified vapor stream to provide a compressed vapor stream.
In yet another aspect, a method of liquefying a gas feed stream includes the steps of cooling a gas feed gas stream to provide a cooled feed gas stream, expanding the cooled feed gas stream to provide an expanded gas stream, separating the expanded gas stream into a liquid stream containing selected components and a purified vapor stream having a purified vapor temperature, compressing the purified vapor stream to provide a compressed vapor stream and cooling the compressed vapor stream to form a liquefied gas stream.
Mixed refrigerant liquefaction systems and methods including embodiments of the component removal system of the disclosure are illustrated in
With reference to
Generally, with reference to
Alternative designs and types of heat exchangers may be substituted for the BAHX illustrated at 16 in
The system of
The removal of heat is accomplished in the heat exchanger using a mixed refrigerant that is processed and reconditioned using a mixed refrigerant compressor system indicated in general at 26. The mixed refrigerant compressor system includes a high pressure accumulator 32 that receives and separates a mixed refrigerant (MR) mixed-phase stream 34 after a last compression and cooling cycle. While an accumulator drum 32 is illustrated, alternative separation devices may be used, including, but not limited to, another type of vessel, a cyclonic separator, a distillation unit, a coalescing separator or mesh or vane type mist eliminator. High pressure vapor refrigerant stream 36 exits the vapor outlet of the accumulator 32 and travels to the warm end portion 18 of the heat exchanger 16.
High pressure liquid refrigerant stream 38 exits the liquid outlet of accumulator 32 and also travels to the warm end of the heat exchanger. After cooling in the heat exchanger, it travels as mixed phase stream 40 to mid-temp standpipe 42.
After the high pressure vapor stream 36 from the accumulator 32 is cooled in the heat exchanger 16, a mixed phase stream 44 flows to a cold vapor separator 46. A resulting vapor refrigerant stream 48 exits the vapor outlet of the separator 46 and, after cooling in the heat exchanger 16, travels to cold temperature standpipe 52 as mixed-phase stream 54. Vapor and liquid streams 56 and 58 exit the cold temperature standpipe 52 and feed into the primary refrigeration passage 62 at the cold end 20 of the heat exchanger 16.
A vaporized mixed refrigerant stream 63 exits the warm end 18 of the heat exchanger and, after passing through an optional suction drum 65, is directed to the inlet of a compressor of an initial compression and cooling cycle.
A liquid stream 64 exits the cold vapor separator 46, is cooled in heat exchanger 16 and exits the heat exchanger as mixed-phase stream 66. Mixed phase stream 66 is directed to the mid-temp standpipe 42 and combined with the mixed phase stream 40 from the liquid outlet of accumulator 32. Vapor and liquid streams 72 and 74 exit the mid-temp standpipe and feed into the primary refrigeration passage 62 as illustrated.
An interstage separation device 76 receives and separates a mixed refrigerant mixed-phase stream 78 after the initial compression and cooling cycle. While a separation drum 76 is illustrated, alternative separation devices may be used, including, but not limited to, another type of vessel, a cyclonic separator, a distillation unit, a coalescing separator or mesh or vane type mist eliminator. A liquid stream 82 exits the liquid outlet of the interstage separation device, is cooled in heat exchanger 16, and the resulting stream 84 is expanded and directed to the primary refrigeration passage 62. A vapor stream 85 exits a vapor outlet of the interstage separation device and travels to the last compression and cooling cycle of the compression system. In alternative embodiments of the system, the interstage separation device may include only a vapor outlet, or it may be eliminated entirely.
In accordance with the disclosure, the component removal system 12 receives a cooled gas feed stream 86, which is produced by cooling feed gas stream 22 in a first cooling passage 88a of the main heat exchanger 16.
Cooled feed gas stream 86, after withdrawal from the main heat exchanger 16, is directed to an optional suction drum 92. A vapor stream 94 from the suction drum travels to an expander 96, which is preferably an expansion turbine, so that the gas stream pressure is reduced below the critical pressure. This causes the components that would freeze and/or other components that would condense in the main heat exchanger to condense so that a mixed-phase stream 98 is formed. This mixed-phase stream 98 travels to a separation device 102, where a liquid stream 104 containing the condensed freezing components and other selected components is withdrawn from the bottom.
While an expansion turbine is illustrated as the expander 96, alternative expansion devices including, but not limited to, expansion valves or orifices could be used.
Any liquid collected in the suction drum 92 may be directed to the mixed phase stream 98 traveling to the separation device by opening a drain valve 106 in a liquid drain line 108 exiting the bottom of the suction drum. This prevents potential damage to the expander 96. Alternatively, the liquid from the suction drum may go directly into the separation device 102 after exiting valve 106.
As indicated above, the suction drum 92, and thus liquid line 108 and drain valve 106, is optional and thus may be omitted with the feed stream withdrawn from the main heat exchanger being routed directly to the inlet of the expander 96. Or, in an alternative embodiment, the stream routed to the inlet of the expander 96 may be slightly heated (such as by a passage through a portion of the heat exchanger 16 or a dedicated heat exchanger) to vaporize any liquid in the stream or hot gas bypass of the feed gas.
A purified methane-rich vapor stream 112 exits the top of the separation device 102 at a purified vapor temperature and is directed to a compressor (or compressors) 114, which may be powered by the expander 96 (in versions of the system where the expander is a turbine) or a motor 115, or a combination of both. Use of the expander to power the compressor recovers energy from the high pressure gas stream received by the expander.
The ideal pressure for optimal efficiency for the stream returning to the heat exchanger for liquefaction (the “return pressure”) is a pressure corresponding to a temperature (the “return temperature”) that is nearly equal to the temperature of the suction drum or stream exiting heat exchanger passage 88a. By receiving the vapor stream 112 at the purified vapor temperature (or at approximately the purified vapor temperature due to potential incidental warming of the purified vapor stream as it flows from the separation device 102 to the compressor inlet), the compressor 114 “cold compresses” the vapor stream 112 to a higher pressure and a temperature, where the temperature of the compressed stream is approximately equal to or slightly below the temperature of the vapor in the suction drum 92 or the cooled gas stream 86 withdrawn from the main heat exchanger. The return temperature of the vapor stream 118 exiting the compressor is ideally near or below the temperature of the gas in the suction drum 92 (or stream 86) because the system does not heat the vapor exiting the separation device 102 prior to entry into the compressor 114. Furthermore, by having cold vapor enter the compressor 114, the pressure of the vapor exiting the compressor is higher and the temperature is lower than if the vapor from the separation device 102 was heated prior to entry into the compressor (for the same compressor power level). As a result, the refrigeration power required for a given level of liquid natural gas production is reduced or, conversely, a higher liquid natural gas production is obtained if the refrigeration power is fixed. The compressed vapor stream 118 is returned to a second cooling passage 88b of the heat exchanger 16 at a return pressure and a return temperature to be liquefied so that LNG product stream 24 is produced.
While first and second cooling passages 88a and 88b of
The process shown is for a natural gas liquefaction process, however, the system and process illustrated at 12 may be used with any other process that requires separating at least part of the incoming feed gas at a lower pressure and temperature and benefits from returning the feed gas at a higher pressure.
As illustrated in
As illustrated in
A compression system provides mixed refrigerant streams to, and receives a mixed refrigerant stream 128 from, the heat exchanger 116 and conditions the mixed refrigerant in the same manner as compression system 26 of
As is known in the art, the CWHX heat exchanger 116 includes a shell 132 that receives the conditioned mixed refrigerant streams 134, 136, 138 and 140. Mixed refrigerant stream 134 is formed by cooling and expanding the vapor stream 142 from the cold vapor separator 144. Mixed refrigerant stream 136 is formed by cooling and expanding the liquid stream 146 from the cold vapor separator 144. Mixed refrigerant stream 138 is formed by cooling and expanding the liquid stream 148 from the high pressure accumulator 152. Mixed refrigerant stream 140 is formed by cooling and expanding the liquid stream 154 from the interstage separation device 156.
The cooling passages 188a and 188b of the heat exchanger 116, and the passages used to cool the mixed refrigerant, are formed by tube bundles wrapped around a core or mandrel and positioned within the shell 132 of the heat exchanger. As a result, the exterior surfaces of the tube bundles are exposed to the mixed refrigerant streams 134, 136, 138 and 140 entering the shell.
Similar to the system and process of
An alternative embodiment of the component removal system is indicated in general at 200 in
As explained below, the component removal system 200 of
With reference to
The component removal system 200 receives a cooled gas feed stream 206, which is produced by cooling feed gas stream 202 in the first cooling passage 88a of the main heat exchanger 16.
Cooled feed gas stream 206, after withdrawal from the main heat exchanger 16, is directed to an optional suction drum 208. A vapor stream 210 from the suction drum travels to an expander 212, which is preferably an expansion turbine, so that the gas stream pressure is reduced below the critical pressure. This causes the components that would freeze and/or other selected components that would condense in the main heat exchanger to condense so that a mixed-phase stream 214 is formed. While an expansion turbine is illustrated as the expander 212, alternative expansion devices including, but not limited to, expansion valves or orifices could be used.
This mixed-phase stream 214 travels to a separation column, indicated in general at 216. The column 216 includes a separation section 218 and a stripping section 220. As is known in the art, the stripping section 220 may include mesh pads, trays, packing and similar components.
Mixed-phase stream 214 enters the separation section 218 of the column and is separated into vapor and liquid portions. The liquid portion flows down into the stripping section 220 directly and/or through an internal or external distribution arrangement including, for example, distribution line 224 and distribution device 226.
A stripping gas is provided through stripping gas line 228 which directs a portion of the feed gas stream 202 to the bottom portion of the stripping section 220 under the control of valve 230. Alternatively, stripping gas may be withdrawn from stream 88a at a colder temperature.
A liquid stream 232 containing the condensed freezing components and other selected components is withdrawn from the bottom of the column 216.
Any liquid collected in the suction drum 208 may be directed to the stripping section 220 of column 216 by opening a drain valve 236 in a liquid line 234 exiting the bottom of the suction drum. This prevents potential damage to the expander 212.
The suction drum 208, and thus liquid line 234 and drain valve 236, is optional and thus may be omitted with the feed stream withdrawn from the main heat exchanger being routed directly to the inlet of the expander 212.
A purified methane-rich vapor stream 238 exits the top of the separation column 216 and is directed to a compressor 242, which may be powered by the expander 212 (in versions of the system where the expander is a turbine) or a motor 244, or a combination of both. By receiving the vapor stream at the temperature of the separation device, the compressor 242 “cold compresses” the vapor stream 238 to a higher pressure and a temperature, where the temperature of the compressed gas stream is ideally approximately equal to or slightly below the temperature of the vapor in the suction drum 208 or the cooled gas stream 206 withdrawn from the main heat exchanger. The outlet temperature of the vapor stream 246 exiting the compressor is near or below the temperature of the gas in the suction drum 208 (or stream 206) because the system does not heat the vapor exiting the separation column 216 prior to entry into the compressor 242. Furthermore, by having cold vapor enter the compressor 242, the pressure of the vapor exiting the compressor is higher than if the vapor from the separation column 216 was heated prior to entry into the compressor (for the same compressor power level). As a result, the refrigeration power required for a given level of liquid natural gas production is reduced or, conversely, a higher liquid natural gas production is obtained if the refrigeration power is fixed. The compressed vapor stream 246 is returned to the second cooling passage 88b of the heat exchanger 16 to be liquefied so that LNG product stream 204 is produced.
An alternative version of the system of
The remaining aspects of the contamination system 300, separation column 302 and the liquefaction system 14 of
An alternative embodiment of the component removal system is indicated in general at 400 in
The system 400 includes a main heat exchanger 406 including a warm end portion 406, a cold end portion 410 and first and second cooling passages 408a and 408b. As illustrated in
In the embodiment of
The component removal system embodiments presented above recompress a gas from a separation device, wherein selected components are removed from the gas, without warming the gas such that the compressor suction is cold, that is, at the temperature of the separation device. Power required for compression and discharge temperature of the compressor are proportional to the suction temperature. Therefore, compressing cold allows the compressor discharge pressure to be higher and the temperature to be lower than if the suction was warmed first, with the fixed power available, and the desired return temperature and return pressure to the main heat exchanger. As a result, the refrigeration power required for a given level of liquid natural gas production is reduced or, conversely, a higher liquid natural gas production is obtained if the refrigeration power is fixed.
While the preferred embodiments of the invention have been shown and described, it will be apparent to those skilled in the art that changes and modifications may be made therein without departing from the spirit of the invention, the scope of which is defined by the appended claims.
This application claims the benefit of U.S. Provisional Application No. 63/034,112, filed Jun. 3, 2020, the contents of which are hereby incorporated by reference.
Number | Date | Country | |
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63034112 | Jun 2020 | US |