Claims
- 1. An aqueous, liquid, hard surface detergent composition having improved cleaning and good filming/streaking characteristics comprising:(A) from about 0.001% to about 3% of a blooming perfume composition comprising at least about 50% of blooming perfume ingredients selected from the group consisting of: ingredients having a boiling point of less than about 260° C. and a ClogP of at least about 3, and wherein said perfume composition comprises at least 5 different blooming perfume ingredients; (B) from about 0.001% to about 2% of detergent surfactant system selected from the group consisting of anionic surfactants, amphoteric detergent surfactants including zwitterionic surfactants; and mixtures thereof; and (C) from about 0.5% to about 30% of hydrophobic solvent; (D) the balance being an aqueous solvent system comprising water and, optionally, non-aqueous polar solvent with only minimal cleaning action selected from the group consisting of methanol, ethanol, isopropanol, ethylene glycol, polypropylene glycol, glycol ethers having a hydrogen bonding parameter of greater than 7.7, and mixtures thereof and any minor ingredients.
- 2. The composition of claim 1 wherein said blooming perfume composition does not contain any single ingredient at a level of more than about 60% by weight of the perfume composition.
- 3. The composition of claim 2 wherein component (B) is selected from the group consisting of:(1) from about 0.001% to about 2% detergent surfactant having the generic formula: RN(R1)(CH2)nN(R2)(CH2)pC(O)OM wherein R is a C6-C10 hydrophobic moiety, including fatty acyl moiety containing from about 6 to about 10 carbon atoms which in combination with the nitrogen atom forms an amido group, R1 is hydrogen or a C1-2 alkyl group, R2 is a C1-2 alkyl, carboxymethoxy ethyl, or hydroxy ethyl, each n is an integer from 1 to 3, each p is an integer from 1 to 2 and M is a water soluble cation selected from alkali metal, ammonium, alkanolammonium, and mixtures thereof cations; (2) from about 0.001% to about 2% detergent surfactant having the generic formula: R3—[C(O)—N(R4)—(CR52)n1—]mN(R6)2(+)—(CR52)p1—Y(−) wherein each R3 is an alkyl, or alkylene, group containing from about 10 to about 18 carbon atoms, each (R4) and (R6) is selected from the group consisting of hydrogen, methyl, ethyl, propyl, hydroxy substituted ethyl or propyl and mixtures thereof, each (R5) is selected from the group consisting of hydrogen and hydroxy groups, with no more than about one hydroxy group in any (CR52)p1 moiety; m is 0 or 1; each n1 and p1 is a number from 1 to about 4; and Y is a carboxylate or sulfonate group; (3) from about 0.001% to about 2.0% detergent surfactant having the generic formula: R9—(R10)0-1—SO3(−)M(+) wherein R9 is a C6-C20 alkyl chain; R10 is a C6-C20 alkylene chain, a C6H4 phenylene group, or O; and M is the same as before; and(4) mixtures thereof.
- 4. The composition of claim 3 wherein the blooming perfume ingredients are selected from the group consisting of: Allo-Ocimene, allyl cyclohexanepropionate, Allyl Heptoate, trans Anethol, Benzyl Butyrate, Camphene, Cadinene, Carvacrol, cis-3-Hexenyl Tiglate, Citronellol, Citronellyl Acetate, Citronellyl Nitrile, Citronellyl Propionate, Cyclohexyl Ethyl Acetate, Decyl Aldehyde, Dihydromycernol, Dihydromyrcenyl Acetate, 3,7 dimethyl-1-Octanol, Diphenyl Oxide, Fenchyl Acetate, Geranyl Acetate, Geranyl Formate, Geranyl Nitrile, cis-3-Hexenyl Isobutyrate, Hexyl Neopentanoate, Hexyl Tiglate, alpha-Ionone, Isobornyl Acetate, Isobutyl Benzoate, Isononyl Acetate, Isononyl Alcohol, Isopulegyl acetate lauraldehyde, d-Limonene, Linalyl Acetate, (−)-L-Menthyl Acetate, Methyl Chavicol, Methyl -n-Nonyl Acetaldehyde, Methyl Octyl Acetaldehyde, beta-Myrcene, Neryl Acetate, Nonyl Acetate, Nonyl Aldehyde, para-Cymene, alpha-Pinene, beta-Pinene, alpha-Terpinene, gamma-Terpinene, alpha-Terpinyl acetate, Tetrahydro Linalool, Tetrahydro Myrcenol, 2-Undecenal, Veratrol, Verdox, and Vertenex.
- 5. The composition of claim 3 wherein said blooming perfume composition also includes delayed blooming perfume ingredients selected from the group consisting of perfume ingredients having a boiling point of less than about 260° C. and a ClogP of less than about 3, wherein the ratio of blooming perfume ingredients to delayed blooming ingredients is at least 1:1.
- 6. The composition of claim 5 wherein the delayed blooming perfume ingredients are selected from the group consisting of: Allyl Caproate, Amyl Acetate, Amyl Propionate, p-anisaldehyde, Anisole, Benzaldehyde, Benzyl Acetate, Benzyl Acetone, Benzyl Alcohol, Benzyl Formate, Benzyl Iso Valerate, Benzyl Propionate, Beta Gamma Hexenol, (+)-Camphor, (+)-Carvone, L-Carvone, Cinnamic Alcohol, Cinnamyl Formate, cis-Jasmone, cis-3-Hexenyl Acetate, Citral, Cumic alcohol, Cuminic aldehyde, Cyclal, Dimethyl Benzyl Carbinol, Dimethyl Benzyl Carbinyl Acetate, Ethyl Acetate, Ethyl acetoacetate, Ethyl Amyl Ketone, Ethyl Benzoate, Ethyl butanoate, Ethyl Hexyl Ketone, Ethyl Phenyl Acetate, Eucalyptol, Eugenol, Fenchyl Alcohol, Flor Acetate, Frutene, gamma Nonalactone, trans-Geraniol, cis-3-Hexen-1-ol, Hexyl Acetate, Hexyl Formate, Hydratropic Alcohol, Hydroxycitronellal, Indole, Isoamyl Alcohol, Isopulegol, isopropylphenylacetate, Isoquinoline, Ligustral, Linalool, Linalool Oxide, Linalyl Formate, Menthone, 4-Methyl Acetophenone, Methyl Pentyl Ketone, Methyl Anthranilate, Methyl Benzoate, Methyl Phenyl Carbinyl Acetate, Methyl Eugenol, Methyl Heptenone, Methyl Heptine Carbonate, Methyl Heptyl Ketone, Methyl Hexyl Ketone, Methyl Salicylate, Dimethyl Anthranilate, Nerol, gamma-Octalactone, 2-Octanol, Octyl Aldehyde, para-Cresol, para-Cresyl Methyl Ether, Acetanisole, 2-Phenoxy Ethanol, Phenyl Acetaldehyde, 2-Phenyl Ethyl Acetate, Phenyl Ethyl Alcohol, Phenyl Ethyl Dimethyl Carbinol, Prenyl Acetate, Propyl Butanoate, (+)-Pulegone, Rose Oxide, Safrole, 4-Terpinenol, Terpolene, Veratrole, and Veridine.
- 7. The composition of claim 1 wherein the blooming perfume composition has at least 55% of blooming perfume ingredients.
- 8. The composition of claim 7 wherein the blooming perfume composition has at least 60% of blooming perfume ingredients.
- 9. The composition of claim 8 wherein the blooming perfume composition has at least 70% of blooming perfume ingredients.
- 10. The composition of claim 1 wherein the level of said blooming perfume composition is from about 0.01% to about 1% by weight of the total composition.
- 11. The composition of claim 10 wherein the level of said blooming perfume composition is from about 0.01% to about 0.5%.
- 12. The composition of claim 11 wherein the blooming perfume composition has at least 70% of blooming perfume ingredients.
- 13. The process of cleaning glass with an effective amount of the composition of claim 1.
REFERENCE TO RELATED APPLICATIONS
This is a continuation-in-part of U.S. Ser. No. 08/618,523, filed Mar. 19, 1996 now abandoned.
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
08/618523 |
Mar 1996 |
US |
Child |
09/025229 |
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US |