Patent Application
20050144982
This application claims priority of Taiwanese Patent Application No. 093100345, filed on Jan. 7, 2004.
1. Field of the Invention
This invention relates to a glass molding tool including a molding core and a protective structure, more particularly to a glass molding tool including a molding core and a multi-layer protective structure.
2. Description of the Related Art
Up to now, the problem encountered in the art of glass molding cores is that no suitable protective material for the glass molding core is available. The alloy film of noble metals plated on the glass molding core as the protective material is chemically inert, has difficulty in reacting with glass to be molded and active gases that exist in the molding atmosphere, and thus is an ideal material for the protective material. However, when the molding operation of glass is conducted continuously for a long period of time, the surface of the alloy film tends to be roughened due to grain growth. Hence, the molded glass thus made cannot satisfy the required optical quality. In addition, although ceramic films (such as chromium nitride and tantalum nitride, etc.) have good thermo-resistance and good adhesion to a tungsten carbide substrate of the glass molding core, they tend to react with glass to be molded and the active gases that exist in the molding atmosphere. Consequently, the surface of the ceramic films tends to be discolored and adhere to the glass to be molded. As shown in
Although the grain growth of the metallic layers, the discoloration of the ceramic layers, and the adhesion of the ceramic layers to the glass can be avoided by using the mold 1 as described in the aforesaid Japanese publication, the adhesivity between each ceramic layer and an adjacent metallic layer is poor as a result of the great difference in surface properties between the metallic layers and the ceramic layers. Therefore, how to improve the adhesivity between the ceramic layers and the metallic layers is a pressing need in the art of glass molding cores.
Therefore, the object of the present invention is to provide a glass molding tool that can overcome the aforesaid drawbacks of the prior art.
According to the present invention, a glass molding tool includes a molding core and a protective structure that is formed on the molding core and that includes a ceramic layer formed on the molding core, a buffer layer that is formed on the ceramic layer and that has a composition including a ceramic material and a metallic material, and a metallic layer formed on the buffer layer. The buffer layer has a ceramic concentration gradient that gradually decreases along a direction from the ceramic layer toward the metallic layer, and has a metallic concentration gradient that gradually increases along the direction from the ceramic layer toward the metallic layer.
Other features and advantages of the present invention will become apparent in the following detailed description of the preferred embodiment of the invention, with reference to the accompanying drawings. In the drawings:
Referring to
Preferably, the glass molding tool of this embodiment further includes a second protective structure 4 that includes a second buffer layer 411 formed on the first metallic layer 313 of the first protective structure 3 and having a composition including a second ceramic material and a second metallic material, a second ceramic layer 412 formed on the second buffer layer 411, a third buffer layer 413 formed on the second ceramic layer 412 and having a composition including a third ceramic material and a third metallic material, and a second metallic layer 414 formed on the third buffer layer 413. The second buffer layer 411 has a ceramic concentration gradient that gradually increases along a direction from the first metallic layer 313 of the first protective structure 3 toward the second ceramic layer 412 of the second protective structure 4, and a metallic concentration gradient that gradually decreases along the direction from the first metallic layer 313 of the first protective structure 3 toward the second ceramic layer 412 of the second protective structure 4. The third buffer layer 413 has a ceramic concentration gradient that gradually decreases along a direction from the second ceramic layer 412 toward the second metallic layer 414, and a metallic concentration gradient that gradually increases along the direction from the second ceramic layer 412 toward the second metallic layer 414.
In this embodiment, each of the first, second and third ceramic materials and the first and second ceramic layers 311, 412 is made from a compound selected from the group consisting of nitride, carbide and boride. Preferably, the nitride is selected from the group consisting of titanium chromium nitride (TiCrN), titanium aluminum nitride (TiAlN), chromium nitride (CrN), tantalum nitride (TaN), titanium nitride (TiN), and aluminum nitride (AlN). Preferably, the carbide is selected from the group consisting of titanium carbide (TiC), chromium carbide (Cr3C2), zirconium carbide (ZrC), niobium carbide (NbC), and tantalum carbide (TaC).
In addition, in this embodiment, each of the first, second and third metallic materials and the first and second metallic layers 313, 414 is made from a noble metal selected from the group consisting of iridium (Ir), rhenium (Re), ruthenium (Ru), rhodium (Rh), platinum (Pt), osmium (Os), and alloys thereof. Preferably, each of the first, second and third metallic materials and the first and second metallic layers 313, 414 is made from an alloy of iridium (Ir) and rhenium (Re). Alternatively, each of the first, second and third metallic material and the first and second metallic layers 313, 414 is made from an alloy of iridium (Ir) and ruthenium (Ru).
In another aspect, each of the first metallic layer 313 of the first protective structure 3 and the second metallic layer 414 of the second protective structure 4 may contain an additional element that has a high melting point and that is selected from the group consisting of tantalum (Ta), carbon (C), titanium (Ti), chromium (Cr), tungsten (W), and manganese (Mn). Preferably, the element is tantalum (Ta). The grain growth at the grain boundary of each of the first and second metallic layers 313, 414 can be inhibited by including a high melting point element in these metallic layers 313, 414.
The glass molding tool of this invention may include a plurality of the second protective structures 4, as best shown in
The structural feature of the glass molding tool and the ceramic and metallic concentration gradients will be explained in greater detail with reference to the following examples:
In this Example, the molding core 2 is made from WC, the first ceramic layer 311 is a TiCrN layer, and the first metallic layer 313 is an Ir—Re layer. The first buffer layer 312 has a TiCrN concentration gradient that gradually decreases along the direction from the first ceramic layer 311 toward the first metallic layer 313, and an Ir—Re concentration gradient that gradually increases along the direction from the first ceramic layer 311 toward the first metallic layer 313.
The second ceramic layer 412 is a TiCrN layer. The second metallic layer 414 is an Ir—Re layer. The second buffer layer 411 has a TiCrN concentration gradient that gradually increases along the direction from the first metallic layer 313 of the first protective structure 3 toward the second ceramic layer 412 of the second protective structure 4, and an Ir—Re concentration gradient that gradually decreases along the direction from the first metallic layer 313 of the first protective structure 3 toward the second ceramic layer 412 of the second protective structure 4. The third buffer layer 413 has a TiCrN concentration gradient that gradually decreases along the direction from the second ceramic layer 412 toward the second metallic layer 414, and a metallic concentration gradient that gradually increases along the direction from the second ceramic layer 412 toward the second metallic layer 414.
Each of the first, second and third buffer layers 312, 411, 413 is prepared by co-sputtering techniques. During the sputtering operation, the powers for a ceramic target and a metal target disposed on a cathode are adjusted so as to form the ceramic concentration gradient and the metallic concentration gradient in the first and third buffer layers 312, 413 (as shown in
In this example, the thickness of each of the first and second ceramic layers 311, 412, the first, second and third buffer layers 312, 411, 413, and the first and second metallic layers 313, 414 ranges from about 10 to 30 nm. The total thickness of the first and second protective structures 3, 4 is preferably less than 1 μm. As such, the grain size thus obtained in the interior of the first and second metallic layers 313, 414 can be as small as to prevent nucleation from taking place, thereby inhibiting the grain growth therein and avoiding the roughening of the metallic surfaces of the Ir—Re layers 313, 414.
The glass molding tool prepared in this Example is similar to that of Example 1, except that the first and second ceramic layers 311, 412 and the first, second and third ceramic materials are made from TiC, and that the first and second metallic layers 313, 414 and the first, second and third metallic materials are made from Ir—Ru.
The glass molding tool prepared in this Example is similar to that of Example 1, except that the first and second ceramic layers 311, 412 and the first, second and third ceramic materials are made from TiC, and that the first and second metallic layers 313, 414 and the first, second and third metallic materials are made from Ir—Re—Ta.
As described above, the grain growth at the grain boundary of each of the first and second metallic layers 313, 414 can be inhibited by including an additional high melting point element, Ta, in the first and second metallic layers 313, 414.
In view of the foregoing, the glass molding tool according to this invention has specific functions and properties as follows:
(1) The adhesion of the first and second ceramic layers 311, 412 to the respective first and second metallic layers 313, 414 can be considerably improved through the buffer layers 312, 411, 413.
(2) Since the thickness of each of the first and second ceramic layers 311, 412, the first, second and third buffer layers 312, 411, 413, and the first and second metallic layers 313, 414 is controlled within a range of 10 to 30 nm, the grain size in the interior of the first and second metallic layers 313, 414 is smaller than that required for undesirable nucleation so as to inhibit the grain growth therein and so as to avoid the roughening of the surfaces of the first and second metallic layers 313, 414.
(3) The ceramic layers 311, 412 provide sufficient hardness to resist wearing and thermal shock, thereby prolonging the service life of the glass molding tool.
While the present invention has been described in connection with what is considered the most practical and preferred embodiment, it is understood that this invention is not limited to the disclosed embodiments but is intended to cover various arrangements included within the spirit and scope of the broadest interpretations and equivalent arrangements.
| Number | Date | Country | Kind |
|---|---|---|---|
| 093100345 | Jan 2004 | TW | national |
