Patent Application
20210061694
This application claims the benefit of priority under 35 U.S.C. § 119 of Korean Application Serial No. 10-2018-0004050 filed on Jan. 11, 2018, the content of which is relied upon and incorporated herein by reference in its entirety.
The present disclosure relates to a glass product manufacturing apparatus, and more particularly, to a glass product manufacturing apparatus having improved cooling and manufacturing efficiency.
Molten glass is generated by melting a batch material and is further processed, e.g., fined, stirred, and formed, to produce glass products. When the molten glass is processed, the molten glass is heated to a high temperature and is then conveyed to other apparatuses for carrying out various processes. The temperature of the molten glass needs to be precisely controlled to be suitable for each process step. For this purpose, much research has been conducted on how to properly control the temperature of the molten glass.
According to embodiments of the present disclosure, a glass manufacturing apparatus is disclosed, comprising a stirring vessel disposed in a chamber and configured to stir molten glass. A conduit arranged in the chamber and having an inner space through which molten glass from the stirring vessels flows, and a nozzle disposed in the chamber adjacent to the conduit and configured to jet a fluid around the conduit.
The glass manufacturing apparatus may further include an environment control unit configured to adjust environment parameters inside the chamber.
The nozzle may be connected to a nitrogen source.
The nitrogen source may provide nitrogen that has not passed through the environmental control unit, to the nozzle.
The environment control unit may be connected to the chamber and further configured to supply the chamber with a fluid having a predetermined humidity, temperature, and atmospheric composition ratio.
The environment control unit may be further configured to provide a fluid to the chamber, wherein the fluid jetted by the nozzle and the fluid provided by the environment control unit are different from each other.
The fluid jetted by the nozzle and the fluid provided by the environmental control unit may differ in at least one of a temperature, a humidity, and an atmospheric composition ratio.
The glass manufacturing apparatus may further include a first controller configured to control the environment control unit and a second controller configured to control a flow of the fluid jetted by the nozzle.
The first controller and the second controller may be separate from each other.
The nozzle is configured to jet the fluid in a direction substantially perpendicular to a horizontal plane.
The nozzle is configured to jet the fluid at an angle with respect to a horizontal plane.
According to embodiments of the disclosure, a glass manufacturing apparatus is disclosed, including a conduit having an inner space through which molten glass flows and extending in a first direction, and a plurality of nozzles configured to jet a fluid around the conduit, wherein the plurality of nozzles are arranged along the first direction.
The plurality of nozzles may be arranged at substantially equal intervals along an extension direction of the conduit.
The plurality of nozzles may be arranged at different intervals along an extension direction the conduit.
The plurality of nozzles may be arranged at substantially equal intervals along an extension direction of extension of the conduit.
The plurality of nozzles may be arranged at different intervals along an extension direction of extension of the conduit.
At least some of the plurality of nozzles may be disposed above the conduit.
At least some of the plurality of nozzles may be disposed below the conduit.
According to embodiments of the disclosure, a method of manufacturing glass includes stirring molten glass in a stirring vessel, flowing the molten glass through a conduit after the stirring, and jetting a fluid around the conduit.
The molten glass may be cooled by the jetted fluid and the jetted fluid and atmosphere around the stirring vessel may have different compositions from each other.
The fluid may include nitrogen and H2O.
The disclosure will now be described more fully with reference to the accompanying drawings, in which example embodiments are shown. The subject matter of the disclosure may, however, be embodied in many different forms and should not be construed as being limited to the example embodiments set forth herein. Rather, these embodiments are provided so that the disclosure will convey the subject matter to those skilled in the art. In the drawings, the thicknesses of layers and regions may be exaggerated for clarity. Wherever possible, like reference numerals in the drawings will denote like elements. Therefore, the disclosure is not limited by relative sizes or intervals as shown in the accompanied drawings.
While such terms as “first,” “second,” etc., may be used to describe various components, such components are not limited to the above terms. The above terms are used only to distinguish one component from another. For example, a first component may indicate a second component or a second component may indicate a first component without conflicting.
The terms used herein in various example embodiments are used to describe example embodiments only, and should not be construed to limit the various additional embodiments. Singular expressions, unless defined otherwise in contexts, include plural expressions. The terms “comprises” or “may comprise” used herein in various example embodiments may indicate the presence of a corresponding function, operation, or component and do not limit one or more additional functions, operations, or components. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, may be used to specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. Also, expressions such as “at least one of”, when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.
When a certain embodiment may be implemented differently, a specific process order may be performed differently from the described order. For example, two consecutively described processes may be performed substantially at the same time or performed in an order opposite to the described order.
Variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected. Thus, embodiments of the disclosure should not be construed as limited to the particular shapes of regions illustrated herein, but are to include deviations in shapes that result, for example, from manufacturing. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
Referring to
The melting vessel 100, the fining vessel 200, the stirring vessel 300, the delivery vessel 500, and the forming apparatus 700 may be glass manufacturing process stations located in series. Predetermined processes for manufacturing glass products are performed at these stations. According to some embodiments, manufacturing processes may include a down-draw process and a slot-draw fusion-forming process. According to some embodiments, fabrication processes may include a double fusion process and a float glass forming process.
According to some embodiments, each of the melting vessel 100, the fining vessel 200, the stirring vessel 300, the delivery vessel 500, and the forming apparatus 700 may include platinum-containing metals such as platinum or platinum-rhodium, platinum-iridium, and combinations thereof. According to some embodiments, each of the melting vessel 100, the fining vessel 200, the agitation vessel 300, the delivery vessel 500, and the forming apparatus 700 may include palladium, rhenium, ruthenium, and osmium, and other refractory metals. According to some embodiments, the forming apparatus 700 may include a ceramic material or a glass-ceramic refractory material
The melting vessel 100 may receive a batch material 11 from a storage vessel 10. The batch material 11 may be inserted in the storage vessel 10 by a batch delivery apparatus 13 powered by a drive device 15. A selective controller 17 may be configured to operate the drive device 15 to insert a desired amount of the batch material 11 into the melting vessel 100 as indicated by an arrow a1. According to some embodiments, a glass level probe 19 may be used to measure a level of molten glass MG in a standpipe 21 and to transmit the measured level of molten glass MG to the controller 17 through a communication line 23.
The melting vessel 100 may heat and melt the batch material 11. When the batch material 11 is melted in the melting vessel 100, a bubble FM may be formed. The melting vessel 100 may be configured to receive the molten glass MG produced by melting the batch material 11 from the storage vessel 10. The batch material 11 is a glass raw material. According to some embodiments, a fining agent such as a tin oxide may be added to the batch material 11.
According to some embodiments, the fining vessel 200 may be connected to the melting vessel 100 by a first conduit 150. The first conduit 150 may include an inner space that is a passage through which the molten glass MG may flow. Second and third conduits 250 and 350 described below may also provide a passage through which the molten glass MG may flow. The first to third conduits 150, 250, and 350 may each include a material having electrical conductivity and usable at a high temperature condition. According to some embodiments, the first to third conduits 150, 250, and 350 may each include a platinum-containing metal, e.g., platinum, platinum-rhodium, platinum-iridium, or a combination thereof. According to some embodiments, the first to third conduits 150, 250, and 350 may each include a refractory metal, e.g., molybdenum, palladium, rhenium, tantalum, titanium, tungsten, ruthenium, osmium, zirconium, or an alloy thereof, and/or zirconium dioxide.
According to some embodiments, the third conduit 350 may have a hollow, approximately cylindrical, or hollow, approximately elliptic cylindrical shape. However, this embodiment is not limited thereto, and if necessary, the third conduit 350 may have a hollow quadrangular prism shape or a square quadrangular prism shape with rounded corners.
According to some embodiments, the fining vessel 200 serves as a refining tube. According to some embodiments, the fining vessel 200 may be located downstream of the melting vessel 100. The fining vessel 200 may receive the molten glass MG from the melting vessel 100. According to some embodiments, a high temperature process may be performed in the fining vessel 200 to remove blisters from the molten glass MG. According to some embodiments, the fining vessel 200 is configured to remove blisters from the molten glass MG while the molten glass MG passes through the fining vessel 200 by heating the molten glass MG. According to some embodiments, as the molten glass MG is heated in the fining vessel 200, the fining agent contained in the molten glass MG may cause a redox reaction, thereby oxygen being removed from the molten glass MG. Specifically, the blisters contained in the molten glass MG may include oxygen, carbon dioxide, and/or sulfur dioxide and may be combined with oxygen generated in the reduction reaction of the fining agent, and thus, a volume of the blister may increase. The grown blisters may float toward the free surface of the molten glass MG in the fining vessel 200 and be separated from the molten glass MG. The blisters may be discharged outside the fining vessel 200 through a gas-phase space at an upper part of the fining vessel 200.
The delivery vessel 500 may be located downstream of the stirring vessel 300. The delivery vessel 500 may be connected to the stirring vessel 300 by a third conduit 350. An outlet conduit 600 may be connected to the delivery vessel 500. The molten glass MG may be transferred to the inlet 650 of the forming apparatus 700 through the outlet conduit 600.
The forming apparatus 700 may receive the molten glass MG from the delivery vessel 500. The forming apparatus 700 may form the molten glass MG into a sheet-shaped glass product. For example, the forming apparatus 700 may include a fusion drawing machine for forming the molten glass MG. Part of the molten glass MG flowing into the forming apparatus 700 may overflow in the forming apparatus 700. The overflowing molten glass MG moves in a downward direction by gravity and a combination of suitably arranged rolls such as edge roll 750 and pulling rolls 800 to form molten glass ribbon RBB.
According to some embodiments, the stirring vessel 300 may be located downstream of the fining vessel 200. The stirring vessel 300 may homogenize the molten glass MG supplied from the fining vessel 200. A stirrer 310 may be positioned in the stirring vessel 300, to rotate relative to the stirring vessel 300 to make the molten glass MG flow therein. The stirrer 310 may stir the molten glass MG in such a manner that components of the molten glass MG are uniformly distributed.
The glass manufacturing apparatus 1a may be configured to heat the molten glass MG passing through the first conduit 150 in such a manner that the molten glass MG is maintained above a predetermined temperature until the molten glass MG reaches the fining vessel 200. For example, cooling of the molten glass MG may be prevented by supplying to the molten glass MG flowing through the first conduit 150 an amount of heat equal to or greater than heat loss due to conduction and convection of heat from the molten glass MG flowing through the first conduit 150. According to some embodiments, the molten glass MG passing through the first conduit 150 may have a higher temperature than the molten glass MG contained in the melting vessel 100. According to some embodiments, the molten glass MG passing through the first conduit 150 may have a lower temperature than the molten glass MG contained in the fining vessel 200.
The glass manufacturing apparatus 1a may be configured to directly heat the molten glass MG flowing along the first conduit 150. Specifically, the first conduit 150 may be configured to allow a current to flow there through. Due to the first conduit 150 heated by the current, the molten glass MG flowing along the first conduit 150 may be heated.
According to some embodiments, to apply the current to the first conduit 150, the glass manufacturing apparatus 1a may include flanges connected to the first conduit 150 and a power source electrically connected to the flanges through cables. According to some embodiments the power source may generate an alternating current or a direct current. The flanges may be provided in a plural number. For example, two flanges may be provided at two ends of the first conduit 150. However, according to some embodiments, the glass manufacturing apparatus 1a may include an external heat source for heating the first conduit 150.
According to some embodiments, the glass manufacturing apparatus 1a may also include a chamber CB. According to some embodiments, the chamber CB may have an inner space in which the fining vessel 200, the stirring vessel 300, and the delivery vessel 500 may be disposed. According to some embodiments, the storage vessel 10, the melting vessel 100, the first conduit 150, and the forming apparatus 700 may be disposed outside the chamber CB. According to some embodiments, the second conduit 250 and the third conduit 350 may be disposed in the chamber CB. According to some embodiments, the chamber CB may have a substantially rectangular parallelepiped shape, but is not limited thereto. Since precise environmental control is required to make high quality glass, precise control of the environment of the vessels corresponding to each process and the conduit connecting the vessels is necessary. According to some embodiments, the chamber CB may provide precise control of the process environment by separating the atmosphere around the conduit and the vessel containing the molten glass MG from the normal atmosphere during the fining process and subsequent processes. According to some embodiments, the chamber CB is configured to separate the atmosphere around the fining vessel 200, the second conduit 250, the stirring vessel 300, the third conduit 350, and the delivery vessel 500 from the atmosphere outside the chamber CB.
For convenience of description, embodiments will be described below on the assumption that the chamber CB has a substantially rectangular parallelepiped shape. However, those skilled in the art will readily understand that these embodiments may be applied in substantially the same manner to a chamber CB having other various shapes.
For convenience of explanation, first to third directions (X, Y, and Z directions) are defined as follows. When the chamber CB has a substantially rectangular parallelepiped shape, the first direction (the X direction) and the second direction (the Y direction) may be parallel to the bottom surface of the chamber CB. The first direction (the X direction) may be a direction in which the molten glass MG substantially moves in accordance with the progress of the process. The second direction (the Y direction) may be a direction substantially perpendicular to the first direction (the X direction). The second direction (the Y direction) may correspond to a direction perpendicular to the drawing in the sectional view. The third direction (the Z direction) may be a direction substantially perpendicular to the first direction (the X direction) and the second direction (the Y direction)
According to some embodiments, the glass manufacturing apparatus 1a may also include an environmental control system 450. The environmental control system 450 may be configured to control the environment in the chamber CB. According to some embodiments, the environmental control system 450 may be configured to control the atmosphere in the chamber CB. According to some embodiments, the environmental control system 450 may control at least one of a temperature, a humidity, and atmospheric composition ratio in the chamber CB. According to some embodiments, the environmental control system 450 may include an environmental control unit 460 and a first controller 470.
According to some embodiments, the environment control unit 460 may provide a fluid to the chamber CB. According to some embodiments, the environment control unit 460 may supply a fluid having a predetermined condition. According to some embodiments, the environment control unit 460 may supply a fluid having a predetermined humidity, temperature, and atmospheric composition ratio to the chamber CB. According to some embodiments, the environment control unit 460 may supply a fluid to the chamber CB through the fluid inlet VT provided in the chamber CB. According to some embodiments, the environmental control unit 460 may include a cooling coil, a heating coil, a humidifier, and a gas source capable of providing various gases. The various gases may be nitrogen or oxygen.
The first controller 470 may include a processor capable of issuing various commands to the environment control unit 460 to control the environment of the chamber CB. According to some embodiments, the first controller 470 may send an instruction to the environment control unit 460 to control the environment in the chamber CB. The first controller 470 may be a computing device, such as a workstation computer, a desktop computer, a laptop computer, a tablet computer, or the like. The first controller 470 may store software for performing functions such as receiving feedback on the environment within the chamber, receiving measurement data, adjusting the environment, and the like. According to some embodiments, the first controller 470 may send an instruction to the environment control unit 460 to control the atmosphere in the chamber CB. According to some embodiments, the first controller 470 may send an instruction to the environmental control unit 460 to control at least one of the temperature, the humidity, and the atmospheric composition ratio of the chamber CB.
According to some embodiments, the glass manufacturing apparatus 1a may include a direct cooling system 400a. According to some embodiments, the direct cooling system 400a includes at least one nozzle 410, a fluid source 430 configured to supply a fluid to the nozzle 410, a fluid conduit 420 connecting the nozzle 410 to the fluid source 430, and a second controller 440 that controls the direct cooling system 400a.
According to some embodiments, the nozzle 410 is disposed in the chamber CB.
According to some embodiments, the nozzle 410 may be disposed adjacent to the third conduit 350. According to some embodiments, the nozzle 410 is configured to jet a fluid around the third conduit 350.
According to some embodiments, the nozzle 410 may be aligned toward the third conduit 350. According to some embodiments, the third conduit 350 may be disposed along a direction in which the nozzle 410 emits fluid substantially. According to some embodiments, the nozzle 410 may jet the fluid at a bottom surface of the chamber CB, or in a direction substantially perpendicular to the horizontal plane, e.g., the third direction (the Z direction). According to some embodiments, the nozzle 410 may be disposed above the third conduit 350. According to some embodiments, the nozzle 410 may vertically overlap the third conduit 350. According to some embodiments, the nozzle 410 may be configured to jet the fluid directly toward the third conduit 350. A direct jet of the fluid toward the third conduit 350 indicates that the jetted fluid reaches the third conduit 350 while travelling substantially in the same direction as the direction in which it was initially jetted. However, this description does not exclude other situations in which the jetted fluid reaches the conduit 350 while travelling not in the same direction in which it was initially jetted.
According to some embodiments, the nozzle 410 may uniformly jet the fluid around the third conduit 350. According to some embodiments, the nozzle 410 may jet the fluid such that a temperature change of the molten glass MG along the first direction (the X direction) is uniform. Herein, the uniformity of the temperature change along the first direction (the X direction) of the molten glass MG indicates that the temperature of the molten glass MG is dependent on the first direction (the X direction), but is not substantially dependant on the second direction (the Y direction).
According to some embodiments, the fluid jetted by the nozzle 410 may spread to reach a predetermined area. According to some embodiments, the nozzle 410 may jet the fluid in a spraying manner. The jetted fluid may be radiated horizontally. According to some embodiments, the fluid jetted from each of the nozzles 410 may reach a region having a predetermined area of the surface of the third conduit 350. According to some embodiments, the fluid jetted by the nozzle 410 may reach at least a portion of the upper surface of the third conduit 350. According to some embodiments, the area covered by the fluid jetted by the nozzle 410 may be equal to or greater than an area of the top surface of the third conduit 350. According to some embodiments, the fluid jetted by the nozzle 410 may substantially cover the entire upper surface of the third conduit 350. The upper surface may be the outer surface of the portion of the third conduit 350 located above the plane passing through the center of the conduit 350 and parallel to the extending direction. Alternatively, the upper surface may refer to a portion of the outer surface of the third conduit 350 facing the ceiling of the chamber CB. When the extension line of the normal line of the specific portion of the third conduit 350 is brought into contact with the plane extending the ceiling of the chamber CB, the specific portion of the third conduit 350 and the chamber CB face each other. However, the above descriptions of the upper surface of the conduit 350 are for the sake of understanding and do not exclude other situations regarding the surface of the conduit 350 covered by the fluid jetted by the nozzle 410. In some cases, some of the fluid jetted by the nozzle 410 may reach the lower surface of the third conduit 350. The meaning of the lower surface may be similar to that of the upper surface described above.
According to some embodiments, the nozzle 410 may comprise a plurality of nozzles. According to some embodiments, the plurality of nozzles 410 is arranged along a direction. According to some embodiments, the plurality of nozzles 410 may be arranged along the first direction (the X direction).
However, the arrangement of the nozzles 410 is not limited thereto. According to other embodiments, the arrangement of the nozzles 410 may differ from that of
Referring to
Referring to
Referring to
Referring to
Referring to
Referring to
Referring to
Referring to
Referring to
Referring again to
According to some embodiments, the nozzle 410 may be configured to jet a fluid around the third conduit 350 to cool the third conduit 350. According to some embodiments, the nozzle 410 may be configured to jet nitrogen for cooling to the third conduit 350. According to some embodiments, a fluid source 430 may include a nitrogen source. According to some embodiments, the nozzle 410 is configured to jet high purity nitrogen (e.g., a ratio of a partial pressure of nitrogen is 99.9% or greater). According to some embodiments, the nozzle 410 may jet a fluid for humidity control. According to some embodiments, the nozzle 410 may jet H2O. According to some embodiments, the nozzle 410 may spray H2O. According to some embodiments, the nozzle 410 may spray H2O, which is a vaporized state or in a fine liquid particle state. According to some embodiments, the nozzle 410 may jet H2O in a vapor state and H2O in a fine liquid particle state. According to some embodiments, the fluid source 430 may include an H2O source. According to some embodiments, the nozzle 410 may jet nitrogen and H2O at the same time. According to some embodiments, the nozzle 410 may include a regulator for regulating the jet of nitrogen. According to some embodiments, a regulator for regulating the jet of nitrogen may regulate at least one of start and stop, velocity, and flow rate of nitrogen. According to some embodiments, the nozzle 410 may include a regulator for regulating the jet or spray of H2O. A regulator for regulating the jet or spray of H2O may regulate at least one of the start and stop, speed, and flow rate of H2O.
The second controller 440 may generate certain instructions to control the direct cooling system 400a. According to some embodiments, the second controller 440 may include a processor capable of issuing various commands to control a state of the third conduit 350. According to some embodiments, the second controller 440 may control the jet of the nozzles 410. According to some embodiments, the second controller 440 may also control a flow (a flow rate, for example) of the fluids jetted by the nozzles 410. According to some embodiments, the second controller 440 may control the temperature of the molten glass MG contained in the third conduit 350. According to some embodiments, the second controller 440 may be a computing device, such as a workstation computer, a desktop computer, a laptop computer, a tablet computer, and the like. According to some embodiments, the second controller 440 may store software for performing functions such as receiving feedback on the state of the molten glass MG in the third conduit 350 and receiving measurement data for adjusting the jet of the nozzles 410. According to some embodiments, temperature sensors are provided to measure the temperature of the molten glass MG, and the second controller 440 may adjust the temperature of the molten glass MG in the third conduit 350 based on temperature measurement results of the temperature sensors through feedback control. For example, when the temperature of the molten glass is higher than a required value, the amount of the fluid jetted by the nozzle 410 may be increased. On the other hand, when the temperature of the molten glass MG is lower than the required value, the amount of the fluid jetted by the nozzle 410 may be decreased.
According to some embodiments, the second controller 440 may control at least one of a type, a composition, a velocity, a flow rate, and an area of reach for the third conduit 350 of fluid to be jetted. Thus, the amount of the fluid reaching the third conduit may be controlled, and accordingly, cooling of the third conduit may be controlled.
According to some embodiments, the second controller 440 may be provided separately from the first controller 470. The second controller 440 may be separated from the first controller 470. According to some embodiments, the first controller 470 and the second controller 440 may be separate processors and/or software components included in an identical computing device such as a workstation computer, a desktop computer, laptop computer, and a tablet computer, etc.
The cooling process is a process of lowering the temperature of the molten glass MG.
Conventionally, the environment control unit 460 cools the molten glass MG in the third conduit 350 by circulation of the fluid provided to the chamber CB. In this case, as fluid flow stagnation occurs around the third conduit 350, the heat exchange between the fluid in the chamber CB and the third conduit 350 is poor so that the cooling efficiency is low. Conventionally, conduits including refractories have been researched to improve the cooling efficiency. However, the improvement in the cooling efficiency has not been significant. As a result, the cooling process has lowered the production efficiency of glass.
To address this problem, the glass manufacturing apparatus 1a according to some embodiments may include a plurality of nozzles 410 configured to jet fluid directly to the third conduit 350 separately from the environment control unit 460 in the chamber CB. Accordingly, the cooling efficiency for the molten glass MG in the third conduit 350 may be improved. Specifically, by jetting the fluid around the third conduit 350, the jetted fluid can push out the airflow surrounding layer around the third conduit 350. Thus, it is possible to prevent stagnation of fluid from being formed around the third conduit 350.
The atmosphere of the chamber CB for glass production requires precise control. Therefore, it is desirable that the atmospheric environment of the chamber CB for glass production does not change due to nitrogen provided by the nozzles 410. Therefore, by reducing the amount of nitrogen supplied by the environment control unit 460 via the amount of nitrogen supplied by the nozzle 410, the atmospheric composition (such as partial pressures of component gases), the temperature, and the humidity in the entire chamber CB may be maintained at levels equivalent to the conventional ones. A partial pressure of oxygen and a total pressure in the chamber CB may be maintained at pre-determined values in order to prevent needle Pt defects from occurring due to changes in the atmosphere of the chamber CB. Because the temperature inside the first to third conduit 350 is very high, platinum may combine with oxygen and become volatilized in the form of PtO2. When the volatilized PtO2 is cooled and encounters nitrogen, NO is formed and Pt solidifies and remains in the molten glass. Needle Pt is a needle-like defect formed in a glass product caused by solid Pt contained in the molten glass. To this end, the total amount of nitrogen jetted by the nozzle 410 may be less than the amount of nitrogen provided by the environment control unit 450. However, this embodiment is not limited thereto and depending on the process conditions and environment, the total amount of nitrogen jetted by the nozzle 410 may be greater than the amount of nitrogen provided by the environment control unit 450.
The high purity nitrogen jetted by the nozzle 410 may have lower humidity than the atmosphere in the entire chamber, thereby causing a local humidity drop around the third conduit 350. According to some embodiments, the nozzles 410 may adjust the humidity around the third conduit 350 by spraying H2O around the third conduit 350. Accordingly, defects such as blister may be prevented from occurring due to a hydrogen permeation phenomenon on high-temperature platinum which may occur in a drying environment. The molten glass inside the conduit has a relatively high concentration of hydrogen. Because the atomic mass and atomic size of H2 are very small, H2 molecules are capable of travelling through platinum-based conduits or vessels. This phenomenon is referred to as hydrogen permeation. The hydrogen concentration in the chamber CB is maintained at a certain level to prevent permeation of hydrogen. The external hydrogen concentration is controlled through humidity, and when the local hydrogen concentration outside the conduit drops, the possibility of hydrogen permeation increases. Because hydrogen exists in the form of OH— ion inside the molten glass, when H2 permeation occurs, O2 remains in the molten glass and causes blister defects in glass products.
Referring to
As the flow rate of the glass increased by about 45.36 kg/hr as the cooling power of the third conduit 350 in glass manufacturing increased by about 5.0 kW, the glass manufacturing apparatus 1a according to some embodiments is estimated to be capable of increasing the flow rate of the glass by about 93.44 kg/hr.
According to the experimental example, it was confirmed that there is no side effect such as a change of the glass flow due to introduction of the nozzle 410, an increase of the number of defects, a deterioration of the quality of the produced glass products, and the like. Specifically, the total amount of glass lost by melting in the glass manufacturing process was reduced from 4.4% in the conventional example to 4.38% in the experimental example. Melting loss of glass means the percentage of products with defects such as blister or needle Pt, etc to the gross production.
Referring to
While the present disclosure has been particularly shown and described with reference to example embodiments thereof, it will be understood that various changes in form and details may be made therein without departing from the spirit and scope of the following claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2018-0004050 | Jan 2018 | KR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/KR2019/000386 | 1/10/2019 | WO | 00 |
