1. Field of the Invention
Embodiments of the present invention relate generally to protective articles such as gloves and other wearable items providing an inner fabric support and an outer polymeric coating and, particularly, to gloves having crush-resistant fingertips.
2. Description of the Related Art
Gloves, and particularly gloves used in work settings, require properties providing safety while ensuring comfort during prolonged wear throughout the course of work activities. Fingers, and particularly fingertips, encounter the most danger and are often injured during work activities, such as from impact, crush, severance, and pinch hazards. However, workers often complain that gloves are too bulky and inflexible for the work that they perform. As a consequence, the gloves are often not worn, leading to even greater injuries. Accordingly, gloves must be flexible to be useful while performing work activities as well as inexpensive and easy to manufacture while protecting hands against additional concerns, such as protection from chemicals, oils, gases, and the like. Moreover, it is often desirable to protect workpieces (electronic equipment, touchscreens, and the like) from contact, natural skin oils, and perspiration by the wearer of the glove. Therefore, attempts have been made to create gloves addressing these needs.
One such glove discloses crush-resistant fingertips made of plastic or metal. Specifically, the glove comprises fingertips shaped as tubular members. The tubular members are inserted into or onto a liner. The liner may then be received within an outer glove. However, the glove requires many manufacturing steps, does not provide an integrally formed glove, and does not address many safety and other concerns.
Accordingly, there is a need for an improved glove and improved methods for manufacturing gloves that are comfortable and easy and inexpensive to manufacture while addressing the aforementioned concerns. It would therefore be a significant advance in the art to provide a comfortable, thin, flexible glove comprising a polymeric-coated knitted liner having crush-resistant fingertips.
A thin flexible glove comprising a liner, crush-resistant fingertips, and a shell, and methods for manufacturing, substantially as shown in and/or described in connection with at least one of the figures, as set forth more completely in the claims, are disclosed. Various advantages and features of the present invention will be more fully understood from the following description and drawings.
So that the manner in which the above recited features of the present invention can be understood in detail, a more particular description of the invention, briefly summarized above, may be had by reference to embodiments, some of which are illustrated in the appended drawings. It is to be noted, however, that the appended drawings illustrate only illustrative embodiments of this invention and are therefore not to be considered limiting of its scope, for the invention may admit to other equally effective embodiments.
To facilitate understanding, identical reference numerals have been used, where possible, to designate comparable elements that are common to the figures. The figures are not drawn to scale and may be simplified for clarity. It is contemplated that elements and features of one embodiment may be beneficially incorporated in other embodiments without further recitation.
It has now been discovered that one can obtain thin, flexible gloves having protective properties, which include a liner and crush-resistant metal, composite, or plastic fingertips, and a foamed or unfoamed elastomeric or polymeric coating disposed thereon.
In yet other embodiments of the invention, the inside and outside surfaces of the crush-resistant fingertips can comprise surface treatments, surface finishes, roughened surfaces, and the like to promote adhesion of the fingertips to the liner and shell. For example, where the fingertips are injection molded components and are to be, for example, glued on a liner for attachment, the inside surface may be formed having one of several different electric discharge machine (EDM) finishes known to those of ordinary skill in the art. Alternatively, if the fingertip is to be placed within a liner for attachment by gluing, the outside surface of the fingertip may have one of several different EDM finishes. Furthermore, the material the crush-resistant fingertips components are made of can be selected to balance service properties with manufacturability concerns, such as choosing a plastic that easily bonds with both a specific adhesive and the adhesive to a specific liner yarn. In some embodiments, the crush-resistant fingertips may comprise metals, plastics, and/or reinforced composite materials such as carbon-reinforced fiber composites and the like. In some embodiments of the invention, the plastics and/or composite materials may be doped with metallic materials to add conductivity properties. Carbon-reinforced materials are also used where conductive applications are contemplated. In addition, any of the crush-resistant fingertips may comprise embodiments addressing other service concerns, such as puncture and chemical resistance.
The support/liner 104 can be made from a yarn having one of various deniers and using 7, 10, 13, 15, or 18 knit gauges, and can be comprised of such materials as KEVLAR®, p-aramids, NOMEX®, m-aramids, SPECTRA®, DYNEEMA®, TSUNOOGA®, SPANDEX®, nylons, polyesters, rayon, cotton, metal wires, fiberglass, and the like, and blends of the foregoing. Various yarns may be specified for flame- and/or heat-resistance as well as for cut-resistance. In some embodiments, the yarns may be treated with chemicals to impart properties known to those having ordinary skill in the art. In some embodiments of the invention, knitted liners may have various yarns plaited into the knit to impart a balance of properties, for instance, comfort, moisture control and absorbance, scratch resistance, cushioning, strength, and the like. Also, if the support is a knitted liner, the knitted liners may comprise separately knitted sections, and knitted variable stitch dimensions, such as those disclosed in commonly assigned U.S. Pat. No. 6,962,064 and U.S. Patent Appl. Publ. 2009/0211305, which are incorporated herein by reference in their entireties.
The fingertips may be attached to the liner using glues, hot melts, or sprayed adhesives, or other suitable attachment means. In other embodiments, the fingertips are held in place on the inside or outside surface of the liner with friction. For example, as discussed above, a series of rings having varying diameters may impart friction on the liner and/or on the fingers of the wearer to hold the fingertips in place. This alternative has the added feature of allowing greater circulation of air around the fingers, which can promote comfort and breathability. Other embodiments contemplate wherein the rings are oval-shaped and/or sized so that the crux of a wearer's finger at the knuckle receives a ring 410. In yet other embodiments, the fingertips may be held in place by forcing oversized fingertips into the finger stalls of the liner and stretching the yarn of the liner, creating an interference fit.
In other embodiments, the coating may be disposed on the liner via a molding process, such as an injection-molding process, and may coat the palm area or be extended to a ¾ coating (palm, fingers, knuckles) or full coat to the wrist.
Alternately, any of the foregoing embodiments of the crush-resistant fingertips may be molded directly onto the former-supported liner using a molding process, such as transfer, compression, or injection molding. The injection-molded components may have engineered profiles, textures, finishes, or contours to impart properties promoting ease of use during service, grip-ability, and the like. Such embodiments are included in commonly assigned provisional application 61/464,956, filed on Mar. 11, 2011, which is incorporated herein by reference in its entirety. Furthermore, the crush-resistant fingertips may be injection-molded directly onto a glove already comprising an elastomeric-coated liner. This glove may also then be coated with an additional elastomeric coating. It is further to be noted that any of the various fingertip designs can be incorporated into any embodiment of any glove liner and shell/coating disclosed herein.
In some embodiments of the invention, the support/liner can be mounted onto a former and optionally dipped into a coagulant composition; and dipped into an elastomeric or polymeric emulsion; forming the coating from the emulsion, such as a coating that penetrates less than the entire thickness of the support; and curing the coating. The coating can be applied to all or most of the support, or a portion thereof. After dipping, the former can be turned over to distribute the elastomeric or polymeric material evenly. The dipping depth into the emulsion composition can be chosen to ensure that the resulting coating penetrates the glove body for good adherence but with minimal to no strikethrough to the hand-contacting side. The process variables, which control the penetration of the polymeric or elastomeric emulsion can include, control of viscosity of the emulsion and control of dip depth in the elastomeric or polymeric emulsion tank. Without intending to be bound by theory, hydraulic pressure in the tank of aqueous polymeric emulsion can contribute to the depth of penetration. Typical elastomeric or polymeric materials that may be used include natural rubbers, synthetic rubbers, guayule, natural and synthetic polyisoprene, butadiene, styrene-butadienes, nitriles, poly (vinyl chloride), polyurethane, polychloroprene, blends, mixtures thereof, and the like. The coating may optionally be foamed, embodiments of the invention comprising a foamed coating are produced using a suitable combination of a surfactant, control of air content in the foamed coating, control of the viscosity of the elastomeric lattices and suitable former temperatures for liner supported dipping processes.
The elastomeric or polymeric emulsion composition may comprise ingredients such as surfactants, defoamers, pigments, plasticizers, thixotropic agents, thickeners, processing aids, fillers, and the like, as known to those of ordinary skill in the art.
The concentration of the coagulant can be varied to regulate the amount the polymer penetrates the support. Similarly, the amount and orientation of pre-cure drying can be adjusted to limit excessive penetration. The support/liner can be partially dried after dipping into a coagulant solution. Coagulant solutions that can be used with the invention include calcium nitrate, calcium citrate, acetic acid, tricarboxylic acid, aluminum sulfate, zinc acetate, sodium chloride, alcohol, dilute HCl, formic acid, other divalent and trivalent metal ion salts, mixtures thereof, and the like.
Although some embodiments have been discussed above, other implementations and applications are also within the scope of the following claims. Although the invention herein has been described with reference to particular embodiments, it is to be understood that these embodiments are merely illustrative of the principles and applications of the present invention. It is therefore to be understood that numerous modifications may be made to the illustrative embodiments and that other arrangements may be devised without departing from the spirit and scope of the present invention as defined by the following claims.
Publications and references, including but not limited to patents and patent applications, cited in this specification are herein incorporated by reference in their entireties as if each individual publication or reference were specifically and individually fully set forth herein. Any patent application to which this application claims priority is also incorporated by reference herein in the manner described above for publications and references.
This application claims priority under 35 U.S.C. 119(e) to U.S. Provision Application Ser. No. 61/539,251 filed Sep. 26, 2011, which is hereby incorporated by reference in its entirety.
Number | Date | Country | |
---|---|---|---|
61539251 | Sep 2011 | US |