Patent Application
20210138307
This application claims priority on and the benefit of Patent Application No. 2019-201977 filed in JAPAN on Nov. 7, 2019. The entire disclosures of this Japanese Patent Application are hereby incorporated by reference.
The present invention relates to golf balls. Specifically, the present invention relates to golf balls having a core, an inner cover, an outer cover, and dimples.
A typical golf ball has a core, an inner cover, and an outer cover. The core is formed by crosslinking a rubber composition. The core can have two or more layers. The inner cover is formed from a resin composition. The outer cover is formed from another resin composition.
The face of a golf club has a loft angle. When a golf ball is hit with the golf club, the golf ball is launched at a launch angle corresponding to the loft angle. Furthermore, in the golf ball, backspin due to the loft angle occurs. The golf ball flies with the backspin.
Golf balls have a large number of dimples on the surfaces thereof. The dimples disturb the air flow around the golf ball during flight to cause turbulent flow separation. This phenomenon is referred to as “turbulization”. Due to turbulization, separation points of the air from the golf ball shift backwards leading to a reduction of drag. The turbulization promotes the displacement between the separation point on the upper side and the separation point on the lower side of the golf ball, which results from the backspin, thereby enhancing the lift force that acts upon the golf ball. The reduction of drag and the enhancement of lift force are referred to as a “dimple effect”. Excellent dimples efficiently disturb the air flow. Excellent dimples produce a large flight distance. There have been various proposals for dimples.
The greatest interest to golf players concerning golf balls is flight distance. Golf players particularly place importance on flight distances upon shots with drivers. Golf balls with which a large flight distance is achieved upon a shot with a driver can contribute to a good score.
A flight distance depends on the initial speed of the golf ball. The initial speed depends on a resilience coefficient. A golf ball that has a high resilience coefficient when being hit with a driver is advantageous in terms of flight distance.
An appropriate trajectory height is required in order to achieve a large flight distance. A trajectory height depends on a spin rate. With a golf ball that has a high spin rate, a large trajectory height is achieved.
Various improvements have been proposed regarding the structures, materials, dimple patterns, etc., of golf balls for the purpose of improving flight performance. An example of the improvements is disclosed in JP2004-49270.
An excessive spin rate causes loss of kinetic energy. Therefore, a sufficient flight distance cannot be achieved with a golf ball in which the trajectory height greatly depends on the spin rate.
On the other hand, with a golf ball having an excessively low spin rate, the lift force is insufficient. With this golf ball as well, a sufficient flight distance cannot be achieved.
An object of the present invention is to provide a golf ball that flies on an appropriate trajectory and therefore achieves a large flight distance.
A golf ball according to the present invention includes a core, an inner cover positioned outside the core, and an outer cover positioned outside the inner cover. The golf ball further has a plurality of dimples on a surface thereof. The golf ball satisfies the following mathematical formulas (I) and (II).
Vw=54+0.01(2.5A−B+5Cv)≥58.0 (I)
0.08X2−4.25X+345−20≤D≤0.08X2−4.25X+345+20 (II)
A: a compression (Atti) of the golf ball
B: a hardness difference (Shore C) between a surface and a center of the core
Cv: (Hi×Ti+Ho×To)/(Ti+To)
Cs: (Hi×Ti+2Ho×To)/(Ti+2To)
D: a dimple total volume (mm3)
X: Sw/Vw
Hi: a hardness (Shore D) of the inner cover
Ho: a hardness (Shore D) of the outer cover
Ti: a thickness (mm) of the inner cover
To: a thickness (mm) of the outer cover
Sw: 3000+10(A−B−1.5Cs)
In the golf ball according to the present invention, the balance between the hardness distribution of the core, the hardness and the thickness of the cover, and the compression of the golf ball is appropriate. When the golf ball is hit with a driver, the golf ball is launched at a high ball speed with an appropriate spin rate. Furthermore, with the golf ball, a dimple effect that matches the spin rate is exhibited. The trajectory of the golf ball is appropriate. Upon a shot of the golf ball with a driver, a large flight distance can be achieved.
Preferably, the golf ball further satisfies the following mathematical formula (III).
Sa=4500+10(A−0.5B−2Cs)≥4000 (III)
Preferably, in the golf ball, a lift force coefficient CL satisfies the following mathematical formula (IV)
CLL≤CL≤CLU
CLU: Sw/60×(−9.5×10−6×D+6.1×10−3)+(1.871×10−4×D−3.5×10−3)
CLL: Sw/60×(−3.8×10−6×D+3.0×10−3)+(4.52×10−5×D+8.32×10−2) (IV)
The following will describe in detail the present invention based on preferred embodiments with appropriate reference to the drawings.
A golf ball 2 shown in
The golf ball 2 preferably has a diameter of not less than 40 mm and not greater than 45 mm. From the viewpoint of conformity to the rules established by the United States Golf Association (USGA), the diameter is particularly preferably not less than 42.67 mm. In light of suppression of air resistance, the diameter is more preferably not greater than 44 mm and particularly preferably not greater than 42.80 mm.
The golf ball 2 preferably has a weight of not less than 40 g and not greater than 50 g. In light of attainment of great inertia, the weight is more preferably not less than 44 g and particularly preferably not less than 45.00 g. From the viewpoint of conformity to the rules established by the USGA, the weight is particularly preferably not greater than 45.93 g.
The core 4 is formed by crosslinking a rubber composition. Examples of preferable base rubbers for use in the rubber composition include polybutadienes, polyisoprenes, styrene-butadiene copolymers, ethylene-propylene-diene copolymers, and natural rubbers. In light of resilience performance of the golf ball 2, polybutadienes are preferable. When a polybutadiene and another rubber are used in combination, it is preferred if the polybutadiene is a principal component. Specifically, the proportion of the polybutadiene to the entire base rubber is preferably not less than 50% by weight and particularly preferably not less than 80% by weight. A polybutadiene in which the proportion of cis-1,4 bonds is not less than 80% is particularly preferable.
The rubber composition of the core 4 preferably includes a co-crosslinking agent. Preferable co-crosslinking agents in light of durability and resilience performance of the golf ball 2 are monovalent or bivalent metal salts of an α,β-unsaturated carboxylic acid having 2 to 8 carbon atoms. Examples of preferable co-crosslinking agents include zinc acrylate, magnesium acrylate, zinc methacrylate, and magnesium methacrylate. Zinc acrylate and zinc methacrylate are particularly preferable.
The rubber composition may include a metal oxide and an α,β-unsaturated carboxylic acid having 2 to 8 carbon atoms. They both react with each other in the rubber composition to obtain a salt. The salt serves as a co-crosslinking agent. Examples of preferable α,β-unsaturated carboxylic acids include acrylic acid and methacrylic acid. Examples of preferable metal oxides include zinc oxide and magnesium oxide.
The amount of the co-crosslinking agent per 100 parts by weight of the base rubber is preferably not less than 10 parts by weight and not greater than 45 parts by weight. The golf ball 2 in which this amount is not less than 10 parts by weight has excellent resilience performance. From this viewpoint, this amount is more preferably not less than 15 parts by weight and particularly preferably not less than 20 parts by weight. The golf ball 2 in which this amount is not greater than 45 parts by weight has excellent feel at impact. From this viewpoint, this amount is more preferably not greater than 40 parts by weight and particularly preferably not greater than 35 parts by weight.
Preferably, the rubber composition of the core 4 includes an organic peroxide. The organic peroxide serves as a crosslinking initiator. The organic peroxide contributes to the durability and the resilience performance of the golf ball 2. Examples of suitable organic peroxides include dicumyl peroxide, 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, and di-t-butyl peroxide. An organic peroxide with particularly high versatility is dicumyl peroxide.
The amount of the organic peroxide per 100 parts by weight of the base rubber is preferably not less than 0.1 parts by weight and not greater than 3.0 parts by weight. The golf ball 2 in which this amount is not less than 0.1 parts by weight has excellent resilience performance. From this viewpoint, this amount is more preferably not less than 0.3 parts by weight and particularly preferably not less than 0.5 parts by weight. The golf ball 2 in which this amount is not greater than 3.0 parts by weight has excellent feel at impact. From this viewpoint, this amount is more preferably not greater than 2.5 parts by weight and particularly preferably not greater than 2.0 parts by weight.
Preferably, the rubber composition of the core 4 includes an organic sulfur compound. The organic sulfur compound contributes to flight distance upon a shot with a driver. Organic sulfur compounds include naphthalenethiol compounds, benzenethiol compounds, and disulfide compounds.
Examples of naphthalenethiol compounds include 1-naphthalenethiol, 2-naphthalenethiol, 4-chloro-1-naphthalenethiol, 4-bromo-1-naphthalenethiol, 1-chloro-2-naphthalenethiol, 1-bromo-2-naphthalenethiol, 1-fluoro-2-naphthalenethiol, 1-cyano-2-naphthalenethiol, and 1-acetyl-2-naphthalenethiol.
Examples of benzenethiol compounds include benzenethiol, 4-chlorobenzenethiol, 3-chlorobenzenethiol, 4-bromobenzenethiol, 3-bromobenzenethiol, 4-fluorobenzenethiol, 4-iodobenzenethiol, 2,5-dichlorobenzenethiol, 3,5-dichlorobenzenethiol, 2,6-dichlorobenzenethiol, 2,5-dibromobenzenethiol, 3,5-dibromobenzenethiol, 2-chloro-5-bromobenzenethiol, 2,4,6-trichlorobenzenethiol, 2,3,4,5,6-pentachlorobenzenethiol, 2,3,4,5,6-pentafluorobenzenethiol, 4-cyanobenzenethiol, 2-cyanobenzenethiol, 4-nitrobenzenethiol, and 2-nitrobenzenethiol.
Examples of disulfide compounds include diphenyl disulfide, bis(4-chlorophenyl)disulfide, bis(3-chlorophenyl)disulfide, bis(4-bromophenyl)disulfide, bis(3-bromophenyl)disulfide, bis(4-fluorophenyl)disulfide, bis(4-iodophenyl)disulfide, bis(4-cyanophenyl)disulfide, bis(2,5-dichlorophenyl)disulfide, bis(3,5-dichlorophenyl)disulfide, bis(2,6-dichlorophenyl)disulfide, bis(2,5-dibromophenyl)disulfide, bis(3,5-dibromophenyl)disulfide, bis(2-chloro-5-bromophenyl)disulfide, bis(2-cyano-5-bromophenyl)disulfide, bis(2,4,6-trichlorophenyl)disulfide, bis(2-cyano-4-chloro-6-bromophenyl)disulfide, bis(2,3,5,6-tetrachlorophenyl)disulfide, bis(2,3,4,5,6-pentachlorophenyl)disulfide, and bis(2,3,4,5,6-pentabromophenyl)disulfide.
The amount of the organic sulfur compound per 100 parts by weight of the base rubber is preferably not less than 0.1 parts by weight and not greater than 1.5 parts by weight. The golf ball 2 in which this amount is not less than 0.1 parts by weight has excellent resilience performance. From this viewpoint, this amount is more preferably not less than 0.2 parts by weight and particularly preferably not less than 0.3 parts by weight. The golf ball 2 in which this amount is not greater than 1.5 parts by weight has excellent feel at impact. From this viewpoint, this amount is more preferably not greater than 1.0 part by weight and particularly preferably not greater than 0.8 parts by weight. Two or more organic sulfur compounds may be used in combination.
Preferably, the rubber composition of the core 4 includes a carboxylic acid or a carboxylate. The carboxylic acid and the carboxylate can contribute to making the hardness distribution of the core 4 appropriate. The appropriate hardness distribution can reduce a spin rate. An example of preferable carboxylic acids is benzoic acid. Examples of preferable carboxylates include zinc octoate and zinc stearate. The amount of the carboxylic acid and the carboxylate per 100 parts by weight of the base rubber is preferably not less than 0.5 parts by weight, more preferably not less than 0.8 parts by weight, and particularly preferably not less than 1.0 part by weight. This amount is preferably not greater than 20 parts by weight, more preferably not greater than 15 parts by weight, and particularly preferably not greater than 10 parts by weight.
The rubber composition of the core 4 may include a filler for the purpose of specific gravity adjustment and the like. Examples of suitable fillers include zinc oxide, barium sulfate, calcium carbonate, and magnesium carbonate. The amount of the filler is determined as appropriate so that the intended specific gravity of the core 4 is achieved.
The rubber composition of the core 4 may include various additives, such as sulfur, an anti-aging agent, a coloring agent, a plasticizer, a dispersant, and the like, in an adequate amount. The rubber composition may include crosslinked rubber powder or synthetic resin powder.
The core 4 preferably has a diameter of not less than 35.0 mm and not greater than 40.5 mm. The golf ball 2 that includes the core 4 having a diameter of not less than 35.0 mm has excellent resilience performance. From this viewpoint, the diameter is more preferably not less than 36.0 mm and particularly preferably not less than 36.5 mm. The golf ball 2 that includes the core 4 having a diameter of not greater than 40.5 mm has excellent durability. From this viewpoint, the diameter is more preferably not greater than 40.0 mm and particularly preferably not greater than 39.5 mm.
A hardness Hc at the central point of the core 4 is preferably not less than 35 and not greater than 70. The golf ball 2 in which the hardness Hc is not less than 35 has excellent resilience performance. From this viewpoint, the hardness Hc is more preferably not less than 40 and particularly preferably not less than 45. The golf ball 2 in which the hardness Hc is not greater than 70 has excellent feel at impact. From this viewpoint, the hardness Hc is more preferably not greater than 67 and particularly preferably not greater than 65.
The hardness Hc is measured with a Shore C type hardness scale mounted to an automated hardness meter (trade name “digi test II” manufactured by Heinrich Bareiss Prüfgerätebau GmbH). The hardness scale is pressed against the central point of the cross-section of a hemisphere obtained by cutting the golf ball 2. The measurement is conducted in an environment of 23° C.
A hardness Hs at the surface of the core 4 is preferably not less than 55 and not greater than 95. The golf ball 2 in which the hardness Hs is not less than 55 has excellent resilience performance. From this viewpoint, the hardness Hs is more preferably not less than 60 and particularly preferably not less than 65. The golf ball 2 in which the hardness Hs is not greater than 95 has excellent feel at impact. From this viewpoint, the hardness Hs is more preferably not greater than 90 and particularly preferably not greater than 85.
The hardness Hs is measured with a Shore C type hardness scale mounted to an automated hardness meter (trade name “digi test II” manufactured by Heinrich Bareiss Prüfgerátebau GmbH). The hardness scale is pressed against the surface of the core 4. The measurement is conducted in an environment of 23° C.
The difference B (=Hs−Hc) between the hardness Hs at the surface of the core 4 and the hardness Hc at the center of the core 4 is preferably not less than 0 and not greater than 40. The golf ball 2 having the core 4 in which the difference B is not less than 0 can fly with an appropriate spin rate. From this viewpoint, the difference B is more preferably not less than 10 and particularly preferably not less than 15. The core 4 in which the difference B is not greater than 40 is easily produced. From this viewpoint, the difference B is more preferably not greater than 37 and particularly preferably not greater than 35.
The core 4 preferably has an amount of compressive deformation Df of not less than 3.0 mm and not greater than 4.5 mm. The golf ball 2 having the core 4 having an amount of compressive deformation Df of not less than 3.0 mm has excellent feel at impact. From this viewpoint, the amount of compressive deformation Df is more preferably not less than 3.2 mm and particularly preferably not less than 3.3 mm. When the golf ball 2 having the core 4 having an amount of compressive deformation Df of not greater than 4.5 mm is hit with a driver, the golf ball 2 can be launched at a high initial speed. From this viewpoint, the amount of compressive deformation Df is more preferably not greater than 4.4 mm and particularly preferably not greater than 4.3 mm.
For measurement of the amount of compressive deformation Df, a YAMADA type compression tester “SCH” is used. In the tester, the core 4 is placed on a hard plate made of metal. Next, a cylinder made of metal gradually descends toward the core 4. The core 4, squeezed between the bottom face of the cylinder and the hard plate, becomes deformed. A migration distance of the cylinder, starting from the state in which an initial load of 98 N is applied to the core 4 up to the state in which a final load of 1274 N is applied thereto, is measured. A moving speed of the cylinder until the initial load is applied is 0.83 mm/s. A moving speed of the cylinder after the initial load is applied until the final load is applied is 1.67 mm/s.
The core 4 preferably has a weight of not less than 10 g and not greater than 42 g. The temperature Te for crosslinking the core 4 is not lower than 140° C. and not higher than 180° C. The time period Tm for crosslinking the core 4 is not shorter than 10 minutes and not longer than 60 minutes. The core 4 may have two or more layers.
The inner cover 6 is positioned outside the core 4. The inner cover 6 is formed from a thermoplastic resin composition. Examples of the base polymer of the resin composition include ionomer resins, thermoplastic polyester elastomers, thermoplastic polyamide elastomers, thermoplastic polyurethane elastomers, thermoplastic polyolefin elastomers, and thermoplastic polystyrene elastomers. Ionomer resins are particularly preferable. Ionomer resins are highly elastic. The golf ball 2 that includes the inner cover 6 including an ionomer resin has excellent resilience performance. The golf ball 2 has excellent flight distance upon a shot with a driver.
An ionomer resin and another resin may be used in combination. In this case, in light of resilience performance, the ionomer resin is included as the principal component of the base polymer. The proportion of the ionomer resin to the entire base polymer is preferably not less than 50% by weight.
Examples of preferable ionomer resins include binary copolymers formed with an α-olefin and an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms. A preferable binary copolymer includes 80% by weight or more but 90% by weight or less of an α-olefin, and 10% by weight or more but 20% by weight or less of an α,β-unsaturated carboxylic acid. The binary copolymer has excellent resilience performance. Examples of other preferable ionomer resins include ternary copolymers formed with: an α-olefin; an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms; and an α,β-unsaturated carboxylate ester having 2 to 22 carbon atoms. A preferable ternary copolymer includes 70% by weight or more but 85% by weight or less of an α-olefin, 5% by weight or more but 30% by weight or less of an α,β-unsaturated carboxylic acid, and 1% by weight or more but 25% by weight or less of an α,β-unsaturated carboxylate ester. The ternary copolymer has excellent resilience performance. For the binary copolymer and the ternary copolymer, preferable α-olefins are ethylene and propylene, while preferable α,β-unsaturated carboxylic acids are acrylic acid and methacrylic acid. A particularly preferable ionomer resin is a copolymer formed with ethylene and acrylic acid. Another particularly preferable ionomer resin is a copolymer formed with ethylene and methacrylic acid.
In the binary copolymer and the ternary copolymer, some of the carboxyl groups are neutralized with metal ions. Examples of metal ions for use in neutralization include sodium ions, potassium ions, lithium ions, zinc ions, calcium ions, magnesium ions, aluminum ions, and neodymium ions. The neutralization may be carried out with two or more types of metal ions. Particularly suitable metal ions in light of resilience performance and durability of the golf ball 2 are sodium ions, zinc ions, lithium ions, and magnesium ions.
Specific examples of ionomer resins include trade names “Himilan 1555”, “Himilan 1557”, “Himilan 1605”, “Himilan 1706”, “Himilan 1707”, “Himilan 1856”, “Himilan 1855”, “Himilan AM7311”, “Himilan AM7315”, “Himilan AM7317”, “Himilan AM7329”, and “Himilan AM7337”, manufactured by DOW-MITSUI POLYCHEMICALS CO., LTD.; trade names “Surlyn 6120”, “Surlyn 6910”, “Surlyn 7930”, “Surlyn 7940”, “Surlyn 8140”, “Surlyn 8150”, “Surlyn 8940”, “Surlyn 8945”, “Surlyn 9120”, “Surlyn 9150”, “Surlyn 9910”, “Surlyn 9945”, “Surlyn AD8546”, “HPF1000”, and “HPF2000”, manufactured by E.I. du Pont de Nemours and Company; and trade names “IOTEK 7010”, “IOTEK 7030”, “IOTEK 7510”, “IOTEK 7520”, “IOTEK 8000”, and “IOTEK 8030”, manufactured by ExxonMobil Chemical Corporation. Two or more ionomer resins may be used in combination.
Preferably, the resin composition of the inner cover 6 includes a styrene block-containing thermoplastic elastomer. The styrene block-containing thermoplastic elastomer includes a polystyrene block as a hard segment, and a soft segment. A typical soft segment is a diene block. Examples of compounds for the diene block include butadiene, isoprene, 1,3-pentadiene, and 2,3-dimethyl-1,3-butadiene. Butadiene and isoprene are preferable. Two or more compounds may be used in combination.
Examples of styrene block-containing thermoplastic elastomers include styrene-butadiene-styrene block copolymers (SBS), styrene-isoprene-styrene block copolymers (SIS), styrene-isoprene-butadiene-styrene block copolymers (SIBS), hydrogenated SBS, hydrogenated SIS, and hydrogenated SIBS. Examples of hydrogenated SBS include styrene-ethylene-butylene-styrene block copolymers (SEBS). Examples of hydrogenated SIS include styrene-ethylene-propylene-styrene block copolymers (SEPS). Examples of hydrogenated SIBS include styrene-ethylene-ethylene-propylene-styrene block copolymers (SEEPS).
In light of resilience performance of the golf ball 2, the content of the styrene component in the styrene block-containing thermoplastic elastomer is preferably not less than 10% by weight, more preferably not less than 12% by weight, and particularly preferably not less than 15% by weight. In light of feel at impact of the golf ball 2, the content is preferably not greater than 50% by weight, more preferably not greater than 47% by weight, and particularly preferably not greater than 45% by weight.
In the present invention, styrene block-containing thermoplastic elastomers include an alloy of an olefin and one or more members selected from the group consisting of SBS, SIS, SIBS, SEBS, SEPS, and SEEPS. The olefin component in the alloy is presumed to contribute to improvement of compatibility with another base polymer. The alloy can contribute to the resilience performance of the golf ball 2. An olefin having 2 to 10 carbon atoms is preferable. Examples of suitable olefins include ethylene, propylene, butene, and pentene. Ethylene and propylene are particularly preferable.
Specific examples of polymer alloys include trade names “TEFABLOC T3221C”, “TEFABLOC T3339C”, “TEFABLOC SJ4400N”, “TEFABLOC SJ5400N”, “TEFABLOC SJ6400N”, “TEFABLOC SJ7400N”, “TEFABLOC SJ8400N”, “TEFABLOC SJ9400N”, and “TEFABLOC SR04”, manufactured by Mitsubishi Chemical Corporation. Other specific examples of styrene block-containing thermoplastic elastomers include trade name “Epofriend A1010” manufactured by Daicel Corporation, and trade name “SEPTON HG-252” manufactured by Kuraray Co., Ltd.
In light of feel at impact, the proportion of the styrene block-containing thermoplastic elastomer to the entire base polymer is preferably not less than 10% by weight, more preferably not less than 15% by weight, and particularly preferably not less than 20% by weight. In light of resilience performance, this proportion is preferably not greater than 50% by weight.
The resin composition of the inner cover 6 may include a coloring agent, a filler, a dispersant, an antioxidant, an ultraviolet absorber, a light stabilizer, a fluorescent material, a fluorescent brightener, and the like in an adequate amount. When the hue of the golf ball 2 is white, a typical coloring agent is titanium dioxide.
The inner cover 6 preferably has a thickness Ti of not less than 0.50 mm and not greater than 1.50 mm. The golf ball 2 in which the thickness Ti is not less than 0.50 mm has excellent feel at impact. From this viewpoint, the thickness Ti is more preferably not less than 0.70 mm and particularly preferably not less than 0.80 mm. The golf ball 2 in which the thickness Ti is not greater than 1.50 mm has excellent resilience performance. From this viewpoint, the thickness Ti is more preferably not greater than 1.30 mm and particularly preferably not greater than 1.20 mm. The thickness is measured at a position immediately below the land 12.
The inner cover 6 preferably has a hardness Hi of not less than 25 and not greater than 75. The golf ball 2 in which the hardness Hi is not less than 25 has excellent resilience performance. From this viewpoint, the hardness Hi is more preferably not less than 30 and particularly preferably not less than 35. The golf ball 2 in which the hardness Hi is not greater than 75 has excellent feel at impact. From this viewpoint, the hardness Hi is more preferably not greater than 72 and particularly preferably not greater than 70.
The hardness Hi of the inner cover 6 is measured according to the standards of “ASTM-D 2240-68”. The hardness Hi is measured with a Shore D type hardness scale mounted to an automated hardness meter (trade name “digi test II” manufactured by Heinrich Bareiss Prüfgerätebau GmbH). For the measurement, a sheet that is formed by hot press, is formed from the same material as that of the inner cover 6, and has a thickness of about 2 mm is used. Prior to the measurement, a sheet is kept at 23° C. for two weeks. At the time of measurement, three sheets are stacked.
The outer cover 8 is positioned outside the inner cover 6. The outer cover 8 is formed from a thermoplastic resin composition. Examples of the base polymer of the resin composition include ionomer resins, thermoplastic polyester elastomers, thermoplastic polyamide elastomers, thermoplastic polyurethane elastomers, thermoplastic polyolefin elastomers, and thermoplastic polystyrene elastomers. Ionomer resins are particularly preferable. Ionomer resins are highly elastic. The golf ball 2 that includes the outer cover 8 including an ionomer resin has excellent resilience performance. The golf ball 2 has excellent flight distance upon a shot with a driver. The ionomer resin described above for the inner cover 6 can be used for the outer cover 8.
An ionomer resin and another resin may be used in combination. In this case, in light of resilience performance, the ionomer resin is included as the principal component of the base polymer. The proportion of the ionomer resin to the entire base polymer is preferably not less than 50% by weight, more preferably not less than 70% by weight, and particularly preferably not less than 80% by weight.
Another base polymer suitable for the outer cover 8 is a polyurethane. When a polyurethane and another resin are used in combination for the outer cover 8, the proportion of the polyurethane to the entire base resin is preferably not less than 50% by weight, more preferably not less than 60% by weight, and particularly preferably not less than 70% by weight.
The resin composition of the outer cover 8 may include a thermoplastic polyurethane or may include a thermosetting polyurethane. In light of productivity of the golf ball 2, the thermoplastic polyurethane is preferable. The thermoplastic polyurethane includes a polyurethane component as a hard segment, and a polyester component or a polyether component as a soft segment. The thermoplastic polyurethane is flexible. The outer cover 8 in which the polyurethane is used has excellent scuff resistance.
The thermoplastic polyurethane has a urethane bond within the molecule. The urethane bond can be formed by reacting a polyol with a polyisocyanate. The polyol, as a material for the urethane bond, has a plurality of hydroxyl groups. Low-molecular-weight polyols and high-molecular-weight polyols can be used.
Examples of low-molecular-weight polyols include diols, triols, tetraols, and hexaols. Specific examples of diols include ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, dipropylene glycol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, 2,3-dimethyl-2,3-butanediol, neopentyl glycol, pentanediol, hexanediol, heptanediol, octanediol, and 1,6-cyclohexanedimethylol. Aniline diols or bisphenol A diols may be used. Specific examples of triols include glycerin, trimethylol propane, and hexanetriol. Specific examples of tetraols include pentaerythritol and sorbitol.
Examples of high-molecular-weight polyols include polyether polyols such as polyoxyethylene glycol (PEG), polyoxypropylene glycol (PPG), and polytetramethylene ether glycol (PTMG); condensed polyester polyols such as polyethylene adipate (PEA), polybutylene adipate (PBA), and polyhexamethylene adipate (PHMA); lactone polyester polyols such as poly-ε-caprolactone (PCL); polycarbonate polyols such as polyhexamethylene carbonate; and acrylic polyols. Two or more polyols may be used in combination. In light of feel at impact of the golf ball 2, the high-molecular-weight polyol has a number average molecular weight of preferably not less than 400 and more preferably not less than 1000. The number average molecular weight is preferably not greater than 10000.
Examples of polyisocyanates, as a material for the urethane bond, include aromatic diisocyanates, alicyclic diisocyanates, and aliphatic diisocyanates. Two or more types of diisocyanates may be used in combination.
Examples of aromatic diisocyanates include 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 4,4′-diphenylmethane diisocyanate (MDI), 1,5-naphthylene diisocyanate (NDI), 3,3′-bitolylene-4,4′-diisocyanate (TODI), xylylene diisocyanate (XDI), tetramethylxylylene diisocyanate (TMXDI), and paraphenylene diisocyanate (PPDI). One example of aliphatic diisocyanates is hexamethylene diisocyanate (HDI). Examples of alicyclic diisocyanates include 4,4′-dicyclohexylmethane diisocyanate (Hi2MDI), 1,3-bis(isocyanatomethyl)cyclohexane (H6XDI), isophorone diisocyanate (IPDI), and trans-1,4-cyclohexane diisocyanate (CHDI). 4,4′-dicyclohexylmethane diisocyanate is preferable.
Specific examples of the thermoplastic polyurethane include trade names “Elastollan NY80A”, “Elastollan NY82A”, “Elastollan NY83A”, “Elastollan NY84A”, “Elastollan NY85A”, “Elastollan NY88A”, “Elastollan NY90A”, “Elastollan NY95A”, “Elastollan NY97A”, “Elastollan NY585”, and “Elastollan KP016N”, manufactured by BASF Japan Ltd.; and trade names “RESAMINE P4585LS” and “RESAMINE PS62490”, manufactured by Dainichiseika Color & Chemicals Mfg. Co., Ltd.
The resin composition of the outer cover 8 may include a coloring agent, a filler, a dispersant, an antioxidant, an ultraviolet absorber, a light stabilizer, a fluorescent material, a fluorescent brightener, and the like in an adequate amount. When the hue of the golf ball 2 is white, a typical coloring agent is titanium dioxide.
The outer cover 8 preferably has a thickness To of not less than 0.30 mm and not greater than 2.30 mm. In the golf ball 2 in which the thickness To is not less than 0.30 mm, the outer cover 8 can contribute to resilience performance or spin performance. From this viewpoint, the thickness To is more preferably not less than 0.35 mm and particularly preferably not less than 0.40 mm. In the golf ball 2 in which the thickness To is not greater than 2.30 mm, the outer cover 8 does not impair resilience performance or feel at impact. From this viewpoint, the thickness To is more preferably not greater than 2.20 mm and particularly preferably not greater than 2.10 mm. The thickness is measured at a position immediately below the land 12.
The ratio (Ti/To) of the thickness Ti of the inner cover 6 to the thickness To of the outer cover 8 is preferably not less than 0.3 and not greater than 3.0.
The outer cover 8 preferably has a hardness Ho of not less than 20 and not greater than 75. The golf ball 2 in which the hardness Ho is not less than 20 has excellent resilience performance. From this viewpoint, the hardness Ho is more preferably not less than 23 and particularly preferably not less than 25. The golf ball 2 in which the hardness Ho is not greater than 75 has excellent feel at impact. From this viewpoint, the hardness Ho is more preferably not greater than 72 and particularly preferably not greater than 70.
The hardness Ho of the outer cover 8 is measured according to the standards of “ASTM-D 2240-68”. The hardness Ho is measured with a Shore D type hardness scale mounted to an automated hardness meter (trade name “digi test II” manufactured by Heinrich Bareiss Prüfgerätebau GmbH). For the measurement, a sheet that is formed by hot press, is formed from the same material as that of the outer cover 8, and has a thickness of about 2 mm is used. Prior to the measurement, a sheet is kept at 23° C. for two weeks. At the time of measurement, three sheets are stacked.
The golf ball 2 may include a reinforcing layer between the inner cover 6 and the outer cover 8. The reinforcing layer firmly adheres to the inner cover 6 and also to the outer cover 8. The reinforcing layer suppresses separation of the outer cover 8 from the inner cover 6. The reinforcing layer is formed from a resin composition. Examples of a preferable base polymer of the reinforcing layer include two-component curing type epoxy resins and two-component curing type urethane resins. The reinforcing layer preferably has a thickness of not less than 5 μm and not greater than 30 μm.
An index Cv relates to the specifications of the inner cover 6 and the outer cover 8. The index Cv correlates with the initial speed of the golf ball 2 when the golf ball 2 is hit with a driver. The index Cv is calculated by the following mathematical formula.
Cv=(Hi×Ti+Ho×To)/(Ti+To)
The index Cv is preferably not less than 25 and not greater than 75, more preferably not less than 40 and not greater than 60, and particularly preferably not less than 45 and not greater than 55.
An index Cs relates to the specifications of the inner cover 6 and the outer cover 8. The index Cs correlates with the spin rate of the golf ball 2 when the golf ball 2 is hit with a driver. The index Cs is calculated by the following mathematical formula.
Cs=(Hi×Ti+2Ho×To)/(Ti+2To)
The index Cs is preferably not less than 25 and not greater than 75, more preferably not less than 35 and not greater than 65, and particularly preferably not less than 42 and not greater than 60.
The golf ball 2 preferably has a compression A of not less than 20 and not greater than 120. When the golf ball 2 having a compression A of not less than 20 is hit with a driver, the golf ball 2 can be launched at a high initial speed. From this viewpoint, the compression A is more preferably not less than 50 and particularly preferably not less than 70. The golf ball 2 having a compression A of not greater than 120 has excellent feel at impact. From this viewpoint, the compression A is more preferably not greater than 110 and particularly preferably not greater than 105.
The compression A can be measured with an ATTI compression tester manufactured by Atti Engineering Company.
As shown in
The number of the dimples A is 60; the number of the dimples B is 158; the number of the dimples C is 72; the number of the dimples D is 36; and the number of the dimples E is 12. The total number of the dimples 10 is 338. A dimple pattern is formed by these dimples 10 and the land 12.
In
The diameter Dm of each dimple 10 is preferably not less than 2.0 mm and not greater than 6.0 mm. The dimple 10 having a diameter Dm of not less than 2.0 mm contributes to turbulization. From this viewpoint, the diameter Dm is more preferably not less than 2.5 mm and particularly preferably not less than 2.8 mm. The dimple 10 having a diameter Dm of not greater than 6.0 mm does not impair a fundamental feature of the golf ball 2 being substantially a sphere. From this viewpoint, the diameter Dm is more preferably not greater than 5.5 mm and particularly preferably not greater than 5.0 mm.
In
In light of suppression of rising of the golf ball 2 during flight, the first depth Dp1 of each dimple 10 is preferably not less than 0.10 mm, more preferably not less than 0.13 mm, and particularly preferably not less than 0.15 mm. In light of suppression of dropping of the golf ball 2 during flight, the first depth Dp1 is preferably not greater than 0.65 mm, more preferably not greater than 0.60 mm, and particularly preferably not greater than 0.55 mm.
The area S of the dimple 10 is the area of a region surrounded by the contour line of the dimple 10 when the central point of the golf ball 2 is viewed at infinity. In the case of the dimple 10 which has a circular shape, the area S is calculated by the following mathematical formula.
S=(Dm/2)2*π
In the golf ball 2 shown in
In the present invention, the ratio of the sum of the areas S of all the dimples 10 relative to the surface area of the phantom sphere 14 is referred to as an occupation ratio So. From the viewpoint of achieving sufficient turbulization, the occupation ratio So is preferably not less than 78%, more preferably not less than 80%, and particularly preferably not less than 82%. The occupation ratio So is preferably not greater than 95%. In the golf ball 2 shown in
From the viewpoint of achieving a sufficient occupation ratio So, the total number of the dimples 10 is preferably not less than 250, more preferably not less than 280, and particularly preferably not less than 300. From the viewpoint that each dimple 10 can contribute to turbulization, the total number is preferably not greater than 450, more preferably not greater than 410, and particularly preferably not greater than 390.
In the present invention, the “volume of the dimple” means the volume of a portion surrounded by the surface of the dimple 10 and the plane including the contour of the dimple 10. The total volume D of the dimples 10 is preferably not less than 200 mm3 and not greater than 500 mm3. With the golf ball 2 in which the total volume D is not less than 200 mm3, rising of the golf ball 2 during flight is suppressed. From this viewpoint, the total volume D is more preferably not less than 250 mm3 and particularly preferably not less than 270 mm3. With the golf ball 2 in which the total volume D is not greater than 500 mm3, dropping of the golf ball 2 during flight is suppressed. From this viewpoint, the total volume D is more preferably not greater than 400 mm3 and particularly preferably not greater than 370 mm3.
In the golf ball 2 shown in
The golf ball 2 satisfies the following mathematical formulas (I) and (II).
Vw=54+0.01(2.5A−B+5Cv)≥58.0 (I)
0.08X2−4.25X+345−20≤D≤0.08X2−4.25X+345+20 (II)
A: the compression (Atti) of the golf ball 2
B: the hardness difference (Shore C) between the surface and the center of the core 4
Cv: (Hi×Ti+Ho×To)/(Ti+To)
Cs: (Hi×Ti+2Ho×To)/(Ti+2To)
D: the total volume (mm3) of the dimples 10
X: Sw/Vw
Hi: the hardness (Shore D) of the inner cover 6
Ho: the hardness (Shore D) of the outer cover 8
Ti: the thickness (mm) of the inner cover 6
To: the thickness (mm) of the outer cover 8
Sw: 3000+10(A−B−1.5Cs)
In the golf ball 2 that satisfies the mathematical formula (I), the index Vw is not less than 58.0. When the golf ball 2 in which the index Vw is not less than 58.0 is hit with a driver, the golf ball 2 is launched at a high initial speed. The golf ball 2 has excellent flight performance upon a shot with a driver. In light of flight performance, the index Vw is more preferably not less than 58.2 and particularly preferably not less than 58.4. The index Vw is preferably not greater than 59.5, more preferably not greater than 59.3, and particularly preferably not greater than 59.1.
In the golf ball 2 that satisfies the mathematical formula (II), the balance between the lift force caused due to spin and the lift force caused due to the dimples 10 is appropriate. With the golf ball 2, there is little loss of kinetic energy. When the golf ball 2 is hit with a driver, the trajectory height and the flight duration are appropriate. The golf ball 2 has excellent flight performance upon a shot with a driver. In light of flight performance, the golf ball 2 more preferably satisfies the following mathematical formula.
0.08X2−4.25X+345−15≤D≤0.08X2−4.25X+345+15
In light of flight performance, the golf ball 2 particularly preferably satisfies the following mathematical formula.
0.08X2−4.25X+345−10≤D≤0.08X2−4.25X+345+10
Preferably, the golf ball 2 satisfies the following mathematical formula (III).
Sa=4500+10(A−0.5B−2Cs)≥4000 (III)
In the golf ball 2 that satisfies the mathematical formula (III), the index Sa is not less than 4000. When the golf ball 2 in which the index Sa is not less than 4000 is hit with a golf club, the golf ball 2 is launched with an appropriate spin rate. The golf ball 2 has excellent flight performance and controllability. From these viewpoints, the index Sa is more preferably not less than 4050 and particularly preferably not less than 4100. The index Sa is preferably not greater than 4700, more preferably not greater than 4650, and particularly preferably not greater than 4600.
Preferably, a lift force coefficient CL of the golf ball 2 satisfies the following mathematical formula (IV).
CLL≤CL≤CLU
CLU: Sw/60×(−9.5×10−6×D+6.1×10−3)+(1.871×10−4×D−3.5×10−3)
CLL: Sw/60×(−3.8×10−6×D+3.0×10−3)+(4.52×10−5×D+8.32×10−2) (IV)
In the golf ball 2 that satisfies the mathematical formula (IV), the lift force caused due to the dimples 10 is appropriate. With the golf ball 2, rising and dropping of the golf ball 2 during flight are suppressed. The golf ball 2 has excellent flight performance upon a shot with a driver.
The following will show the effects of the present invention by means of Examples, but the present invention should not be construed in a limited manner on the basis of the description of these Examples.
A rubber composition was obtained by kneading 100 parts by weight of a high-cis polybutadiene (trade name “BR-730”, manufactured by JSR Corporation), an appropriate amount of zinc diacrylate, 5 parts by weight of zinc oxide, an appropriate amount of barium sulfate, 2.0 parts by weight of benzoic acid, 0.5 parts by weight of diphenyl disulfide, and 0.9 parts by weight of dicumyl peroxide. This rubber composition was placed into a mold including upper and lower mold halves each having a hemispherical cavity, and heated to obtain a core with a diameter of 38.2 mm. The amount of zinc diacrylate was adjusted such that a predetermined amount of compressive deformation Df was obtained. The amount of barium sulfate was adjusted such that a core having a predetermined weight was obtained. The crosslinking temperature Te was 160° C. The crosslinking time period Tm was 20 minutes.
A resin composition a was obtained by kneading 30 parts by weight of an ionomer resin (the aforementioned “Himilan AM7337”), 30 parts by weight of another ionomer resin (the aforementioned “Himilan AM7329”), 40 parts by weight of a styrene block-containing thermoplastic elastomer (the aforementioned “TEFABLOC T3221C”), 4 parts by weight of titanium dioxide, and 0.2 parts by weight of a light stabilizer (trade name “JF-90”, manufactured by Johoku Chemical Co., Ltd.) with a twin-screw kneading extruder. The core was placed into a mold including upper and lower mold halves each having a hemispherical cavity. The core was covered with the resin composition a by injection molding to form an inner cover. The thickness of the inner cover was 1.00 mm.
A resin composition c was obtained by kneading 40 parts by weight of an ionomer resin (the aforementioned “Himilan AM7329”), 52 parts by weight of another ionomer resin (the aforementioned “Himilan 1605”), 8 parts by weight of a styrene block-containing thermoplastic elastomer (the aforementioned “TEFABLOC T3221C”), 4 parts by weight of titanium dioxide, and 0.2 parts by weight of a light stabilizer (the aforementioned “JF-90”) with a twin-screw kneading extruder. The sphere consisting of the core and the inner cover was placed into a mold including upper and lower mold halves each having a hemispherical cavity. The sphere was covered with the resin composition c by injection molding to form an outer cover. The thickness of the outer cover was 1.25 mm.
A clear paint including a two-component curing type polyurethane as a base material was applied to this outer cover to obtain a golf ball of Example 1 with a diameter of about 42.7 mm and a weight of about 45.6 g. Dimple specifications I-1 of the golf ball are shown in detail in Tables 3 and 4 below.
Golf balls of Examples 2 to 21 and Comparative Examples 1 to 15 were obtained in the same manner as Example 1, except the specifications of the core, the inner cover, the outer cover, and the dimples were as shown in Tables 5 to 10 below. The compositions of the inner cover and the outer cover are shown in detail in Table 1 below. The specifications of the dimples are shown in detail in Tables 3 and 4 below.
A rubber composition was obtained by kneading 100 parts by weight of a high-cis polybutadiene (trade name “BR-730”, manufactured by JSR Corporation), an appropriate amount of zinc diacrylate, 5 parts by weight of zinc oxide, an appropriate amount of barium sulfate, 2.0 parts by weight of benzoic acid, 0.5 parts by weight of diphenyl disulfide, and 0.9 parts by weight of dicumyl peroxide. This rubber composition was placed into a mold including upper and lower mold halves each having a hemispherical cavity, and heated to obtain a core with a diameter of 39.6 mm. The amount of zinc diacrylate was adjusted such that a predetermined amount of compressive deformation Df was obtained. The amount of barium sulfate was adjusted such that a core having a predetermined weight was obtained. The crosslinking temperature Te was 160° C. The crosslinking time period Tm was 20 minutes.
A resin composition d was obtained by kneading 50 parts by weight of an ionomer resin (the aforementioned “Himilan AM7329”), 42 parts by weight of another ionomer resin (the aforementioned “Himilan 1605”), 8 parts by weight of still another ionomer resin (the aforementioned “Surlyn 8150”), 4 parts by weight of titanium dioxide, and 0.2 parts by weight of a light stabilizer (trade name “JF-90”, manufactured by Johoku Chemical Co., Ltd.) with a twin-screw kneading extruder. The core was placed into a mold including upper and lower mold halves each having a hemispherical cavity. The core was covered with the resin composition d by injection molding to form an inner cover. The thickness of the inner cover was 1.00 mm.
A paint composition (trade name “POLIN 750LE”, manufactured by SHINTO PAINT CO., LTD.) including a two-component curing type epoxy resin as a base polymer was prepared. The base material liquid of this paint composition includes 30 parts by weight of a bisphenol A type epoxy resin and 70 parts by weight of a solvent. The curing agent liquid of this paint composition includes 40 parts by weight of a modified polyamide amine, 55 parts by weight of a solvent, and 5 parts by weight of titanium dioxide. The weight ratio of the base material liquid to the curing agent liquid is 1/1. This paint composition was applied to the surface of the inner cover with a spray gun, and kept at 23° C. for 12 hours to obtain a reinforcing layer. The thickness of the reinforcing layer was 10 μm.
A resin composition f was obtained by kneading 100 parts by weight of a thermoplastic polyurethane elastomer (the aforementioned “Elastollan NY84A”), 4 parts by weight of titanium dioxide, and 0.2 parts by weight of a light stabilizer (trade name “JF-90”, manufactured by Johoku Chemical Co., Ltd.) with a twin-screw kneading extruder. Half shells were obtained from this resin composition f by compression molding. The sphere consisting of the core and the inner cover was covered with two of these half shells. These half shells and the sphere were placed into a final mold that includes upper and lower mold halves each having a hemispherical cavity and having a large number of pimples on its cavity face, and an outer cover was obtained by compression molding. The thickness of the outer cover was 0.55 mm. Dimples having a shape that is the inverted shape of the pimples were formed on the outer cover.
A clear paint including a two-component curing type polyurethane as a base material was applied to this outer cover to obtain a golf ball of Example 22 with a diameter of about 42.7 mm and a weight of about 45.6 g. Dimple specifications I-2 of the golf ball are shown in detail in Tables 3 and 4 below.
Golf balls of Examples 23 to 35 and Comparative Examples 16 to 21 were obtained in the same manner as Example 22, except the specifications of the core, the inner cover, the outer cover, and the dimples were as shown in Tables 11 to 14 below. The composition of the inner cover is shown in detail in Table 1 below. The composition of the outer cover is shown in detail in Table 2 below. The specifications of the dimples are shown in detail in Tables 3 and 4 below.
[Flight Test]
A driver with a head made of a titanium alloy (trade name “XXIO 9”, manufactured by Sumitomo Rubber Industries, Ltd., shaft hardness: R, loft angle: 10.5°) was attached to a swing machine manufactured by Golf Laboratories, Inc. A golf ball was hit under a condition of a head speed of 40 m/sec, and the flight distance was measured. The flight distance is the distance from the launch point to the stop point. During the test, the weather was almost windless. The average value of data obtained by 12 measurements is shown in Tables 5 to 14 below.
As shown in Tables 5 to 14, the golf ball of each Example has excellent flight performance. From the evaluation results, advantages of the present invention are clear.
The golf ball according to the present invention is suitable for, for example, playing golf on golf courses and practicing at driving ranges. The above descriptions are merely illustrative examples, and various modifications can be made without departing from the principles of the present invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2019-201977 | Nov 2019 | JP | national |
