The invention relates to a golf club head. More particularly, the invention is related to a golf club head with a face provided with localized grooves on the exterior of the face and a reinforced central region on the interior of the face.
The complexities of golf club design are well-known. The choice of specifications for each component of the club (i.e., the club head, shaft, hosel, grip, and subcomponents thereof) directly impacts the performance of the club. Thus, by varying the design specifications, a golf club can be tailored to desired performance characteristics.
The design of club heads has long been studied. Among the more prominent considerations in club head design are loft, lie, face angle, horizontal face bulge, vertical face roll, face progression, sole curvature, center of gravity location, and overall head weight. While this basic set of criteria is generally the focus of golf club engineering, several other considerations must also be addressed. The interior design of the club head may be tailored to achieve particular characteristics, such as by including hosel or shaft attachment means, perimeter weighting on the face or body of the club head, and fillers within hollow club heads. The choice of materials for manufacture of the club head, must also be considered.
The type of surface treatment on the outer surface of the face is an additional design consideration. The United States Golf Association (USGA), the organization that sets the rules of golf in the United States, has instituted a rule that prohibits the competitive use in any USGA sanctioned event of a golf club where the surface roughness within an impact area of the face exceeds that of decorative sandblasting or fine milling. To spite this rule, it is widely known that many players create a roughened club head face, in order to obtain a greater backspin on their shots.
Additionally, faces are traditionally provided with stria or grooves, at regularly spaced intervals on the surface. The grooves are usually parallel, and must conform to standards established by the USGA covering groove cross-sectional symmetry, groove edge roundness, distance between adjacent grooves, and groove depth.
Various theories have been advanced to either explain or dismiss the importance and influence of grooves. The physical influence of the groove on ball trajectory, for example, may be partly attributed to the momentary deformation of the golf ball cover into the groove upon impact. This deformation is dictated by the modulus of elasticity of the golf ball cover material. Grooves are generally credited with providing large-scale, or macro-roughening on the club head face, thereby increasing back spin. Grooves in the club face may also assist a player in club alignment at address. While the degree of influence of club facial grooves on ball trajectory is disputed, grooves are largely recognized as a meaningful consideration in club head design.
The designs for golf club heads also must be strong enough to withstand the impact forces that occur due to contact between the head and the ball. The loading that occurs during this brief impact can confer an acceleration to the golf ball that is 20,000 times the acceleration of gravity, which is about four orders of magnitude greater than that of gravity. Thus, the club face and body should be designed to resist permanent deformations or catastrophic failure, such as by cracking.
It is not unusual for the club heads of prior art woods to have a face thickness exceeding 0.12 inch. This thickness has typically been required so that the club head face can withstand the impact forces. The faces of irons must also withstand considerable stresses, and as disclosed in U.S. Pat. No. 5,971,868 to Kosmatka. Thus, the faces of irons may be provided with a contoured back surface to provide increased structural integrity. Nevertheless, the design of hollow woods presents distinctly different challenges from irons, particularly due to the cavities defined within hollow woods. Whether produced by investment casting, molding, or otherwise, woods are subjected to different manufacturing stresses, and different performance requirements than irons.
The thickness of the club head face impacts various club head parameters, including the overall weight of the club head, the rigidity of the face, the vibration characteristics of the club head, the sound produced upon impact of the face with a ball, and the location of the center of gravity of the club head. In some club heads, it is desirable to minimize face thickness. Any decrease in thickness, however, must be compensated for by adjusting other design considerations. Such adjustments may include the provision of other structural features on the back surface of the club face, or the inner surface of the club head shell. Another optional adjustment includes the use of a filler material in the shell. Furthermore, the overall construction of the club head may be adjusted, such as by using a face plate insert that is fit to a club head shell, by welding, soldering or other means. Alternatively, the face plate insert may be integrally formed with the shell.
Particularly during casting of a club head, it is difficult to repeatedly produce the desired shape to a tight dimensional tolerance. However, the performance of a golf club head, particularly a metal wood, is in part a function of the proper shape and size of the club face. One especially vexing problem encountered during casting of prior art club heads is that the club head face, which is initially cast with a generally convex exterior surface, upon cooling often collapses inward and fails to retain the desired shape. Such a problem may be exacerbated in club heads with thin faces.
Thus, there is a need for a golf club head that can be consistently manufactured with a desired club head shape and size, and has a face that can withstand the impact stresses encountered during ball striking. More particularly, there is a need for a club head with a thin face that performs well. Additionally, there is a need for a club head that minimizes the degree of backspin imparted to a golf ball.
The present invention relates to a golf club head adapted for attachment to a shaft. The head includes a shell that defines an inner cavity. The shell includes a face and a body. The face has an exterior surface and an interior surface. Grooves are formed on the exterior surface of the face offset from the sweet spot or center of the face.
Preferably, a localized reinforcement portion is provided on the interior surface of the face at the sweet spot or center. As a result, the face has two portions with different thicknesses. The localized reinforcement portion has a first thickness greater than the second thickness of the remaining portion of the face. The second portion surrounding the first portion has a second thickness less than or equal to about 0.12 inches, and the first thickness is greater than the second thickness. A grooveless region on the exterior of the face comprises at least 25% of the face area including the center thereof. Preferably, grooves do not extend across the exterior surface of the face at the localized reinforcement portion, and the grooves bound an area less than or equal to about 50% of an area of the face. The grooves preferably are spaced from the center of the face at least 0.375 inches in any direction.
In one embodiment, the first thickness or thickness of the reinforcement portion is greater than or equal to about 0.08 inches and less than or equal to about 0.12 inches. The second thickness is less than or equal to about 0.12 inches and more preferably less than or equal to about 0.08 inches. Most preferably the second thickness is less than or equal to about 0.06 inches. The first thickness can be uniform or varied across the reinforcement portion. The first portion and second portion are formed of the same material. At least one groove preferably extends substantially between a toe end and a heel end of the golf club
In another embodiment, the localized reinforcement portion has an area between about 10% to about 90% of the face area. Preferably, the reinforcement portion area is less than about 15% of the face area. In yet another embodiment, the area of the localized reinforcement portion is less than about 25% of the face area. Preferably, the shell of the club head has a crown plate, a sole plate, the face, and a hosel, with the sole plate formed integral with the shell. Alternatively, the crown plate is formed integral with the shell.
The present invention is also directed to a golf club head adapted for attachment to a shaft that includes a shell that defines an inner cavity. The shell further includes a face with first and second portions. The first portion is in the center of the face and has a first thickness. The second portion has a second thickness less than or equal to about 0.12 inches. The first thickness is greater than the second thickness. In addition, the face has an exterior surface with a substantially smooth portion having an area greater than about 25% of an area of the face. Preferably, the smooth portion is in the center of the face and is the part that lacks grooves. The smooth portion includes at least a portion of the first portion.
The present invention is also related to a method of forming a golf club head comprising the steps of forming a shell defining an inner cavity with a face and a body. The step of forming the shell includes the steps of: forming the face with a first portion of the face in the center of the face and having a first thickness, and a second portion surrounding the first portion and having a second thickness less than or equal to about 0.12, with the first thickness being greater than the second thickness; and forming grooves in the face spaced from the center. Preferably, the step of forming the shell further includes casting the first portion simultaneously with the face. Alternatively, the step of forming the shell includes casting the first portion separate from the face and subsequently coupling the first portion to the face. In one embodiment, the face is stamped. In another embodiment, the face is engraved.
Preferred features of the present invention are disclosed in the accompanying drawings, wherein similar reference characters denote similar elements throughout the several views, and wherein:
With reference to
During use, a golf club shaft (not shown) is attached at hosel 27. The hosel may extend to the bottom of the club head, may terminate at a location intermediate the top portion 27 and sole plate 26, or the hosel 27 may terminate at the top portion 24 of the head.
Inner cavity 30 of club head 10 may be empty, or alternatively may be filled with a foam or other low specific gravity material. Preferably, the shell is entirely cast, or at least face 16 is formed from a higher strength alloy than body 14. More preferably, shell 12 is formed so that the body 14 and face 16 may be combined to be integral, such as by welding, thus forming a homogeneous shell.
In an alternate embodiment, shell 12 has a body 14, face 16, toe portion 18, heel portion 20, sole plate 26, and hosel 27. The sole plate is formed integral with shell 12. In this embodiment, a separate crown plate (not shown) is fitted to shell 12, thereby creating the hollow, inner cavity. The crown plate may alternatively be formed integral with the shell.
In a preferred embodiment, face 16 is cold forged or stamped from as-rolled sheet stock of high strength SP-700 titanium alloy (Ti-4.5% AI-3% V-2% Mo-2% Fe).
Alternatively, face 16 is formed of a high strength forging titanium alloy such as 10-2-3 (Ti-10% V-2% Fe-3% AI) or 15-3-3-3 (Ti-15% V-3% Cr-3% Sn-3% AI). Body 14 along with sole plate 26 or a crown plate are produced from a different titanium alloy from that of face 16, preferably by casting a 6-4 alloy (Ti-6% Al-4% V).
Referring to
Referring to
It is recommended that reinforcement portion 36 has an area that is between about 10% and about 90% of the interior surface area 40 or face area. The interior surface and exterior face areas are substantially the same. However, in an embodiment where they vary, either can be used as a comparison to the reinforcement area. In a preferred embodiment, the reinforcement area is approximately about 25% of the face area. Most preferably, the reinforcement area is about 15% of the face area.
Referring to
Reinforcement portion 36 is provided at or aligned with a sweet spot or the center of face 16, as defined below, where impact forces are expected to be greatest. This permits a thinner face 16 to be used, as compared with a non-reinforced design. The reinforcement distributes the stresses such that the structural integrity of face 16 is sound.
The sweet spot is generally defined, in mechanical terms, as the intersection of a longitudinal line passing through the center of gravity and the face 16. The center of the face includes the sweet spot, but refers to a larger area of the face. The center is a portion of the face that can be defined and still be surrounded on all four sides with a remaining portion of the face without the reinforcement portion. Thus, the reinforcement portion can be located aligned with the sweet spot or more generally in the center of the face.
Preferably, the horizontal projection of the center of gravity intersects the face 16 in the reinforcement portion 36, the thickened region of the club face. More preferably, the intersection of the horizontal projection of the center of gravity with the face is located substantially in the center of reinforcement portion 36.
As shown in
It should be noted that the lack of grooves 32 in the sweet spot or central area of face 16 (as shown in
The design of a club head may be evaluated using computational techniques, which can include the use of finite element analysis models. When computer modeling club heads, a mass of 200 grams was maintained by adjusting the value of the point masses as the thickness of the face changed. Facial stresses were determined assuming a 109 mph club head speed, and such stresses may be used to evaluate face integrity. Also of interest in the design of the club head is the coefficient of restitution (COR), which is the ratio of the velocity of separation to the velocity of approach. In this model, therefore, COR was determined using the following formula:
(vball-post−vclub-post)/vclub-pre
where,
Referring to
Line 62 has points that represent Conventional Club Heads with different face thickness t1. Line 62 shows that as thickness increases from 0.80 inches to 0.105 inches COR decreases. The club head represented by point A exhibits a safety factor of 1.0 and therefore is acceptable. The club head at point A has a face thickness of 0.105 inches. The club head at point A has a COR of about 0.72 for the considered club head.
Line 64 represents Inventive Club Heads with a central reinforcement portion so that the club head at point B had a reinforcement thickness greater than remaining face thickness t 1, as discussed above. The club head represented by point B exhibits a safety factor of greater than 1.0, therefore the point B is within the shaded or acceptable area 60. The club head at point B has a COR of about 0.77, which is greater than the COR for the club head at point A.
Drivers (Comparative Club 1, Comparative Club 2, and Comparative Club 3) were produced having uniform face thicknesses of 0.08 inches, 0.09 inches and 0.10 inches, respectively. A robot manufactured by True Temper and called Iron Byron was used to test these clubs.
COR values for Comparative Club I, Comparative Club 2 and Comparative Club 3 were 104%, 101.3% and 98.7% of regulated value, respectively. Thus, as thickness increased from Club 1 to Club 3, COR decreased undesirably. Comparative Club 1 and Comparative Club 2 both exhibited face collapse under the testing conditions (i.e., a swing speed of 109 mph). Thus, Comparative Club 1 and Comparative Club 2 are unacceptable.
An Inventive Club has a 1.2 inch by 0.9 inch reinforcement portion at the center. The reinforcement thickness t2 is 0.12 inches. The thickness of the remaining portion is 0.08 inches. Computer modeling confirmed that the Inventive Club has reduced stress in the face center compared to uniform thickness conventional clubs. The thickness t1 may be further adjusted to account for off-center hits, possibly decreasing COR.
Advantageously, the use of a reinforcement portion, such as with the Inventive Club, allows an acceptable COR to be obtained with a club head that exhibits superior behavior under stress when compared, for example, to Comparative Club 3. In addition, a portion of the face of such an Inventive Club has a substantially smaller thickness than permitted by acceptable uniform face thickness clubs, such as Comparative Club 3.
While various descriptions of the present invention are described above, it should be understood that the various features of each embodiment can be used singly or in any combination thereof. Therefore, this invention is not to be limited to only the specifically preferred embodiments depicted herein. Further, it should be understood that variations and modifications within the spirit and scope of the invention may occur to those skilled in the art to which the invention pertains. Accordingly, all expedient modifications readily attainable by one versed in the art from the disclosure set forth herein that are within the scope and spirit of the present invention are to be included as further embodiments of the present invention. The scope of the present invention is accordingly defined as set forth in the appended claims.
This application is a continuation of U.S. patent application Ser. No. 10/943,978, filed Sep. 20, 2004, which is a continuation of U.S. patent application Ser. No. 09/551,893, filed Apr. 19, 2000, each of which is incorporated by reference herein in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
1318325 | Klin | Oct 1919 | A |
1319233 | Mattern | Oct 1919 | A |
1467435 | Kinnear | Sep 1923 | A |
1525352 | Aitken | Feb 1925 | A |
1543691 | Beat | Jun 1925 | A |
1582836 | Link | Apr 1926 | A |
1589363 | Butchart | Jun 1926 | A |
1595589 | Tyler | Aug 1926 | A |
1605551 | Mattern | Nov 1926 | A |
1699874 | Buhrke | Jan 1929 | A |
1704119 | Buhrke | Mar 1929 | A |
1704165 | Buhrke | Mar 1929 | A |
1720867 | Webster et al. | Jul 1929 | A |
2034936 | Barnhart | Mar 1936 | A |
2087685 | Hackney | Jul 1937 | A |
3567228 | Lynn | Mar 1971 | A |
3571900 | Hardesty | Mar 1971 | A |
3625518 | Solheim | Dec 1971 | A |
3659855 | Hardesty | May 1972 | A |
3863932 | Lezatte | Feb 1975 | A |
3985363 | Jepson et al. | Oct 1976 | A |
4023802 | Jepson et al. | May 1977 | A |
4193601 | Reid, Jr. et al. | Mar 1980 | A |
4213613 | Nygren | Jul 1980 | A |
4214754 | Zebelean | Jul 1980 | A |
D267965 | Kobayashi | Feb 1983 | S |
4429879 | Schmidt | Feb 1984 | A |
4449707 | Hayashi et al. | May 1984 | A |
4451041 | Hayashi et al. | May 1984 | A |
4451042 | Hayashi et al. | May 1984 | A |
4465221 | Schmidt | Aug 1984 | A |
4471961 | Masghati et al. | Sep 1984 | A |
4489945 | Kobayashi | Dec 1984 | A |
4511145 | Schmidt | Apr 1985 | A |
4762324 | Anderson | Aug 1988 | A |
4792140 | Yamaguchi et al. | Dec 1988 | A |
4826172 | Antonious | May 1989 | A |
4842243 | Butler | Jun 1989 | A |
4913438 | Anderson | Apr 1990 | A |
4915385 | Anderson | Apr 1990 | A |
4915386 | Antonious | Apr 1990 | A |
4919430 | Antonious | Apr 1990 | A |
4919431 | Antonious | Apr 1990 | A |
4921252 | Antonious | May 1990 | A |
4930781 | Allen | Jun 1990 | A |
4932658 | Antonious | Jun 1990 | A |
4955610 | Creighton et al. | Sep 1990 | A |
D312858 | Anderson et al. | Dec 1990 | S |
5000454 | Soda | Mar 1991 | A |
5024437 | Anderson | Jun 1991 | A |
5028049 | McKeighen | Jul 1991 | A |
5046733 | Antonious | Sep 1991 | A |
5056705 | Wakita et al. | Oct 1991 | A |
5060951 | Allen | Oct 1991 | A |
5067715 | Schmidt et al. | Nov 1991 | A |
5090702 | Viste | Feb 1992 | A |
5094383 | Anderson et al. | Mar 1992 | A |
5106094 | Desbiolles et al. | Apr 1992 | A |
5141230 | Antonious | Aug 1992 | A |
5163682 | Schmidt et al. | Nov 1992 | A |
5180166 | Schmidt et al. | Jan 1993 | A |
5183255 | Antonious | Feb 1993 | A |
5213328 | Long et al. | May 1993 | A |
5221087 | Fenton et al. | Jun 1993 | A |
5240252 | Schmidt et al. | Aug 1993 | A |
5242167 | Antonious | Sep 1993 | A |
5255918 | Anderson et al. | Oct 1993 | A |
5261663 | Anderson | Nov 1993 | A |
5261664 | Anderson | Nov 1993 | A |
5271621 | Lo | Dec 1993 | A |
5292129 | Long et al. | Mar 1994 | A |
5295689 | Lundberg | Mar 1994 | A |
5301945 | Schmidt et al. | Apr 1994 | A |
5318300 | Schmidt et al. | Jun 1994 | A |
5328184 | Antonious | Jul 1994 | A |
5344140 | Anderson | Sep 1994 | A |
5346218 | Wyte | Sep 1994 | A |
5351958 | Helmstetter | Oct 1994 | A |
5358249 | Mendralla | Oct 1994 | A |
5362047 | Shaw et al. | Nov 1994 | A |
5362055 | Rennie | Nov 1994 | A |
5390924 | Antonious | Feb 1995 | A |
5395113 | Antonious | Mar 1995 | A |
5397126 | Allen | Mar 1995 | A |
5397127 | Kawada et al. | Mar 1995 | A |
5401021 | Allen | Mar 1995 | A |
5405137 | Vincent et al. | Apr 1995 | A |
5407202 | Igarashi | Apr 1995 | A |
RE34925 | McKeighen | May 1995 | E |
5417419 | Anderson et al. | May 1995 | A |
5417559 | Schmidt | May 1995 | A |
5423535 | Shaw et al. | Jun 1995 | A |
5429357 | Kobayashi | Jul 1995 | A |
5431396 | Shieh | Jul 1995 | A |
5433440 | Lin | Jul 1995 | A |
5437088 | Igarashi | Aug 1995 | A |
5447307 | Antonious | Sep 1995 | A |
5447309 | Vincent | Sep 1995 | A |
5451056 | Manning | Sep 1995 | A |
5460376 | Schmidt et al. | Oct 1995 | A |
5467983 | Chen | Nov 1995 | A |
5470069 | Schmidt et al. | Nov 1995 | A |
5474296 | Schmidt et al. | Dec 1995 | A |
5482279 | Antonious | Jan 1996 | A |
5497993 | Shan | Mar 1996 | A |
5505450 | Stuff | Apr 1996 | A |
5505453 | Mack | Apr 1996 | A |
5522593 | Kobayashi et al. | Jun 1996 | A |
5524331 | Pond | Jun 1996 | A |
5527034 | Ashcraft et al. | Jun 1996 | A |
5533729 | Leu | Jul 1996 | A |
5536006 | Shieh | Jul 1996 | A |
5547630 | Schmidt | Aug 1996 | A |
5549297 | Mahaffey | Aug 1996 | A |
5564994 | Chang | Oct 1996 | A |
5584770 | Jensen | Dec 1996 | A |
5595552 | Wright et al. | Jan 1997 | A |
5611741 | Schmidt et al. | Mar 1997 | A |
5611742 | Kobayashi | Mar 1997 | A |
5620382 | Cho et al. | Apr 1997 | A |
D379393 | Kubica et al. | May 1997 | S |
5626530 | Schmidt et al. | May 1997 | A |
5643104 | Antonious | Jul 1997 | A |
5643108 | Cheng | Jul 1997 | A |
5643110 | Igarashi | Jul 1997 | A |
5649872 | Antonious | Jul 1997 | A |
5651409 | Sheehan | Jul 1997 | A |
5655976 | Rife | Aug 1997 | A |
5669827 | Nagamoto | Sep 1997 | A |
5669829 | Lin | Sep 1997 | A |
D387113 | Burrows | Dec 1997 | S |
5695411 | Wright et al. | Dec 1997 | A |
5697855 | Aizawa | Dec 1997 | A |
5709614 | Horiba | Jan 1998 | A |
5709615 | Liang | Jan 1998 | A |
5709617 | Nishimura et al. | Jan 1998 | A |
5711722 | Miyajima et al. | Jan 1998 | A |
5716292 | Huang | Feb 1998 | A |
5718641 | Lin | Feb 1998 | A |
5720673 | Anderson | Feb 1998 | A |
5743813 | Chen et al. | Apr 1998 | A |
5753170 | Muang | May 1998 | A |
5755624 | Helmstetter | May 1998 | A |
5755627 | Yamazaki et al. | May 1998 | A |
5762567 | Antonious | Jun 1998 | A |
5766092 | Mimeur et al. | Jun 1998 | A |
5766094 | Mahaffey et al. | Jun 1998 | A |
5766095 | Antonious | Jun 1998 | A |
5776011 | Su et al. | Jul 1998 | A |
5797807 | Moore | Aug 1998 | A |
5800285 | Thorne et al. | Sep 1998 | A |
5807190 | Krumme et al. | Sep 1998 | A |
5827132 | Bamber | Oct 1998 | A |
RE35955 | Lu | Nov 1998 | E |
D401652 | Burrows | Nov 1998 | S |
5830084 | Kosmatka | Nov 1998 | A |
5839975 | Lundberg | Nov 1998 | A |
5842934 | Ezaki et al. | Dec 1998 | A |
5851159 | Burrows | Dec 1998 | A |
5863261 | Eggiman | Jan 1999 | A |
5873791 | Allen | Feb 1999 | A |
5873795 | Wozny et al. | Feb 1999 | A |
D406294 | Burrows | Mar 1999 | S |
5888148 | Allen | Mar 1999 | A |
5890973 | Gamble | Apr 1999 | A |
D411272 | Burrows | Jun 1999 | S |
5908357 | Hsieh | Jun 1999 | A |
5921872 | Kobayashi | Jul 1999 | A |
5931746 | Soong | Aug 1999 | A |
5935019 | Yamamoto | Aug 1999 | A |
5938541 | Allen et al. | Aug 1999 | A |
5954596 | Noble et al. | Sep 1999 | A |
5961394 | Minabe | Oct 1999 | A |
5967905 | Nakahara et al. | Oct 1999 | A |
5971868 | Kosmatka | Oct 1999 | A |
6089992 | Onuki et al. | Jul 2000 | A |
6224497 | Antonious | May 2001 | B1 |
6248025 | Murphy et al. | Jun 2001 | B1 |
6338683 | Kosmatka | Jan 2002 | B1 |
6354962 | Galloway et al. | Mar 2002 | B1 |
6428426 | Helmstetter et al. | Aug 2002 | B1 |
6428427 | Kosmatka | Aug 2002 | B1 |
6443856 | Galloway et al. | Sep 2002 | B1 |
6575845 | Galloway et al. | Jun 2003 | B2 |
6582323 | Soracco et al. | Jun 2003 | B2 |
6602150 | Kosmatka | Aug 2003 | B1 |
6605007 | Bissonnette et al. | Aug 2003 | B1 |
6623377 | Evans et al. | Sep 2003 | B2 |
6663504 | Hocknell et al. | Dec 2003 | B2 |
6824475 | Burnett et al. | Nov 2004 | B2 |
6863626 | Evans et al. | Mar 2005 | B2 |
6966848 | Kusumoto | Nov 2005 | B2 |
7014570 | Evans et al. | Mar 2006 | B2 |
7018303 | Yamamoto | Mar 2006 | B2 |
7220190 | Hirano | May 2007 | B2 |
7384348 | Lin et al. | Jun 2008 | B2 |
7387579 | Lin et al. | Jun 2008 | B2 |
7682262 | Soracco et al. | Mar 2010 | B2 |
7753808 | Matsunaga | Jul 2010 | B2 |
20030064823 | Yamamoto | Apr 2003 | A1 |
Number | Date | Country |
---|---|---|
1114911 | Jan 1996 | CN |
0484931 | May 1992 | EP |
2268693 | Jan 1994 | GB |
2331938 | Jun 1999 | GB |
59207169 | Nov 1984 | JP |
61033682 | Feb 1986 | JP |
61162967 | Jul 1986 | JP |
61181477 | Aug 1986 | JP |
61185281 | Aug 1986 | JP |
61240977 | Oct 1986 | JP |
1244770 | Sep 1989 | JP |
4020357 | Jan 1992 | JP |
4327864 | Nov 1992 | JP |
5212526 | Aug 1993 | JP |
6007487 | Jan 1994 | JP |
6114126 | Apr 1994 | JP |
6126002 | May 1994 | JP |
6154367 | Jun 1994 | JP |
6182005 | Jul 1994 | JP |
6269518 | Sep 1994 | JP |
08164229 | Jun 1996 | JP |
8168541 | Jul 1996 | JP |
8243194 | Sep 1996 | JP |
8280853 | Oct 1996 | JP |
8280854 | Oct 1996 | JP |
8294550 | Nov 1996 | JP |
9028842 | Feb 1997 | JP |
9047531 | Feb 1997 | JP |
9154985 | Jun 1997 | JP |
9168613 | Jun 1997 | JP |
09168613 | Jun 1997 | JP |
9192270 | Jul 1997 | JP |
9192273 | Jul 1997 | JP |
9239074 | Sep 1997 | JP |
9239075 | Sep 1997 | JP |
9248353 | Sep 1997 | JP |
09253243 | Sep 1997 | JP |
9294833 | Nov 1997 | JP |
9299519 | Nov 1997 | JP |
09322952 | Dec 1997 | JP |
10024126 | Jan 1998 | JP |
10024128 | Jan 1998 | JP |
2717759 | Feb 1998 | JP |
10085369 | Apr 1998 | JP |
10118227 | May 1998 | JP |
10137372 | May 1998 | JP |
10155943 | Jun 1998 | JP |
10258142 | Sep 1998 | JP |
10263121 | Oct 1998 | JP |
10323410 | Dec 1998 | JP |
10337347 | Dec 1998 | JP |
2880109 | Apr 1999 | JP |
11169493 | Jun 1999 | JP |
11299938 | Nov 1999 | JP |
2000296190 | Oct 2000 | JP |
2001161868 | Jun 2001 | JP |
2002-191727 | Jul 2002 | JP |
2003-210623 | Jul 2003 | JP |
2003339921 | Dec 2003 | JP |
2004-135963 | May 2004 | JP |
2004-187795 | Jul 2004 | JP |
2004-222905 | Aug 2004 | JP |
2004329544 | Nov 2004 | JP |
2006043460 | Feb 2006 | JP |
2006087928 | Apr 2006 | JP |
2007007276 | Jan 2007 | JP |
Number | Date | Country | |
---|---|---|---|
20110034272 A1 | Feb 2011 | US |
Number | Date | Country | |
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Parent | 10943978 | Sep 2004 | US |
Child | 12887173 | US | |
Parent | 09551893 | Apr 2000 | US |
Child | 10943978 | US |