Grain refinement of titanium alloys

Information

  • Patent Application
  • 20080035250
  • Publication Number
    20080035250
  • Date Filed
    August 09, 2006
    17 years ago
  • Date Published
    February 14, 2008
    16 years ago
Abstract
A process for casting titanium alloy based parts includes the steps of melting a quantity of titanium alloy to form a molten titanium alloy; adding to the molten titanium alloy a quantity of boron in an amount of about 0.2 weight percent to about 1.3 weight percent of the molten titanium alloy to form a molten boron modified titanium alloy; and casting a boron modified titanium alloy based part.
Description

BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a flowchart representing an exemplary process for casting a boron modified titanium alloy based part; and



FIG.2 is a flowchart representing an exemplary process for making boron modified wrought titanium alloy based part.





Like reference numbers and designations in the various drawings indicate like elements.


DETAILED DESCRIPTION

The exemplary processes of the present invention refine the as-cast or forged grain structure of a titanium alloy through minor additions of boron in the melting stage. With a reduced grain size in the ingot form, the subsequent thermo-mechanical processing (“TMP”), such as converting to billet and then to forging, can be performed in either the beta or alpha plus beta phase fields to produce a final microstructure of fully refined transformed beta grains or a duplex microstructure with fully refined transformed beta grains with fine primary alpha grains. These microstructure refinements improve the fatigue and strength capabilities of the titanium alloy. Furthermore, since the as-cast grain structure may be refined, boron modified titanium alloy based parts may be produced via a casting process.


Referring now to FIG. 1, a flowchart representing an exemplary process for casting a boron modified titanium alloy based part is shown. A solid titanium alloy may be melted to form molten titanium alloy using techniques known to one of ordinary skill in the art at a step 10. Titanium alloys commonly utilized in the aerospace industry include, but are not limited to, Ti-5.8Al-4Sn-3.5Zr-0.7Nb-0.5Mo-0.35Ti-0.06C commercially available as IMI834 from IMI Titanium Ltd., London, United Kingdom; Ti-6Al-4V; Ti-6Al-2Sn-4Zr-2Mo; Ti-6Al-2Sn-4Zr-6Mo, and the like.


A quantity of boron sufficient to impart the desired grain refinement may be added to any suitable molten titanium alloy at a step 12. The amount of boron added is preferably tailored to the boron solubility of the molten titanium alloy. Each titanium alloy possesses a boron solubility value, which influences the quantity of boron that may be added. Generally, the solubility of boron in titanium may be less than about 0.05 weight percent of titanium. The quantity of boron typically added is about 0.2 weight percent to about 1.3 weight percent of the molten titanium alloy. Suitable boron sources may include, but are not limited to, AlB12, TiB2, TiB, combinations comprising at least one of the foregoing, and the like. The molten boron-modified titanium alloy may then be cast at a step 14 to form the desired part, component, etc. The resultant boron-modified titanium alloy may comprise the aforementioned titanium alloys and about 0.2 weight percent to about 1.3 weight percent of boron in the form of at least one boride or dissolved boron, or both borides and dissolved boron.


The minor addition of boron in the melting stage refines the as-cast or forged grain structure of the titanium alloy. With a reduced grain size in the ingot form, the subsequent thermo-mechanical processing (“TMP”), such as converting to billet and then to forging, can be performed in either the beta or alpha plus beta phase fields to produce a final microstructure of fully refined transformed beta grains or a duplex microstructure with fully refined transformed beta grains with fine primary alpha grains. These microstructure refinements improve the fatigue and strength capabilities of the titanium alloy. Furthermore, since the as-cast grain structure may be refined, boron modified titanium alloy based parts may be produced via a casting process.


Referring now to FIG. 2, an exemplary process for forging a boron modified titanium based part is shown. Any suitable titanium alloy composition may be melted to form a molten titanium alloy using techniques known to one of ordinary skill in the art at a step 20. As described, a quantity of boron sufficient to impart the desired grain refinement, and preferably tailored to the boron solubility of the molten titanium alloy, may be added to the molten titanium alloy at a step 22. The boron modified titanium alloy may then be cast into an ingot at a step 24 using any one of a number of techniques known to one of ordinary skill in the art. In order to form a wrought part, the cast ingot may undergo a primary processing technique to form a billet at a step 26 as known to one of ordinary skill in the art. The billet composed of the boron modified titanium alloy may then undergo a secondary processing technique at a step 28 to further refine the grain microstructure of the titanium alloy as known to one of ordinary skill in the art. Lastly, the processed billet may be forged to form a wrought part, or “mill product”, at a step 30 using any one of a number of techniques known to one of ordinary skill in the art.


One or more embodiments of the present invention have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the invention. Accordingly, other embodiments are within the scope of the following claims.

Claims
  • 1. A process for casting boron modified titanium alloy based parts, comprising: melting a quantity of titanium alloy to form a molten titanium alloy;adding to said molten titanium alloy a quantity of boron in an amount of about 0.2 weight percent to about 1.3 weight percent of said molten titanium alloy to form a molten boron modified titanium alloy; andcasting a boron modified titanium alloy based part.
  • 2. The process of claim 1, wherein adding further comprises forming said molten boron modified titanium alloy containing at least one boride particle in a solute form.
  • 3. The process of claim 1, wherein adding comprises adding at least one of: AlB12, TiB2 and TiB.
  • 4. The process of claim 1, wherein melting comprises melting at least one of: Ti-5.8Al-4Sn-3.5Zr-0.7Nb-0.5Mo-0.35Ti-0.06C;Ti-6Al-4V;Ti-6Al-2Sn-4Zr-2Mo; andTi-6Al-2Sn-4Zr-6Mo.
  • 5. A process for making wrought titanium alloy based parts, comprising: melting a quantity of titanium alloy to form a molten titanium alloy;adding to said molten titanium alloy a quantity of boron in an amount of about 0.2 weight percent to about 1.3 weight percent of said molten titanium alloy to form a molten boron modified titanium alloy;casting a boron modified titanium alloy based ingot using said molten boron modified titanium alloy;processing said boron modified titanium alloy based ingot to form a boron modified titanium alloy based billet;processing said boron modified titanium alloy based billet to form a wrought titanium alloy based part.
  • 6. The process of claim 5, wherein melting comprises melting Ti-6Al-2Sn-4Zr-6Mo.
  • 7. The process of claim 5, wherein adding further comprises forming said molten boron modified titanium alloy containing at least one boride particle in a solute form.
  • 8. The process of claim 5, wherein adding comprises adding at least one of: AlB12, TiB2 and TiB.
  • 9. The process of claim 5, wherein melting comprises melting at least one of: Ti-5.8Al-4Sn-3.5Zr-0.7Nb-0.5Mo-0.35Ti-0.06C;Ti-6Al-4V;Ti-6Al-2Sn-4Zr-2Mo; andTi-6Al-2Sn-4Zr-6Mo.
  • 10. A titanium alloy comprising about 0.2 weight percent to about 1.3 weight percent boron.
  • 11. The titanium alloy of claim 10, wherein the boron comprises at least one boride or a dissolved boron or both said at least one boride and said dissolved boron.
  • 12. The titanium alloy of claim 11, wherein said at least one boride comprises at least one of the following: AlB12, TiB2 and TiB.
  • 13. The titanium alloy of claim 10, wherein the titanium alloy comprises at least one of: Ti-5.8Al-4Sn-3.5Zr-0.7Nb-0.5Mo-0.35Ti-0.06C;Ti-6Al-4V;Ti-6Al-2Sn-4Zr-2Mo; andTi-6Al-2Sn-4Zr-6Mo.