Patent Application
20190023594
The present invention relates to technology for a granule-foiling method and a wastewater treatment method.
Conventionally, biological wastewater treatments of organic matter-containing wastewater, which contains organic matter or the like, have used the activated sludge method that utilizes an aggregate of microbes known as a floc (aerobic biological sludge). However, in the activated sludge method, when separating the floc (aerobic biological sludge) and the treated water in a settling pond, because the settling rate of the floc is slow the surface area of the settling pond must sometimes be made extremely large. Further, the treatment rate of the activated sludge method depends on the sludge concentration inside the biological treatment tank, and while the treatment rate can be increased by increasing the sludge concentration, if the sludge concentration is increased to a range from 1,500 to 5,000 mg/L or even higher, then solid-liquid separation becomes difficult due to bulking or the like within the settling pond, and the treatment cannot be maintained in some cases.
On the other hand, anaerobic biological treatments generally utilize aggregates in a particulate form known as granules (anaerobic biological sludge), which contain densely aggregated microbes. Granules have an extremely fast settling rate, and because the microbes are densely aggregated, the sludge concentration inside the biological treatment tank can be increased, and a high-speed treatment of the wastewater can be achieved. However, anaerobic biological treatments can suffer problems, including restrictions on the types of wastewater that can be treated compared with aerobic treatments (activated sludge method), and a requirement to hold the temperature of the treated water at approximately 30 to 35° C. Further, if only an anaerobic biological treatment is used, then the water quality of the treated water is poor, and when the treated water is to be discharged into a river or the like, a separate aerobic treatment such as the activated sludge method may sometimes be required.
In recent years, it has become clear that by using a semi-batch reaction tank that repeatedly carries out an operation cycle that includes (1) a wastewater introduction step, (2) a biological treatment step of the treatment target substances, (3) a biological sludge settling step, and (4) a treated water discharge step, granules having good settling properties can be formed not only with anaerobic biological sludges, but also with aerobic biological sludges (for example, see Patent Documents 1 to 4). By forming granules having good settling properties as described above, the sludge concentration inside the tank can be maintained at a high concentration, thereby enabling a high-speed treatment.
Patent Document 1: WO 2004/024638
Patent Document 2: JP 2008-212878 A
Patent Document 3: JP 4975541 B
Patent Document 4: JP 4804888 B
In granule-forming methods using a semi-batch reaction tank, the creation of a satiated state (a state where the organic matter concentration inside the tank is high)/starved state (a state where the organic matter concentration inside the tank is low) in each operation cycle by forming an organic matter concentration gradient inside the tank is considered to be an important factor. However, for example, if the organic matter concentration in the wastewater is low (for example, a BOD of approximately 50 to 200 mg/L), such as in sewage and the like, because the organic matter is treated in a short period of time in the biological treatment step, it becomes difficult to form an adequate satiated state inside the tank. As a result, the formation of granules having good settling properties may sometimes become difficult.
Accordingly, an object of the present invention is to provide a granule-forming method using a semi-batch reaction tank, wherein the granule-forming method is capable of forming granules having good settling properties.
(1) The present invention provides a granule-forming method using a semi-batch reaction tank, the method including forming granules by repeatedly performing an operation cycle having an introduction step of introducing an organic matter-containing wastewater, a biological treatment step of biologically treating treatment target substances in the organic matter-containing wastewater by using a microbiological sludge, a settling step of allowing the microbial sludge to settle, and a discharge step of discharging a biologically treated water that has been biologically treated, wherein the operation cycle includes a first operation cycle for performing the biological treatment step at a first sludge load, and a second operation cycle, performed after the first operation cycle, for performing the biological treatment step at a second sludge load, and the first sludge load is set such that a soluble BOD concentration inside the semi-batch reaction tank upon completion of the biological treatment step of the first operation cycle does not fall to a threshold value or below, and the second sludge load is set such that a soluble BOD concentration inside the semi-batch reaction tank upon completion of the biological treatment step of the second operation cycle does not exceed a threshold value.
(2) In the granule-forming method according to (1) above, a first sludge load/second sludge load ratio is preferably two times or more.
(3) In the granule-forming method according to (1) or (2) above, it is preferable that the second sludge load is set such that an ammoniacal nitrogen concentration inside the semi-batch reaction tank upon completion of the biological treatment step of the second operation cycle becomes 1 mgN/L or less.
(4) In the granule-forming method according to any one of (1) to (3) above, it is preferable that a biologically treated water outlet of the semi-batch reaction tank is provided above a wastewater inlet, and the biologically treated water is discharged from the treated water outlet by introducing the organic matter-containing wastewater into the semi-batch reaction tank from the wastewater inlet.
(5) The present invention also provides a wastewater treatment method using a continuous biological treatment tank that performs biological treatment of an organic matter-containing wastewater with a biological sludge while the wastewater is introduced continuously, the method comprising supplying granules formed by the granule-forming method according to any one of (1) to (4) above to the continuous biological treatment tank.
The present invention enables granules having good settling properties to be formed by a granule-forming method using a semi-batch reaction tank.
Embodiments of the present invention are described below. These embodiments are merely examples of implementing the present invention, and the present invention is in no way limited by these embodiments.
An outline of an example of a granule-forming device according to an embodiment of the present invention is shown in
The granule-forming device 1 is operated, for example, using the following operation cycle.
The wastewater inlet pump 12 is activated, and a predetermined amount of an organic matter-containing wastewater is introduced into the semi-batch reaction tank 10 through the wastewater supply line 22.
The wastewater inlet pump 12 is stopped, an oxygen-containing gas such as air is supplied to the semi-batch reaction tank 10 from the aeration pump 14, and the treatment target substances in the organic matter-containing wastewater inside the semi-batch reactor 10 are biologically treated with a microbial sludge. The biological reactions are not limited to aerobic reactions, and anoxic reactions can also be performed by stirring the wastewater without supplying air or the like, or a combination of aerobic reactions and anoxic reactions may be used. An anoxic state refers to a state in which, although no dissolved oxygen exists, oxygen derived from nitrites or nitrates and the like is present. For example, as shown in
After the biological treatment step has been performed for a predetermined period of time, the aeration pump 14 is stopped, for example by the control device 20 (the stirring device is also stopped in the granule-forming device of
After the aeration pump 14 is stopped, the device is left to stand for a predetermined period of time to allow the sludge inside the semi-batch reactor 10 to settle.
By opening the biologically treated water discharge valve 18, the supernatant water obtained in the settling step is discharged from the biologically treated water outlet 16 through the biologically treated water line 24 as a biologically treated water. In this case, the biologically treated water may also be discharged using a pump instead of the biologically treated water discharge valve 18.
By repeating the operation cycle composed of (1) to (4) above, granules composed of granular aggregates of densely aggregated microbes are formed. The activation and stopping of the wastewater inlet pump 12, the aeration pump 14 and the stirring device motor 28, and the opening and closing of the biologically treated water discharge valve 18 may be controlled by the control device 20, or performed by an operator or the like.
The biological treatment step of the present invention includes a case where the biological treatment step is performed at a first sludge load, and a case where the biological treatment step is performed at a second sludge load. That is, the present embodiment includes a first operation cycle having an introduction step, a biological treatment step for performing the biological treatment at the first sludge load, a settling step, and a discharge step, and a second operation cycle, performed following the first operation cycle, having an introduction step, a biological treatment step for performing the biological treatment at the second sludge load, a settling step, and a discharge step.
The first sludge load represents a sludge load that ensures that the soluble BOD concentration inside the semi-batch reaction tank 10 upon completion of the biological treatment step does not fall to a threshold value or below, or a sludge load that ensures that the ammoniacal nitrogen concentration inside the semi-batch reaction tank 10 upon completion of the biological treatment step does not fall to a threshold value or below. Further, the second sludge load represents a sludge load that ensures that the soluble BOD concentration inside the semi-batch reaction tank 10 upon completion of the biological treatment step does not exceed a threshold value, or a sludge load that ensures that the ammoniacal nitrogen concentration inside the semi-batch reaction tank upon completion of the biological treatment step does not exceed a threshold value.
The threshold is set to an organic matter concentration (soluble BOD concentration), which represents feed for microorganisms, at which the activity of the microorganisms decreases as a result of a reduction in the organic matter concentration (soluble BOD concentration) and the system entering a starved state. That is, in the region above the threshold, the system enters a satiated state having a high soluble BOD concentration, whereas in the region below the threshold, the system enters a starved state having a low soluble BOD concentration. The threshold for the first sludge load and the threshold for the second sludge load may be the same value, but in terms of adequately maintaining both the satiated state and the starved state, the thresholds may be set individually (first sludge load threshold>second sludge load threshold).
In the granule-forming method according to the present embodiment, the second operation cycle may be performed after repeating the first operation cycle multiple times. Further, the second operation cycle may be repeated multiple times after the first operation cycle. In addition, the second operation cycle may be repeated multiple times after the first operation cycle has been repeated multiple times. Moreover, an operation cycle having a sludge load lower than that of the first operation cycle but higher than that of the second cycle may be inserted between the first operation cycle and the second operation cycle.
In
The first sludge load/second sludge load ratio is preferably set to two times or more, and more preferably set to three times or more. In this manner, by making the difference between the first sludge load and the second sludge load large, the satiated state can be maintained for a longer period of time, or the starved state can be maintained for a longer period of time.
The first sludge load in the first operation cycle is preferably a sludge load that ensures that the soluble BOD concentration inside the semi-batch reaction tank 10 upon completion of the biological treatment step does not fall to 5 mg/L or lower, more preferably does not fall to 10 mg/L or lower, and even more preferably does not fall to 25 mg/L or lower. Alternatively, the first sludge load in the first operation cycle is preferably a sludge load that ensures that the ammoniacal nitrogen concentration inside the semi-batch reaction tank 10 upon completion of the biological treatment step does not fall to 5 mgN/L or lower, more preferably does not fall to 10 mgN/L or lower, and even more preferably does not fall to 25 mgN/L or lower. As a result, the satiated state can be maintained for a longer period of time.
Although the first sludge load in the first operation cycle depends on the types of organic matter in the wastewater and the like, for example, a range of 0.4 to 2.0 kgBOD/kgMLSS/day is preferable, and a range of 0.6 to 1.5 kgBOD/kgMLSS/day is more preferable. Outside of the above ranges, it may sometimes become difficult to maintain the satiated state for a sufficient period of time.
The second sludge load in the second operation cycle is preferably a sludge load that ensures that the soluble BOD concentration inside the semi-batch reaction tank 10 upon completion of the biological treatment step does not exceed 5 mg/L, more preferably does not exceed 1 mg/L, and even more preferably does not exceed 0.5 mg/L. Alternatively, the second sludge load in the second operation cycle is preferably a sludge load that ensures that the ammoniacal nitrogen concentration inside the semi-batch reaction tank 10 upon completion of the biological treatment step does not exceed 5 mgN/L, more preferably does not exceed 1 mgN/L, and even more preferably does not exceed 0.5 mgN/L. As a result, the starved state can be maintained for a longer period of time.
Although the second sludge load in the second operation cycle depends on the types of organic matter in the wastewater and the like, for example, a range of 0.02 to 0.3 kgBOD/kgMLSS/day is preferable, and a range of 0.05 to 0.2 kgBOD/kgMLSS/day is more preferable. Outside of the above ranges, it may sometimes become difficult to maintain the starved state for a sufficient period of time.
The first sludge load and the second sludge load are set, for example, by adjusting the biological treatment step time. For example, if the length of time taken for the soluble BOD concentration inside the tank to fall to the threshold is measured during preliminary testing and device initialization and the like, and the biological treatment step time is then set to be shorter than the measured length of time, the sludge load at that time becomes the first sludge load, whereas if the biological treatment step time is set to be longer than the measured length of time, the sludge load at that time becomes the second sludge load. The soluble BOD concentration inside the semi-batch reaction tank 10 is determined by measuring a filtrate obtained upon filtration according to the method prescribed in JIS K0102 and the like. The sludge load (kgBOD/kgMLSS/day) is calculated from the amount of BOD supplied to the semi-batch reaction tank 10 per day (kgBOD/day) and the amount of MLSS inside the semi-batch reaction tank 10 (kgMLSS).
The dissolved oxygen (DO) inside the semi-batch reaction tank 10, under aerobic conditions, is at least 0.5 mg/L, and a concentration of at least 1 mg/L is particularly preferable.
In terms of promoting the granulation of the biological sludge, ions that form hydroxides, such as Fe2+, Fe3+, Ca2+, and Mg2+ are preferably added to the organic matter-containing wastewater inside the semi-batch reaction tank 10, or to the organic matter-containing wastewater prior to introduction into the semi-batch reaction tank 10. Most typical organic matter-containing wastewaters include microparticles that can act as nuclei for granules, but the addition of the ions above can further promote the nucleation of granules.
The organic matter-containing wastewater that represents the treatment target of the granule-forming method according to the present embodiment is an organic wastewater containing biodegradable organic matter, such as a food processing plant wastewater, a chemical plant wastewater, a semiconductor plant wastewater, a machinery plant wastewater, sewage, or human waste. Further, when the wastewater contains organic matter that is resistant to biodegradation, the organic matter can be converted to biodegradable substances and thus a treatable target by performing a physicochemical treatment such as an ozone treatment or a Fenton treatment in advance. In addition, although the granule-forming method according to the present invention may be used against a variety of BOD components, oils and fats may have an adverse effect by adhering to the sludge and the granules, and therefore it is preferable that prior to introduction into the semi-batch reaction tank 10, a known technique such as flotation separation, flocculation pressure flotation, or adsorption is performed in advance to remove the oils and fats, for example, down to a level of approximately 150 mg/L or less.
The BOD concentration in the organic matter-containing wastewater representing the treatment target is not particularly limited, but the granule-forming method according to the present invention enables the formation of granules having good settling properties even at a low concentration of 50 to 200 mg/L, which is considered to be a concentration at which formation of granules is difficult.
The granule-forming method according to the present embodiment enables the formation, for example, of granules having a SVI30 of 50 mL/g or less, and a SVI5 of 70 mL/g or less, wherein these values are indicators of the settling properties.
Another example of a granule-forming device according to the present embodiment is shown in
In the granule-forming device 1 of
(1) The introduction step/discharge step is a process in which the discharge step is carried out while performing the introduction step, and more specifically, by opening the wastewater inlet valve 32 and activating the wastewater inlet pump 12 to introduce organic matter-containing wastewater from the wastewater inlet 34, through the wastewater supply line 22, and then out from the wastewater discharge unit 36 and into the semi-batch reaction tank 10, the biologically treated water is discharged from the biologically treated water outlet 16 through the biologically treated water line 24. (2) The biological treatment step and (3) the settling step are performed as described above. The activation and stopping of the wastewater inlet pump 12 and the aeration pump 14, and the opening and closing of the wastewater inlet valve 32 and the biologically treated water discharge valve 18 may be controlled by the control device 20, or performed by an operator or the like.
In the granule-forming device 1 of
The wastewater treatment device 2 shown in
One end of the wastewater inlet line 58a is connected to a wastewater outlet of the wastewater storage tank 50, and the other end is connected to a wastewater inlet of the continuous biological treatment tank 54. Further, one end of the wastewater inlet line 58b is connected to a wastewater outlet of the continuous biological treatment tank 54, and the other end is connected to a wastewater inlet of the solid-liquid separation tank 56. The treated water discharge line 60 is connected to a treated water outlet of the solid-liquid separation tank 56. One end of the sludge return line 62 is connected to a sludge outlet of the solid-liquid separation tank 56, and the other end is connected to a sludge inlet of the continuous biological treatment tank 54. The sludge discharge line 64 is connected to the sludge return line 62. One end of the granule supply line 66 is connected to a sludge outlet of the granule-forming device 52, and the other end is connected to a sludge supply port of the continuous biological treatment tank 54.
The continuous biological treatment tank 54 shown in
The solid-liquid separation tank 56 shown in
The granule-forming device 52 shown in
An example of the operation of the wastewater treatment device 2 shown in
The organic matter-containing wastewater that represents the treatment target is a wastewater containing biodegradable organic matter, such as a food processing plant wastewater, a chemical plant wastewater, a semiconductor plant wastewater, a machinery plant wastewater, sewage, or human waste. When the wastewater contains organic matter that is resistant to biodegradation, it is desirable to convert the organic matter to biodegradable substances by performing a physicochemical treatment beforehand.
The organic matter-containing wastewater is preferably delivered to the wastewater storage tank 50 for water quality stabilization of the wastewater prior to being supplied to the continuous biological treatment tank 54. The wastewater storage tank 50 may be omitted when the water quality of the wastewater is comparatively stable, or when the wastewater introduction rate is high. Further, when the wastewater contains solid matter, it is preferable for the solid matter to be removed beforehand by using a screen or a settling pond or the like before the wastewater is supplied to the wastewater storage tank 50.
The treatment target wastewater inside the wastewater storage tank 50 is supplied to the continuous biological treatment tank 54 from the wastewater inlet line 58a by activating the wastewater inlet pump 68. The treatment target wastewater inside the wastewater storage tank 50 may be supplied to the granule-forming device 52. The operation cycle described above is repeatedly performed in the granule-forming device 52, resulting in the formation of granules. The granules formed inside the granule-forming device 52 are supplied to the continuous biological treatment tank 54 from the granule supply line 66 by activating the granule supply pump 72.
The supply of the granules from the granule-forming device 52 may be performed (2) during the biological treatment step, (3) during the settling step, or (4) during the discharge step (or the introduction step/discharge step). It is desirable that the granules supplied from the granule-forming device 52 to the continuous biological treatment tank 54 contain granules having a SVI30 of 50 mL/g or less and a SVI5 of 70 mL/g or less, wherein these values are indicators of the settling properties. For example, by periodically measuring the SVI values of the sludge inside the granule-forming device 52 by performing a settling properties test, supply of the granules to the continuous biological treatment tank 54 may be started at a stage where the SVI5, which is calculated from a volume fraction after allowing settling for 5 minutes falls to a predetermined value or less (for example, 70 mL/g or less).
In the continuous biological treatment tank 54, for example, biological treatment of the organic matter-containing wastewater is performed under aerobic conditions using a biological sludge containing the granules described above. After treatment in the continuous biological treatment tank 54, the treated water is supplied to the solid-liquid separation tank 56 from the wastewater inlet line 58b, and the biological sludge is separated from the treated water. The sludge obtained from the solid-liquid separation is returned to the continuous biological treatment tank 54 from the sludge return line 62 by activating the sludge return pump 74. Further, the sludge obtained from the solid-liquid separation may be discharged outside the system from the sludge discharge line 64 by opening the valve 76. In addition, the treated water inside the solid-liquid separation tank 56 is discharged outside the system from the treated water discharge line 60.
According to the wastewater treatment device 2 of the present embodiment, because granules having good settling properties are supplied to the continuous biological treatment tank 54 by the granule-forming device 52, an efficient biological treatment of the organic-matter containing wastewater can be performed in the continuous biological treatment tank 54.
The following testing was performed using the semi-batch reaction tank shown in
A water flow test was performed using sewage. The BOD concentration of the sewage was 80 to 140 mg/L. The BOD concentration of the wastewater was measured according to JIS K 0102 21.
The operation cycle of the semi-batch reaction tank was performed as follows. An activated sludge collected from a sewage treatment plant was placed in the semi-batch reaction tank as a seed sludge before operation.
(1) Introduction/discharge step: the wastewater was introduced to the semi-batch reaction tank over a predetermined period of time, and the biologically treated water was also discharged from the biologically treated water outlet.
(2) Biological treatment step: at the same time introduction of the wastewater and discharging of the biologically treated water were stopped, air was supplied by the aeration device installed in the lower portion of the reaction tank, and biological treatment of the wastewater was performed for a predetermined period of time. After this period of time had elapsed, the operation shifted to the settling step below.
(3) Settling step: the supply of air from the aeration device was stopped, and the system was left to stand for a predetermined period of time, allowing the sludge inside the reaction tank to settle.
The above operations (1) to (3) were performed repeatedly.
From day 0 to day 15 of operation, an operation cycle consisting of an introduction/discharge step time of 90 minutes, a biological treatment step time of 200 minutes, and a settling step time of 8 minutes was repeated. The sludge load during the biological treatment step was 0.24 kgBOD/kgMLSS/day. Further, during day 0 to day 15 of operation, upon performing biological treatment using the above sludge load, the soluble BOD concentration inside the tank upon completion of the biological treatment step was 1 mg/L or less, and the ammoniacal nitrogen concentration was 0.5 mg/L or less.
From day 16 to day 50 of operation, an operation cycle consisting of an introduction/discharge step time of 90 minutes, a biological treatment step time of 150 minutes, and a settling step time of 8 minutes was repeated. The sludge load during the biological treatment step was 0.3 kgBOD/kgMLSS/day. Further, during day 16 to day 50 of operation, upon performing biological treatment using the above sludge load, the soluble BOD concentration inside the tank upon completion of the biological treatment step was 1 mg/L or less, and the ammoniacal nitrogen concentration was 0.5 mg/L or less.
From day 51 to day 78 of operation, a first operation cycle consisting of an introduction/discharge step time of 90 minutes, a biological treatment step time of 40 minutes and a settling step time of 8 minutes, and a second operation cycle consisting of an introduction/discharge step time of 90 minutes, a biological treatment step time of 240 minutes and a settling step time of 8 minutes were repeated alternately. The sludge load during the biological treatment step in the first operation cycle was 1.3 kgBOD/kgMLSS/day, while the soluble BOD concentration inside the tank upon completion of the biological treatment step was 10 mg/L or higher, and the ammoniacal nitrogen concentration was 10 mg/L or higher. The sludge load during the biological treatment step in the second operation cycle was 0.2 kgBOD/kgMLSS/day, while the soluble BOD concentration inside the tank upon completion of the biological treatment step was 1 mg/L or less, and the ammoniacal nitrogen concentration was 0.5 mg/L or less.
An SVI measurement of the biological sludge inside the tank was performed in the Example and in Comparative Examples 1 and 2. The SVI is an indicator of the settling properties of a biological sludge, and is determined according to the following method. Firstly, 1 L of the sludge is placed in a 1 L graduated cylinder, and after gently stirring the sludge such that the sludge concentration becomes as uniform as possible, the sludge interface is measured after being left to stand for 5 minutes, and then after 30 minutes. The volume fraction (%) occupied by the sludge in the graduated cylinder is then calculated. Next, the MLSS (mg/L) of the sludge is measured. These values are substituted into the following equation to calculate a SVI5 and a SVI30.
SVI (mL/g)=volume fraction occupied by sludge×10,000/MLSS
On day 0 of operation, the SVI5 was 141 mL/g and the SVI30 was 76 mL/g, but a decrease in the SVI values was confirmed with the passage of the number of days of operation, and the SVI5 was 114 mL/g and the SVI30 was 67 mL/g on day 8 of water flow. Thereafter, the SVI5 became stagnant at approximately 110 mL/g.
From day 16 of operation onwards, as a result of performing the operation with a higher sludge load during the biological treatment step, the SVI5 remained stagnant at approximately 110 to 115 mL/g until day 30 of operation, but on day 33 of water flow, the SVI5 decreased to 90 mL/g. Thereafter, the SVI became stagnant such that on day 50 the SVI5 was 98 mL/g, and the SVI30 was 60 mL/g.
From day 51 of operation onwards, as a result of performing the operation by alternatingly repeating the operation cycle in which the biological treatment was performed at a sludge load of 1.3 kgBOD/kgMLSS/day, and the operation cycle in which the biological treatment was performed at a sludge load of 0.2 kgBOD/kgMLSS/day, the SVI values decreased with the passage of the number of days of operation such that the SVI5 was 47 mL/g and the SVI30 was 37 mL/g on day 72. Thereafter, the SVI5 stabilized at approximately 50 mL/g, and the SVI30 stabilized at approximately 38 mL/g.
Although a decrease in the SVI was observed in both the Example and the Comparative Examples, the Example resulted in a lower value. In other words, it can be stated that granules having better settling properties were formed in the Example.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2016-003894 | Jan 2016 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2016/089167 | 12/28/2016 | WO | 00 |
