The present application is a national phase entry under 35 U.S.C. § 371 of International Application No. PCT/KR2017/002946 filed Mar. 17, 2017, which claims priority from Korean Patent Application No. 10-2016-0034679, filed on Mar. 23, 2016, all of which are incorporated herein by reference.
The present invention relates to a grinder using induced electric fields, and more particularly, to a grinder using induced electric fields, which is improved in grinding efficiency of CNT and CNF that are highly dispersive conductive materials to improve dispersibility.
In general, conductive materials serve as moving paths of electrons in lithium secondary batteries. In recent years, carbon nano fibers (CNFs) or carbon nano tubes (CNTs), which have high conductivity and provide direct paths between active materials to realize similar resistance even when a small amount of CNFs or CNTs is used, are getting attention instead of existing carbon black.
In case of the CNFs or the CNTs, it is conveyed in a compression manner because of poor processability and transportability due to a high specific surface area and structural characteristics. Also, a grinding process to facilitate dispersion when applied to secondary batteries has to be performed.
Here, in the related art, a plurality of grinding operations are required to obtain a desired size and a desired dispersed state through the grinding process. To solve this problem, it is necessary to reduce a production time and to ensure uniformity of production quality through improvement of the process.
However, in the grinder according to the related art, grinding characteristics in a predetermined size or less may be deteriorated due to the structural characteristic in which the grinding of the CNFs or the CNTs has directionality. As a result, there is a problem that the grinding extends in process time.
An object of the present invention is to provide a grinder using induced electric fields so as to solve the above problems, and more particularly, to improve grinding efficiency of CNT and CNF that are highly dispersive conductive materials to improve dispersibility.
A grinder using induced electric fields, which disperses and grinds conductive materials, according to the present invention comprises: a grinding unit on which a plurality of protrusions for cutting are disposed on an outer circumferential surface thereof; a power unit disposed in the grinding unit to generate electric fields and attach the conductive materials to the grinding unit; and a chamber disposed outside the grinding unit and comprising beads that disperse and grind the conductive materials attached to the grinding unit, wherein the conductive materials have directionality by the electric fields of the power unit.
The grinding unit may have a cylindrical spike mill structure and is rotatable.
The conductive materials may comprise carbon nano fibers (CNFs) or carbon nano tubes (CNTs).
The beads provided in the chamber may comprise zirconia beads.
The chamber may have a function of grounding the grinding unit.
The conductive materials may be aligned in a direction perpendicular to the grinding unit by the electric fields of the power unit and ground through the protrusions when the grinding unit rotates.
A distance between each of the protrusions of the grinding unit and each of the beads of the chamber may be set to adjust a ground length of each of the conductive materials.
As described above, according to the present invention, the CNFs and the CNTs may be fixed in the direction perpendicular to the grinder through the electric fields to improve the grinding efficiency and thus to reduce the number of grinding processes, thereby reducing the process costs and time.
Hereinafter, an exemplary embodiment of the present invention will be described in detail with reference to the accompanying drawings.
As illustrated in
As illustrated in
Here, the grinding unit 100 has a cylindrical spike mill structure and performs the grinding while rotating.
As illustrated in
The chamber 120 is disposed outside the grinding unit 100. The beads 121 are disposed in the chamber 120. Thus, when the grinding unit 100 rotates, the conductive materials 130 that will be described below may be physically ground by kinetic energy between the beads 121 and the protrusions 101.
Also, the chamber 120 may have a grounding function so that the grinding unit 100 is grounded when the power is generated by the power unit 110.
As illustrated in
Here, the conductive materials 130 may comprise carbon nano fibers (CNFs) or carbon nano tubes (CNTs).
Also, the beads disposed on the chamber 120 may comprise zirconia beads, which are minerals having high refractive index, corrosion resistance, and melting point so that the beads 121 are not worn due to their high strength when the conductive materials 130 are ground.
As described above, the conductive materials 130 are aligned in a direction perpendicular to the grinding unit 100 when induced electric fields are generated by the electric fields of the power unit 110. Thus, when the grinding unit 100 rotates, the conductive materials 130 are ground through the protrusions 101 in the state in which the conductive materials 130 are vertically disposed between the protrusions 101 of the grinding unit 100 and the beads 121 of the chamber 120.
Here, a distance between each of the protrusions 101 of the grinding unit 100 and each of the beads 121 of the chamber 120 may be set to adjust a ground length of each of the conductive materials 130.
That is, the grinder according to the present invention comprises the grinding unit 100 on which the protrusions 101 for the cutting are disposed on the outer circumferential surface thereof, the power unit 110 disposed in the grinding unit 100 to generate the electric fields, the chamber 120 disposed outside the grinding unit 100 and comprising the beads 121 therein, and the conductive materials 130 disposed between the protrusions 101 of the grinding unit 100 and the beads 121 of the chamber 120 and having the directionality by the electric fields of the power unit 110. Therefore, the CNFs and the CNTs may be fixed in the direction perpendicular to the grinder through the induced electric fields to improve the grinding efficiency of the conductive materials 130 and thus to reduce the number of grinding processes, thereby reducing the process costs and time.
Accordingly, the scope of the present invention is defined by the appended claims rather than the foregoing description and the exemplary embodiments described therein. Various modifications made within the meaning of an equivalent of the claims of the invention and within the claims are to be regarded to be in the scope of the present invention.
Number | Date | Country | Kind |
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10-2016-0034679 | Mar 2016 | KR | national |
Filing Document | Filing Date | Country | Kind |
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PCT/KR2017/002946 | 3/17/2017 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2017/164591 | 9/28/2017 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
3937405 | Stephanoff | Feb 1976 | A |
4134557 | Lazzari | Jan 1979 | A |
4632316 | Watanabe et al. | Dec 1986 | A |
4856717 | Kamiwano | Aug 1989 | A |
8846248 | Ryu | Sep 2014 | B2 |
20020119200 | Haskell | Aug 2002 | A1 |
20140186522 | Woo et al. | Jul 2014 | A1 |
20140263768 | Noge | Sep 2014 | A1 |
20150375235 | Roitto | Dec 2015 | A1 |
20160315331 | Yoshiwara | Oct 2016 | A1 |
Number | Date | Country |
---|---|---|
2430216 | May 2001 | CN |
1718282 | Jan 2006 | CN |
102166540 | Aug 2011 | CN |
S58076151 | May 1983 | JP |
S62125839 | Jun 1987 | JP |
20120002043 | Jan 2012 | KR |
20120033766 | Apr 2012 | KR |
20140073936 | Jun 2014 | KR |
20140086811 | Jul 2014 | KR |
20150085923 | Jul 2015 | KR |
20150142735 | Dec 2015 | KR |
Entry |
---|
Extended European Search Report for Application No. EP17770561.3 dated Jan. 23, 2019, 7 pages. |
Search report from Internationa Application No. PCT/KR2017/002946, dated Jun. 16, 2017. |
Chinese Search Report for Application No. CN201780002543.9 dated Sep. 2, 2019. |
Gao J, He Y, Gong X. Effect of electric field induced alignment and dispersion of functionalized carbon nanotubes on properties of natural rubber. Results in Physics. Jun. 1, 2018;9:493-9. |
Amani, A.M. et al, Chapter 5 “Electric Field Induced Alignment of Carbon Nanotubes: Methodology and Outcomes,” Carbon Nanoubes—Recent Progress, Published Apr. 26, 2018, edited by Mohammed Muzibur Rahman; ISBN 978-1-78923-053-6, copyright 2018, pp. 71-88. |
Number | Date | Country | |
---|---|---|---|
20180264478 A1 | Sep 2018 | US |