The present invention relates generally to the field of composite materials and, more particularly, to gypsum composites used in fire resistant building materials.
Many methods and techniques for manufacturing fire rated doors have been developed over time. But most of these prior art designs do not lend themselves well to fully automated manufacturing processes. Moreover, the prior art fire rated doors are expensive and require the internal mineral core. The internal core can be exposed in routed details and may reduce the strength of the door as a result of the reduced thickness of the door panels. In addition, alignment of the panels during assembly can be troublesome and require additional finishing to square the door after assembly.
Cement-based composites have been used in building materials for many years. For example, U.S. Pat. Nos. 5,549,859, 5,618,341, 5,631,097, 5,641,584, 5,658,624, 5,702,787, 5,766,525, 5,798,151, 5,849,155 and 6,379,446, and U.S. Published Patent Applications 2008/0099122, 2010/0136269 and 2011/0120349 describe various compositions and processes for making extruded cement-based composite products, all of which are hereby incorporated by reference in their entirety. These patents and published patent applications, however, do not disclose fire resistant composite components having the necessary fire resistant capabilities to produce doors, door cores and building panels that can receive fire rated certifications.
The present invention provides fire resistant composite components having the necessary fire resistant capabilities to produce doors, door cores and building panels that can receive fire rated certifications. In most cases, the length and width of the fire rated door core will match the length and width specifications of the final door product. The dimensions of the fire rated door core will typically be in widths of three feet and four feet and having a length ranging from seven feet to ten feet. The thickness of the fire core can range from 1.50 inches to 2.00 inches. In some cases, an exterior banding may be added to the sides and ends of the fire rated door core. In other cases, an intumescent banding may be added between the exterior banding and fire rated door core.
More specifically, the present invention provides a composite product including gypsum in an amount of 70 to 90% by weight, fibers in an amount of 1.5 to 26% by weight substantially homogeneously distributed through the composite, and a rheology-modifying agent in an amount of 0.5 to 6% by weight. The composite is caused or allowed to cure to form a cured composite. The cured composite is a fire resistant component used in a fire-rated door core, a fire-rated door or a fire-rated building panel. The fire resistant component may include a building panel, a door panel, a door core, a door rail, a door stile, a door lock block, a door border, or a door insert.
In addition, the present invention provides a composite product including gypsum in an amount of 70 to 90% by weight, fibers in an amount of 1.5 to 5% by weight substantially homogeneously distributed through the composite, an aggregate in an amount of 1 to 4% by weight substantially homogeneously distributed through the composite, a starch in an amount of 2 to 7% by weight and a rheology-modifying agent in an amount of 0.5 to 4% by weight. The composite is caused or allowed to cure to form a cured composite. The fire resistant component may include a building panel, a door panel, a door core, a door rail, a door stile, a door lock block, a door border, or a door insert used in a fire-rated door core, a fire-rated door or a fire-rated building panel.
The present invention also provides a composite product including gypsum in an amount of 70 to 90% by weight, glass fibers in an amount of 2 to 10% by weight substantially homogeneously distributed through the composite, cellulose fibers in an amount of 2 to 8% by weight substantially homogeneously distributed through the composite, polyvinyl alcohol fibers in an amount of 1 to 4% by weight substantially homogeneously distributed through the composite, polypropylene fibers in an amount of 0.3 to 4% by weight substantially homogeneously distributed through the composite, and a rheology-modifying agent in an amount of 0.5 to 6% by weight. The composite is caused or allowed to cure to form a cured composite. The fire resistant component may include a building panel, a door panel, a door core, a door rail, a door stile, a door lock block, a door border, or a door insert used in a fire-rated door core, a fire-rated door or a fire-rated building panel.
Moreover, the present invention provides a core for a fire rated door that includes a fire resistant center panel and an extruded fire resistant border. The fire resistant center panel has a bottom, a top, a first side, a second side, a first end and a second end. The fire resistant center panel is made of a first fire resistant material that includes gypsum in an amount of 70 to 90% by weight, fibers in an amount of 1.5 to 5% by weight substantially homogeneously distributed through the composite, an aggregate in an amount of 1 to 4% by weight substantially homogeneously distributed through the composite, a starch in an amount of 2 to 7% by weight and a rheology-modifying agent in an amount of 0.5 to 4% by weight. The extruded fire resistant border is attached to the first side, the second side, the first end and the second end of the fire resistant center panel. The extruded fire resistant border is made of a second fire resistant material that includes gypsum in an amount of 70 to 90% by weight, glass fibers in an amount of 2 to 10% by weight substantially homogeneously distributed through the composite, cellulose fibers in an amount of 2 to 8% by weight substantially homogeneously distributed through the composite, polyvinyl alcohol fibers in an amount of 1 to 4% by weight substantially homogeneously distributed through the composite, polypropylene fibers in an amount of 0.3 to 4% by weight substantially homogeneously distributed through the composite, and a rheology-modifying agent in an amount of 0.5 to 6% by weight.
The present invention also provides a fire rated door that includes a core, a first decorative panel and a second decorative panel. The core includes: (a) a fire resistant center panel having a bottom, a top, a first side, a second side, a first end and a second end, wherein the fire resistant center panel is made of a first fire resistant material that includes gypsum in an amount of 70 to 90% by weight, fibers in an amount of 1.5 to 5% by weight substantially homogeneously distributed through the composite, an aggregate in an amount of 1 to 4% by weight substantially homogeneously distributed through the composite, a starch in an amount of 2 to 7% by weight and a rheology-modifying agent in an amount of 0.5 to 4% by weight, and (b) an extruded fire resistant border attached to the first side, the second side, the first end and the second end of the fire resistant center panel, wherein the extruded fire resistant border is made of a second fire resistant material that includes gypsum in an amount of 70 to 90% by weight, glass fibers in an amount of 2 to 10% by weight substantially homogeneously distributed through the composite, cellulose fibers in an amount of 2 to 8% by weight substantially homogeneously distributed through the composite, polyvinyl alcohol fibers in an amount of 1 to 4% by weight substantially homogeneously distributed through the composite, polypropylene fibers in an amount of 0.3 to 4% by weight substantially homogeneously distributed through the composite, and a rheology-modifying agent in an amount of 0.5 to 6% by weight. The first decorative panel is attached to the top of the fire resistant center panel and the extruded fire resistant border. The second decorative panel is attached to the bottom of the fire resistant center panel and the extruded fire resistant border.
The present invention is described in detail below with reference to the accompanying drawings.
The above and further advantages of the invention may be better understood by referring to the following description in conjunction with the accompanying drawings, in which:
While the making and using of various embodiments of the present invention are discussed in detail below, it should be appreciated that the present invention provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed herein are merely illustrative of specific ways to make and use the invention and do not delimit the scope of the invention. The discussion herein relates primarily to fire rated doors, but it will be understood that the concepts of the present invention are applicable to any type of door.
The composite product of the present invention provides fire resistant components having the necessary fire resistant capabilities to produce doors, door cores and building panels that can receive fire rated certifications. The composite includes gypsum in an amount of 70 to 90% by weight, fibers in an amount of 1.5 to 26% by weight substantially homogeneously distributed through the composite, and a rheology-modifying agent in an amount of 0.5 to 6% by weight. The gypsum can be 70%, 71%, 72%, 73%, 74%, 75%, 76%, 77%, 78%, 79%, 80%, 81%, 82%, 83%, 84%, 85%, 86%, 87%, 88%, 89% or 90% by weight or other incremental percentage between. The fibers can be 1.5%, 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5%, 5.5%, 6%, 6.5%, 7%, 7.5%, 8%, 8.5%, 9%, 9.5%, 10%, 10.5%, 11%, 11.5%, 12%, 12.5%, 13%, 13.5%, 14%, 14.5%, 15%, 15.5%, 16%, 16.5%, 17%, 17.5%, 18%, 18.5%, 19%, 19.5%, 20%, 20.5%, 21%, 21.5%, 22%, 22.5%, 23%, 23.5%, 24%, 24.5%, 25%, 25.5% or 26% by weight or other incremental percentage between. The fibers can be glass fibers, cellulose fibers polyvinyl alcohol fibers, polypropylene fibers, or a combination thereof. Other types of fibers can be used. The rheology-modifying agent can be 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%, 1.8%, 1.9%, 2%, 2.1%, 2.2%, 2.3%, 2.4%, 2.5%, 2.6%, 2.7%, 2.8%, 2.9%, 3%, 3.1%, 3.2%, 3.3%, 3.4%, 3.5%, 3.6%, 3.7%, 3.8%, 3.9%, 4%, 4.1%, 4.2%, 4.3%, 4.4%, 4.5%, 4.6%, 4.7%, 4.8%, 4.9%, 5%, 5.1%, 5.2%, 5.3%, 5.4%, 5.5%, 5.6%, 5.7%, 5.8%, 5.9% or 6% by weight or other incremental percentage between. The rheology-modifying agent can be hydroxypropoyl methyl celluose (HPMC), methyl hydroxyethyl cellulose (MHEC), hydroxyethyl cellulose (HEC) or carboxymethyl cellulose (CMC). Other types of rheology-modifying agent can be used.
The composite is caused or allowed to cure to form a cured composite. The actual component weights used will depend on the density desired for the fire resistant component. The cured composite is a fire resistant component used in a fire-rated door core, a fire-rated door or a fire-rated building panel. The fire resistant component may include a building panel, a door panel, a door core, a door rail, a door stile, a door lock block, a door border, or a door insert. The fire resistant component typically has a cross-sectional thickness of 0.125 inches to 2 inches, a width of 1 inch to 4 feet and a length of 3 to 10 feet. Moreover and unlike many prior art composite materials, the composite product in accordance with the present invention does not include any cement or flyash.
The door core of the present invention provides the fire resistant capabilities necessary to receive the necessary certification. The length and width of the fire core will match the length and width specifications of the final door product. The dimensions of the fire core will typically be in widths of three feet and four feet and having a length ranging from seven feet to ten feet. The thickness of the door core will typically be between 0.125″ and 1.5″. A door manufacturer can use any of the completed core designs described herein as the fire resistant core of the manufacturer's fire-rated door. The resulting fire rated door can have fire ratings of 20-30, 45, 60, 90 or 120 minutes depending on the configuration and materials used. The manufacturer will typically finish the final door product by adding a final piece of wood or veneer to the door to provide the aesthetic appeal of the product.
Now referring to
The gypsum can be 70%, 71%, 72%, 73%, 74%, 75%, 76%, 77%, 78%, 79%, 80%, 81%, 82%, 83%, 84%, 85%, 86%, 87%, 88%, 89% or 90% by weight or other incremental percentage between. The glass fibers can be 1.5%, 2%, 2.5%, 3%, 3.5%, 4%, 4.5% or 5% by weight or other incremental percentage between. The glass fibers can have a diameter of 6 mm to 25 mm. The lightweight aggregate can be 1%, 1.5%, 2%, 2.5%, 3%, 3.5% or 4% by weight or other incremental percentage between. The lightweight aggregate, such as Poraver® porous glass spheres, can have average particle diameters of 1 to 2 mm or 2 to 4 mm. The starch can be 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5%, 5.5%, 6%, 6.5% or 7% by weight or other incremental percentage between. The starch is a pregelatinized or cook-up starch. The rheology-modifying agent can be cellulose ether, such as hydroxypropoyl methyl celluose (HPMC), methyl hydroxyethyl cellulose (MHEC), hydroxyethyl cellulose (HEC), carboxymethyl cellulose (CMC) or similar materials. The rheology-modifying agent can be 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%, 1.8%, 1.9%, 2%, 2.1%, 2.2%, 2.3%, 2.4%, 2.5%, 2.6%, 2.7%, 2.8%, 2.9%, 3%, 3.1%, 3.2%, 3.3%, 3.4%, 3.5%, 3.6%, 3.7%, 3.8%, 3.9% or 4% by weight or other incremental percentage between. Other materials can be substituted as will be appreciated by those skilled in the art.
The extruded fire resistant border 104 is made of a second fire resistant material having a higher density than the first fire resistant material so that second fire resistant material has holding capacity (e.g., fasteners will adhere to the second fire resistant material and remain fixed once installed) and can be shaped using an extrusion process. One example of such a material in accordance with the present invention is:
The gypsum can be 70%, 71%, 72%, 73%, 74%, 75%, 76%, 77%, 78%, 79%, 80%, 81%, 82%, 83%, 84%, 85%, 86%, 87%, 88%, 89% or 90% by weight or other incremental percentage between. The glass fibers can be 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5%, 5.5%, 6%, 6.5%, 7%, 7.5%, 8%, 8.5%, 9%, 9.5% or 10% by weight or other incremental percentage between. The glass fibers can have a diameter of 6 mm to 25 mm. The cellulose fibers can be 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5%, 5.5%, 6%, 6.5%, 7%, 7.5% or 8% by weight or other incremental percentage between. The cellulose fibers can be hardwood or softwood fiber. The polyvinyl alcohol (PVA) fibers can be 1%, 1.5%, 2%, 2.5%, 3%, 3.5% or 4% by weight or other incremental percentage between. The PVA fibers can have a diameter of 6 mm to 10 mm with a decitex of approximately 15. The polypropylene (PP) fibers can be 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%, 1.8%, 1.9%, 2%, 2.1%, 2.2%, 2.3%, 2.4%, 2.5%, 2.6%, 2.7%, 2.8%, 2.9%, 3%, 3.1%, 3.2%, 3.3%, 3.4%, 3.5%, 3.6%, 3.7%, 3.8%, 3.9% or 4% by weight or other incremental percentage between. The PP fibers can have a diameter of 6 mm to 25 mm. The rheology-modifying agent can be 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%, 1.8%, 1.9%, 2%, 2.1%, 2.2%, 2.3%, 2.4%, 2.5%, 2.6%, 2.7%, 2.8%, 2.9%, 3%, 3.1%, 3.2%, 3.3%, 3.4%, 3.5%, 3.6%, 3.7%, 3.8%, 3.9%, 4%, 4.1%, 4.2%, 4.3%, 4.4%, 4.5%, 4.6%, 4.7%, 4.8%, 4.9%, 5%, 5.1%, 5.2%, 5.3%, 5.4%, 5.5%, 5.6%, 5.7%, 5.8%, 5.9% or 6% by weight or other incremental percentage between. The rheology-modifying agent can be a cellulose ether, such as hydroxypropoyl methyl cellulose (HPMC), methyl hydroxyethyl cellulose (MHEC), hydroxyethyl cellulose (HEC), carboxymethyl cellulose (CMC) or similar materials. Other materials can be substituted as will be appreciated by those skilled in the art.
The extruded fire resistant border 104 can be made of a molded piece of the second fire resistant material (e.g.,
The physical dimensions of the core 100 and other cores described below in reference to
The core 100 and other cores described below in reference to
Referring now to
The physical dimensions of the core 200 and other cores described below in reference to
Now referring to
Referring now to
Now referring to
Referring now to
Now referring to
Referring now to
Now referring to
Referring now to
Note that the cores shown in
Referring now to
Now referring to
Referring now to
Now referring to
Referring now to
Now referring to
In one embodiment, a notch is formed in the first side of the fire resistant center panel, a fire resistant lock block is inserted within the notch and the fire resistant lock block is attached to the fire resistant center panel and the extruded fire resistant border, wherein the fire resistant lock block is made of the second fire resistant material. In another embodiment, the fire resistant center panel includes: (a) a first fire resistant center panel disposed between the first side and the second side proximate to the first end, wherein the first fire resistant center panel is made of the first fire resistant material; (b) a second fire resistant center panel disposed between the first side and the second side proximate to the second end, wherein the second fire resistant center panel is made of the first fire resistant material; and (c) a fire resistant insert disposed between and attached to the first fire resistant center panel and the second fire resistant center panel, and extending between and attached to the extruded fire resistant border at the first side and the second side, wherein the fire resistant material is made of the second fire resistant material. In yet another embodiment, a set of male-female connectors are formed in the extruded fire resistant border and the fire resistant center panel. The male-female connectors can be triangular-shaped, curved-shaped, rectangular-shaped, angled, tongue-and-groove, or a combination thereof.
In another embodiment, the first fire resistant material is extruded or molded to form the fire resistant center panel, and the second fire resistant material is extruded or molded to form the first stile, the second stile, the first rail and the second rail of the extruded fire resistant border. In yet another embodiment, the first fire resistant material is extruded or molded to form the fire resistant center panel, and the second fire resistant material is extruded or molded to form a sheet that is then gang ripped to form one or more of the first stile, the second stile, the first rail and the second rail of the extruded fire resistant border. In either embodiment the panels, stiles and rails may undergo one or more finishing steps (e.g., sanding, trimming, cutting, denibbing, etc.) so that the pieces have the proper smoothness, size and shape.
Furthermore, a top panel can be attached to the top of the fire resistant center panel and the extruded fire resistant border, or a bottom panel can be attached to the bottom of the fire resistant center panel, or both the top panel and the bottom panel can be attached to the fire resistant center panel. The top panel or the bottom panel can be a lignocellulosic substrate, a wood, a wood composite, a medium density fiberboard, a high density fiberboard, a particleboard, a masonite, a fiberglass, a metal, a plastic, one or more protective layers or a combination thereof. The one or more protective layers can be a fire resistant material, a blast resistant material, a ballistic resistant material, a shielding material, a chemical resistant material, a biohazard resistant material, a radiation resistant material, a dampening material, a grounding material, insulating material or a combination thereof. For example, the one or more protective layers can be one or more gypsum boards, one or more metallic sheets, one or more lead sheets, one or more Kevlar sheets, one or more ceramic sheets, a layer of urethane foam, a layer of graphite, a wire mesh or a combination thereof.
Referring now to
In one embodiment, a notch is formed in the first side of the fire resistant center panel, a fire resistant lock block is inserted within the notch and the fire resistant lock block is attached to the fire resistant center panel and the extruded fire resistant border, wherein the fire resistant lock block is made of the second fire resistant material. In another embodiment, the fire resistant center panel includes: (a) a first fire resistant center panel disposed between the first side and the second side proximate to the first end, wherein the first fire resistant center panel is made of the first fire resistant material; (b) a second fire resistant center panel disposed between the first side and the second side proximate to the second end, wherein the second fire resistant center panel is made of the first fire resistant material; and (c) a fire resistant insert disposed between and attached to the first fire resistant center panel and the second fire resistant center panel, and extending between and attached to the extruded fire resistant border at the first side and the second side, wherein the fire resistant material is made of the second fire resistant material. In yet another embodiment, a set of male-female connectors are formed in the extruded fire resistant border and the fire resistant center panel. The male-female connectors can be triangular-shaped, curved-shaped, rectangular-shaped, angled, tongue-and-groove, or a combination thereof.
In another embodiment, the first fire resistant material is extruded or molded to form the fire resistant center panel, and the second fire resistant material is extruded or molded to form the first stile, the second stile, the first rail and the second rail of the extruded fire resistant border. In yet another embodiment, the first fire resistant material is extruded or molded to form the fire resistant center panel, and the second fire resistant material is extruded or molded to form a sheet that is then gang ripped to form one or more of the first stile, the second stile, the first rail and the second rail of the extruded fire resistant border.
Furthermore, a top panel can be attached to the top of the fire resistant center panel and the extruded fire resistant border, or a bottom panel can be attached to the bottom of the fire resistant center panel, or both the top panel and the bottom panel can be attached to the fire resistant center panel. The top panel or the bottom panel can be a lignocellulosic substrate, a wood, a wood composite, a medium density fiberboard, a high density fiberboard, a particleboard, a masonite, a fiberglass, a metal, a plastic, one or more protective layers or a combination thereof. The one or more protective layers can be a fire resistant material, a blast resistant material, a ballistic resistant material, a shielding material, a chemical resistant material, a biohazard resistant material, a radiation resistant material, a dampening material, a grounding material, insulating material or a combination thereof. For example, the one or more protective layers can be one or more gypsum boards, one or more metallic sheets, one or more lead sheets, one or more Kevlar sheets, one or more ceramic sheets, a layer of urethane foam, a layer of graphite, a wire mesh or a combination thereof.
Now referring to
Although preferred embodiments of the present invention have been described in detail, it will be understood by those skilled in the art that various modifications can be made therein without departing from the spirit and scope of the invention as set forth in the appended claims.
This patent application is a continuation application of U.S. patent application Ser. No. 13/603,405 filed on Sep. 4, 2012 and entitled “Gypsum Composites Used in Fire Resistant Building Components”, which is a continuation-in-part application of: (1) U.S. patent application Ser. No. 13/538,788 filed on Jun. 29, 2012 and entitled “Fire Rated Door Core”; and (2) U.S. patent application Ser. No. 13/538,828 filed on Jun. 29, 2012, now U.S. Pat. No. 9,243,444, and entitled “Fire Rated Door”. All these applications are hereby incorporated by reference in their entirety.
Number | Name | Date | Kind |
---|---|---|---|
570391 | Fox | Oct 1896 | A |
1048923 | Wheeler | Dec 1912 | A |
3517468 | Woods | Jun 1970 | A |
3852083 | Yang | Dec 1974 | A |
3908062 | Roberts | Sep 1975 | A |
3987600 | Baehr | Oct 1976 | A |
3994110 | Ropella | Nov 1976 | A |
4014149 | Yamamoto | Mar 1977 | A |
4045937 | Stucky | Sep 1977 | A |
4075804 | Zimmerman | Feb 1978 | A |
4084571 | McFarland | Apr 1978 | A |
4159302 | Greve et al. | Jun 1979 | A |
4171985 | Motoki | Oct 1979 | A |
4225247 | Hodson | Sep 1980 | A |
4225357 | Hodson | Sep 1980 | A |
4284119 | Martin et al. | Aug 1981 | A |
4302127 | Hodson | Nov 1981 | A |
4308065 | Walls-Muycelo | Dec 1981 | A |
4339487 | Mullet | Jul 1982 | A |
4343127 | Greve et al. | Aug 1982 | A |
4347653 | Martin et al. | Sep 1982 | A |
4398842 | Hodson | Aug 1983 | A |
4428775 | Johnson et al. | Jan 1984 | A |
4434899 | Rivkin | Mar 1984 | A |
4443992 | Shechter | Apr 1984 | A |
4489121 | Luckanuck | Dec 1984 | A |
4552463 | Hodson | Nov 1985 | A |
4660338 | Wagner | Apr 1987 | A |
4664707 | Wilson et al. | May 1987 | A |
4695494 | Fowler et al. | Sep 1987 | A |
4704834 | Turner | Nov 1987 | A |
4716700 | Hagemeyer | Jan 1988 | A |
4716702 | Dickson | Jan 1988 | A |
4800538 | Passmore et al. | Jan 1989 | A |
4811538 | Lehnert et al. | Mar 1989 | A |
4864789 | Thorn | Sep 1989 | A |
4889428 | Hodson | Dec 1989 | A |
4896471 | Turner | Jan 1990 | A |
4922674 | Thorn | May 1990 | A |
4944595 | Hodson | Jul 1990 | A |
4946504 | Hodson | Aug 1990 | A |
4998598 | Mardian et al. | Mar 1991 | A |
5061319 | Hodson | Oct 1991 | A |
5066080 | Woodward | Nov 1991 | A |
5074087 | Green | Dec 1991 | A |
5100586 | Jennings et al. | Mar 1992 | A |
5108677 | Ayres | Apr 1992 | A |
5154358 | Hartle | Oct 1992 | A |
5169566 | Stucky et al. | Dec 1992 | A |
5232496 | Jennings et al. | Aug 1993 | A |
5239799 | Bies et al. | Aug 1993 | A |
5242078 | Haas et al. | Sep 1993 | A |
5250578 | Cornwell | Oct 1993 | A |
5305577 | Richards et al. | Apr 1994 | A |
5311381 | Lee | May 1994 | A |
5317119 | Ayres | May 1994 | A |
5339522 | Paquin et al. | Aug 1994 | A |
5344490 | Roosen et al. | Sep 1994 | A |
5347780 | Richards et al. | Sep 1994 | A |
5356579 | Jennings et al. | Oct 1994 | A |
5358676 | Jennings et al. | Oct 1994 | A |
5376320 | Tiefenbacher et al. | Dec 1994 | A |
5385764 | Andersen et al. | Jan 1995 | A |
5395571 | Symons | Mar 1995 | A |
5401588 | Garvey et al. | Mar 1995 | A |
5417024 | San Paolo | May 1995 | A |
5433189 | Bales et al. | Jul 1995 | A |
5440843 | Langenhorst | Aug 1995 | A |
5453310 | Andersen et al. | Sep 1995 | A |
5482551 | Morris et al. | Jan 1996 | A |
5505987 | Jennings et al. | Apr 1996 | A |
5506046 | Andersen et al. | Apr 1996 | A |
5508072 | Andersen et al. | Apr 1996 | A |
5514430 | Andersen et al. | May 1996 | A |
5522195 | Bargen | Jun 1996 | A |
5527387 | Andersen et al. | Jun 1996 | A |
5540026 | Gartland | Jul 1996 | A |
5543186 | Andersen et al. | Aug 1996 | A |
5545297 | Andersen et al. | Aug 1996 | A |
5545450 | Andersen et al. | Aug 1996 | A |
5549859 | Andersen et al. | Aug 1996 | A |
5557899 | Dube et al. | Sep 1996 | A |
5569514 | Ayres | Oct 1996 | A |
5580409 | Andersen et al. | Dec 1996 | A |
5580624 | Andersen et al. | Dec 1996 | A |
5582670 | Andersen et al. | Dec 1996 | A |
5601888 | Fowler | Feb 1997 | A |
5614307 | Andersen et al. | Mar 1997 | A |
5618341 | Andersen et al. | Apr 1997 | A |
5626954 | Andersen et al. | May 1997 | A |
5631052 | Andersen et al. | May 1997 | A |
5631053 | Andersen et al. | May 1997 | A |
5631097 | Andersen et al. | May 1997 | A |
5635292 | Jennings et al. | Jun 1997 | A |
5637412 | Jennings et al. | Jun 1997 | A |
5641584 | Andersen et al. | Jun 1997 | A |
5644870 | Chen | Jul 1997 | A |
5653075 | Williamson | Aug 1997 | A |
5654048 | Andersen et al. | Aug 1997 | A |
5658603 | Andersen et al. | Aug 1997 | A |
5658624 | Andersen et al. | Aug 1997 | A |
5660900 | Andersen et al. | Aug 1997 | A |
5660903 | Andersen et al. | Aug 1997 | A |
5660904 | Andersen et al. | Aug 1997 | A |
5662731 | Andersen et al. | Sep 1997 | A |
5665439 | Andersen et al. | Sep 1997 | A |
5665442 | Andersen et al. | Sep 1997 | A |
5676905 | Andersen et al. | Oct 1997 | A |
5679145 | Andersen et al. | Oct 1997 | A |
5679381 | Andersen et al. | Oct 1997 | A |
5683772 | Andersen et al. | Nov 1997 | A |
5691014 | Andersen et al. | Nov 1997 | A |
5695811 | Andersen et al. | Dec 1997 | A |
5702787 | Andersen et al. | Dec 1997 | A |
5705203 | Andersen et al. | Jan 1998 | A |
5705237 | Andersen et al. | Jan 1998 | A |
5705238 | Andersen et al. | Jan 1998 | A |
5705239 | Andersen et al. | Jan 1998 | A |
5705242 | Andersen et al. | Jan 1998 | A |
5707474 | Andersen et al. | Jan 1998 | A |
5709827 | Andersen et al. | Jan 1998 | A |
5709913 | Andersen et al. | Jan 1998 | A |
5711908 | Andersen et al. | Jan 1998 | A |
5714217 | Andersen et al. | Feb 1998 | A |
5716675 | Andersen et al. | Feb 1998 | A |
5720142 | Morrison | Feb 1998 | A |
5720913 | Andersen et al. | Feb 1998 | A |
5736209 | Andersen et al. | Apr 1998 | A |
5738921 | Andersen et al. | Apr 1998 | A |
5740635 | Gil et al. | Apr 1998 | A |
5746822 | Espinoza et al. | May 1998 | A |
5749178 | Garmong | May 1998 | A |
5753308 | Andersen et al. | May 1998 | A |
5766525 | Andersen et al. | Jun 1998 | A |
5776388 | Andersen et al. | Jul 1998 | A |
5782055 | Crittenden | Jul 1998 | A |
5783126 | Andersen et al. | Jul 1998 | A |
5786080 | Andersen et al. | Jul 1998 | A |
5798010 | Richards et al. | Aug 1998 | A |
5798151 | Andersen et al. | Aug 1998 | A |
5800647 | Andersen et al. | Sep 1998 | A |
5800756 | Andersen et al. | Sep 1998 | A |
5810961 | Andersen et al. | Sep 1998 | A |
5830305 | Andersen et al. | Nov 1998 | A |
5830548 | Andersen et al. | Nov 1998 | A |
5843544 | Andersen et al. | Dec 1998 | A |
5849155 | Gasland | Dec 1998 | A |
5851634 | Andersen et al. | Dec 1998 | A |
5868824 | Andersen et al. | Feb 1999 | A |
5879722 | Andersen et al. | Mar 1999 | A |
5887402 | Ruggie et al. | Mar 1999 | A |
5916077 | Tang | Jun 1999 | A |
5928741 | Andersen et al. | Jul 1999 | A |
5976235 | Andersen et al. | Nov 1999 | A |
6030673 | Andersen et al. | Feb 2000 | A |
6067699 | Jackson | May 2000 | A |
6083586 | Andersen et al. | Jul 2000 | A |
6090195 | Andersen et al. | Jul 2000 | A |
6115976 | Gomez | Sep 2000 | A |
6119411 | Mateu Gill et al. | Sep 2000 | A |
6161363 | Herbst | Dec 2000 | A |
6168857 | Andersen et al. | Jan 2001 | B1 |
6180037 | Andersen et al. | Jan 2001 | B1 |
6200404 | Andersen et al. | Mar 2001 | B1 |
6231970 | Andersen et al. | May 2001 | B1 |
6268022 | Schlegel et al. | Jul 2001 | B1 |
6299970 | Richards et al. | Oct 2001 | B1 |
6311454 | Kempel | Nov 2001 | B1 |
6327821 | Chang | Dec 2001 | B1 |
6347934 | Andersen et al. | Feb 2002 | B1 |
6379446 | Andersen et al. | Apr 2002 | B1 |
6402830 | Schaffer | Jun 2002 | B1 |
6434899 | Fortin et al. | Aug 2002 | B1 |
6475275 | Nebesnak et al. | Nov 2002 | B1 |
6485561 | Dattel | Nov 2002 | B1 |
6494704 | Andersen et al. | Dec 2002 | B1 |
6503751 | Hugh | Jan 2003 | B2 |
6528151 | Shah et al. | Mar 2003 | B1 |
6572355 | Bauman et al. | Jun 2003 | B1 |
6573340 | Khemani et al. | Jun 2003 | B1 |
6581588 | Wiedemann et al. | Jun 2003 | B2 |
6619005 | Chen | Sep 2003 | B1 |
6643991 | Moyes | Nov 2003 | B1 |
6665997 | Chen | Dec 2003 | B2 |
6668499 | Degelsegger | Dec 2003 | B2 |
6684590 | Frumkin | Feb 2004 | B2 |
6688063 | Lee et al. | Feb 2004 | B1 |
6696979 | Manten et al. | Feb 2004 | B2 |
6743830 | Soane et al. | Jun 2004 | B2 |
6745526 | Autovino | Jun 2004 | B1 |
6764625 | Walsh | Jul 2004 | B2 |
6766621 | Reppermund | Jul 2004 | B2 |
6773500 | Creamer et al. | Aug 2004 | B1 |
6779859 | Koons | Aug 2004 | B2 |
6818055 | Schelinski | Nov 2004 | B2 |
6843543 | Ramesh | Jan 2005 | B2 |
6866081 | Nordgard et al. | Mar 2005 | B1 |
6886306 | Churchill et al. | May 2005 | B2 |
6890604 | Daniels | May 2005 | B2 |
6961998 | Furchheim et al. | Nov 2005 | B2 |
6964722 | Taylor et al. | Nov 2005 | B2 |
6981351 | Degelsegger | Jan 2006 | B2 |
7059092 | Harkin et al. | Jun 2006 | B2 |
7090897 | Hardesty | Aug 2006 | B2 |
RE39339 | Andersen et al. | Oct 2006 | E |
7185468 | Clark et al. | Mar 2007 | B2 |
7241832 | Khemani et al. | Jul 2007 | B2 |
7279437 | Kai et al. | Oct 2007 | B2 |
7297394 | Khemani et al. | Nov 2007 | B2 |
7386368 | Andersen et al. | Jun 2008 | B2 |
7598460 | Roberts, IV et al. | Oct 2009 | B2 |
7617606 | Robbins et al. | Nov 2009 | B2 |
7669383 | Darnell | Mar 2010 | B2 |
7721500 | Clark et al. | May 2010 | B2 |
7775013 | Bartlett et al. | Aug 2010 | B2 |
7803723 | Herbert et al. | Sep 2010 | B2 |
7832166 | Daniels | Nov 2010 | B2 |
7886501 | Bartlett et al. | Feb 2011 | B2 |
7897235 | Locher et al. | Mar 2011 | B1 |
7927420 | Francis | Apr 2011 | B2 |
7964051 | Lynch et al. | Jun 2011 | B2 |
8037820 | Daniels | Oct 2011 | B2 |
8097544 | Majors | Jan 2012 | B2 |
8209866 | Daniels | Jul 2012 | B2 |
8381381 | Daniels | Feb 2013 | B2 |
8650834 | Hardwick et al. | Feb 2014 | B2 |
8915033 | Daniels | Dec 2014 | B2 |
9027296 | Daniels | May 2015 | B2 |
9475732 | Daniels | Oct 2016 | B2 |
9890083 | Daniels | Feb 2018 | B2 |
20010032367 | Sasage et al. | Oct 2001 | A1 |
20010047741 | Gleeson et al. | Dec 2001 | A1 |
20020053757 | Andersen et al. | May 2002 | A1 |
20020078659 | Hunt | Jun 2002 | A1 |
20020100996 | Moyes et al. | Aug 2002 | A1 |
20020124497 | Fortin et al. | Sep 2002 | A1 |
20020128352 | Soane et al. | Sep 2002 | A1 |
20020166479 | Jiang | Nov 2002 | A1 |
20030015124 | Klus | Jan 2003 | A1 |
20030033786 | Yulkowski | Feb 2003 | A1 |
20030084980 | Seufert et al. | May 2003 | A1 |
20030115817 | Blackwell et al. | Jun 2003 | A1 |
20030205187 | Carlson et al. | Nov 2003 | A1 |
20030209403 | Daniels | Nov 2003 | A1 |
20030211251 | Daniels | Nov 2003 | A1 |
20030211252 | Daniels | Nov 2003 | A1 |
20040025465 | Aldea | Feb 2004 | A1 |
20040026002 | Weldon | Feb 2004 | A1 |
20040231285 | Hunt et al. | Nov 2004 | A1 |
20040258901 | Luckevich | Dec 2004 | A1 |
20050092237 | Daniels | May 2005 | A1 |
20050227006 | Segall | Oct 2005 | A1 |
20050241541 | Hohn et al. | Nov 2005 | A1 |
20050284030 | Autovino et al. | Dec 2005 | A1 |
20060070321 | Au | Apr 2006 | A1 |
20060096240 | Fortin | May 2006 | A1 |
20060168906 | Tonyan et al. | Aug 2006 | A1 |
20060287773 | Andersen et al. | Dec 2006 | A1 |
20070021515 | Glenn et al. | Jan 2007 | A1 |
20070053852 | Beutler et al. | Mar 2007 | A1 |
20070077436 | Naji et al. | Apr 2007 | A1 |
20070092712 | Hodson | Apr 2007 | A1 |
20070095570 | Roberts, IV et al. | May 2007 | A1 |
20070125043 | Clark et al. | Jun 2007 | A1 |
20070125044 | Clark et al. | Jun 2007 | A1 |
20070157537 | Nicolson et al. | Jul 2007 | A1 |
20070175139 | Nicolson et al. | Aug 2007 | A1 |
20070193220 | Daniels | Aug 2007 | A1 |
20070283660 | Blahut | Dec 2007 | A1 |
20080016820 | Robbins, Sr. et al. | Jan 2008 | A1 |
20080027583 | Andersen et al. | Jan 2008 | A1 |
20080027584 | Andersen et al. | Jan 2008 | A1 |
20080027685 | Andersen et al. | Jan 2008 | A1 |
20080041014 | Lynch et al. | Feb 2008 | A1 |
20080066653 | Andersen et al. | Mar 2008 | A1 |
20080086982 | Parenteau et al. | Apr 2008 | A1 |
20080099122 | Andersen et al. | May 2008 | A1 |
20080145580 | McAllister et al. | Jun 2008 | A1 |
20080152945 | Miller | Jun 2008 | A1 |
20080156225 | Bury | Jul 2008 | A1 |
20080286519 | Nicolson et al. | Nov 2008 | A1 |
20090011207 | Dubey | Jan 2009 | A1 |
20090151602 | Francis | Jun 2009 | A1 |
20090197991 | Bury | Aug 2009 | A1 |
20100064943 | Guevara et al. | Mar 2010 | A1 |
20100071597 | Perez-Pena | Mar 2010 | A1 |
20100095622 | Niemoller | Apr 2010 | A1 |
20100136269 | Andersen et al. | Jun 2010 | A1 |
20100251632 | Chen et al. | Oct 2010 | A1 |
20110040401 | Daniels | Feb 2011 | A1 |
20110120349 | Andersen et al. | May 2011 | A1 |
20110131921 | Chen | Jun 2011 | A1 |
20110167753 | Sawyers et al. | Jul 2011 | A1 |
20120276310 | Andersen et al. | Jan 2012 | A1 |
20120164402 | Murakami | Jun 2012 | A1 |
20120208003 | Beard | Aug 2012 | A1 |
20130008115 | Bierman | Jan 2013 | A1 |
20130086858 | Daniels et al. | Apr 2013 | A1 |
20130216802 | Leung et al. | Aug 2013 | A1 |
20130280518 | Stahl et al. | Oct 2013 | A1 |
20140000193 | Daniels et al. | Jan 2014 | A1 |
20140000194 | Daniels et al. | Jan 2014 | A1 |
20140000195 | Daniels et al. | Jan 2014 | A1 |
20140000196 | Daniels et al. | Jan 2014 | A1 |
20150086769 | Daniels et al. | Mar 2015 | A1 |
20150107172 | Daniels et al. | Apr 2015 | A1 |
Number | Date | Country |
---|---|---|
2799983 | Dec 2012 | CA |
101113077 | Jan 2008 | CN |
101132999 | Feb 2008 | CN |
101239838 | Aug 2008 | CN |
102001832 | Nov 2010 | CN |
102167619 | Aug 2011 | CN |
102220829 | Oct 2011 | CN |
102643013 | Aug 2012 | CN |
102712531 | Oct 2012 | CN |
10200601544 | Oct 2007 | DE |
1266877 | Dec 2002 | EP |
2189612 | May 2010 | EP |
2230075 | Sep 2010 | EP |
2314462 | Apr 2011 | EP |
2583954 | Apr 2013 | EP |
1265471 | Mar 1972 | GB |
1508866 | Apr 1978 | GB |
H05-052075 | Mar 1993 | JP |
H05-097487 | Apr 1993 | JP |
H06-56497 | Mar 1994 | JP |
H11-147777 | Jun 1999 | JP |
2004332401 | Nov 2004 | JP |
2008036549 | Feb 2008 | JP |
2008201613 | Sep 2008 | JP |
2132829 | Jul 1999 | RU |
2411218 | Feb 2011 | RU |
199105744 | May 1991 | WO |
0231306 | Apr 2002 | WO |
03004432 | Jan 2003 | WO |
2005105700 | Nov 2005 | WO |
2006138732 | Dec 2006 | WO |
2007051093 | May 2007 | WO |
2007053852 | May 2007 | WO |
20080144186 | Nov 2008 | WO |
2009038621 | Mar 2009 | WO |
2010141032 | Dec 2010 | WO |
2011066192 | Jun 2011 | WO |
2012084716 | Jun 2012 | WO |
2013082524 | Jun 2013 | WO |
Entry |
---|
EP 14759514.4 Extended European Search Report dated Sep. 23, 2016. |
Extended Search Report EP 13845068 dated Oct. 16, 2016. |
Kralj, D., “Experimental study of recycling lightweight concrete with aggregates containing expanded glass.” Process Safety and Environmental Protection, vol. 87, No. 4, Jul. 1, 2809 (Jul. 1, 2009), pp. 267-273. |
Search Report PCT/US07/04605, dated Oct. 4, 2007. |
Search Report PCT US12/059053 dated Mar. 12, 2013. |
International Search Report (KIPO) PCT/US2013/048642 dated Sep. 2, 2013. |
International Search Report (KIPO) PCT/US2013/048712 dated Sep. 10, 2013. |
International Search Report [KIPO] PCT/US2014/035313 dated Aug. 19, 2014. |
International Search Report [KIPO] PCT/US2014/035277 dated Sep. 2, 2014. |
European Extended Search Report for EP 14854429.9 dated Jun. 1, 2017. |
Supplementary European Search Report for EP 15803724 dated Jan. 23, 2018. |
XP 000375896 6001 Chemical Abstracts 117 Aug. 24, 1992, No. 8, Columbus, Ohio, US. |
Office Action [EP 13809252.3] dated Sep. 3, 2018. |
Office Action [EP 14788791.3] dated Jan. 8, 2019. |
Number | Date | Country | |
---|---|---|---|
20160303826 A1 | Oct 2016 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 13603405 | Sep 2012 | US |
Child | 15193274 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 13538788 | Jun 2012 | US |
Child | 13603405 | US | |
Parent | 13538828 | Jun 2012 | US |
Child | 13538788 | US |