TREA

Hair-Treatment Agent Comprising Terpolymer Of Vinylpyrrolidone, Methacrylamide And Vinylimidazole And Active Ingredients And Additives

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Information

  • Patent Application
  • 20080020004
  • Publication Number
    20080020004
  • Date Filed
    February 18, 2005
    20 years ago
  • Date Published
    January 24, 2008
    17 years ago
Information
Abstract
A hair-treatment agent is described with a content of a combination of a terpolymer constructed from vinylpyrrolidone, methacrylamide and vinylimidazole, and at least one active ingredient or additive chosen from viscosity-modifying substances, haircare substances, hair-setting substances, silicone compounds, photoprotective substances, oils, waxes, preservatives, pigments, soluble dyes, particulate substances, and surfactants in a suitable cosmetic base. The hair-treatment agent can be in the form of a gel, a viscous lotion, a spray gel, an O/W emulsion, a W/O emulsion, a microemulsion, a hair spray, a foamable product in combination with a device for foaming, or in the form of a hair wax. Preference is given to products which are foamable with a propellant in which the active ingredient or additive is chosen from chitosan, chitosan salts, chitosan derivatives, cationic cellulose compounds and copolymers of vinylpyrrolidone, vinylcaprolactam and a basic acrylamide monomer.
Description
EXAMPLES

Substances used in the examples:

  • Luviset® Clear: Terpolymer of vinylpyrrolidone, methacrylamide and vinylimidazole (BASF)
  • Surfactant 193: Ethoxylated dimethylpolysiloxane; INCI: PEG-12 Dimethicone (Dow Corning)
  • Emulgin® L: INCI: PEG-1-PEG-9 LAURYL GLYCOL ETHER
  • Natrosol G: Hydroxyethylcellulose
  • Aculyn® 48: PEG-150/STEARYL ALCOHOL/SMDI COPOLYMER, 19% strength in water (Rohm and Haas)
  • Aquaflex® SF 40: VP/VINYL CAPROLACTAM/DMAPA ACRYLATES COPOLYMER, 40% strength in ethanol (ISP)
  • Pemulen®: ACRYLATES/C10-30 ALKYL ACRYLATE CROSSPOLYMER
  • Synthalen® W 2000: ACRYLATES/PALMETH-25 ACRYLATE COPOLYMER (31% strength in water)
  • Structure® 3001: ACRYLATES/CETETH-20 ITACONATE COPOLYMER 30% strength in water (National Starch)
  • Dekaben® LMB: IODOPROPYNYL BUTYLCARBAMATE, 10% strength in butylene glycol
  • Dekaben® LMP: Phenoxyethanol and iodopropynyl butylcarbamate
  • Celquat® L200: Copolymer of hydroxyethylcellulose and diallyldimethylammonium chloride; Polyquaternium-4
  • Dow Corning 1401: High molecular weight Dimethiconol, 13% strength in cyclomethicone
  • Copolymer 845: VP/DIMETHYLAMINOETHYLMETHACRYLATE COPOLYMER, 20% strength in water (ISP)
  • Abilquat® 3270: Quaternium-80, 50% strength in propylene glycol (Goldschmidt)
  • Aquaflex® FX-64: ISOBUTYLENE/ETHYLMALEIMIDE/HYDROXY-ETHYLMALEIMIDE COPOLYMER, 40% strength in water/ethanol (ISP)
  • Diaformer Z-711: ACRYLATES/LAURYL ACRYLATE/STEARYL ACRYLATE/ETHYLAMINE OXIDE METHACRYLATE COPOLYMER, 40% strength (Clariant)


Example 1
Liquid Gel


















Luviset ® Clear
 1.0 g



Surfactant 193
 1.5 g



Carbomer
 0.3 g



AMP 95%
 0.3 g



Emulgin L
 0.2 g



Perfume
0.15 g



Natrosol ®
 0.4 g



Ethanol
16.5 g



Water
ad 100










Example 2
Liquid Gel


















Luviset ® Clear
 1.0 g



Vinylpyrrolidone/vinyl acetate copolymer
 1.0 g



Surfactant 193
 1.0 g



Xanthan Gum
 1.2 g



Citric acid
 0.1 g



Perfume
0.15 g



Ethanol
 6.5 g



DMDM Hydantoin
 0.3 g



Water
ad 100










Example 3
Liquid Gel


















Luviset ® Clear
 0.5 g



Glucose
 7.0 g



Propylene glycol
 3.8 g



Hydroxypropylguar
 0.3 g



AMP 95%
 0.2 g



PEG-25 PABA
 0.5 g



PEG-40 Hydrogenated Castor Oil
0.18 g



PPG-1-PEG-9 Lauryl Glycol Ether
0.18 g



Perfume
0.15 g



Ethanol
16.5 g



Water
ad 100










Example 4
Spray Gel


















Luviset ® Clear
1.5 g



VP/VA COPOLYMER (Luviskol ® VA 64)
3.0 g



Ethanol
 18 g



Aminomethylpropanol 95%
0.1 g



PEG-40 Hydrogenated Castor Oil
0.2 g



Perfume
0.2 g



Aculyn ® 48
0.5 g



Water
ad 70










The composition is packaged in a packaging with pump spray device.


Example 5
Rapidly Drying Gel


















Luviset ® Clear
 3.0 g



Aquaflex ® SF 40
 2.8 g



Surfactant 193
 1.5 g



Pemulen ®
0.35 g



AMP 95%
0.26 g



Methylmethoxycinnamate
0.30 g



Perfume
0.30 g



Ethanol 510
34.2 g



Water
ad 100










Example 6
Gel Spray


















Luviset ® Clear
 1.0 g



Surfactant 193
 1.0 g



Carbomer (Carbopol)
0.23 g



AMP 95%
0.22 g



Perfume
0.15 g



Ethanol 510
 6.5 g



Water
ad 100










The composition is packaged in a packaging with pump spray device.


Example 7
Blow-Drying Gel


















Luviset ® Clear
 1.0 g



Surfactant 193
 1.0 g



Hydroxypropylcellulose (Klucel ® HF)
0.95 g



Citric acid
 0.1 g



Perfume
0.15 g



Ethanol 510
 6.5 g



Water
ad 100










Example 8
Gel


















Luviset ® Clear
 1.0 g



Polyvinylpyrrolidone K 90
 1.8 g



Surfactant 193
 1.5 g



Synthalen ® W 2000
 1.0 g



AMP 95%
 0.3 g



PEG-25 PABA (Uvinul ® P 25)
 0.3 g



Panthenol
0.15 g



Perfume
 0.3 g



Ethanol 510
34.2 g



Keratin hydrolysate
 0.1 g



Water
ad 100










Example 9
Gel—Strong Hold















Luviset ® Clear
1.0 g


VA/CROTONATES COPOLYMER (Luviset ® CA 66)
2.5 g


Sorbitol
4.2 g


Carbomer (Tego Carbomer)
0.8 g


AMP 95%
0.3 g


Methylparaben
0.2 g


PEG-40 Hydrogenated Castor Oil
0.2 g


Panthenol
0.1 g


Perfume
0.2 g


Ethanol 510
5.0 g


Water
ad 100









Example 10
Gel—Strong Hold


















Luviset ® Clear
 1.0 g



Aquaflex ® SF 40
 1.5 g



Vinyl acetate/crotonic acid copolymer
 1.2 g



Sorbitol
 4.2 g



Structure ® 3001
0.12 g



AMP 95%
0.35 g



PEG-25 PABA
 0.5 g



Dekaben ® LMB
 0.2 g



PEG-40 Hydrogenated Castor Oil
 0.2 g



Panthenol
 0.1 g



Perfume
 0.2 g



Ethanol 510
 5.0 g



Water
ad 100










Example 11
Gel—Normal Hold


















Luviset ® Clear
 1.5 g



Glycerol
 5.2 g



Propylene glycol
 4.0 g



Ammonium Acryloyldimethyltaurate/VP
0.35 g



Copolymer (Aristoflex AVC)



AMP 95%
0.26 g



Polysorbate-40
 1.0 g



Methylparaben
 0.2 g



PEG-25 PABA
 0.5 g



Perfume
 0.2 g



Ethanol 510
 4.5 g



Water
ad 100










Example 12
Pump—Setting Foam


















Luviset ® Clear
1.3



Vinyl acetate/crotonic acid copolymer
0.3



Cocamidopropyl Hydroxysultaine
0.4



Citric acid
0.1



Ethanol 510
8.9



Betaine
0.1



Perfume
0.15



Water
ad 100










The composition is packaged in a packaging with mechanically operated pump foaming device.


Example 13
Pump—Setting Foam


















Luviset ® Clear
1.5



Acrylic acid/ethyl acrylate/N-tert-
0.4



butylacrylamide Copolymer



Cocamidopropyl Hydroxysultaine
0.4



Citric acid
0.1



Dekaben ® LMP
0.2



Camomile blossom extract
0.1



Perfume
0.15



Water
ad 100










The composition is packaged in a packaging with mechanically operated pump foaming device.


Example 14
Pump—Setting Foam


















Luviset ® Clear
1.2



Polyquaternium- 6
0.35



Cocamidopropyl Hydroxysultaine
0.4



Panthenol
0.1



Ethanol 510
8.9



Betaine
0.1



Perfume
0.15



Water
ad 100










The composition is packaged in a packaging with mechanically operated pump foaming device.


Example 15
Pump—Setting Foam


















Luviset ® Clear
 2.5 g



Ethanol
 8.9 g



Cocamidopropyl Hydroxysultaine
 0.2 g



Cetyltrimethylammonium chloride
 0.2 g



Perfume
0.15 g



Silk fibroin hydrolysate (Silkpro ®)
 0.1 g



Water
ad 100










The composition is packaged in a packaging with mechanically operated pump foaming device.


Example 16
Pump—Setting Foam


















Luviset ® Clear
 2.0 g



Celquat ® L200
 0.3 g



Ethanol
 8.9 g



Cocamidopropyl Hydroxysultaine
 0.2 g



Cetyltrimethylammonium chloride
 0.2 g



Perfume
0.15 g



Citric acid
 0.1 g



Betaine
 0.1 g



Water
ad 100










The composition is packaged in a packaging with mechanically operated pump foaming device.


Example 17
Pump—Setting Foam


















Luviset ® Clear
1.3



Polyquaternium-11
0.3



Cocamidopropyl Hydroxysultaine
0.4



Propylene glycol
1.0



Methylparaben
0.2



Perfume
0.15



Water
ad 100










The composition is packaged in a packaging with mechanically operated pump foaming device.


Example 18
Pump—Setting Foam


















Luviset ® Clear
1.8



Cocamidopropyl Hydroxysultaine
0.4



Rosemary leaf extract (Extrapon ® Rosemary)
0.1



Ethanol 510
8.9



Extrapon ® seven herbs - extract
0.1



Panthenyl ethyl ether
0.1



Perfume
0.15



Water
ad 100










The composition is packaged in a packaging with mechanically operated pump foaming device.


Example 19
Aerosol—Setting Foam—Normal Hold


















Luviset ® Clear
1.5



Butyl monoester of methyl vinyl
0.5



ether/maleic acid copolymer



Butane
4.0



Propane
4.0



Ethanol 510
8.9



PEG-25 PABA
0.4



Betaine
0.15



Perfume
0.15



Laureth-4
0.2



Cetrimonium bromide
0.05



Amodimethicone
0.5



Water
ad 100










The composition is bottled in an aerosol can with foaming head.


Example 20
Aerosol—Setting Foam—Normal Hold


















Luviset ® Clear
1.5



Polyquaternium-47
0.5



Butane
4.0



Propane
4.0



Betaine
0.15



Dow Corning 1401
0.25



2-Ethylhexyl 4-methoxycinnamate
0.2



Perfume
0.15



Laureth-4
0.2



Cetrimonium chloride
0.07



Water
ad 100










The composition is bottled in an aerosol can with foaming head.


Example 21
Aerosol—Setting Foam—Extra Strong Hold


















Luviset ® Clear
2.1



Copolymer 845
2.5



Polyquaternium-4
1.0



Butane
4.0



Propane
4.0



Panthenol
0.2



Perfume
0.2



Abilquat ® 3270
0.7



Cetrimonium chloride
0.07



Water
ad 100










The composition is bottled in an aerosol can with foaming head.


Example 22
Aerosol—Setting Foam—Extra Strong Hold


















Luviset ® Clear
2.1



Vinyl acetate/crotonic acid copolymer
0.6



Polyquaternium-7
0.5



Butane
4.0



Propane
4.0



Ethanol 510
8.9



PEG-25 PABA
0.4



Panthenol
0.2



Perfume
0.2



Laureth-4
0.2



C9-C11 Pareth-8
0.07



Water
ad 100










The composition is bottled in an aerosol can with foaming head.


Example 23
Setting Spray


















Luviset ® Clear
1.5



Aquaflex ® FX-64
1.0



Ethanol 510
2.7



Polyquaternium-35
1.0



PEG-25 PABA
0.7



Panthenol
0.35



Perfume
0.25



Cetrimonium chloride
0.2



PEG-40 Hydrogenated Castor Oil
0.21



Water
ad 100










The composition is bottled in a packaging with pump spray device.


Example 24
Setting Spray


















Luviset ® Clear
 2.5 g



Octylacrylamide/Acrylates/Butylaminoethyl-
 2.0 g



methacrylate Copolymer (Amphomer ®)



Ethanol
28.5 g



Aminomethylpropanol 95%
 0.6 g



Perfume
0.25 g



Cetyltrimethylammonium bromide
0.20 g



Water
ad 60










The composition is bottled in a packaging with pump spray device.


Example 25
Setting Spray


















Luviset ® Clear
 1.0 g



Octylacrylamide/Acrylates/Butylaminoethyl-
0.65 g



methacrylate Copolymer (Amphomer ®)



Celquat ® L200
 0.2 g



Ethanol
28.5 g



Aminomethylpropanol 95%
 0.6 g



Perfume
0.25 g



Cetyltrimethylammonium chloride
0.20 g



Water
ad 60










The composition is bottled in a packaging with pump spray device.


Example 26
Nonaerosol Blow-Drying Lotion


















Luviset ® Clear
 2.8 g



Vinyl Caprolactam/VP/Dimethylaminoethyl
 2.0 g



Methacrylate Copolymer (Advantage ® S)



Ethanol
28.5 g



Perfume
0.25 g



Cetyltrimethylammonium chloride
0.20 g



Water
ad 60










Example 27
Nonaerosol Blow-Drying Lotion


















Luviset ® Clear
 3.1 g



Celquat ® L200
0.05 g



Diaformer ® Z-711
 0.5 g



Ethanol
  27 g



Betaine
 0.1 g



Perfume
0.25 g



PEG-40 Hydrogenated Castor Oil
0.21 g



Cetyltrimethylammonium bromide
0.20 g



Water
ad 100










Example 28
Nonaerosol Blow-Drying Lotion


















Luviset ® Clear
3.00 g



Sodium polystyrenesulfonate (Flexan ®)
2.30 g



Perfume
0.20 g



Phenyltrimethicone (Baysilon ® oil PD 5)
0.02 g



Water
10.00 g 



Ethanol
ad 100










The active ingredient solution is bottled in the ratio 45:55 with DME as propellant in an aerosol can.


Example 29
VOC 80 Pump Spray—Strong Hold


















Luviset ® Clear
6.5



t-Butyl acrylate/Ethyl acrylate/Methacrylic
0.5



acid Copolymer (Luvimer ® 100 P)



Perfume
0.2



AMP
0.10



Betaine
0.05



Ethanol 510
55



Demineralized water
ad 100










The composition is bottled in a packaging with pump spray device.


Example 30
Aerosol—Hairspray


















Octylacrylamide/Acrylic acid/Butylaminoethyl
3.00



methacrylate/Methyl methacrylate/



hydroxypropyl methacrylate Copolymer



(Amphomer ®)



Luviset ® Clear
1.50



Phenyl trimethicone (Baysilon ® oil PD 5)
0.02



Perfume
0.20



Water
10.00



AMP 95%
0.48



Ethanol 510
ad 100










The active ingredient solution is bottled in the ratio 45:55 with DME as propellant in an aerosol can.


Example 31
Aerosol—Hairspray


















t-Butyl acrylate/Ethyl acrylate/Methacrylic
3.3



acid Copolymer (Luvimer ® 100 P)



Luviset ® Clear
3.3



VA/CROTONATES COPOLYMER
1.0



(Luviset ® CA 66)



Perfume
0.2



Water
10.0



AMP 95%
0.84



Ethanol 510
ad 100










The active ingredient solution is bottled in the ratio 45:55 with DME as propellant in an aerosol can.


Example 32
Aerosol—Hairspray


















Luviset ® Clear
2.50 g



t-Butyl acrylate/Ethyl acrylate/Methacrylic
3.30 g



acid Copolymer (Luvimer ® 100 P)



Aminomethylpropanol 95%
0.85 g



Perfume
0.20 g



Baysilon ® oil PD 5
0.02 g



Water
10.00 g 



Ethanol
ad 100










The active ingredient solution is bottled in the ratio 45:55 with DME as propellant in an aerosol can.


Example 33
Volumizing Aerosol Foam


















VP/Methacrylamide/Vinyl Imidazole Copolymer
1.9



(Luviset ® Clear)



Polyquaternium-4 (Celquat ® L200)
0.9



VP/Vinyl Caprolactam/DMAPA Acrylates
0.4



Copolymer (Aquaflex ® SF 40)



Laureth-4
0.2



Cetrimonium chloride
0.1



Perfume
0.1



Butane
2.2



Propane
3



Isobutane
0.8



Water
ad 100










The composition is bottled in an aerosol can with foaming head. Through use of the product on the hair, the hairstyle is given long-lasting volume.


Example 34
Volumizing Aerosol Foam


















VP/Methacrylamide/Vinyl Imidazole Copolymer
1.1



(Luviset ® Clear)



Chitosan
1.0



Polyquaternium-4 (Celquat ® L200)
0.9



VP/Vinyl Caprolactam/DMAPA Acrylates
0.4



Copolymer (Aquaflex ® SF 40)



Pyrrolidone carboxylic acid
0.85



Laureth-4
0.2



Cetrimonium chloride
0.1



Perfume
0.1



Butane
2.2



Propane
3



Isobutane
0.8



Water
ad 100










The composition is bottled in an aerosol can with foaming head. Through use of the product on the hair, the hairstyle is given long-lasting volume.


Example 35
Volumizing Aerosol Foam


















VP/Methacrylamide/Vinyl Imidazole Copolymer
2.0



(Luviset ® Clear)



Chitosan
0.27



Polyquaternium-4 (Celquat ® L200)
1.0



Pyrrolidone carboxylic acid
0.23



Laureth-4
0.2



Cetrimonium chloride
0.1



Perfume, preservative
q.s.



Water
ad 100










The composition is bottled with propane/butane 4.8 bar in the ratio of active ingredient solution:propellant gas=94:6 in an aerosol can with foaming head. Through use of the product on the hair, the hairstyle is given long-lasting volume.

Claims
  • 1. A hair-treatment agent with a content of a combination of (A) a terpolymer constructed from vinylpyrrolidone, methacrylamide and vinylimidazole and(B) at least one active ingredient or additive chosen from viscosity-modifying substances, haircare substances, hair-setting substances, silicone compounds, photoprotective substances, oils, waxes, preservatives, pigments, soluble dyes, particulate substances, and surfactants
  • 2. The agent as claimed in claim 1, characterized in that the terpolymer (A) is present in an amount of from 0.1 to 10% by weight and that the viscosity-modifying substance present in an amount of from 0.1 to 5% by weight is, a thickening polymer, chosen from copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, and at least one second monomer type, which is chosen from esters of acrylic acid and ethoxylated fatty alcohol; crosslinked polyacrylic acid; crosslinked copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, and at least one second monomer type, which is chosen from esters of acrylic acid with C10- to C30-alcohols; copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, and at least one second monomer type, which is chosen from esters of itaconic acid and ethoxylated fatty alcohol; copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, at least one second monomer type, which is chosen from esters of itaconic acid and ethoxylated C10- to C30- alcohol and a third monomer type, chosen from C1- to C4-aminoalkyl acrylates; copolymers of two or more monomers chosen from acrylic acid, methacrylic acid, acrylic esters and methacrylic esters; copolymers of vinylpyrrolidone and ammonium acryloyldimethyltaurate; copolymers of ammonium acryloyldimethyltaurate and monomers chosen from esters of methacrylic acid and ethoxylated fatty alcohols; hydroxyethylcellulose; hydroxypropylcellulose; hydroxypropylguar; glyceryl polyacrylate; glyceryl polymethacrylate; copolymers of at least one C2-, C3- or C4-alkylene and styrene; polyurethanes; hydroxypropyl starch phosphate; polyacrylamide; copolymer of maleic anhydride and methyl vinyl ether crosslinked with decadiene; carob seed flour; guar gum; xanthan; dehydroxanthan; carrageenan; karaya gum; hydrolyzed corn starch; copolymers of polyethylene oxide, fatty alcohols and saturated methylenediphenyl diisocyanate.
  • 3. The agent as claimed in claim 1 characterized in that the haircare or hair-setting substance present is a polymer with anionic or anionizable groups, chosen from terpolymers of acrylic acid, ethyl acrylate and N-tert-butylacrylamide; crosslinked or uncrosslinked vinyl acetate/crotonic acid copolymers; terpolymers of tert-butyl acrylate, ethyl acrylate and methacrylic acid; sodium polystyrenesulfonate; copolymers of vinyl acetate, crotonic acid and vinyl propionate; copolymers of vinyl acetate, crotonic acid and vinyl neodecanoate; aminomethylpropanol acrylate copolymers; copolymers of vinylpyrrolidone and at least one further monomer chosen from acrylic acid, methacrylic acid, acrylic esters and methacrylic esters; copolymers of methyl vinyl ether and maleic monoalkyl esters; aminomethylpropanol salts of copolymers of allyl methacrylate and at least one further monomer chosen from acrylic acid, methacrylic acid, acrylic esters and methacrylic esters; crosslinked copolymers of ethyl acrylate and methacrylic acid; copolymers of vinyl acetate, mono-n-butyl maleate and isobornyl acrylate; copolymers of two or more monomers chosen from acrylic acid, methacrylic acid, acrylic esters and methacrylic esters, copolymers of octylacrylamide and at least one monomer chosen from acrylic acid, methacrylic acid, acrylic esters and methacrylic esters; polyesters of diglycol, cyclohexanedimethanol, isophthalic acid and sulfoisophthalic acid.
  • 4. The agent as claimed in claim 1 characterized in that the haircare or hair-setting substance present is a polymer with cationic or cationizable groups chosen from cationic cellulose derivatives of hydroxyethylcellulose and diallyldimethylammonium chloride; cationic cellulose derivatives of hydroxyethylcellulose and with trimethylammonium substituted epoxide; poly(dimethyldiallylammonium chloride); copolymers of acrylamide and dimethyldiallylammonium chloride; quaternary ammonium polymers formed by the reaction of diethyl sulfate and a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate; quaternary ammonium polymers of methylvinylimidazolium chloride and vinylpyrrolidone; polyquaternium-35; polymer of trimethylammonium-ethyl methacrylate chloride; polyquaternium-57; dimethylpolysiloxanes terminally substituted by quaternary ammonium groups; copolymer of vinylpyrrolidone, dimethylaminopropylmethacrylamide and methacryloylaminopropyllauryldimethylammonium chloride; chitosan and salts thereof; hydroxyalkylchitosans and salts thereof; alkylhydroxyalkylchitosans and salts thereof; N-hydroxyalkylchitosan alkyl ethers; N-hydroxyalkylchitosan benzyl ethers; copolymer of vinylcaprolactam, vinylpyrrolidone and dimethylaminoethyl methacrylate; copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, copolymers of vinylpyrrolidone, vinylcaprolactam and dimethylaminopropylacrylamide; polyesters or oligoesters constructed from at least one first monomer type which is chosen from hydroxy acid substituted by at least one quaternary ammonium group.
  • 5. The agent as claimed in claim 1 characterized in that the haircare or hair-setting substance present is a zwitterionic and/or an amphoteric polymer chosen from copolymers of octylacrylamide, acrylic acid, butylaminoethyl methacrylate, methyl methacrylate and hydroxypropyl methacrylate; copolymers of lauryl acrylate, stearyl acrylate, ethylamine oxide methacrylate and at least one monomer chosen from acrylic acid, methacrylic acid, acrylic esters and methacrylic esters; copolymers of methacryloylethylbetaine and at least one monomer chosen from methacrylic acid and methacrylic esters; copolymers of acrylic acid, methyl acrylate and methacrylamidopropyltrimethylammonium chloride; oligomers or polymers preparable from quaternary croton betaines or quaternary croton betaine esters.
  • 6. The agent as claimed in claim 1 characterized in that the haircare or hair-setting substance present is a nonionic polymer chosen from polyvinylpyrrolidone, polyvinylcaprolactam, vinylpyrrolidone/vinyl acetate copolymers, polyvinyl alcohol, isobutylene/ethylmaleimide/hydroxyethylmaleimide copolymer; copolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate.
  • 7. The agent as claimed in claim 1 characterized in that at least one silicone compound is present chosen from cyclic dimethylsiloxanes, linear polydimethylsiloxanes, block polymers of polydimethylsiloxane and polyethylene oxide and/or polypropylene oxide, polydimethylsiloxanes with terminal or lateral polyethylene oxide or polypropylene oxide radicals, polydimethylsiloxanes with terminal hydroxyl groups, phenyl-substituted polydimethylsiloxanes, silicone emulsions, silicone elastomers, silicone waxes, silicone gums and amino-substituted silicones.
  • 8. The agent as claimed in claim 1 characterized in that at least one photo-protective substance is present chosen from 2-ethylhexyl 4-methoxycinnamate, methyl methoxycinnamate, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and polyethoxylated p-aminobenzoates.
  • 9. The agent as claimed in claim 1 characterized in that at least one oil or wax is present chosen from paraffin waxes, polyolefin waxes, wool wax, wool wax alcohols, candelilla wax, olive wax, carnauba wax, Japan wax, apple wax, hydrogenated fats, fatty acid esters, fatty acid glycerides, fatty acid triglycerides, mineral oils, isoparaffin oils, paraffin oils, squalane, sunflower oil, coconut oil, castor oil, lanolin oil, jojoba oil, corn oil, soybean oil.
  • 10. The agent as claimed in claim 1 characterized in that at least one haircare or hair-setting substance is present chosen from betaine; panthenol; panthenyl ethyl ether; sorbitol; protein hydrolysates; plant extracts; A-B block copolymers of alkyl acrylates and alkyl methacrylates; A-B block copolymers of alkyl methacrylates and acrylonitrile; A-B-A block copolymers of lactide and ethylene oxide; A-B-A block copolymers of caprolactone and ethylene oxide; A-B-C block copolymers of alkylene or alkadiene compounds, styrene and alkyl methacrylates; A-B-C block copolymers of acrylic acid, styrene and alkyl methacrylates; star-shaped block copolymers; hyperbranched polymers, dendrimers, intrinsically electrically conductive 3,4-polyethylenedioxythiophenes and intrinsically electrically conductive polyanilines.
  • 11. The agent as claimed in claim 1 characterized in that at least one surfactant is present chosen from addition products of from 2 to 30 mol of ethylene oxide and/or 1 to 5 mol of propylene oxide onto C8- to C22-fatty alcohols, addition products of from 2 to 30 mol of ethylene oxide and/or 1 to 5 mol of propylene oxide onto C12- to C22-fatty acids, addition products of from 2 to 30 mol of ethylene oxide and/or 1 to 5 mol of propylene oxide onto alkyl phenols having 8 to 15 carbon atoms in the alkyl group, C12- to C22-fatty acid mono- and diesters of addition products of from 1 to 30 mol of ethylene oxide onto glycerol, addition products of from 5 to 60 mol of ethylene oxide onto castor oil or onto hydrogenated castor oil, mono-, di- or triesters of phosphoric acid with addition products of from 2 to 30 mol of ethylene oxide onto C8- to C22-fatty alcohols, esters of sucrose and one or two C8- to C22-fatty acids, esters of sorbitan and one, two or three C8- to C22-fatty acids and a degree of ethoxylation of from 4 to 20, polyglyceryl fatty acid esters of one, two or more C8- to C22-fatty acids and polyglycerol having 2 to 20 glyceryl units, alkyl glycosides, C8-22-alkyldimethylbenzylammonium compounds, C8-22-alkyltrimethylammonium compounds, C8-22-alkyldimethylhydroxyethylammonium compounds, di(C8-22-alkyl)dimethylammonium compounds, C8-22-alkylpyridinium salts, C8-22-alkylamidoethyltrimethylammonium ether sulfates, C8-22-alkylmethylamine oxides, C8-22-alkylaminoethyldimethylamine oxides.
  • 12. The agent as claimed in claim 1 characterized in that a preservative is present chosen from phenoxyethanol, benzyl paraben, butyl paraben, ethyl paraben, isobutyl paraben, isopropyl paraben, methyl paraben, propyl paraben, methyldibromoglutaronitrile, DMDM hydantoin.
  • 13. The agent as claimed in claim 1 characterized in that at least one pigment is present chosen from titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultramarine (CI 77007), chromium oxide hydrate (CI 77289), Prussian blue (CI 77510), bismuth oxychloride (CI 77163), carmine (cochineal), pearlescent and colored pigments based on mica which are coated with a metal oxide or a metal oxychloride, such as titanium dioxide or bismuth oxychloride, and optionally further color-imparting substances, such as iron oxides, iron blue, ultramarine or carmine and where the color is determined by varying the layer thickness.
  • 14. The agent as claimed in claim 1 characterized in that at least one particulate substance is present chosen from silica, silicates, aluminates, clay earths, mica, insoluble metal salts, metal oxides, minerals and insoluble polymer particles.
  • 15. The agent as claimed in claim 1 characterized in that it is in the form of a gel, in the form of a viscous lotion or in the form of a spray gel which is sprayed with a mechanical device, comprises at least one thickening polymer according to claim 2 and has a viscosity of at least 250 mPa s (measured using a Bohlin rheometer CS, measurement body C25 at 25° C. and a shear rate of 50 s−1).
  • 16. The agent as claimed in claim 1 characterized in that it is in the form of an O/W emulsion, a W/O emulsion or a microemulsion, and comprises at least one oil or wax according to claim 9, and at least one surfactant according to claim 11.
  • 17. The agent as claimed in claim 1 characterized in that it is in the form of a spray product and is either in combination with a mechanical pump spray device or in combination with at least one propellant chosen from propane, butane, dimethyl ether and fluorinated hydrocarbons.
  • 18. The agent as claimed in claim 1 characterized in that it is in the form of a foamable product in combination with a device for foaming, comprises at least one foam-forming surfactant or at least one foam-forming polymer and is either in combination with a mechanical pump foam device or in combination with at least one propellant chosen from propane, butane, dimethyl ether and fluorinated hydrocarbons.
  • 19. The agent as claimed in claim 1 characterized in that it is in the form of a hair wax.
  • 20. The agent as claimed in claim 1 characterized in that it is in the form of a foamable product in combination with a device for foaming, comprises at least one foam-forming surfactant or at least one foam-foaming polymer and is either in combination with a mechanical pump foaming device or in combination with at least one propellant, and the active ingredient or additive is chosen from chitosan, chitosan salts, chitosan derivatives, cationic cellulose compounds, copolymers of vinylpyrrolidone, vinylcaprolactam and a basic acrylamide monomer or mixtures of these polymers.
  • 21. The agent as claimed in claim 20, characterized in that the active ingredient or additive is chosen from chitosan, chitosan salts, copolymers of hydroxyethylcellulose and diallyldimethylammonium chloride (polyquaternium-4), copolymers of vinylpyrrolidone, vinylcaprolactam and dimethylaminopropylacrylamide or mixtures of these polymers.
  • 22. The agent as claimed in claim 20 characterized in that either copolymers of hydroxyethylcellulose and diallyldimethylammonium chloride (polyquaternium-4) or copolymers of vinylpyrrolidone, vinylcaprolactam and dimethylaminopropylacrylamide are present.
  • 23. The agent as claimed in claim 20 characterized in that either copolymers of hydroxyethylcellulose and diallyldimethylammonium chloride (polyquaternium-4), or copolymers of vinylpyrrolidone, vinylcaprolactam and dimethylaminopropylacrylamide, or at least one chitosan salt are present.
Priority Claims (1)
Number Date Country Kind
202004002471.3 Feb 2004 DE national
PCT Information
Filing Document Filing Date Country Kind 371c Date
PCT/EP05/01693 2/18/2005 WO 00 5/4/2007