The present invention generally relates to the construction of the hearth of a metallurgical reactor, in particular of an iron-making furnace such as a blast furnace. More specifically, the invention relates to the configuration of the refractory that lines the wall of the hearth.
A hearth of a metallurgical furnace usually has an outer steel shell, typically with at least one taphole for tapping molten metal, and a lining of refractory material for containing the molten metal bath at high temperatures, in excess of 1100° C. The lining includes a lateral lining of the shell, hereinafter called wall lining, and a lining in the bottom of the hearth i.e. the hearth pad.
In the field of blast furnaces, there are various approaches for constructing a wall lining. In a well-known approach, the wall lining is a brickwork of multiple concentric rings of comparatively small bricks. These are typically made of high-conductivity hot-pressed carbon. Another approach uses comparatively larger blocks of refractory, typically also of carbonaceous material (including carbon, hot-pressed carbon, graphite, semi-graphite and hot-pressed semi-graphite). Usually, large blocks are installed in a single thickness reaching from the shell to the hot face so that the lining consists of the same material over its entire cross-section. A further known approach, which aims at increasing protection and durability of the wall lining, consists in providing an additional so-called ceramic cup including a lateral inner layer of high-melting point ceramics, e.g. high alumina content pre-cast blocs, for protecting the carbonaceous blocs of the wall lining. Also well-known are hearth configurations with a composite lining of two annular layers of different materials. Usually, materials are used so that thermal conductivity of the outer layer is higher than that of the inner layer with the hot face in contact with molten iron.
A composite lining configuration, especially for the bosh and for the shaft zone of a blast furnace is disclosed for example in U.S. Pat. No. 3,953,007. This patent suggests two separate layers of different carbonaceous refractory material e.g. an outer layer of high-thermal conductivity graphite blocs and an inner layer of silicon-carbide having high resistance to wear and chemical attack. In fact, in the field of blast furnace refractories it is known to add silicon carbide or silicon metal to the carbonaceous mix in order to improve (reduce) permeability, reduce pore sizes and improve abrasion resistance.
Concerning the hearth wall lining more specifically, a similar layered approach is proposed in U.S. Pat. No. 3,520,526. This patent suggests providing two layers of substantially equal thickness, with the thickness of the outer layer being preferably from 0.8 to 1.2 times that of the inner layer. More specifically, U.S. Pat. No. 3,520,526 suggests that the radially outer layer, which is in contact with the cooling system, e.g. with the staves, should have a thermal conductivity that is substantially higher than that of the radially inner layer, in particular at least five times higher.
Durability of the refractory lining of the furnace hearth is a critical factor as regards campaign duration, since failure of the refractory lining is one of the most common reasons for premature shut-downs. Accordingly, in order to achieve the desired campaign duration, sophisticated refractory materials and configurations are state-of-the-art and related expenses are accepted. Required qualities are among others: good resistance to erosion by molten pig iron, good resistance to oxidation, low carburization dissolution rate, high mechanical strength and high thermal conductivity to maintain the hot face at a temperature as low as possible. Consequently, considering the total construction cost of a hearth, the refractory lining on its own may well make up more than two thirds (66%) of the total cost, i.e. exceed the cost of the steel shell and the hearth cooling system. Obviously, in case of a reline keeping the existing shell and cooling construction, the refractory constitutes an even more important proportion in total cost.
On the other hand, as is also well-known, there is an ongoing trend towards ever increasing production rates. The production capacity of a blast furnace is limited, among others but in notable manner, by the useful internal volume of the hearth, which volume is radially limited by the lining thickness and the shell diameter.
In view of the foregoing, there is obviously a desire for reducing the total wall thickness of the hearth wall lining so as to achieve either, or preferably both, of the benefits of reduced lining cost and increased useful internal volume of the hearth.
Accordingly, the invention provides a hearth configuration for a metallurgical furnace, in particular for a blast furnace, which permits a reduction of the wall thickness (i.e. thickness in radial direction) of the wall lining with minimum or no adverse impact on durability of the wall lining.
In known manner, the hearth of a metallurgical reactor, in particular of a blast furnace, comprises an outer metallic support structure (hereinafter: the shell), which, in case of a blast furnace, has at least one tap hole for tapping molten metal. For containing the bath including molten metal, the hearth has an annular fully circumferential wall lining of refractory material that is contained inside the shell and that is typically backed by a cooling system, e.g. outer rings of stave coolers between the shell and the lining. The present invention is specifically concerned with the configuration of the lower region of the wall lining, which is most typically exposed to the most severe conditions. In a blast furnace, the lower region is located below the tap hole. In accordance with the invention, this lower region includes a first radially inner layer that faces the interior of the hearth and comprises at least one and typically several vertically stacked rings of refractory elements, e.g. small bricks or comparatively large blocks. The lower region further comprises a second radially outer layer that faces the outer shell and backs the inner layer. The outer layer also comprises at least one and typically several vertically stacked rings of refractory elements. Further in accordance with the invention, at least one of the inner rings in the lower region comprises elements made of a first carbonaceous refractory material that is different from the one or more carbonaceous refractory materials of which the elements in the outer layer are made.
According to an important aspect of the invention, the carbonaceous refractory material of the at least one inner ring is a high-performance refractory that, to this effect, contains at least one property-enhancing additive, in a proportion of at least 5% by mass in total, that is not contained in the refractory material of the elements in the outer layer and that is provided in addition to or as an alternative to either or both of the well-known property-enhancing additives metallic silicon and silicon carbide, which are comparatively inexpensive.
According to another important aspect, the at least one inner ring has a thickness of less than 45%, preferably less than 35%, of the total wall thickness of the wall lining at the height of the inner ring in question.
As will be appreciated, the present invention proposes proceeding contrary to accepted practice and widely held belief, according to which the more economical i.e. less expensive refractory should be placed at the exposed hot face (see for instance the aforementioned U.S. Pat. No. 3,520,526). Moreover, in the course of developments leading to the present invention, it has been theorized that even a comparatively small thickness of high-performance refractory, e.g. a TiC boosted refractory, when located on the exposed surface, may lead to significantly increased lining performance and durability. Accordingly, the proposed configuration allows reducing the thickness of the backing outer layer and more generally the total wall lining thickness significantly when compared to the prior art. Moreover, the proposed configuration is expected to enable, at considerably lower cost, a lining performance equivalent to what has hitherto been achievable only with a full-extent thickness (hot face to cold face) of corresponding high-performance refractory material. Thus, constituting an inner layer with a refractory material having improved properties, e.g. increased resistance to wear by liquid hot metal, allows to reduce wall lining thickness with minimum or no adverse impact on durability of the wall lining.
According to an important aspect of the invention, the first refractory material contains 50-85% by mass of carbon and, as an additional property-enhancing additive, 5-20% by mass in total of one or more material(s) chosen from the group of metallic titanium, titanium carbide, titanium nitride and titantium carbonitride or titanium oxide. A most preferable refractory further contains 5-15% by mass in total of metallic silicon; and 5-15% by mass in total of alumina. An exemplary method for making such a refractory is known e.g. from EP 1 275 626. According to another aspect, the first refractory material preferably has a thermal conductivity of at least 15 W/mK at 600° C., as is achieved with this most preferred refractory for example.
According to an important aspect of the invention, the at least one inner ring comprises elements having an anchoring portion on their outer face and the at least one outer ring comprises elements having an anchoring portion on their inner face, each pair of anchoring portions cooperating for securing against radially inward and circumferentially tangential dislocation an element of the inner ring to a corresponding element of the outer ring. As will be appreciated, this configuration enables a further reduction of the thickness of the inner layer without compromising mechanical stability of its construction as opposed to a simple masonry-like construction. In this configuration, the cooperating anchoring portions preferably have conjugated, ideally smoothly rounded, shapes that provide a continuous gap in between the outer and inner faces of facing elements.
With the aforementioned anchoring, the at least one outer ring can beneficially comprise large-width blocks made of a second carbonaceous refractory material, the at least one outer ring comprising large-width blocks that have a width greater than 65% of the total wall thickness of the wall lining at the height of the outer ring. Accordingly, the at least one inner ring can comprises small-width blocks having a width of less than 35% of the total wall thickness of the wall lining at this height. In a preferred and simple type of anchoring, the at least one inner ring has small-width blocks with a mushroom-shaped anchoring protrusion on their outer face whereas the at least one outer ring has large-width blocks with a conjugated mushroom-shaped anchoring recess on their inner face. The protrusions and recesses are thus engaged and cooperated to secure the small-width blocks against radially inward and circumferentially tangential dislocation with respect to the large-width blocks so as to further increase constructional stability. In a configuration that reduces manufacturing cost by reducing the amount of special block with anchoring means, the at least one inner ring comprises small-width blocks of a first type and small-width blocks of a second type that are arranged in alternating fashion. The first type has an anchoring portion whereas the second type is devoid of anchoring portion. In order to secure the second type of small-width blocks, the first and second type of small-width blocks have respective conjugated horizontal cross-sections.
In a preferred embodiment, the lower region further comprises an intermediate ramming layer that extends vertically in between the outer and the inner layer. Preferably, this ramming layer is made of a composition that comprises: a fine granular phase comprising graphite and a coarse granular phase comprising microporous carbon.
In a most simple construction, the inner ring is made, in radial direction, of a single refractory block having a width equal to the thickness of the inner ring and, similarly, the outer ring is made, in radial direction, of a single refractory block having a width equal to the thickness of the outer ring. Typically, the inner layer comprises a vertical sequence of at least two, preferably three to four, vertically stacked inner rings of refractory elements, in particular refractory blocks, made of the first refractory material.
Concerning achievable reductions in total wall-thickness, in case the inner layer forms the hot face of the lining, the inner layer can have a thickness in the range of 200 mm to 600 mm, preferably in the range of 250 to 550 mm, and the wall lining has a total wall thickness of less than 1350 mm, preferably less than 1100 mm (at the level of the lowermost inner ring). In case a ceramic cup is provided to form the hot face, the inner layer has a thickness in the range of 250 mm to 400 mm and the wall lining, including the ceramic layer, has a total wall thickness of less than 1500 mm (at the level of the lowermost inner ring).
As will be understood, a hearth according the present invention is, although not exclusively, particularly suited for industrial application in a blast furnace, either as a retrofit by relining an existing furnace or as a design for a new construction.
Further details and advantages of the present invention will be apparent from the following detailed description of several not limiting embodiments with reference to the attached drawings, wherein:
Throughout these drawings, features which have substantially identical function or structure are referred to by identical reference numerals.
The annular wall lining 16 extends over the full circumference of the hearth 10 and has, except for a limited circumferential angular sector around the taphole(s) 14 having an extent of 10-35°, a rotationally symmetrical configuration as shown in
The present invention is specifically concerned with the configuration of a lower region of the wall lining 16, as illustrated at “h” in
According to section lines IB-IB of
More specifically, as shown in
More specifically and according to the invention, the refractory blocks 21 of the inner ring 24 are made of a special high-performance carbonaceous first refractory material that contains as significant proportion of at least 5% by mass in total of a special property-enhancing additive in addition to or as an alternative to well-known metallic silicon and/or silicon carbide. Preferred carbonaceous refractory materials contain 50-85% by mass of carbon and, as a property-enhancing additive, 5-20% by mass in total of one or more material(s) chosen from the group of metallic titanium, titanium carbide, titanium nitride, titantium carbonitride or titanium oxide. Most preferably, a titanium carbide or titantium carbonitride (TiC) enhanced refractory according to EP 1 275 626, the contents of which are incorporated by reference herein, is used for making the blocks 21 of the inner rows 24. The refractory according to EP 1 275 626 further comprises 5-15% by mass in total of metallic silicon and 5-15% by mass in total of alumina. Other high-performance refractories are not excluded for producing refractory blocks 21 suitable for use in the inner rings 24 according to the invention. Other additives include graphite particles and ceramics other than silicon carbide, which may be included in the carbonaceous refractory material to improve its properties. Another less-preferred refractory is known from U.S. Pat. No. 3,007,805, which proposes, among others, a zirconium carbide-bonded graphite refractory as an alternative to a silicon carbide-bonded graphite refractory. However, in the inner refractory blocks 21, a refractory material according to EP 1 275 626, as available e.g. under the commercial designation BC-15SRT from Nippon Electrode Company Ltd, is preferred because of its additional resistance against carburization dissolution, especially in case the bath 10 is not saturated in carbon (e.g. in view of reducing carbon oxide emissions).
In the embodiment illustrated in
Further according to the invention and as illustrated (not to scale) in
As further seen in
A specific preferred example of a configuration of the lower region below the taphole 14 of the wall lining 16 according to the above description of
As will be appreciated, the proposed wall lining 16 has the incontestable merit of minimizing the required total quantity of high-performance refractory, e.g. BC-15 SRT, and related cost while nevertheless reducing the total wall thickness (D) and maintaining a durable long-life configuration of the wall lining 16. As will be noted, a total wall thickness D of about 1200 mm, which is the maximum wall thickness at the lowermost row of blocks, represents a considerable reduction of up to 25% or more by comparison to functionally equivalent prior art linings that have typical wall thicknesses in the order of 1700-2000 m.
The embodiment of
Hereinafter, only major differences and relevant common features of the wall lining 216 with respect to that of
The wall lining 216, as best seen in
To this effect, as best seen in the enlarged view of
Furthermore, as best seen by virtue of different hatching in
As will also be noted, in the embodiment of
Accordingly, as seen in
Accordingly, the embodiment of
Another preferred embodiment of a wall lining 416 is illustrated in
In conclusion, as will be appreciated, a configuration of the wall lining 16, 216, 316, 416 according to the present invention permits achieving a total wall thickness D of the wall lining 16 of less than 1350 mm, even less than 1100 mm, in case no ceramic layer 300 is provided, and less than 1500 in case a ceramic layer 300 is provided. This is achieved in cost effective manner by providing a multi-layer wall lining 16 by virtue of a small-width inner layer of high-performance carbonaceous refractory that has a width d of less than 600 mm, preferably less than 400 mm.
While not being limited in application thereto, the present invention is particularly applicable to blast furnace hearths 10.
Number | Date | Country | Kind |
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91 713 | Jul 2010 | LU | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP11/62852 | 7/26/2011 | WO | 00 | 1/25/2013 |