Heat curable composite textile

Information

  • Patent Grant
  • 11806920
  • Patent Number
    11,806,920
  • Date Filed
    Wednesday, May 15, 2019
    5 years ago
  • Date Issued
    Tuesday, November 7, 2023
    7 months ago
Abstract
A heat curable, circular knitted fabric includes reinforcing and meltable resin fibers that can be cured to form a more rigid material form. In one embodiment, the fabric includes a core spun yarn, wherein the core may be made from glass, carbon, basalt, aramid or metal. The wrap surrounding the core may include resin type fibers such as Poly(p-phenylene sulfide) PPS, Polyetherimide (PEI), Polyether ether ketone (PEEK), Polysulfone (PES), Polyphthalamide (PPA), nylon, polyester, or polypropylene.
Description
BACKGROUND OF THE INVENTION

The present invention relates generally to heat curable composite textile fabrics that may be cured to form a more rigid, non-flammable, heat resistant and insulating fabric. More specifically, the present invention includes a heat curable, circular or warp knitted fabric containing reinforcing and meltable resin fibers that can be cured to produce a more rigid material form. This composite textile may be used in any application that requires a rigid, heat resistant, non-flammable insulation or sleeve positioned around machine components having a specific shape. Application examples include exhaust insulation covers, pipe insulation covers, machinery covers (such as covers for turbines), rigid fire barrier panels, gun barrel covers, engine component covers, and the like.


Traditional composite structures are typically woven or axial fabric with longitudinal fibers to maximize composite strength and rigidity, but typically require a liquid resin and some form of molding, usually compression molding or vacuum molding, which are time consuming and expensive manufacturing processes that require complex equipment.


Compression molding is a forming process in which a plastic material is placed directly into a heated metal mold, then is softened by the heat, and forced to conform to the shape of the mold as the mold closes. The compression molding starts, with an allotted amount of plastic or gelatin placed over or inserted into a mold. Afterward the material is heated to a pliable state in and by the mold. Shortly there after the hydraulic press compresses the pliable plastic against the mold, resulting in a perfectly molded piece, retaining the shape of the inside surface of the mold. After the hydraulic press releases, an ejector pin in the bottom of the mold quickly ejects the finish piece out of the mold and then the process is finished. Compression molding is a high-volume, high-pressure method suitable for molding complex, high-strength fiberglass reinforcements. Advanced composite thermoplastics can also be compression molded with unidirectional tapes, woven fabrics, randomly oriented fiber mat or chopped strand. The advantage of compression molding is its ability to mold large, fairly intricate parts. However, compression molding often provides poor product consistency and difficulty in controlling flashing, and it is not suitable for some types of parts. Fewer fiber lines are produced and a smaller amount of fiber-length degradation is noticeable when compared to injection molding. Compression-molding is also suitable for ultra-large basic shape production in sizes beyond the capacity of extrusion techniques. Materials that are typically manufactured through compression molding include: Polyester fiberglass resin systems (SMC/BMC), Torlon, Vespel, Poly(p-phenylene sulfide) (PPS), and many grades of PEEK.


Vacuum molding or forming is a simplified version of thermoforming, whereby a sheet of plastic is heated to a forming temperature, stretched onto or into a single-surface mold, and held against the mold by applying a vacuum between the mold surface and the sheet. The vacuum forming process can be used to make most product packaging, speaker casings, and even car dashboards. Vacuum forming is usually, but not always, restricted to forming plastic parts that are rather shallow in depth. A thin sheet is formed into rigid cavities for unit doses of pharmaceuticals and for loose objects that are carded or presented as point-of-purchase items. Thick sheet is formed into permanent objects such as turnpike signs and protective covers. Relatively deep parts can be formed if the form-able sheet is mechanically or pneumatically stretched prior to bringing it in contact with the mold surface and before vacuum is applied. Suitable materials for use in vacuum forming are conventionally thermoplastics. The most common and easiest to use thermoplastic is High Impact Polystyrene Sheeting (HIPS). This is molded around a wood, structural foam or cast/machined aluminum mold and can form to almost any shape.


Each of these methods has disadvantages, including expensive equipment and time-consuming processes. Thus, there is a need for a composite textile material that may be cured and formed into any desired shape, wherein the final material becomes more rigid, tough, and is resistant to heat. Further, there is a need for a more cost-effective, less time-consuming process for manufacturing such a product. It would be desirable to provide a product and method for applying a protective cover or wrap to mechanical components of various shapes and sizes, without having to produce individual molds for each specific cover.


For example, a company may produce thousands of different components of varying shapes and sizes, many of which require a cover or wrap for purposes of insulation and protection against heat and corrosion. In order to provide such covers or wraps for these various components using compression molding or vacuum molding, it would be necessary to provide a mold for each section of covering to be applied to the thousands of corresponding components to be wrapped or covered. Thus, the present invention is directed to a product and process that may be used to apply these wraps or covers to components of any size and shape, without the necessity of providing individual molds for each different size or shape.


BRIEF SUMMARY OF THE INVENTION

In accordance with one aspect of the invention, a heat curable, circular or warp knitted fabric includes reinforcing and meltable resin fibers that can be cured to form a more rigid material form. In one embodiment, the fabric includes a core spun yarn, wherein the core may be made from glass, carbon, basalt, aramid or metal. The wrap surrounding the core may include resin type fibers such as Poly(p-phenylene sulfide) PPS (sold under the trade name Ryton), Polyetherimide (PEI) sold under the trade name Ultem, Polyether ether ketone (PEEK), Polysulfone (PES), Polyphthalamide (PPA), nylon, polyester, or polypropylene. Reinforcing fibers can additionally be added to the wrap. The fabric may contain from about 10% to 100% of the core spun yarn.


In use, the core spun yarn is knitted into a circular or warp knit fabric, which may optionally include reinforcing fibers. The circular knit fabric may then be heat molded into any desired shape to serve as a protective covering for a mechanical or industrial component, or may be cut and sewn into or onto custom parts and then cured on the part or item.





DESCRIPTION OF THE DRAWINGS

These and other features, aspects, and advantages of the present invention will become better understood with regard to the following description, appended claims, and accompanying drawings where:



FIG. 1 is a perspective view of one embodiment of a protective cover in accordance with the present invention, wherein a pipe is wrapped with a heat curable knit fabric cover formed at least partially from core spun yarn;



FIG. 2 is a cross-sectional view of one embodiment of the protective cover shown in FIG. 1, wherein the protective cover is a fitted sleeve formed from a circular knit;



FIG. 3 is a cross-sectional view of one embodiment of a protective cover, wherein the protective cover has been cut and sewn and then fitted onto a pipe, and wherein the seam is shown on an underside of the protective cover; and



FIG. 4 is a cross-sectional view of one embodiment of a core spun yarn, having a core yarn made from multiple fibers and a meltable wrap, also made from multiple fibers, wherein the wrap is disposed about the core yarn.





DETAILED DESCRIPTION OF THE INVENTION

The present invention includes, in a first embodiment, a heat curable, knitted fabric 10 containing yarn with a meltable resin outer layer, as well as optional reinforcing fibers, which can be cured to produce a more rigid material form that can be used to serve as a protective wrap or cover 14 for various types of mechanical or industrial components, or other similar applications. In one embodiment, the fabric 10 includes a core spun yarn 12. Typically, core spun yarn is a yarn consisting of an inner core yarn 16 surrounded by staple fibers. A core spun yarn 12 combines the strength and/or elongation of the core thread 16 and the characteristics of the staple fibers which form the outer surface, or the “wrap” 18, as shown in FIG. 4. In the present case, the core spun yarn includes a core 16 preferably made from fibers of glass, carbon, basalt, aramid or metal. The meltable wrap 18 surrounding the core may include one or more of resin type fibers such as Poly(p-phenylene sulfide) PPS (sold under the trade name Ryton), Polyetherimide (PEI) sold under the trade name Ultem, Polyether ether ketone (PEEK), Polysulfone (PES), Polyphthalamide (PPA), nylon, polyester, or polypropylene. The meltable wrap may contain more than one type of resin fiber and may also include reinforcing fibers. In a preferred embodiment, the meltable wrap 18 is made from material having a melting point of at least about 250° F., and preferably at least about 400° F. Reinforcing fibers can additionally be added to the textile composite fabric together with the core spun yarn 12, wherein the reinforcing fibers include but are not limited to glass, carbon, aramid, or metal. The fabric 10 may contain from about 10% to 100% of the core spun yarn 12, depending on the desired properties and function of the final product, and the rest of the fabric 10 may comprise reinforcing fibers or yarns.


After the core spun yarns 12 (and optionally, the reinforcing fibers) have been formed into a knit composite textile material (preferably circular or warp knit), the composite textile fabric 10 may be cut and sewn into a preformed article and then positioned on or around a component or item, as shown in FIGS. 1 and 3, wherein the textile material is disposed about a pipe in the form of a cover 14. Then, heat may be applied to the covered component, so that the meltable wrap 18 of the core spun yarn 12 melts (wholly or partially) and then the fabric 10 re-hardens into the desired shape around the component. It is preferable to provide a core spun yarn 12 having a meltable wrap 18 made from material that has a melting point higher than the operating temperature of the component, so that the wrap 18 does not melt during operation or use of the component. Thus, the core spun yarn 12 may be specifically engineered for specific components or purposes, based on the estimated operating temperature of the covered component.


In an alternate embodiment, the yarn may be knitted into a tape or slit into a tape, wrapped around an item and cured as above.


In another alternate embodiment, the fabric 10 may be formed of a circular knit sleeve that is manufactured to specific specifications, so that the sleeve fits around a component, such as a pipe 22, as shown in FIGS. 1 and 2. It may be advantageous to provide clamps 20 (or other securing means), as shown in FIG. 1, in order to securely hold the cover 14 onto the pipe or other component.


Alternatively, after the core spun yarns 12 (and optionally, the reinforcing fibers) have been formed into a circular knit composite fabric 10, the composite fabric 10 may be placed into a mold and heated until the wrap 18 around the core 16 of the core spun yarn 12 has melted, in whole or in part. Then, when the composite fabric 10 is allowed to cool, the meltable wrap 18 hardens, so that the composite fabric 10 retains the shape of the mold.


It is contemplated that multiple layers of the composite fabric 10 material may be used together. In one embodiment, the core spun yarns 12 of the first layer are made from the same material as the second layer, which may include core spun yarns 12 alone, or may further include reinforcing fibers. In a second embodiment of the multi-layer composite textile, the core spun yarns 12 of the first layer may be formed of different material from the core spun yarns 12 of the second layer. In this way, the composite fabric 10 may be engineered to produce different features or characteristics, depending on the desired use thereof. Such characteristics may include melting point of the wraps, strength of the material, desired thickness, improved abrasion resistance, reduced cost, and improved environmental stability.


In another embodiment, a single layer knit fabric 10 is formed, wherein the yarns alternate between core spun yarn 12 and reinforcing yarn, such as glass, carbon, aramid or metal. In another embodiment, a three-dimensional knit fabric 10 may be formed, wherein the outer layer is formed of 100% core spun yarn 12, and wherein the spacer material and the inner layer is formed of 100% glass fibers. It should be understood that various types of knit constructions may be used, so long as the core spun yarns 12 are used in the range of about 10% to 100% of the fabric 10, with reinforcing yarns being used for the remainder of the fabric 10.


This composite textile fabric 10 may be used in any application that requires a rigid, heat resistant, non-flammable cover 14, insulation or sleeve positioned around machine components having a specific shape. Application examples include exhaust insulation covers, pipe insulation covers, machinery covers (such as covers for turbines), rigid fire barrier panels, gun barrel covers, engine component covers, and the like.


Because this heat curable composite textile fabric 10 is engineered to be used for a protective cover 14 over industrial and mechanical components, and the like, it need not be developed to exhibit high levels of strength and/or rigidity. Instead, the concept is to provide a textile material that may be easily shaped and molded to fit over these components, and need only have enough rigidity to maintain its shape during use. Thus, using a knit construction (which allows the textile to be formed from thicker and bulkier yarns, but does not maximize strength) is preferable to a weave, which requires less bulky yarns, and maximizes strength and rigidity. Thus, it is contemplated that the composite textile fabric 10 may be formed by utilizing various knit constructions, including but not limited to circular knits, warp knits, multi-layer fabrics and three-dimensional fabrics with spacer materials.


Although the present invention has been described in considerable detail with reference to certain preferred versions thereof, other versions are possible. Therefore, the spirit and scope of the appended claims should not be limited to the description of the preferred versions contained herein. All features disclosed in this specification may be replaced by alternative features serving the same, equivalent or similar purpose, unless expressly stated otherwise. Thus, unless expressly stated otherwise, each feature disclosed is one example only of a generic series of equivalent or similar features.

Claims
  • 1. An insulated exhaust component, the component comprising: a hollow tubular member;an insulating sleeve positioned around at least a portion of the hollow tubular member, wherein the sleeve comprises first and second layers, each of the first and second layers comprising sleeve reinforcing fibers and a heat curable material, wherein edges of the insulating sleeve are sewn together; andwherein the insulating sleeve is configured to form a rigid, heat resistant, and non-flammable cover for at least the portion of the hollow tubular member when the sleeve is heated to a predetermined temperature.
  • 2. The insulated exhaust component set forth in claim 1, wherein the sleeve reinforcing fibers are made from at least one selected from the group consisting of glass, carbon, basalt, aramid and metal.
  • 3. The insulated exhaust component set forth in claim 1, wherein the heat curable material comprises at least one selected from the group consisting of Poly(p-phenylene sulfide), Polyetherimide, Polyether ether ketone, Polysulfone, Polyphthalamide, nylon, polyester and polypropylene.
  • 4. The insulated exhaust component set forth in claim 1, wherein the insulating sleeve further comprises a core spun yarn comprising an inner core yarn surrounded by a wrap including the heat curable material.
  • 5. The insulated exhaust component set forth in claim 1, wherein the second layer comprises a core spun yarn formed into a circular knit structure, wherein the second layer is connected to and overlays the first layer of the insulating sleeve.
  • 6. The insulated exhaust component set forth in claim 1, wherein the insulating sleeve further comprises a core spun yarn comprising between about 10% and about 99% of the cover.
  • 7. The insulated exhaust component set forth in claim 1, wherein the insulating sleeve comprises a knit structure selected from the group consisting of circular knit, warp knit, multi-layer knit and a three-dimensional knit.
  • 8. The insulated exhaust component set forth in claim 1, wherein the insulated exhaust component has a predetermined operating temperature and wherein a melting point of the heat curable material is higher than the operating temperature of the insulated exhaust component.
  • 9. The insulated exhaust component set forth in claim 1, wherein the heat curable material has a melting point of at least 250ºF.
  • 10. A method of manufacturing an insulated exhaust component, the method comprising the steps of: providing a hollow tubular member;forming a rigid, heat resistant, and non-flammable cover positioned around at least a portion of the hollow tubular member, wherein forming the cover further comprises: providing an insulating sleeve positioned around at least a portion of the hollow tubular member, wherein the sleeve comprises first and second layers, each of the first and second layers comprising sleeve reinforcing fibers and a heat curable material;cutting the insulating sleeve into a desired shape;sewing edges of the insulating sleeve together;wrapping and covering at least the portion of the hollow tubular member with the insulating sleeve;heating the hollow tubular member wrapped in the insulating sleeve to a predetermined temperature; andallowing the hollow tubular member and the insulating sleeve to cool, so that the insulating sleeve hardens maintains its shape about the hollow tubular member to form the rigid, heat resistant, and non-flammable cover.
  • 11. The method set forth in claim 10, wherein the sleeve reinforcing fibers are made from at least one selected from the group consisting of glass, carbon, basalt, aramid and metal.
  • 12. The method set forth in claim 10, wherein the heat curable material comprises at least one selected from the group consisting of Poly(p-phenylene sulfide), Polyetherimide, Polyether ether ketone, Polysulfone, Polyphthalamide, nylon, polyester and polypropylene.
  • 13. The method set forth in claim 10, wherein the insulating sleeve further comprises a core spun yarn comprising an inner core yarn surrounded by a wrap including the heat curable material.
  • 14. The method set forth in claim 10, wherein the insulated exhaust component has a predetermined operating temperature, wherein the heat curable material has a melting point, and wherein the melting point of the heat curable material is higher than the operating temperature of the insulated exhaust component.
  • 15. A method of manufacturing an insulated exhaust component, said method comprising the steps of: providing a hollow tubular member;forming a rigid, heat resistant, and non-flammable cover positioned around at least a portion of the hollow tubular member, wherein forming the cover further comprises: providing an insulating textile positioned around at least a portion of the hollow tubular member, wherein the insulating textile comprises first and second layers, each of the first and second layers comprising sleeve reinforcing fibers and a heat curable material;cutting the insulating textile into a desired shape;placing the insulating textile into a mold;heating the insulating textile to a predetermined temperature;allowing the insulating textile to cool, so that the insulating textile hardens maintains its shape about the mold to form an insulating sleeve; andattaching said molded insulating sleeve to the hollow tubular member to form the rigid, heat resistant, and non-flammable cover.
  • 16. The method set forth in claim 15, wherein the sleeve reinforcing fibers are made from at least one material selected from the group consisting of glass, carbon, basalt, aramid and metal.
  • 17. The method set forth in claim 15, wherein said heat curable material comprises at least one selected from the group consisting of Poly(p-phenylene sulfide), Polyetherimide, Polyether ether ketone, Polysulfone, Polyphthalamide, nylon, polyester and polypropylene.
  • 18. The method set forth in claim 15, wherein the heat curable material has a melting point of at least 250° F.
  • 19. The method set forth in claim 15, further comprising placing at least one additional layer of the insulating textile into said mold, and attaching said multi-layer protective composite insulating textile to said hollow tubular member.
  • 20. The method set forth in claim 15, wherein the insulated exhaust component has a predetermined operating temperature, wherein the heat curable material has a melting point, and wherein the melting point of the heat curable material is higher than the operating temperature of the insulated exhaust component.
CROSS-REFERENCE TO RELATED APPLICATION

This application is a continuation of U.S. patent application Ser. No. 15/203,074 filed on Jul. 6, 2016, now U.S. Pat. No. 10,293,544, which itself is a continuation of U.S. patent application Ser. No. 13/629,773, now U.S. Pat. No. 9,388,515, filed on Sep. 28, 2012, both for a “Heat Curable Composite Textile”, both of which are hereby incorporated by reference in their entirety.

US Referenced Citations (85)
Number Name Date Kind
1717215 Huber Jun 1929 A
2148164 Krippendorf Feb 1939 A
2688895 Houghton Sep 1954 A
2924546 Shaw Feb 1960 A
3053715 Labino Sep 1962 A
3092530 Plummer Jun 1963 A
3312250 Sirignano et al. Apr 1967 A
3616123 Reynolds et al. Oct 1971 A
3652375 Johnson Mar 1972 A
3828119 Warburton et al. Aug 1974 A
4026381 Conley May 1977 A
4054710 Botsolas Oct 1977 A
4282284 George Aug 1981 A
4299884 Payen Nov 1981 A
4428999 George et al. Jan 1984 A
4655866 Ferrier Apr 1987 A
4870887 Tresslar et al. Oct 1989 A
5092122 Bainbridge Mar 1992 A
5134846 White Aug 1992 A
5256459 Carlson Oct 1993 A
5274196 Weinberg Dec 1993 A
5343895 King Sep 1994 A
5413149 Ford et al. May 1995 A
5549947 Quigley Aug 1996 A
5556677 Quigley Sep 1996 A
5615711 Lewis Apr 1997 A
5617900 Weil Apr 1997 A
5639552 Fukushima Jun 1997 A
5660899 Rockney et al. Aug 1997 A
5712010 Russek et al. Jan 1998 A
5795835 Bruner et al. Aug 1998 A
5849379 Gladfelter et al. Dec 1998 A
5972512 Boisvert et al. Oct 1999 A
5974784 Feldman Nov 1999 A
5985385 Gottfried Nov 1999 A
6045884 Hess et al. Apr 2000 A
6250193 Head Jun 2001 B1
6276401 Wilson Aug 2001 B1
6527015 Lively Mar 2003 B2
6572723 Tilton et al. Jun 2003 B1
6610928 Synder Aug 2003 B2
6769455 Toas et al. Aug 2004 B2
6978643 Akers et al. Dec 2005 B2
7007720 Chase et al. Mar 2006 B1
7152633 White Dec 2006 B2
7544890 Herborth et al. Jun 2009 B2
8950168 Heitmann et al. Feb 2015 B2
9145627 Wilson et al. Sep 2015 B2
9388515 Goulet Jul 2016 B2
9976687 Goulet May 2018 B2
10293544 Goulet May 2019 B2
10295109 Goulet May 2019 B2
10591104 Goulet Mar 2020 B2
20020168488 Gladfelter et al. Nov 2002 A1
20050126651 Sherwin Jun 2005 A1
20050155663 Dhellemmes et al. Jul 2005 A1
20060229381 Bartko Oct 2006 A1
20070049148 Chien et al. Mar 2007 A1
20070131299 Kombleet Jun 2007 A1
20070251595 Chen Nov 2007 A1
20080017263 Robinson Jan 2008 A1
20090050256 Green et al. Feb 2009 A1
20090078499 Sikes et al. Mar 2009 A1
20090197044 Pelzer et al. Aug 2009 A1
20090277526 Merry Nov 2009 A1
20100139197 Woodhall Jun 2010 A1
20100154916 Jackson et al. Jun 2010 A1
20100154917 Batallas et al. Jun 2010 A1
20100201023 Piccione et al. Aug 2010 A1
20100263761 Niccolls et al. Oct 2010 A1
20100316822 Malloy Dec 2010 A1
20110000572 Ramaswamy et al. Jan 2011 A1
20120082807 Malloy et al. Apr 2012 A1
20120149268 Lake et al. Jun 2012 A1
20120291903 Ekelund et al. Nov 2012 A1
20130097839 Latham et al. Apr 2013 A1
20130299035 Laurent et al. Nov 2013 A1
20130306186 Goulet Nov 2013 A1
20140020766 Kremers Jan 2014 A1
20140090407 Piesker Apr 2014 A1
20150000259 Dietz Jan 2015 A1
20160311152 Goulet Oct 2016 A1
20180023222 Zhang et al. Jan 2018 A1
20200217443 Lubenow et al. Jul 2020 A1
20200217444 Goulet Jul 2020 A1
Foreign Referenced Citations (24)
Number Date Country
675984 Nov 1990 CH
2120185 Oct 1992 CN
101119042 Feb 2008 CN
101848959 Sep 2010 CN
102575115 Jul 2012 CN
102654219 Sep 2012 CN
109073134 Dec 2018 CN
102010028433 Nov 2011 DE
0327148 Aug 1989 EP
0877892 Nov 1999 EP
1772604 Apr 2007 EP
2166512 May 1986 GB
07269340 Oct 1995 JP
2001289392 Oct 2001 JP
2005513226 May 2005 JP
2005163830 Jun 2005 JP
3183361 May 2013 JP
2303744 Jul 2007 RU
2380606 Jan 2010 RU
2438065 Dec 2011 RU
9732067 Sep 1997 WO
2000073695 Dec 2000 WO
2005085608 Sep 2005 WO
2017181197 Oct 2017 WO
Non-Patent Literature Citations (80)
Entry
Supplementary European Search Report dated Aug. 29, 2017, by the European Patent Office for related Patent Application No. 13791680.5.
International Search Report dated Sep. 20, 2013, for related International Patent Application No. PCT/US2013/041391.
Written Opinion dated Sep. 20, 2013, for related International Patent Application No. PCT/US2013/041391.
International Preliminary Report on Patentability dated Nov. 18, 2014, for related International Patent No. PCT/US2013/041391.
Canadian Office Action and Search Report dated Oct. 2, 2018, for related Canadian Patent Application No. 2,919,854.
Decision to Grant dated Sep. 14, 2018, by the European Patent Office for related European Patent No. 13791680.5.
Office Action dated Apr. 12, 2018, by the European Patent Office for European Patent Application No. 13791680.5.
Notice of Allowance dated Jul. 24, 2019, by the Canadian Intellectual Property Office for Canadian Patent Application No. 2,912,854.
Final Office Action issued by the United States Patent and Trademark Office for U.S. Appl. No. 16/818,395, dated Mar. 8, 2021.
Notice of Allowance issued by the United States Patent and Trademark Office for U.S. Appl. No. 16/818,395, dated Mar. 24, 2021.
Office Action issued by the United States Patent and Trademark Office for U.S. Appl. No. 16/818,395 dated Oct. 6, 2020.
Office Action issued by the Canadian Patent Office for Canadian Patent Application No. 3,082,881, dated Aug. 11, 2021.
Examination Search Report issued by the Canadian Patent Office for Canadian Patent Application No. 3,082,881, dated Jul. 16, 2021.
Office Action issued by the Brazilian Patent Office for Patent Application No. BR112019010119-5, dated Aug. 31, 2021.
Second Office Action issued by the Chinese Patent Office for Chinese Patent Application No. 201780083881.X, dated Jul. 12, 2021.
Office Action issued by the United States Patent Office for U.S. Appl. No. 16/092,838, dated Oct. 1, 2021.
Final Rejection issued by the United States Patent Office for U.S. Appl. No. 16/818,395, dated Nov. 10, 2021.
Restriction Requirement issued by the United States Patent and Trademark Office for U.S. Appl. No. 16/092,838, dated May 14, 2021.
Office Action issued by the European Patent Office for European Patent Application No. 17871914.2, dated Jun. 17, 2021.
Office Action issued by the Brazilian Patent Office for Brazilian Patent Application No. BR112018070774-0, dated Jun. 15, 2021.
Final Rejection issued by the United States Patent and Trademark Office for U.S. Appl. No. 16/092,838, dated Mar. 15, 2022.
Office Action issued by the European Patent Office for European Patent Application No. 17 871 914.2, dated Apr. 13, 2022.
Final Rejection issued by the United States Patent Office for U.S. Appl. No. 16/462,115, dated May 13, 2022.
International search report dated Jul. 5, 2017 for related International Patent Application No. PCT/US2017/027994.
Written opinion dated Jul. 5, 2017, for related International Patent Application No. PCT/US2017/027994.
International search report dated Jan. 30, 2018, for corresponding International Patent Application No. PCT/US2017/062573.
Written opinion dated Jan. 30, 2018 for corresponding International Patent Application No. PCT/US2017/062573.
International Preliminary Report on Patentability dated Oct. 16, 2018, for related International Patent Application No. PCT/US2017/027994.
Saprex LLC International patent application No. PCT/US2017/062573, International Preliminary Report on Patentability, dated May 21, 2019.
Canadian office action issued by the Canadian Patent Office for Canadian Patent Application No. 3,060,052, dated Dec. 9, 2020.
Chinese Search Report issued by the Chinese Patent Office for corresponding Chinese Patent Application No. 2017800265042, dated Dec. 11, 2019, 5 pages.
Chinese Office Action issued by the Chinese Patent Office for corresponding Chinese Patent Application No. 2017800265042, dated Dec. 19, 2019, 12 pages.
Chinese Search Report issued by the Chinese Patent Office for Chinese Patent Application No. 201780083881X, dated Sep. 23, 2020.
Chinese Office Action issued by the Chinese Patent Office for Chinese Patent Application No. 201780083881X, dated Sep. 28, 2020.
Extended European Search Report issued by the European Patent Office for corresponding European Patent Application No. 17783373.8-1010 / 3443254, dated Nov. 27, 2019, 7 pages.
Supplementary European Search Report issued by the European Patent Office for corresponding application EP 17871914 dated Jul. 8, 2020.
European Office Action issued by the European Patent Office for European Patent Application No. 17783373.8, dated Mar. 9, 2021.
Japanese Office Action issued by the Japanese Patent Office for corresponding Japanese Patent Application No. 2019505340, dated Jan. 15, 2020, 16 pages.
Office Action issued by the Japanese Patent Office for corresponding Japanese Patent Application No. 2019-527220, dated Aug. 21, 2020.
Saprex LLC Russian Patent Application No. 2018140073, Office Action, dated May 17, 2019.
Russian Search Report issued by the Russian Patent Office for corresponding Russian Patent Application No. 2019118633, dated Nov. 22, 2019, 2 pages.
Russian Office Action issued by the Russian Patent Office for corresponding Russian Patent Application No. 2019118633, dated Nov. 28, 2019, 14 pages.
Decision to Grant issued by the Federal Service for Intellectual Property for corresponding Russian Patent Application No. 2018140073/06 (066643) dated Jun. 17, 2020, 5 pages.
Bondaletova, L. And Bondaletov, V., “Polymer composition materials”. Part I, Tomsk, 2013, pp. 16-63.
Amended Invalidity Contentions filed by defendant, Lincoln Industries on Mar. 29, 2021, in the United States District Court for the District of Nebraska in Case No. 8:20-cv-338-BCB-SMB.
Tighitco Phenolic and Polymide Insulation Blankets webpage, purportedly used or sold by Tighitco, purported Publication Date of Apr. 4, 2003.
Tighitco Phenolic and Polymide Insulation Systems webpage, purportedly used or sold by Tighitco, purported Publication Date of Mar. 7, 2010.
ThermoLinc Elite, purportedly used or sold by Lincoln Industries, purported Publication Date of at least as early as 2016.
Glass Fiber Composite Shell, purportedly used or sold by Bosal, purported Publication Date of Jul. 2, 2017.
Composite Insulation Coating, purportedly used or sold by Thermal Structures, purported Publication Date of at least as early as Jul. 9, 2013.
ThermoJacket S Datasheet, purportedly used or sold by Federal Mogul, purported Publication Date of Mar. 2005.
ThermoJacket S Material Safety Data Sheet, purportedly used or sold by Federal Mogul, purported Publication Date of Sep. 26, 2005.
ThermoJacket S Product Description, purportedly used or sold by Federal Mogul, purported Publication Date of at least as early as 2008.
ThermoJacket R Product Description, purportedly used or sold by Federal Mogul, purported Publication Date of Mar. 24, 2011.
ThermFlex 1212 Product Description, purportedly used or sold by Federal Mogul, purported Publication Date of at least as early as 2008.
ThermFlex 1212 Datasheet, purportedly used or sold by Federal Mogul, purported Publication Date of at least as early as 2008.
ThermFlex 1212 Material Safety Data Sheet, purportedly used or sold by Federal Mogul, purported Publication Date of Aug. 29, 2005.
ThermFlex 1212 (with End Dips) Material Safety Data Sheet, purportedly used or sold by Federal Mogul, purported Publication Date of Aug. 22, 2005.
ThermFlex 1210 Material Safety Data Sheet, purportedly used or sold by Federal Mogul, purported Publication Date of Nov. 14, 2013.
ThermFlex 1210 Product Description, purportedly used or sold by Federal Mogul, purported Publication Date of at least as early as 2008.
High Temperature Sleeving, purportedly used or sold by Techflex, purported Publication Date of May 31, 2010.
Insultherm (FG) webpage, purportedly used or sold by Techflex, purported Publication Date of Mar. 14, 2007.
Insultherm webpage, purportedly used or sold by Techflex, purported Publication Date of Jun. 5, 2010.
“Hard Coat” insulation a new direction for insulation blanket manufacturer, purportedly used or sold by Firwin Corp., purported Publication Date of Nov. 12, 2008.
Insulation Coating, purportedly used or sold by Firwin Corp., purported Publication Date of Dec. 2008.
Hard Coat Insulation for Engine Parts and Exhausts, purportedly used or sold by Firwin Corp., purported Publication Date of Apr. 6, 2009.
Making Hard (or Soft) Choices, purportedly used or sold by Firwin Corp., purported Publication Date of Oct. 2009.
Performance Evaluation of Firwin Hard Coat Insulation, purportedly used or sold by Firwin Corp., purported Publication Date of Oct. 2009.
Hard-Coat Insulation for Engine Parts and Exhausts, purportedly used or sold by Firwin Corp., purported Publication Date of May 2011.
Firwin HC Hard Coat Insulations—FAQ's, purportedly used or sold by Firwin Corp., purported Publication Date of Nov. 3, 2011.
Firwin Hard Coat Composite Insulation webpage, purportedly used or sold by Firwin Corp., purported Publication Date of Aug. 24, 2012.
Office Action issued by the United States Patent Office for U.S. Appl. No. 16/462,115, dated Jan. 13, 2022.
Office Action issued by the Brazil Patent Office for Brazil Patent Application No. BR112018070774-0, dated Jul. 7, 2022.
Office Action issued by the Brazilian Patent Office for Brazilian Patent Application No. BR112018070774-0, dated Jan. 11, 2023.
Office Action issued by the European Patent Office for European Patent Application No. 17 871 914.2, dated Jan. 31, 2023.
Notice of Allowance issued by the United States Patent and Trademark Office for U.S. Appl. No. 16/818,395, dated Feb. 23, 2023.
Corrected Notice of Allowance issued by the United States Patent and Trademark Office for U.S. Appl. No. 16/818,395, dated Mar. 9, 2023.
Office Action issued by the European Patent Office for European Patent Application No. 17 783 373.8, dated Oct. 20, 2022.
Office Action issued by the Brazilian Patent Office for Brazilian Patent Application No. BR112019010119-5, dated Oct. 27, 2022.
Office Action issued by the United States Patent Office for U.S. Appl. No. 16/092,838, dated Nov. 17, 2022.
Related Publications (1)
Number Date Country
20190263049 A1 Aug 2019 US
Continuations (2)
Number Date Country
Parent 15203074 Jul 2016 US
Child 16413353 US
Parent 13629773 Sep 2012 US
Child 15203074 US