The subject matter disclosed herein relates to Rankine cycle systems and, in particular, to arrangements of heat pipes for transferring heat from a waste heat source to an organic Rankine cycle evaporator.
Organic Rankine cycle (“ORC”) systems typically utilize working fluids (e.g., pentane, ammonia, etc.) with relatively low evaporation and condensation temperatures (i.e., lower than water). Such non-water systems allow for transforming heat (e.g., waste heat) from relatively lower temperature sources into useful work, for example, rotary power to drive generators. Sources of available low-temperature waste heat include the exhausts of coal-fired boilers (e.g., exhaust flows located upstream of a wet scrubber), cement and other kiln exhausts, glass furnaces, and other continuous industrial thermal processes. One alternative is to place the evaporator of the ORC system directly in the hot gas path. Another is to use a hot oil loop, with the hot oil exchanger located in the hot gas path.
However, the installation of heat exchangers directly in the hot gas paths of ORC systems poses concerns for flammability and/or toxicity of organic working fluids in the event of leaks in the heat exchanger. Also, the use of hot oil loops that heat the oil via a heat exchanger in the hot gas path and evaporate the ORC working fluid in an external heat exchanger is commonly found in various industrial usages, but is relatively expensive and involves installation of relatively heavy components.
According to one aspect of the invention, a first portion of each of a plurality of Qu-type heat pipes (described in detail hereinafter) is disposed in a hot gas path, and a second portion of each of the plurality of Qu-type heat pipes disposed away from the hot gas path. Also, the first portion of each of the plurality of Qu-type heat pipes extracts heat from the hot gas path and wherein the second portion of each of the plurality of Qu-type heat pipes creates a vapor that exits each second portion of the plurality of Qu-type heat pipes and away from the hot gas path.
According to another aspect of the invention, a heat pipe evaporator includes a first portion of a Qu-type heat pipe disposed in a hot gas path, and a second portion of a Qu-type heat pipe disposed away from the hot gas path. Also, the Qu-type heat pipe extracts heat from the hot gas path and creates a vapor that exits the second portion of the Qu-type heat pipe and away from the hot gas path. Further, the second portion of the Qu-type heat pipe includes a plurality of fins connected with the second portion of the Qu-type heat pipe, wherein an outer portion of each fin is disposed next to a cover having corresponding holes formed therein, wherein each hole receives a portion of each corresponding outer portion of each fin, wherein each corresponding hole includes an extension region not occupied by the corresponding fin through which a working fluid passes and becomes the vapor as it is heated by the second portion of the Qu-type heat pipe.
According to another aspect of the invention, apparatus for extracting heat from a flow of waste heat, the apparatus includes a heat source having a plurality of Qu-type heat pipes arranged in a hot gas path of a waste heat source, wherein the first portion of each of the plurality of Qu-type heat pipes extracts heat from the hot gas path. The apparatus also includes an evaporator disposed apart from the heat source, wherein the evaporator comprises a plurality of Qu-type heat pipes, and a connector Qu-type heat pipe that connects the heat source with the evaporator, wherein the connector Qu-type heat pipe transfers the extracted heat from the heat source to the evaporator for evaporation thereby.
These and other advantages and features will become more apparent from the following description taken in conjunction with the drawings.
The subject matter, which is regarded as the invention, is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other features and advantages of the invention are apparent from the following detailed description taken in conjunction with the accompanying drawings in which:
The detailed description explains embodiments of the invention, together with advantages and features, by way of example with reference to the drawings.
In
The right hand end portion 20 of each heat pipe 12 in the arrangement 10 shown in the embodiment of
In an embodiment, the heat pipes 12 in the arrangement 10 of the embodiment shown in
In general, there are two types of heat pipes 12. One is the more traditional liquid-vapor type and the other is the solid-state, inorganic coated heat pipe (e.g., a Qu-type heat pipe). For liquid-vapor types of heat pipes 12, when one end 18 of the sealed heat pipe 12 is heated, the working fluid inside the pipe 12 at that end 18 evaporates and increases the vapor pressure inside the cavity of the heat pipe 12. The working fluid may comprise water, ethanol, acetone, sodium, mercury, etc. The vapor flows to the second end 20 of the pipe 12 where it condenses, which releases the heat that originally caused the fluid to evaporate into an area (e.g., into the pressurized portion 22 of the evaporator 24). The latent heat of evaporation absorbed by the vaporization of the working fluid reduces the temperature at the hot end of the pipe 12. This vaporization and condensation process tends to create a continuous flow of the fluid material within the heat pipe 12, which efficiently transfers heat from the first end portion 18 of the pipe 12 to the second end portion 20 of the pipe 12.
Qu-type heat pipes are a type of solid-state heat pipe 12, which operate somewhat similarly to liquid-vapor type heat pipes 12 but do not use a fluid-vapor material to transfer heat from one end 18 of the pipe 12 to the other end 20 of the pipe 12. In a Qu-type heat pipe 12, the inner surfaces of the pipe 12 are coated with a relatively high heat conducting, inorganic material. In a Qu-type heat pipe, the internal heat transfer material comprises three basic layers. The first layer includes various combinations of sodium, beryllium, a metal such as manganese or aluminum, calcium, boron and dichromate radical. The second layer is formed over the first layer and includes various combinations of cobalt, manganese, beryllium, strontium, rhodium, copper, beta-titanium, potassium, boron, calcium, a metal such as manganese or aluminum and a dichromate radical. The third layer is formed over the second layer and includes various combinations of rhodium oxide, potassium dichromate, radium oxide, sodium dichromate, silver dichromate, monocrystalline silicon, beryllium oxide, strontium chromate, boron oxide, beta-titanium and a metal dichromate, such as manganese dichromate or aluminum dichromate. The three layers can be applied to a conduit and then heat polarized to form a heat transfer device that transfers heat without any net heat loss, or can be applied to a pair of plates having a small cavity relative to a large surface area to form a heat sink that can immediately disperse heat from a heat source.
Vapor is then removed from within the pipe 12 to create a vacuum inside the pipe 12. The pipe 12 is then sealed. The heat conducting Qu material coated on the inner surfaces of the heat pipe 12 transfers heat from one end 18 of the pipe 12 to the other end 20 of the pipe 12. Qu-type heat pipes 12 can provide for improved transfer of heat from one end to the other than more traditional liquid-vapor types of heat pipes 12 due to the relatively high thermal conductivity of the Qu material. Also, Qu-type heat pipes offer relatively greater axial heat fluxes as compared to other types of heat pipes. Thus, Qu-type heat pipes allow for the realization of embodiments of the invention that the more traditional liquid/vapor type heat pipes do not.
In
Embodiments of the invention contemplate arrangements 10 of the Qu-type heat pipes within the pressurized portion of an evaporator other than the serpentine arrangement. For example, the Qu-type heat pipes 12 may be arranged in individual singular rows or columns in a three-dimensional arrangement with a corresponding inlet 30 and outlet 32 for each row or column. In addition, an embodiment in which only a single row or column of Qu-type heat pipes 12, instead of a three-dimensional arrangement, may be contemplated.
In
In
In this embodiment, the first arrangement 70 of Qu-type heat pipes 72 may be positioned in the ductwork or hot gas path of a waste heat source and act as a heat source. The heat pipes 72 absorb or extract energy from the relatively hot gas, which is collected by the header 74. The Qu-type heat pipe connector 82 may be insulated and is used to transfer this absorbed or extracted heat energy to the header 80 of the second arrangement 76 of heat pipes 78, which function as an evaporator (e.g., an organic Rankine cycle system evaporator) to evaporate the transferred heat. The first and second arrangements 70, 76 may be separated by a relatively large distance (e.g., greater than 100 meters). This allows the evaporator to be located at a relatively long distance from the waste heat source. Also,
Embodiments of the invention provide for the extraction of heat from a hot gas path that avoids the risks inherent in placement of organic Rankine cycle working fluid evaporators in the hot gas path and the costs of the indirect hot oil loops, as in the prior art. Embodiments of the invention use thermal energy of exhaust gas from a waste heat source and Qu-type heat pipes to transfer heat to an organic Rankine cycle working fluid evaporator. Qu-type heat pipes have relatively high axial thermal conductivities and can be used to transfer heat effectively without a fluid flow loop.
In other embodiments, the heat pipe organic Rankine cycle evaporator can be placed at a remote location separated from the heat source. This accomplished by using a heat pipe array to absorb energy from the hot gas. A relatively large insulated Qu-type heat pipe may then be used to transfer the heat over a relatively large distance to the heat pipe organic Rankine cycle evaporator (e.g., greater than 100 meters away from the source).
Using embodiments of the invention, heat is transferred using Qu-type heat pipes directly to the evaporator for the organic working fluid, which is external to the hot gas path. Both cost and weight are relatively less than having both a separate hot oil loop and an external evaporator. Other technical advantages of embodiments of the invention include savings in capital cost versus use of hot oil loop, an improved EHS profile versus direct placement of the evaporator in the hot gas path, a relatively smaller system footprint, and flexibility in the location of the organic Rankine cycle working fluid evaporator within the overall system.
While the invention has been described in detail in connection with only a limited number of embodiments, it should be readily understood that the invention is not limited to such disclosed embodiments. Rather, the invention can be modified to incorporate any number of variations, alterations, substitutions or equivalent arrangements not heretofore described, but which are commensurate with the spirit and scope of the invention. Additionally, while various embodiments of the invention have been described, it is to be understood that aspects of the invention may include only some of the described embodiments. Accordingly, the invention is not to be seen as limited by the foregoing description, but is only limited by the scope of the appended claims.
Number | Name | Date | Kind |
---|---|---|---|
3937017 | Beschorner et al. | Feb 1976 | A |
4303122 | Powell | Dec 1981 | A |
4426959 | McCurley | Jan 1984 | A |
4482004 | Grover | Nov 1984 | A |
4621681 | Grover | Nov 1986 | A |
5664414 | Bronicki et al. | Sep 1997 | A |
6132823 | Qu | Oct 2000 | A |
6332321 | Bronicki et al. | Dec 2001 | B1 |
6598397 | Hanna et al. | Jul 2003 | B2 |
6911231 | Qu | Jun 2005 | B2 |
6981377 | Vaynberg et al. | Jan 2006 | B2 |
7220365 | Qu et al. | May 2007 | B2 |
20020148225 | Lewis | Oct 2002 | A1 |
20080011161 | Finkenrath et al. | Jan 2008 | A1 |
20080104938 | Finkenrath et al. | May 2008 | A1 |
Number | Date | Country |
---|---|---|
2008044008 | Apr 2008 | WO |
Number | Date | Country | |
---|---|---|---|
20110061386 A1 | Mar 2011 | US |