An exhaust system includes catalyst components to reduce emissions. The exhaust system includes an injection system that injects a diesel exhaust fluid (DEF), or a reducing agent such as a solution of urea and water for example, upstream of a selective catalytic reduction (SCR) catalyst which is used to reduce NOx emissions. A mixer is positioned upstream of the SCR catalyst and mixes engine exhaust gases and products of urea transformation. The injection system includes a doser that sprays the fluid into the exhaust stream. The fluid spray should be transformed as much as possible into ammonia (NH3) before reaching the SCR catalyst.
Providing for ultra-low NOx emissions requires dosing at low temperatures to address reducing emissions at cold start and low load cycles. Dosing DEF at low temperatures is a thermolysis and deposit formation problem as there is insufficient heat. Some configurations require ammonia dosing by converting DEF to ammonia prior to introduction into the mixer. This requires storing ammonia and/or heating DEF external to the mixer. This is disadvantageous from a packaging and cost perspective.
In one exemplary embodiment, a vehicle exhaust system has a mixer housing that includes a doser opening and defines an internal mixing chamber. A doser injects fluid into the mixer housing through the doser opening. A flow passage has an inlet end positioned adjacent the doser opening and an outlet end open to the mixing chamber. At least one heating device associated with the flow passage.
In a further embodiment of the above, the heating device is an electric coil that heats a surface of the flow passage.
In a further embodiment of any of the above, the heating device is a heated plate that heats a surface of the flow passage.
In a further embodiment of any of the above, the heating device is positioned at the outlet end of the flow passage.
In a further embodiment of any of the above, the heating device surrounds an outer surface of the flow passage.
In a further embodiment of any of the above, an inner surface of the flow passage surrounds the heating device.
In a further embodiment of any of the above, the system includes a control that selectively activates the heating device when a temperature of the exhaust gas is below a predetermined temperature.
In a further embodiment of any of the above, the system includes at least one temperature sensor that measures exhaust gas temperature prior to entering the mixing chamber.
In a further embodiment of any of the above, the heating device heats the flow passage such that all fluid injected by the doser evaporates prior to entering the mixing chamber.
In a further embodiment of any of the above, an amount of energy required to heat the flow passage is determined based on an amount of injected fluid and the temperature of the exhaust gas.
In a further embodiment of any of the above, the flow passage comprises a solid or porous body, and wherein the flow passage further comprises a cylindrical tube or cone.
In a further embodiment of any of the above, the base end of the flow passage is positioned adjacent the dose opening such that a gap is formed within the mixer housing between the base end of the flow passage and an inner surface of the mixer housing that surrounds the doser opening.
In a further embodiment of any of the above, exhaust gas is directed into the base end of the flow passage to mix with fluid sprayed into the base end of the flow passage such that a mixture of evaporated fluid and exhaust gas exits the outlet end of the flow passage.
In another exemplary embodiment, a vehicle exhaust system includes a mixer housing, a doser to inject fluid into the mixer housing through a doser opening in the mixer housing, and a flow passage comprising a solid or porous body that has an inlet end positioned adjacent the doser opening and an outlet end open to the mixing chamber. At least one heating device is positioned at the outlet end of the flow passage to heat the flow passage such that all fluid injected by the doser evaporates prior to entering the mixing chamber. The system also includes a control that selectively activates the heating device when a temperature of the exhaust gas is below a predetermined temperature.
In a further embodiment of any of the above, the heating device comprises an electric coil or heated plate, and the flow passage comprises a cylindrical tube or cone.
In another exemplary embodiment, a method for injecting a reducing agent into an exhaust component comprising the steps of: providing a mixer housing that defines an internal mixing chamber; providing a doser opening in the mixer housing; positioning a doser to inject fluid into the mixer housing through the doser opening; positioning a flow passage in the mixer housing such that an inlet end of the flow passage is positioned adjacent the doser opening and an outlet end of the flow passage is open to the mixing chamber; and using at least one heating device to heat the flow passage.
In a further embodiment of any of the above, the method includes heating the flow passage such that all fluid injected by the doser evaporates prior to entering the mixing chamber.
In a further embodiment of any of the above, the method includes selectively activating the heating device when a temperature of the exhaust gas is below a predetermined temperature.
These and other features of this application will be best understood from the following specification and drawings, the following of which is a brief description.
In one example configuration, the upstream exhaust component 14 comprises at least one pipe that directs engine exhaust gases into a diesel oxidation catalyst (DOC) 16 having an inlet 18 and an outlet 20. Downstream of the DOC 16 there may be a diesel particulate filter (DPF) 21 that is used to remove contaminants from the exhaust gas as known. Downstream of the DOC 16 and optional DPF 21 is a selective catalytic reduction (SCR) catalyst 22 having an inlet 24 and an outlet 26. The outlet 26 communicates exhaust gases to downstream exhaust components 28. Optionally, component 22 can comprise a catalyst that is configured to perform a selective catalytic reduction function and a particulate filter function. The various downstream exhaust components 28 can include one or more of the following: pipes, filters, valves, catalysts, mufflers etc. These upstream 14 and downstream 28 components can be mounted in various different configurations and combinations dependent upon vehicle application and available packaging space.
A mixer 30 is positioned downstream from the outlet 20 of the DOC 16 or DPF 21 and upstream of the inlet 24 of the SCR catalyst 22. The upstream catalyst and downstream catalyst can be in-line or in parallel. The mixer 30 is used to generate a swirling or rotary motion of the exhaust gas.
An injection system 32 is used to inject a reducing agent, such as a solution of urea and water for example, into the exhaust gas stream upstream from the SCR catalyst 22 such that the mixer 30 can mix the urea and exhaust gas thoroughly together. The injection system 32 includes a fluid supply 34, a doser 36 defining a doser axis A, and a controller 38 that controls injection of the urea as known.
The mixer 30 comprises a mixer housing 40 having an inlet end 42 configured to receive the engine exhaust gases and an outlet end 44 to direct a mixture of swirling engine exhaust gas and products transformed from urea to the SCR catalyst 22. Examples of a mixer 30 that can be used in the exhaust system 10 can be found in U.S. Pat. Nos. 8,661,792 and 9,266,075 for example, which are also assigned to the assignee of the present application and are hereby incorporated by reference.
The inlet 46 and outlet 48 baffles are fixed to the mixer housing 40 which defines an internal mixing chamber 56 between the inlet 46 and outlet 48 baffles. Exhaust gas and injected fluid spray, which is injected via the doser 36, are mixed within the mixing chamber 56. Positioned within the mixing chamber 56 is a flow passage 58 (
In addition to the primary inlet opening 50 and the secondary openings 52, the inlet baffle 46 also includes one or more openings 60 that direct a small portion of exhaust gas away from the primary flow path and toward an outer surface 62 of the flow passage 58. In one example, three openings 60a, 60b, 60c are used to direct exhaust gas toward the outer surface 62 of the flow passage 58. The openings 60a, 60b, 60c are spaced apart from each other about an outer peripheral edge of the inlet baffle 46.
The exhaust gas is directed to enter the base end 66 of the flow passage 58 in an evenly distributed manner about a gap 72 between the base end 66 and an inner surface of the mixer housing 40. A doser sub-assembly 74 is mounted to align with the doser axis A at the base end 66 of the flow passage 58. The doser sub-assembly 74 includes a plate 76 with an opening 78 that aligns with an opening in the mixer housing 40. A doser mount structure 80 abuts against the plate 76 and holds the doser 36. The doser sub-assembly 74 includes a cylindrical housing or sleeve 82 with one or more openings 84.
As shown in
In one example, the sleeve 82 is fixed to the plate 76 and surrounds at least a portion of the flow passage 58. The openings 84 of the sleeve 82 direct exhaust gas in a first flow direction F1 against the outer surface 62 of the flow passage 58. The exhaust gas then flows in a second flow direction F2 along the outer surface 62 of the flow passage 58 toward the base end 66. The exhaust gas then flows in a third flow direction F3 to enter the annular gap 72 extending circumferentially around the base end 66. After flowing through the annular gap 72, the exhaust gas flows in a fourth flow direction F4 where it mixes with the reducing agent and to exits the flow passage 58 at the distal end 68. In one example, the fourth flow direction F4 extends generally along the doser axis A and is opposite of the second flow direction F2. Further, the third flow direction F3 is perpendicular to the fourth flow direction F4.
As shown in
In another example shown in
In each of these examples, the flow passage 58, 58′ comprises a solid structure or body that extends completely about the axis A. However, the flow passages 58, 58′ may optionally include one or more slots 200 (
The doser 36 sprays the fluid into the flow passage 58 to mix with the exhaust gas entering via the gap 72. The fluid should be transformed as much as possible into ammonia (NH3) before exiting the mixer 30 and reaching the SCR catalyst 22. However, dosing at low temperatures has a tendency to create a deposits as there is insufficient heat to evaporate the fluid spray injected by the doser 36.
In order to address this problem, the subject invention provides at least one heating device 88 that is associated with the flow passage 58. The heating device 88 is connected to a power supply 90 and a control 92 selectively activates the heating device 88 when a temperature of the exhaust gas is below a predetermined temperature. The control 92 can be a dedicated electronic control unit, or can be part of the controller 38 for the injection system 32, or can be incorporated into another electronic control unit in the vehicle. One or more temperature sensors 94 can be used to measure exhaust gas temperature prior to entering the mixing chamber 56. The sensors 94 communicate data to the control 92. Typically, the control 92 activates the heating device 88 under cold start or low load conditions, for example. The heating device 88 heats the flow passage 58, 58′ such that all fluid spray injected by the doser 36 evaporates prior to exiting the flow passage 58, 58′ and entering the mixing chamber 56. In one example, an amount of energy required to heat the flow passage 58, 58′ is determined based on an amount of injected fluid and the temperature of the exhaust gas.
In one example (
In another example (
In another example (
In each example, the control 92 activates the plate 96 or coil 98 to heat the flow passage 58 to ensure that all fluid spray injected by the doser 36 evaporates prior to exiting the flow passage 58 and entering the mixing chamber 56. The plate 96 and coil 98 are examples of heating devices 88 that can be used to heat the flow passage 58; however, other types of heating devices could also be used.
As discussed above, the SCR device 22 is used to reduce NOx emissions by using ammonia (NH3) as the catalytic reductant. NH3 is injected as DEF fluid using the doser 36. The catalytic reduction is based on the ammonia decomposition and SCR activation; however, both of these have difficulty occurring at lower temperatures. The first step in ammonia decomposition is to evaporate the water in the DEF fluid, which is a process referred to as thermolysis, i.e. the breakdown of molecules by the action of heat. During the process of mixing, the DEF fluid takes this energy from the exhaust heat. At lower temperatures, the exhaust does not have enough energy, and the water does not evaporate completely which can result in significant deposit formation. This therefore limits the ability to dose at lower temperatures and the NOx produced by the exhaust system can pass to the tail pipe untreated.
The subject invention enables dosing of DEF fluid at lower temperatures by using the heating device 88 to heat surfaces in the mixer to help with the decomposition process when the exhaust gas energy itself is not sufficient to complete the process. The DEF spray impinges on the heated surfaces, which causes the water in the spray to evaporate before it can enter the mixing chamber thereby significantly reducing deposit formation. The amount of energy required to heat the surfaces is based on the amount of DEF injected and energy available in the exhaust. It is also essential that some exhaust gas flows through the heated surface along with the DEF at all times. This helps the heated surface from overheating.
Although an embodiment of this invention has been disclosed, a worker of ordinary skill in this art would recognize that certain modifications would come within the scope of this invention. For that reason, the following claims should be studied to determine the true scope and content of this invention.
Number | Name | Date | Kind |
---|---|---|---|
1462219 | Wagner | Jul 1923 | A |
3150922 | Ashley | Sep 1964 | A |
3524631 | Mare | Aug 1970 | A |
4033123 | Masaki et al. | Jul 1977 | A |
4054418 | Miller et al. | Oct 1977 | A |
4094934 | Tuckey et al. | Jun 1978 | A |
4420933 | Kajitani et al. | Dec 1983 | A |
4459805 | Kamiya et al. | Jul 1984 | A |
4538413 | Shinzawa et al. | Sep 1985 | A |
4576617 | Renevot | Mar 1986 | A |
4662172 | Shinzawa et al. | May 1987 | A |
4912920 | Hirabayashi | Apr 1990 | A |
5020991 | Schaale et al. | Jun 1991 | A |
5605042 | Stutzenberger | Feb 1997 | A |
5606856 | Linder et al. | Mar 1997 | A |
5648022 | Gohara et al. | Jul 1997 | A |
5826428 | Blaschke | Oct 1998 | A |
6192677 | Tost | Feb 2001 | B1 |
6382600 | Mahr | May 2002 | B1 |
6401455 | Mathes et al. | Jun 2002 | B1 |
6444177 | Muller et al. | Sep 2002 | B1 |
6449947 | Liu et al. | Sep 2002 | B1 |
6460340 | Chauvette et al. | Oct 2002 | B1 |
6513323 | Weigl et al. | Feb 2003 | B1 |
6516610 | Hodgson | Feb 2003 | B2 |
6527865 | Sajoto et al. | Mar 2003 | B1 |
6539708 | Hofmann et al. | Apr 2003 | B1 |
6637196 | Tost | Oct 2003 | B1 |
6722123 | Liu et al. | Apr 2004 | B2 |
6755014 | Kawai et al. | Jun 2004 | B2 |
7059118 | Ripper et al. | Jun 2006 | B2 |
7509799 | Amou et al. | Mar 2009 | B2 |
7730721 | Kimura et al. | Jun 2010 | B2 |
7784273 | Kanaya et al. | Aug 2010 | B2 |
7814745 | Levin et al. | Oct 2010 | B2 |
7849676 | Witte-Merl | Dec 2010 | B2 |
7895828 | Satou | Mar 2011 | B2 |
7963104 | Girard et al. | Jun 2011 | B2 |
7980063 | Cooke | Jul 2011 | B2 |
7992379 | Suzuki et al. | Aug 2011 | B2 |
8006487 | Gaiser | Aug 2011 | B2 |
8033101 | Amon et al. | Oct 2011 | B2 |
8079211 | Levin et al. | Dec 2011 | B2 |
8097055 | Staley et al. | Jan 2012 | B2 |
8114364 | Harinath et al. | Feb 2012 | B2 |
8173088 | Makartchouk et al. | May 2012 | B2 |
8216537 | Kouvetakis et al. | Jul 2012 | B2 |
8240137 | Liu et al. | Aug 2012 | B2 |
8250859 | Torisaka et al. | Aug 2012 | B2 |
8371114 | Hayashi et al. | Feb 2013 | B2 |
8371256 | Durrett et al. | Feb 2013 | B2 |
8393834 | Brugman | Mar 2013 | B2 |
8397492 | Kowada | Mar 2013 | B2 |
8425851 | Kimura | Apr 2013 | B2 |
8438839 | Floyd et al. | May 2013 | B2 |
8499739 | Cox et al. | Aug 2013 | B2 |
8539761 | Lebas et al. | Sep 2013 | B2 |
8607550 | Tangemann et al. | Dec 2013 | B2 |
8622316 | Haeberer et al. | Jan 2014 | B2 |
8646258 | Vanvolsem et al. | Feb 2014 | B2 |
8661792 | Greber et al. | Mar 2014 | B2 |
8677738 | Floyd et al. | Mar 2014 | B2 |
8700246 | Kurikuma et al. | Apr 2014 | B2 |
8726643 | Way et al. | May 2014 | B2 |
8756921 | Troxler et al. | Jun 2014 | B2 |
8776509 | Wikaryasz et al. | Jul 2014 | B2 |
8893481 | Katou et al. | Nov 2014 | B2 |
8899026 | Loman et al. | Dec 2014 | B2 |
8915069 | Loman | Dec 2014 | B2 |
8916101 | Iljima et al. | Dec 2014 | B2 |
8955312 | Watahiki et al. | Feb 2015 | B2 |
8966884 | Kruse et al. | Mar 2015 | B2 |
8991160 | Katou et al. | Mar 2015 | B2 |
9003775 | Wright et al. | Apr 2015 | B2 |
9003782 | Werni et al. | Apr 2015 | B2 |
9057312 | Munnannur et al. | Jun 2015 | B2 |
9062582 | Loman et al. | Jun 2015 | B2 |
9062589 | Katou et al. | Jun 2015 | B2 |
9103258 | Norling et al. | Aug 2015 | B2 |
9140163 | Loman | Sep 2015 | B2 |
9145810 | Bisaiji et al. | Sep 2015 | B2 |
9188039 | Nagel et al. | Nov 2015 | B2 |
9194267 | Loman | Nov 2015 | B2 |
9266075 | Chapman et al. | Feb 2016 | B2 |
9289724 | Stanavich et al. | Mar 2016 | B2 |
9308495 | Kimura | Apr 2016 | B2 |
9341100 | Petry | May 2016 | B2 |
9346017 | Greber | May 2016 | B2 |
9364790 | Sampath et al. | Jun 2016 | B2 |
9394821 | Assalve et al. | Jul 2016 | B2 |
9410464 | Hicks et al. | Aug 2016 | B2 |
9422844 | Suzuki et al. | Aug 2016 | B2 |
9441522 | Crandell et al. | Sep 2016 | B2 |
9464546 | Perrot et al. | Oct 2016 | B2 |
9494067 | Niaz | Nov 2016 | B2 |
9518496 | Hill et al. | Dec 2016 | B2 |
9587543 | Haverkamp et al. | Mar 2017 | B2 |
9670811 | De Rudder et al. | Jun 2017 | B2 |
9714598 | Alano et al. | Jul 2017 | B2 |
9719397 | Alano et al. | Aug 2017 | B2 |
9726064 | Alano | Aug 2017 | B2 |
9810127 | Kloeckner et al. | Nov 2017 | B2 |
9849424 | Davidson et al. | Dec 2017 | B2 |
9890682 | Clayton, Jr. | Feb 2018 | B2 |
9920676 | Freeman et al. | Mar 2018 | B2 |
20010018826 | Rusch | Sep 2001 | A1 |
20030110763 | Pawson et al. | Jun 2003 | A1 |
20030226412 | Rumminger et al. | Dec 2003 | A1 |
20040047232 | Terentiev | Mar 2004 | A1 |
20050150211 | Crawley et al. | Jul 2005 | A1 |
20060070374 | Gaiser et al. | Apr 2006 | A1 |
20060218902 | Arellano et al. | Oct 2006 | A1 |
20070092143 | Higgins | Apr 2007 | A1 |
20070092413 | Hirata et al. | Apr 2007 | A1 |
20070163241 | Meingast et al. | Jul 2007 | A1 |
20070175204 | Shirai et al. | Aug 2007 | A1 |
20070193252 | McKinley et al. | Aug 2007 | A1 |
20080011777 | Cooke | Jan 2008 | A1 |
20080022663 | Dodge | Jan 2008 | A1 |
20080022670 | Ichikawa | Jan 2008 | A1 |
20080092526 | Kunkel et al. | Apr 2008 | A1 |
20080141667 | Winter et al. | Jun 2008 | A1 |
20080256931 | Kawakita et al. | Oct 2008 | A1 |
20080282687 | Park et al. | Nov 2008 | A1 |
20080295497 | Kornherr et al. | Dec 2008 | A1 |
20090012066 | Izumo et al. | Jan 2009 | A1 |
20090031714 | Jochumsen et al. | Feb 2009 | A1 |
20090044524 | Fujino | Feb 2009 | A1 |
20090064668 | Herrick et al. | Mar 2009 | A1 |
20090084094 | Goss et al. | Apr 2009 | A1 |
20090107126 | Bugos et al. | Apr 2009 | A1 |
20090120066 | VanderGriend et al. | May 2009 | A1 |
20090127511 | Bruck et al. | May 2009 | A1 |
20090249769 | Flanagan et al. | Oct 2009 | A1 |
20100000203 | Kowada | Jan 2010 | A1 |
20100005790 | Zhang | Jan 2010 | A1 |
20100005791 | Ranganathan et al. | Jan 2010 | A1 |
20100071355 | Brown et al. | Mar 2010 | A1 |
20100101222 | Oesterle et al. | Apr 2010 | A1 |
20100146950 | Hayashi et al. | Jun 2010 | A1 |
20100186393 | Kowada | Jul 2010 | A1 |
20100196225 | Harinath et al. | Aug 2010 | A1 |
20100199645 | Telford | Aug 2010 | A1 |
20100212292 | Rusch et al. | Aug 2010 | A1 |
20100212301 | De Rudder et al. | Aug 2010 | A1 |
20100257849 | Kowada | Oct 2010 | A1 |
20100263359 | Haverkamp et al. | Oct 2010 | A1 |
20100300080 | Peters et al. | Dec 2010 | A1 |
20100307138 | Chen | Dec 2010 | A1 |
20100319329 | Khadiya | Dec 2010 | A1 |
20110036082 | Collinot | Feb 2011 | A1 |
20110041488 | Bisaiji et al. | Feb 2011 | A1 |
20110061374 | Noritake | Mar 2011 | A1 |
20110079003 | Sun et al. | Apr 2011 | A1 |
20110107743 | Ranganathan et al. | May 2011 | A1 |
20110107749 | Tsujimoto et al. | May 2011 | A1 |
20110113759 | Tilinski et al. | May 2011 | A1 |
20110113764 | Salanta et al. | May 2011 | A1 |
20110126529 | Park | Jun 2011 | A1 |
20110131958 | Adelman et al. | Jun 2011 | A1 |
20110162347 | Katare et al. | Jul 2011 | A1 |
20110167810 | Lebas et al. | Jul 2011 | A1 |
20110239631 | Bui et al. | Oct 2011 | A1 |
20110257849 | Alberius et al. | Oct 2011 | A1 |
20110274590 | Floyd et al. | Nov 2011 | A1 |
20120174561 | Troxler et al. | Jul 2012 | A1 |
20120204541 | Li et al. | Aug 2012 | A1 |
20120216513 | Greber et al. | Aug 2012 | A1 |
20120322012 | Tsumagari et al. | Dec 2012 | A1 |
20120324872 | Jaruvatee et al. | Dec 2012 | A1 |
20130164181 | Ilijima et al. | Jun 2013 | A1 |
20130164182 | Iijima et al. | Jun 2013 | A1 |
20130164183 | Iijima et al. | Jun 2013 | A1 |
20130170973 | Staskowiak et al. | Jul 2013 | A1 |
20130216442 | Brunel et al. | Aug 2013 | A1 |
20130239546 | Levin et al. | Sep 2013 | A1 |
20130263575 | Sun | Oct 2013 | A1 |
20130269325 | Hadden et al. | Oct 2013 | A1 |
20130291519 | Patel et al. | Nov 2013 | A1 |
20130303365 | Yin et al. | Nov 2013 | A1 |
20140093439 | De Rudder et al. | Apr 2014 | A1 |
20140230418 | Perrot et al. | Aug 2014 | A1 |
20140318112 | Solbrig et al. | Oct 2014 | A1 |
20140325967 | Kimura | Nov 2014 | A1 |
20140334987 | Stanavich et al. | Nov 2014 | A1 |
20140334988 | Stanavich et al. | Nov 2014 | A1 |
20150004083 | Makartchouk et al. | Jan 2015 | A1 |
20150040547 | Brockman et al. | Feb 2015 | A1 |
20150047329 | Way et al. | Feb 2015 | A1 |
20150071826 | Sampath et al. | Mar 2015 | A1 |
20150101313 | Mitchell et al. | Apr 2015 | A1 |
20150152766 | Brunel | Jun 2015 | A1 |
20150240689 | Guilbaud et al. | Aug 2015 | A1 |
20150267596 | Tobben | Sep 2015 | A1 |
20150290585 | Nagata et al. | Oct 2015 | A1 |
20150315943 | Gschwind | Nov 2015 | A1 |
20150354432 | Gehrlein et al. | Dec 2015 | A1 |
20150361853 | Nagata et al. | Dec 2015 | A1 |
20160032808 | Kobe et al. | Feb 2016 | A1 |
20160084133 | Sampath et al. | Mar 2016 | A1 |
20160115847 | Chapman et al. | Apr 2016 | A1 |
20160129397 | Lee et al. | May 2016 | A1 |
20160131007 | Kauderer et al. | May 2016 | A1 |
20160138454 | Alano et al. | May 2016 | A1 |
20160184783 | Tyni et al. | Jun 2016 | A1 |
20160201539 | Tongu et al. | Jul 2016 | A1 |
20160215673 | Noren, IV et al. | Jul 2016 | A1 |
20160251990 | Dimpelfeld et al. | Sep 2016 | A1 |
20160319720 | Alano | Nov 2016 | A1 |
20160332126 | Nande et al. | Nov 2016 | A1 |
20160348557 | Dalimonte et al. | Dec 2016 | A1 |
20160361694 | Brandl et al. | Dec 2016 | A1 |
20170066012 | Hornback | Mar 2017 | A1 |
20170082007 | Alano et al. | Mar 2017 | A1 |
20170107877 | Johnson et al. | Apr 2017 | A1 |
20170167344 | Alano et al. | Jun 2017 | A1 |
20170175606 | Peace | Jun 2017 | A1 |
20180023446 | Dimpelfeld | Jan 2018 | A1 |
20180080360 | Kurpejovic | Mar 2018 | A1 |
20180142597 | Riepshoff et al. | May 2018 | A1 |
20180156092 | Inclan et al. | Jun 2018 | A1 |
20180171849 | Saupe et al. | Jun 2018 | A1 |
Number | Date | Country |
---|---|---|
101732992 | Jun 2010 | CN |
202012386 | Oct 2011 | CN |
202360191 | Aug 2012 | CN |
202467984 | Oct 2012 | CN |
203452874 | Feb 2014 | CN |
205164443 | Apr 2016 | CN |
106014560 | Oct 2016 | CN |
205627632 | Oct 2016 | CN |
4417238 | Sep 1994 | DE |
10241697 | Apr 2003 | DE |
10312212 | Nov 2003 | DE |
102005061145 | Jun 2007 | DE |
102007034316 | Jan 2009 | DE |
102008023585 | Jan 2009 | DE |
102007051510 | Apr 2009 | DE |
202008001022 | Jun 2009 | DE |
102008008563 | Aug 2009 | DE |
102007052262 | Feb 2010 | DE |
102008040476 | Feb 2010 | DE |
102008041486 | Feb 2010 | DE |
102008052757 | Apr 2010 | DE |
102008059602 | Jun 2010 | DE |
102009046280 | May 2011 | DE |
102011008895 | Jul 2012 | DE |
102011075594 | Nov 2012 | DE |
102011077156 | Dec 2012 | DE |
102012209689 | Dec 2013 | DE |
102013012909 | Feb 2015 | DE |
102014104224 | Oct 2015 | DE |
0268026 | May 1988 | EP |
0956895 | Nov 1999 | EP |
1314864 | May 2003 | EP |
1596044 | Nov 2005 | EP |
2221459 | Aug 2010 | EP |
2405109 | Jan 2012 | EP |
2465602 | Jun 2012 | EP |
2492465 | Aug 2012 | EP |
2551481 | Jan 2013 | EP |
2687286 | Jan 2014 | EP |
2860369 | Apr 2015 | EP |
2860370 | Apr 2015 | EP |
2873157 | Jan 2006 | FR |
2897646 | Aug 2007 | FR |
2910533 | Jun 2008 | FR |
2965011 | Mar 2012 | FR |
2977632 | Jan 2013 | FR |
3004755 | Oct 2014 | FR |
3007068 | Dec 2014 | FR |
174131 | Jan 1922 | GB |
1215148 | Dec 1970 | GB |
2537061 | Oct 2016 | GB |
H0296212 | Apr 1990 | JP |
H04365303 | Dec 1992 | JP |
H11159320 | Jun 1999 | JP |
2001030093 | Feb 2001 | JP |
2004339991 | Dec 2004 | JP |
2005127271 | May 2005 | JP |
2005155404 | Jun 2005 | JP |
2005214175 | Aug 2005 | JP |
2005273578 | Oct 2005 | JP |
2006017043 | Jan 2006 | JP |
2006167576 | Jun 2006 | JP |
2007000783 | Jan 2007 | JP |
2007000784 | Jan 2007 | JP |
2007040149 | Feb 2007 | JP |
2007073957 | Mar 2007 | JP |
2007115748 | May 2007 | JP |
2007146700 | Jun 2007 | JP |
2008014213 | Jan 2008 | JP |
2009002213 | Jan 2009 | JP |
2009030560 | Feb 2009 | JP |
2009114910 | May 2009 | JP |
2009156068 | Jul 2009 | JP |
2009156069 | Jul 2009 | JP |
2009167806 | Jul 2009 | JP |
2009209822 | Sep 2009 | JP |
5066435 | Nov 2012 | JP |
5114219 | Jan 2013 | JP |
2013002367 | Jan 2013 | JP |
2014095367 | May 2014 | JP |
2016188579 | Nov 2016 | JP |
100679716 | Jan 2007 | KR |
20090105593 | Oct 2009 | KR |
102013086287 | Apr 2010 | KR |
20110049152 | May 2011 | KR |
10-2014-0002326 | Jan 2014 | KR |
8200991 | Aug 1983 | SE |
531199 | Jan 2009 | SE |
2004113690 | Dec 2004 | WO |
2008034981 | Mar 2008 | WO |
2008049757 | May 2008 | WO |
2008122724 | Oct 2008 | WO |
2009012819 | Jan 2009 | WO |
2009024815 | Feb 2009 | WO |
2009030858 | Mar 2009 | WO |
2009098096 | Aug 2009 | WO |
2009127449 | Oct 2009 | WO |
2010055239 | May 2010 | WO |
2010149410 | Dec 2010 | WO |
2011110885 | Sep 2011 | WO |
2012052560 | Apr 2012 | WO |
2012120000 | Sep 2012 | WO |
2013004517 | Jan 2013 | WO |
2013010700 | Jan 2013 | WO |
2013035112 | Mar 2013 | WO |
2013099312 | Jul 2013 | WO |
2013099313 | Jul 2013 | WO |
2014098728 | Jun 2014 | WO |
2015012829 | Jan 2015 | WO |
2015018849 | Feb 2015 | WO |
2015076765 | May 2015 | WO |
2015105500 | Jul 2015 | WO |
2015130640 | Sep 2015 | WO |
2015151282 | Oct 2015 | WO |
2016013319 | Jan 2016 | WO |
2016036298 | Mar 2016 | WO |
2016158993 | Oct 2016 | WO |
2017054179 | Apr 2017 | WO |
2017084549 | May 2017 | WO |
2017102813 | Jun 2017 | WO |
2018054490 | Mar 2018 | WO |
Number | Date | Country | |
---|---|---|---|
20200088081 A1 | Mar 2020 | US |