The application relates generally to a heat transfer system suitable for cooling and/or heating an enclosed space or a process.
Phase change materials (PCMs) are often used as thermal management solutions. Usually PCMs are physically fixed within a wall, a ceiling, a woven fabric, or a device of any kind. PCMs do their work of cooling/heating devices by melting and solidifying wherever they are. The main disadvantage of being fixed/stationary is that once the PCM is fully melted or solidified, it looses some of its effectiveness. Improvements are thus desirable.
According to one aspect of the present disclosure, there is provided a heat transfer system wherein a phase change material (PCM) is encapsulated inside a plurality of units/capsules and wherein transfer means are provided to move the PCM units/capsules between a cold environment and a warm environment.
According to another aspect, the PCM has a melting or phase change temperature set between a first temperature of the cold environment and a second temperature of the warm environment.
In another aspect, there is provided a heating and cooling system comprising a first container and a second container, the first container located inside an enclosed space to be heated or cooled, the second container located outside of the enclosed space. Both the first and second containers contain a plurality of encapsulated phase change material (PCM) units or capsules. Transfer means, such as endless screws, conveyor belts, gravity chutes, feeders etc., are provided between the first and second containers to physically move the plurality of individually encapsulated PCM units between the first and second containers. Various fluids, such as air and water to name a few, may be used to cool and/or heat the PCM capsules. In air-based applications, air moving means are provided to cause first and second air streams to respectively flow through the first and second containers in between the PCM capsules contained therein, so that the encapsulated PCM capsules in the first and second containers are exposed to respective air streams.
According to another aspect, the system may further include a PCM capsule reservoir, ready to feed the first and/or the second container, whichever is the one that has priority based on thermal demand, whether it be for coolth or warmth.
In another aspect, while within their respective containers, the PCM capsules are exposed to heat or cold for a given period to absorb thermal energy. A fan or the like may move air through each of the first and second containers, so that the plurality of PCM capsules are exposed to the passing air by forced convection and attain the temperature of their respective air streams. Upon activation of transfer means, the PCM units are displaced physically from one container to the other. By doing so, thermal energy is therefore transferred from the first container to the second container and vice versa. In heating applications, the heat is transferred from the exterior air stream (warm) to the interior (i.e., the cold enclosed space to be heated). In air-conditioning applications, heat is transferred from the interior air stream (i.e., the warm enclosed space to be cooled) to the exterior air stream (cold).
According to another aspect, the system has a controller configured so that the heat transfer between warm and cold sources occurs during the phase-change transformation of the capsules, e.g., while the PCM core of the capsules is melting and/or solidifying. To this end, the controller may be operatively connected to the capsules transfer means and to the air moving means for regulating the movement of the capsules from one environment to the other as well as the flow of air or other heat transfer fluid passing therearound. The transfer rate of the capsules and the flow rate of the heat transfer fluid may be adjusted according to control commands generated by the controller so as to take advantage of the latent heat available during the phase-change transformation of the PCM capsules.
According to another aspect, each encapsulated PCM unit comprises a PCM or storage material core in liquid and/or solid form enclosed within an outer shell. The PCM/storage material is selected to have a melting point temperature set between the respective temperatures of the cold and the hot sources/environments, so that the PCM changes phase (liquid-to-solid or solid-to-liquid) when exposed to the different sources/environments. This contributes to ensure that a maximum amount of thermal energy is transferred between both environments, even though the temperature difference between them can be relatively small. In operation, the encapsulated PCM material is exposed to a heat source to capture (store) heat. It is then transferred/moved to a cold source where the stored heat is discharged. The plurality of encapsulated PCM units travel through mechanical means or the like between the hot and cold sources to supply the desired heating or cooling effect. Heat moves from the cold side to the warm side, so depending on whether the system is being used in cooling or heating mode, the warm and cold PCM units will be travelling in one direction, and then in the opposite direction when the system switches from one mode to the other.
According to another further aspect, in a heating mode of the system, the warm PCM units (filled with melted PCM) will be travelling from an outdoor container (e.g., the first container) to an indoor container (e.g., the second container located in the enclosed space or process to be heated), and the cold PCM units (with solid PCM) will be traveling from the indoor container to the outdoor container. In the cooling mode of the system, the warm PCM units (filled with melted PCM) will be travelling from the indoor container to the outdoor container, and the cold PCM units (with solid PCM) will be traveling from the outdoor container to the indoor container.
In a further aspect, the shape and configuration of the encapsulated PCM units is selected to facilitate handling and transfer of the PCM units/capsules from one container to the other. For instance, the PCM units/capsules can be provided in the form of spherical balls, small cylinders, pouches, pellets or any other form that can facilitate conveying of the individual units by mechanical transfer means between the first and second containers. The outer shell of each PCM unit can be solid or soft. The outer shell is made out of thermally conductive and permeable material; and it should be durable enough to withstand frequent changes in the storage material's volume as phase changes occur.
According to a still further aspect, there is provided an apparatus comprising a first container located in a cold environment, a second container located in a warm environment, a plurality of encapsulated solid-liquid phase change material (PCM) units inside the first and second containers, the plurality of encapsulated solid-liquid PCM units in heat exchange relationship with respective fluid streams flowing through the first and second containers, and transfer means for physically moving the encapsulated solid-liquid PCM units from the first container to the second container and vice versa. By moving the PCM units from one container to the other and exposing the PCM units to fluid streams at different temperatures, thermal energy is transferred from one environment to the other.
According to a still further aspect, there is provided a heat transfer system comprising: a first container and a second container, the first container located in a first environment, the second container located in a second environment, the first environment having a first temperature, the second environment having a second temperature, the first and second temperatures being different, the first and second containers each containing a plurality of capsules having a phase change material (PCM) core encapsulated in a thermally conductive outer shell, the PCM core having a phase change temperature selected between the first and second temperatures; a first fluid circuit for circulating a first fluid in heat exchange relationship with the plurality of capsules inside the first container; a second fluid circuit for circulating a second fluid in heat exchange relationship with the plurality of capsules inside the second container; transfer means between the first and second containers for transferring the plurality of capsules from the first container to the second container and vice versa; and a controller operatively connected to the transfer means and the first and second fluid circuits, the controller configured for controlling a flow rate of the plurality of capsules between the first and the second containers as a function of a temperature and a flow rate of the first fluid through the first container and a temperature and a flow rate of the second fluid through the second container.
According to a still further aspect, there is provided a heat transfer system comprising: a first container; a second container remote from the first container; a solid-liquid phase change material (PCM) having a phase change temperature selected between a first temperature of the first container and a second temperature of the second container, an entirety of the PCM encapsulated in individual capsules; a transfer mechanism for transferring the individual capsules from the first container to the second container and vice versa; a first heat transfer fluid circuit for directing a first heat transfer fluid through the first container, the first heat transfer fluid in heat exchange relationship with the individual capsules inside the first container; and a second heat transfer fluid circuit for directing a second heat transfer fluid through the second container, the second heat transfer fluid in heat exchange relationship with the individual capsules inside the second container.
Reference is now made to the accompanying figures in which:
PCMs are materials that absorb and release heat energy when they change phase. The thermal energy absorbed or released by the material as the phase change occurs, for example solid to liquid, is known as latent heat. That is heat which flows to or from the material without a change in the material temperature while phase change occurs. Such latent heat storage can be more efficient than sensible heat storage (i.e., heat energy stored in a substance as a result of an increase in its temperature) because it requires a smaller temperature difference between the storage and releasing functions. As will be seen hereinafter, the system is configured to maintain the PCM in the heat latent phase.
The system 10 generally comprises a first container 12 and a second container 14. According to one embodiment, the containers 12, 14 have a cylindrical shape. However, it is understood that other shapes and configurations are possible. The first and second containers 12, 14 are disposed in different environments E1, E2. For instance, as shown in
For air-based systems (i.e., systems in which air is circulated in between the PCM capsules 16 inside the containers 12, 14), the first and second fluid circuit are provided with air moving means, such as fans 20, 22, for circulating air in heat exchange relationship with the PCM capsules 16 inside the first and second containers 12, 14. To that end, each container 12, 14 has at least one air inlet 12a, 14a and at least one air outlet 12b, 14b. The air inlets 12a, 14a and air outlets 12b, 14b can take various forms. For instance, the container walls can be perforated to provide a plurality of holes/ports for allowing air to flow into and out of the containers 12, 14. According to some embodiments, each of the containers 12, 14 includes a single air inlet and a single air outlet. The air inlets and the air outlets are suitably disposed on the containers 12, 14 to maximize the exposure of the PCM units/capsules 16 to the first and second air streams A1, A2 (
The use of air as the heat transfer fluid is advantageous in that leaks are much less critical in air-based systems than liquid-based systems. Also, most existing heating, ventilation, and air conditioning (HVAC) systems in North America are air-based, which may be advantageous from a retrofit point of view. Furthermore, air offers no chance of overheating or freezing. Air is also cheap and readily available. However, it is understood that other heat transfer fluids (e.g., water) could be used to carry heat to and away from the PCM capsules 16.
Each encapsulated PCM unit/capsule 16 generally comprises a solid-liquid PCM core encapsulated in a thin outer shell. The PCM core is selected to be subject to liquid-to-solid and solid-to-liquid phase changes within the temperature ranges prevailing in the first and second environments E1, E2. The encapsulated material changes phase from solid to liquid to absorb heat and from liquid to solid to give off heat. According to some embodiments, the PCM core is selected to have a melting temperature between a first temperature of the first environment E1 (e.g., the cold environment) and a second temperature of the second environment E2 (e.g., the warm environment) so that the solid-liquid phase change material changes phases when exposed to the first and second environments E1, E2, thereby providing for a maximum amount of thermal energy transferred between both environments, even though the temperature difference between the environments E1, E2 can be relatively small.
The outer shell of each PCM unit 16 can be solid or soft. The outer shell is made of a heat conducting material that is suitable for containing the PCM in both its liquid and its solid phase. The outer shell material should be durable enough to withstand frequent changes in the storage material's volume as phase changes occur. For instance, the outer shell could be made out of a metallic material, such as aluminium. Alternatively, the PCM core could be encapsulated in a polymer material, less conductive but cheaper to produce, or any other materials suitable to contain PCM and allow for heat transfer.
As shown in
It is understood that the capsule can adopt various shapes other than spherical, provided the PCM capsules 16 can be moved/conveyed from one container to another and allow for around the individual capsules.
The transfer mechanism 18 can take the form of any transfer means suitable to physically transfer/convey the encapsulated PCM units 16 between the containers 12, 14. For instance, the transfer mechanism 18 could include mechanical transfer apparatuses, such as endless screws, pneumatic air tubes, conveyor belts, etc. According to the example illustrated in
The transfer mechanism 18 further comprises a second endless screw conveyor (or other means of capsule transfer) 30 having a bottom intake end 30a and a top discharged end 30b. The bottom intake end 30a of the second screw conveyor 30 is disposed to receive PCM units/capsules 16 from a gravity chute 32 provided at the bottom end of the second container 14. The top discharged end 30b of the second endless screw conveyor 30 communicates with a top end of the first container 12 via a second discharge pipe 34. The second discharge pipe 34 slopes downwardly from the top discharged end 30b of the second endless screw conveyor 30 to an opening defined at a top end of the first container 12. In this way, PCM units/capsules 16 can be transferred from the bottom of the second container 14 to the top of the first container 12.
The controller can be operatively connected to the first and second conveyors 24, 30 to control the flow rate of the PCM capsules 16 from one container to the other as a function of the temperature and fluid flow (e.g., air flow) in the warm environment (heat charge cycle of the system) and the temperature and fluid flow in the cold environment (heat discharge cycle of the system). As mentioned above, the controller may be operatively connected to sensors for measuring various parameters (flow rate, temperature, pressure, etc.) of the fluid flow through the first and second containers. Signals received from the sensors are computed by the controller to generate control commands to the various actuable components of the first and second fluid circuits and to the transfer mechanism of the PCM capsules.
Depending on operational factors and set points, the rate at which the PCM capsules 16 are moved from one container to the other is variable. In some embodiments, the rate of transfer is determined by factors such as: 1) air cooling or heating power required by end-user; 2) availability of cool source; and 3) availability of heat source: if the heat source on the outside varies through a given period (for instance in the case of solar air collectors), the PCM will melt more quickly. That being, for heating applications, the closer the incoming temperature (overshoot) is to the PCM melting temperature, the better. Same with cooling: the closer the nighttime temperature (undershoot) to the solidifying temperature of the PCM, the better (in terms of energy efficiency). In the real world, the lower the temperature differential (positive or negative), the more the use of free, diurnal to nocturnal temperature differences, can be used to the user's advantage.
In operation, one of the objectives is to remain within the phase-change/latent heat state of heat transfer, which will yield greater outputs and efficiency values than for conventional batch/immovable systems where the PCM remains stationary in a given environment. As can be appreciated from
The graphs of
As can be appreciated from
Referring to the graphs of
Heat transfer between the PCM and the surrounding heat transfer fluid (e.g., air) always remains within phase change temperature range, thereby narrowing the gap between melting and fluid temperatures.
The output of the present technology will be a heating or cooling effect of the fluid (e.g., air). To achieve that, the above-described system will consume electricity for moving the PCM capsules from one container to the other, and to move the fluid within each container. According to some applications, the thermal output of the system may be 20 times greater that the electricity input into the system. This ratio of 20 to 1 (20:1) means that the expected coefficient of performance (COP) will be 20 or more. In comparison, most commercially available, conventional heat pumps have a COP of 3, 4 or 5, and at best, up to 8 or 9.
Preferably, the heat source will be free or, at least, as cheap as possible. For instance, the heat source could consists of: waste heat from a process, exhaust air from a building, air or water-based solar collectors, off-peak electric heat, exothermal composting process, ground-source, or water from rivers and lakes.
Again, in at least some embodiments, a low energy consumption (in the form of electricity) will be required compared to the heat output of the apparatus. For instance, some embodiments may provide a 1:20 ratio range.
By moving/transferring the PCM capsules between the environments/sources, the stock of fully melted or fully solid PCM (where only sensible heat transfer occurs) within the system may be kept to a minimum. Most capsules operate within the phase-change zone (where latent heat transfer occurs). In this way, the ratio latent/total heat transfer may be maximized. This means most heat transfer happens, at any time and at any position with the system, at the lowest possible temperature differential between the heat source and the melting point. This allows for low-temperature heat sources (such as provided by transpired unglazed solar air collectors) to be able to be stored for later use in a helpful manner, for example from daytime low-temperature charging to nigh time slow discharging.
Such a low-temperature differential is not insignificant because:
Graphically, as can be appreciated from
The overshoot and undershoot temperatures illustrate the necessary temperature difference between incoming air and melting point required to actually effect latent heat transfer above or below the phase change temperature.
When heat is absorbed during daytime, it can be temporarily stored for later delivery the following evening/night or at any later time when desired. When coolth is absorbed during nighttime, it can be temporarily stored for later delivery the following day or at least following evening/night or at any later time when desired. If a long delay is needed between charging and discharging, there can be storage of the PCM capsules in a buffer container 40 as for instance exemplified in
The demand for air conditioning around the world is larger than for heating. The present technology can advantageously be used for air conditioning purposes, particularly in zones where summer nights are cool, such as in dryer climates. Because cool nighttime air can be used to solidify the PCM capsules/units at night, the technology is well suited for use in places where there is a great daytime vs nighttime temperature difference, where hot days are followed by cold nights. Such conditions can be found in drier climates such as the Western US states, the Canadian prairies or the Pacific coast of South America.
As shown in
Referring to
The various embodiments of the system 10 may be configured and sized for one-day cycle:
Alternatively, the system may be configured and sized for much later use, for example in seasonal storage, that is:
Thermal masses not filled with PCM, that is thermal masses with sensible heat storage only, could be used together with the PCM capsules 16. For instance, rocks, bricks, metal bullets, etc. in the solid-only phase; water, glycol solution, refrigerant, anti-freeze mix, etc., in the liquid-phase only could be used in combination with the encapsulated PCM.
It can be appreciated from the present disclosure that the system 10 allows to actively renew the PCM capsules within one container with new capsules that are not at the same state, thereby allowing improving heat transfer. This may be accomplished by setting the PCM capsules in motion between environments that are different temperatures. It provides for a dynamic system, where the PCM capsules are transferred/moved so that the bulk of the capsules subject to heat charge or heat discharge are in the process of changing from a solid state to a liquid state and from a liquid state to a solid state, respectively (i.e. the PCM is in its latent state). Advantageously, unlike conventional heat pumps, the system operates without the need for a compressor since the cold side and the hot side of the system generally operate at the same pressure (e.g., the atmospheric pressure).
It can be appreciated that at least some of the contemplated embodiments allow cooling or heating an enclosed space or process without having to resort to the combustion of any fossil fuel, thereby making them more environmentally friendly. Indeed, electrical energy may be used to 1) convey the PCM units between the containers with mechanical means and/or gravity, and to 2) move the air (or maybe in some cases water) through the PCM in each container with mechanical fans or pumps. It is noted that the electricity may come from the grid, but also from other sources such photovoltaic panels, making the system in this case operate fully off the electrical grid. It can thus be appreciated that at least some embodiments provide for a low energy input vs high thermal output, thereby providing for an efficient heating and cooling system with COP values that have not so far been reached with refrigerant-charged systems, such as traditional heat pumps
The embodiments described in this document provide non-limiting examples of possible implementations of the present technology. Upon review of the present disclosure, a person of ordinary skill in the art will recognize that changes may be made to the embodiments described herein without departing from the scope of the present technology. Any modifications that could be implemented by a person of ordinary skill in the art in view of the present disclosure would be within the scope of the present technology.
This application claims priority on Provisional U.S. Application No. 63/488,978 filed Mar. 8, 2023, the entire content of which is incorporated by reference herein.
Number | Date | Country | |
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63488978 | Mar 2023 | US |