This application is a National Stage Entry of and claims priority under 35 §§365 and 371 to PCT application serial no. PCT/EP2012/066486, filed Aug. 24, 2012 and entitled “Heating Smokeable Material,” which in turn claims priority to Russian Application Serial No. 2011 136 872, filed Sep. 6, 2011 and entitled “Heating Smokeable Material,” and to Russian Application Serial No. 2012 108 431, filed Mar. 6, 2012 and entitled “Heating Smokeable Material.” The entire contents of the aforementioned applications are herein expressly incorporated by reference.
The invention relates to heating smokable material.
Smoking articles such as cigarettes and cigars burn tobacco during use to create tobacco smoke. Attempts have been made to provide alternatives to these smoking articles by creating products which release compounds without creating tobacco smoke. Examples of such products are so-called heat-not-burn products which release compounds by heating, but not burning, tobacco.
According to the invention, there is provided an apparatus comprising a heating chamber configured to heat smokable material in the chamber, the apparatus being operable in a first configuration to allow a gaseous flow between an interior of the chamber and an exterior of the chamber and operable in a second configuration to prevent the gaseous flow by hermetically sealing the chamber.
The apparatus may comprise a heater configured to heat the smokable material inside the chamber to volatilize at least one component of the smokable material.
In the first configuration the at least one volatized smoke component may be allowed to flow out of the heating chamber for inhalation and in the second configuration the at least one volatized smoke component may be sealed inside the heating chamber.
The apparatus may be configured to operate in the first configuration in response to an indication of a puff at a mouthpiece of the apparatus and may be configured to operate in the second configuration in response to an indication that the puff has ended.
The heating chamber may comprise an inlet which is open in the first configuration and hermetically sealed in the second configuration, the first configuration allowing gaseous flow through the inlet and the second configuration preventing gaseous flow through the inlet.
The inlet may be configured to open in response to a force exerted on the inlet due to a gaseous flow caused by a user puffing at a mouthpiece.
The inlet may be configured to hermetically seal in response to a lack of said force.
The inlet may be configured to open in response to a signal from a puff sensor indicative of a puff and may be configured to hermetically seal in response to an end of the puff.
The inlet may comprise a one-way valve configured to allow a gaseous flow into the heating chamber in the first configuration and to prevent a gaseous flow out of the heating chamber in the second configuration.
The inlet may be provided in insulation, such as vacuum insulation, which is configured to thermally insulate the heating chamber.
The apparatus may comprise an outlet which is open in the first configuration and hermetically sealed in the second configuration, the first configuration allowing gaseous flow through the outlet and the second configuration preventing gaseous flow through the outlet.
The outlet may be configured to open in response to a force exerted on the outlet due to a gaseous flow caused by a user puffing at a mouthpiece.
The outlet may be configured to hermetically seal in response to a lack of said force.
The outlet may be configured to open in response to a signal from a puff sensor indicative of a puff and to hermetically seal in response to an end of the puff.
The outlet may comprise a one-way valve configured to allow a gaseous flow out of the heating chamber in the first configuration and to prevent a gaseous flow into the heating chamber in the second configuration.
The outlet may be provided in insulation, such as vacuum insulation, which is configured to thermally insulate the heating chamber.
The apparatus may be configured to heat the smokable material without combusting the smokable material.
According to the invention, there is also provided a method for heating smokable material in a heating chamber, comprising:
According to an aspect of the invention, there is provided an apparatus configured to heat smokable material to volatilize at least one component of the smokable material, comprising an infra-red heater.
The infra-red heater may comprise a halogen infra-red heater.
For exemplary purposes only, embodiments of the invention are described below with reference to the accompanying figures in which:
As used herein, the term ‘smokable material’ includes any material that provides volatilized components upon heating and includes any tobacco-containing material and may, for example, include one or more of tobacco, tobacco derivatives, expanded tobacco, reconstituted tobacco or tobacco substitutes.
An apparatus 1 for heating smokable material comprises an energy source 2, a heater 3 and a heating chamber 4. The energy source 2 may comprise a battery such as a Li-ion battery, Ni battery, Alkaline battery and/or the like, and is electrically coupled to the heater 3 to supply electrical energy to the heater 3 when required. The heating chamber 4 is configured to receive smokable material 5 so that the smokable material 5 can be heated in the heating chamber 4. For example, the heating chamber 4 may be located adjacent to the heater 3 so that thermal energy from the heater 3 heats the smokable material 5 therein to volatilize aromatic compounds and nicotine in the smokable material 5 without burning the smokable material 5. A mouthpiece 6 is provided through which a user of the apparatus 1 can inhale the volatilized compounds during use of the apparatus 1. The smokable material 5 may comprise a tobacco blend.
As shown in
A housing 7 may contain components of the apparatus 1 such as the energy source 2 and heater 3. As shown in
For example, as shown in
Heat insulation may be provided between the energy source 2 and the heater 3 to prevent direct transfer of heat from one to the other. The mouthpiece 6 can be located at the second end 9 of the housing 7, adjacent the heating chamber 4 and smokable material 5. The housing 7 is suitable for being gripped by a user during use of the apparatus 1 so that the user can inhale volatilized smokable material compounds from the mouthpiece 6 of the apparatus 1.
Referring to
As indicated above and shown in
The heater 3 may optionally comprise a plurality of individual heating regions 10. The heating regions 10 may be operable independently of one another so that different regions 10 can be activated at different times to heat the smokable material 5. The heating regions 10 may be arranged in the heater 3 in any geometric arrangement. However, in the examples shown in the figures, the heating regions 10 are geometrically arranged in the heater 3 so that different ones of the heating regions 10 are arranged to predominately and independently heat different regions of the smokable material 5.
For example, referring to
In this way, when a particular one of the heating regions 10 is activated, it supplies thermal energy to the smokable material 5 located radially around the heating region 10 without substantially heating the remainder of the smokable material 5. For example, referring to
Additionally or alternatively, referring to
In this way, when a particular one of the heating regions 10 is activated, it supplies thermal energy to the smokable material 5 located adjacent to the heating region 10 without substantially heating the remainder of the smokable material 5. The heated section of smokable material 5 may comprise a longitudinal section of smokable material 5 which lies parallel and directly adjacent to the longitudinal heating region 10. Therefore, as with the previous example, the smokable material 5 can be heated in independent sections.
As will be described further below, the heating regions 10 can each be individually and selectively activated.
The smokable material 5 may be comprised in a cartridge 11 which can be inserted into the heating chamber 4. For example, as shown in
The housing 7 of the apparatus 1 may comprise an opening through which the cartridge 11 can be inserted into the heating chamber 4. The opening may, for example, comprise a ring-shaped opening located at the housing's second end 9 so that the cartridge 11 can be slid into the opening and pushed directly into the heating chamber 4. The opening is preferably closed during use of the apparatus 1 to heat the smokable material 5. Alternatively, a section of the housing 7 at the second end 9 is removable from the apparatus 1 so that the smokable material 5 can be inserted into the heating chamber 4. An example of this is shown in
In an alternative configuration of heater 3, the heater 3 comprises a spirally shaped heater 3. The spirally shaped heater 3 may be configured to screw into the smokable material cartridge 11 and may comprise adjacent, axially-aligned heating regions 10 so as to operate in substantially the same manner as described the linear, elongate heater 3 described above.
In an alternative configuration of heater 3 and heating chamber 4, the heater 3 comprises a substantially elongate tube, which may be cylindrical, and the heating chamber 4 is located inside the tube 3 rather than around the heater's outside. The heater 3 may comprise a plurality of axially-aligned heating sections, which may each comprise a heating ring configured to heat smokable material 5 located radially inwardly from the ring. In this way, the heater 3 is configured to independently heat separate sections of smokable material 5 in the heating chamber 4 in a manner similar to the heater 3 described above in relation to
Alternatively, referring to
The elongate smokable material cartridge or body 11 can be installed between, and removed from, the heating chamber 4 and heating plates 10 by removing a section of the housing 7 at the housing's second end 9, as previously described. The heating regions 10 can be individually and selectively activated to heat different sections of the smokable material 5 as required.
In this way, when a particular one or pair of the heating regions 10 is activated, it supplies thermal energy to the smokable material 5 located directly adjacent to the heating region(s) 10 without substantially heating the remainder of the smokable material 5. The heated section of smokable material 5 may comprise a radial section of smokable material 5 located between the heating regions 10, as shown in
The apparatus 1 may comprise a controller 12, such as a microcontroller 12, which is configured to control operation of the apparatus 1. The controller 12 is electronically connected to the other components of the apparatus 1 such as the energy source 2 and heater 3 so that it can control their operation by sending and receiving signals. The controller 12 is, in particular, configured to control activation of the heater 3 to heat the smokable material 5. For example, the controller 12 may be configured to activate the heater 3, which may comprise selectively activating one or more heating regions 10, in response to a user drawing on the mouthpiece 6 of the apparatus 1. In this regard, the controller 12 may be in communication with a puff sensor 13 via a suitable communicative coupling. The puff sensor 13 is configured to detect when a puff occurs at the mouthpiece 6 and, in response, is configured to send a signal to the controller 12 indicative of the puff. An electronic signal may be used. The controller 12 may respond to the signal from the puff sensor 13 by activating the heater 3 and thereby heating the smokable material 5. The use of a puff sensor 13 to activate the heater 3 is not, however, essential and other means for providing a stimulus to activate the heater 3 can alternatively be used. The volatilized compounds released during heating can then be inhaled by the user through the mouthpiece 6. The controller 12 can be located at any suitable position within the housing 7. An example position is between the energy source 2 and the heater 3/heating chamber 4, as illustrated in
If the heater 3 comprises two or more heating regions 10 as described above, the controller 12 may be configured to activate the heating regions 10 in a predetermined order or pattern. For example, the controller 12 may be configured to activate the heating regions 10 sequentially along or around the heating chamber 4. Each activation of a heating region 10 may be in response to detection of a puff by the puff sensor 13 or may be triggered in an alternative way, as described further below.
Referring to
Instead of activating each heating region 10 in response to an individual puff, the heating regions 10 may alternatively be activated sequentially, one after the other, in response to a single, initial puff at the mouthpiece 6. For example, the heating regions 10 may be activated at regular, predetermined intervals over the expected inhalation period for a particular smokable material cartridge 11. The inhalation period may, for example, be between approximately one and approximately four minutes. Therefore, at least the fifth and ninth steps S5, S9 shown in
It will be appreciated that activating individual heating regions 10 in order rather than activating the entire heater 3 means that the energy required to heat the smokable material 5 is reduced over what would be required if the heater 3 were activated fully over the entire inhalation period of a cartridge 11. Therefore, the maximum required power output of the energy source 2 is also reduced. This means that a smaller and lighter energy source 2 can be installed in the apparatus 1.
The controller 12 may be configured to de-activate the heater 3, or reduce the power being supplied to the heater 3, in between puffs. This saves energy and extends the life of the energy source 2. For example, upon the apparatus 1 being switched on by a user or in response to some other stimulus, such as detection of a user placing their mouth against the mouthpiece 6, the controller 12 may be configured to cause the heater 3, or next heating region 10 to be used to heat the smokable material 5, to be partially activated so that it heats up in preparation to volatilize components of the smokable material 5. The partial activation does not heat the smokable material 5 to a sufficient temperature to volatilize nicotine. A suitable temperature could be below 120° C., such as 100° C. or below. An example is a temperature between 60° C. and 100° C., such as a temperature between 80° C. and 100° C. The temperature may be less than 100° C. In response to detection of a puff by the puff sensor 13, the controller 12 can then cause the heater 3 or heating region 10 in question to heat the smokable material 5 further in order to rapidly volatilize the nicotine and other aromatic compounds for inhalation by the user. If the smokable material 5 comprises tobacco, a suitable temperature for volatilizing the nicotine and other aromatic compounds may be 100° C. or above, such as 120° C. or above. An example is a temperature between 100° C. and 250° C., such as between 100° C. and 220° C., between 100° C. and 200° C., between 150° C. and 250° C. or between 130° C. and 180° C. The temperature may be more than 100° C. An example full activation temperature is 150° C., although other values such as 250° C. are also possible. A super-capacitor can optionally be used to provide the peak current used to heat the smokable material 5 to the volatization temperature. An example of a suitable heating pattern is shown in
Three example operational modes of the heater 3 are described below.
In a first operational mode, during full activation of a particular heating region 10, all other heating regions 10 of the heater are deactivated. Therefore, when a new heating region 10 is activated, the previous heating region is deactivated. Power is supplied only to the activated region 10.
Alternatively, in a second operational mode, during full activation of a particular heating region 10, one or more of the other heating regions 10 may be partially activated. Partial activation of the one or more other heating regions 10 may comprise heating the other heating region(s) 10 to a temperature which is sufficient to substantially prevent condensation of components such as nicotine volatized from the smokable material 5 in the heating chamber 4. The temperature of the heating regions 10 which are partially activated is less than the temperature of the heating region 10 which is fully activated. The smokable material 5 located adjacent the partially activated regions 10 is not heated to a temperature sufficient to volatize components of the smokable material 5.
Alternatively, in a third operational mode, once a particular heating region 10 has been activated, it remains fully activated until the heater 3 is switched off. Therefore, the power supplied to the heater 3 incrementally increases as more of the heating regions 10 are activated during inhalation from the cartridge 11. As with the second mode previously described, the continuing activation of the heating regions 10 substantially prevent condensation of components such as nicotine volatized from the smokable material 5 in the heating chamber 4.
The apparatus 1 may comprise a heat shield 3a, which is located between the heater 3 and the heating chamber 4/smokable material 5. The heat shield 3a is configured to substantially prevent thermal energy from flowing through the heat shield 3a and therefore can be used to selectively prevent the smokable material 5 from being heated even when the heater 3 is activated and emitting thermal energy. Referring to
It will be appreciated that a similar result can be obtained by rotating or moving the smokable material 5 relative to the heater 3, heat shield 3a and window 3b. For example, the heating chamber 4 may be rotatable around the heater 3. If this is the case, the above description relating to movement of the heat shield 3a can be applied instead to movement of the heating chamber 4 relative to the heat shield 3a.
The heat shield 3a may comprise a coating on the longitudinal surface of the heater 3. In this case, an area of the heater's surface is left uncoated to form the heat-transparent window 3b. The heater 3 can be rotated or otherwise moved, for example under the control of the controller 12 or user controls, to cause different sections of the smokable material 5 to be heated. Alternatively, the heat shield 3a and window 3b may comprise a separate shield 3a which is rotatable or otherwise moveable relative to both the heater 3 and the smokable material 5 under the control of the controller 12 or other user controls.
Referring to
The apparatus 1 may comprise a smokable material compressor 16 configured to cause the smokable material 5 to compress upon activation of the compressor 16. The apparatus 1 can also comprise a smokable material expander 17 configured to cause the smokable material 5 to expand upon activation of the expander 17. The compressor 16 and expander 17 may, in practice, be implemented as the same unit as will be explained below. The smokable material compressor 16 and expander 17 may optionally operate under the control of the controller 12. In this case, the controller 12 is configured to send a signal, such as an electrical signal, to the compressor 16 or expander 17 which causes the compressor 16 or expander 17 to respectively compress or expand the smokable material 5. Alternatively, the compressor 16 and expander 17 may be actuated by a user of the apparatus 1 using a manual control on the housing 7 to compress or expand the smokable material 5 as required.
The compressor 16 is principally configured to compress the smokable material 5 and thereby increase its density during heating. Compression of the smokable material increases the thermal conductivity of the body of smokable material 5 and therefore provides a more rapid heating and consequent rapid volatization of nicotine and other aromatic compounds. This is preferable because it allows the nicotine and aromatics to be inhaled by the user without substantial delay in response to detection of a puff. Therefore, the controller 12 may activate the compressor 16 to compress the smokable material 5 for predetermined heating period, for example one second, in response to detection of a puff. The compressor 16 may be configured to reduce its compression of the smokable material 5, for example under the control of the controller 12, after the predetermined heating period. Alternatively, the compression may be reduced or automatically ended in response to the smokable material 5 reaching a predetermined threshold temperature. A suitable threshold temperature may be in the range of approximately 100° C. to 250° C., such as between 100° C. and 220° C., between 150° C. and 250° C., between 100° C. and 200° C. or between 130° C. and 180° C. The threshold temperature may be above 100° C., such as a value above 120° C., and may be user selectable. A temperature sensor may be used to detect the temperature of the smokable material 5.
The expander 17 is principally configured to expand the smokable material 5 and thereby decrease its density during puffing. The arrangement of smokable material 5 in the heating chamber 4 becomes more loose when the smokable material 5 has been expanded and this aids the gaseous flow, for example air from the inlets 14, through the smokable material 5. The air is therefore more able to carry the volatilized nicotine and aromatics to the mouthpiece 6 for inhalation. The controller 12 may activate the expander 17 to expand the smokable material 5 immediately following the compression period referred to above so that air can be drawn more freely through the smokable material 5. Actuation of the expander 17 may be accompanied by a user-audible sound or other indication to indicate to the user that the smokable material 5 has been heated and that puffing can commence.
Referring to
Thermal insulation 18 may be provided between the smokable material 5 and an external surface 19 of the housing 7 to reduce heat loss from the apparatus 1 and therefore improve the efficiency with which the smokable material 5 is heated. For example, referring to
Referring to
As shown in
Referring to the schematic illustration in
To reduce heat losses due to the thermal bridge 23, the thermal bridge 23 may be extended to increase its resistance to heat flow from the inwardly-facing section 21 to the outwardly-facing section 22. This is schematically illustrated in
Referring to
The mass of the smokable material 5 which is heated by the heater 3, for example by each heating region 10, may be in the range of 0.2 to 1.0 g. The temperature to which the smokable material 5 is heated may be user controllable, for example to any temperature within the temperature range of 100° C. to 250° C., such as any temperature within the range of 150° C. to 250° C. or the other volatizing temperature ranges previously described. The mass of the apparatus 1 as a whole may be in the range of 70 to 125 g. A battery 2 with a capacity of 1000 to 3000 mAh and voltage of 3.7V can be used. The heating regions 10 may be configured to individually and selectively heat between approximately 10 and 40 sections of smokable material 5 for a single cartridge 11.
It will be appreciated that any of the alternatives described above can be used singly or in combination. For example, as discussed above, the heater 3 may be located around the outside of the smokable material 5 rather than the smokable material 5 being located around the heater 3. The heater 3 may therefore circumscribe the smokable material 5 to apply heat to the smokable material 5 in a substantially radially inward direction.
In order to address various issues and advance the art, the entirety of this disclosure shows by way of illustration various embodiments in which the claimed invention(s) may be practiced and provide for superior smokable material heating apparatuses and methods. The advantages and features of the disclosure are of a representative sample of embodiments only, and are not exhaustive and/or exclusive. They are presented only to assist in understanding and teach the claimed features. It is to be understood that advantages, embodiments, examples, functions, features, structures, and/or other aspects of the disclosure are not to be considered limitations on the disclosure as defined by the claims or limitations on equivalents to the claims, and that other embodiments may be utilised and modifications may be made without departing from the scope and/or spirit of the disclosure. Various embodiments may suitably comprise, consist of, or consist essentially of, various combinations of the disclosed elements, components, features, parts, steps, means, etc. In addition, the disclosure includes other inventions not presently claimed, but which may be claimed in future.
Number | Date | Country | Kind |
---|---|---|---|
2011136872 | Sep 2011 | RU | national |
2012108431 | Mar 2012 | RU | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/EP2012/066486 | 8/24/2012 | WO | 00 | 3/12/2014 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2013/034456 | 3/14/2013 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
1886391 | Gauvin | Nov 1932 | A |
2104266 | McCormick | Jan 1938 | A |
3804100 | Fariello | Apr 1974 | A |
3805806 | Grihalva | Apr 1974 | A |
3889690 | Guarnieri | Jun 1975 | A |
4171000 | Uhle | Oct 1979 | A |
4303083 | Burruss, Jr. | Dec 1981 | A |
4474191 | Steiner | Oct 1984 | A |
4588976 | Jaselli | May 1986 | A |
4638820 | Roberts et al. | Jan 1987 | A |
4735217 | Gerth et al. | Apr 1988 | A |
4756318 | Clearman et al. | Jul 1988 | A |
4765347 | Sensabaugh et al. | Aug 1988 | A |
4907606 | Lilja et al. | Mar 1990 | A |
4922901 | Brooks et al. | May 1990 | A |
4945929 | Egilmex | Aug 1990 | A |
4945931 | Gori | Aug 1990 | A |
4947874 | Brooks et al. | Aug 1990 | A |
4947875 | Brooks et al. | Aug 1990 | A |
5040551 | Schlatter et al. | Aug 1991 | A |
5060671 | Counts et al. | Oct 1991 | A |
5095921 | Losee et al. | Mar 1992 | A |
5179966 | Losee et al. | Jan 1993 | A |
5190060 | Gerding et al. | Mar 1993 | A |
5224498 | Deevi et al. | Jul 1993 | A |
5249586 | Morgan et al. | Oct 1993 | A |
5269327 | Counts et al. | Dec 1993 | A |
5285798 | Banerjee et al. | Feb 1994 | A |
5303720 | Banerjee et al. | Apr 1994 | A |
5322075 | Deevi et al. | Jun 1994 | A |
5327915 | Porenski et al. | Jul 1994 | A |
5331979 | Henley | Jul 1994 | A |
5345951 | Serrano et al. | Sep 1994 | A |
5369723 | Counts et al. | Nov 1994 | A |
5388594 | Counts et al. | Feb 1995 | A |
5402803 | Takagi | Apr 1995 | A |
5408574 | Deevi et al. | Apr 1995 | A |
5573140 | Satomi et al. | Nov 1996 | A |
5613504 | Collins et al. | Mar 1997 | A |
5613505 | Campbell et al. | Mar 1997 | A |
5665262 | Hajaligol et al. | Sep 1997 | A |
5771845 | Pistien et al. | Jun 1998 | A |
5865186 | Volsey, II | Feb 1999 | A |
6089857 | Matsuura et al. | Jul 2000 | A |
6155268 | Takeuchi | Dec 2000 | A |
7374063 | Reid | May 2008 | B2 |
7624739 | Snaidr et al. | Dec 2009 | B2 |
7913688 | Cross et al. | Mar 2011 | B2 |
8061361 | Maeder et al. | Nov 2011 | B2 |
8079371 | Robinson et al. | Dec 2011 | B2 |
8678013 | Crooks et al. | Mar 2014 | B2 |
8807140 | Scatterday | Aug 2014 | B1 |
8833364 | Buchberger | Sep 2014 | B2 |
20030049025 | Neumann et al. | Mar 2003 | A1 |
20040003820 | Iannuzzi | Jan 2004 | A1 |
20040096204 | Gerhardinger | May 2004 | A1 |
20050063686 | Whittle et al. | Mar 2005 | A1 |
20050211711 | Reid | Sep 2005 | A1 |
20050268911 | Cross et al. | Dec 2005 | A1 |
20070074734 | Braunshteyn et al. | Apr 2007 | A1 |
20070155255 | Galauner et al. | Jul 2007 | A1 |
20070204858 | Abelbeck | Sep 2007 | A1 |
20070204868 | Bollinger et al. | Sep 2007 | A1 |
20070283972 | Monsees | Dec 2007 | A1 |
20080092912 | Robinson et al. | Apr 2008 | A1 |
20080216828 | Wensley et al. | Sep 2008 | A1 |
20080233318 | Coyle | Sep 2008 | A1 |
20080302374 | Wengert et al. | Dec 2008 | A1 |
20090032034 | Steinberg | Feb 2009 | A1 |
20090056728 | Baker | Mar 2009 | A1 |
20090126745 | Hon | May 2009 | A1 |
20090151717 | Bowen et al. | Jun 2009 | A1 |
20090272379 | Thorens et al. | Nov 2009 | A1 |
20100126516 | Yomtov et al. | May 2010 | A1 |
20100242975 | Hearn | Sep 2010 | A1 |
20110126848 | Zuber et al. | Jun 2011 | A1 |
20110155153 | Thorens et al. | Jun 2011 | A1 |
20120006342 | Rose et al. | Jan 2012 | A1 |
20120255546 | Goetz et al. | Oct 2012 | A1 |
20130081623 | Buchberger | Apr 2013 | A1 |
20140182843 | Vinegar | Jul 2014 | A1 |
20140202476 | Egoyants et al. | Jul 2014 | A1 |
20140216485 | Egoyants et al. | Aug 2014 | A1 |
20140270726 | Egoyants et al. | Sep 2014 | A1 |
20140283825 | Buchberger | Sep 2014 | A1 |
20140299125 | Buchberger | Oct 2014 | A1 |
20140305449 | Plojoux et al. | Oct 2014 | A1 |
20140326257 | Jalloul et al. | Nov 2014 | A1 |
20140338680 | Abramov et al. | Nov 2014 | A1 |
20140360515 | Vasiliev et al. | Dec 2014 | A1 |
20150040925 | Saleem et al. | Feb 2015 | A1 |
20150223520 | Phillips et al. | Aug 2015 | A1 |
Number | Date | Country |
---|---|---|
86102917 | Nov 1987 | CN |
1040914 | Apr 1990 | CN |
1045691 | Oct 1990 | CN |
119661 | Oct 1998 | CN |
2598364 | Jan 2004 | CN |
101238047 | Aug 2008 | CN |
101267749 | Sep 2008 | CN |
201185656 | Jan 2009 | CN |
101557728 | Oct 2009 | CN |
201375023 | Jan 2010 | CN |
29713866 | Oct 1997 | DE |
0358002 | Mar 1990 | EP |
0358114 | Mar 1990 | EP |
0430559 | Jun 1991 | EP |
0438862 | Jul 1991 | EP |
0488488 | Jun 1992 | EP |
0503767 | Sep 1992 | EP |
0603613 | Jun 1994 | EP |
1618803 | Jan 2006 | EP |
1736065 | Dec 2006 | EP |
2022349 | Feb 2009 | EP |
2110033 | Oct 2009 | EP |
2316286 | May 2011 | EP |
2327318 | Jun 2011 | EP |
2340730 | Jul 2011 | EP |
2394520 | Dec 2011 | EP |
426247 | Mar 1935 | GB |
62501050 | Apr 1987 | JP |
62-17980 | Aug 1988 | JP |
63-127399 | Aug 1988 | JP |
03192677 | Aug 1991 | JP |
03232481 | Oct 1991 | JP |
6189861 | Jul 1994 | JP |
06315366 | Nov 1994 | JP |
4-78508 | Jun 1996 | JP |
08000942 | Jun 1996 | JP |
09107943 | Apr 1997 | JP |
1189551 | Apr 1999 | JP |
11125390 | May 1999 | JP |
11169157 | Jun 1999 | JP |
2005036897 | Feb 2005 | JP |
2005106350 | Apr 2005 | JP |
2006501871 | Jan 2006 | JP |
2008249003 | Oct 2008 | JP |
2009537120 | Oct 2009 | JP |
2010506594 | Mar 2010 | JP |
2010178730 | Aug 2010 | JP |
2010213579 | Sep 2010 | JP |
2011509667 | Mar 2011 | JP |
8602528 | May 1986 | WO |
WO0167819 | Sep 2001 | WO |
WO03037412 | May 2003 | WO |
03059413 | Jul 2003 | WO |
WO03103387 | Dec 2003 | WO |
WO2007017482 | Feb 2007 | WO |
2007131450 | Nov 2007 | WO |
2008108889 | Sep 2008 | WO |
2009001082 | Dec 2008 | WO |
WO2009092862 | Jul 2009 | WO |
2010073018 | Jul 2010 | WO |
WO2010107613 | Sep 2010 | WO |
2010118644 | Oct 2010 | WO |
WO2011050964 | May 2011 | WO |
Entry |
---|
International Search Report and Written Opinion, mailed Jan. 14, 2013, for PCT/EP2012/066486, filed Aug. 24, 2012. |
International Preliminary Report on Patentability, mailed Oct. 22, 2013, for PCT/EP2012/066486, filed Aug. 24, 2012. |
Office Action (with machine English translation), dated Mar. 31, 2015, for JP 2014-519585, referencing JP 2010-506594, JP 03-232481, JP 2010-213579, JP 62-17980, JP 2006-501871, JP 4-78508, and JP 62-501050. |
First Office Action (dated Jun. 15, 2015) and Search Report (dated Jun. 2, 2015) for Chinese Patent Application No. 201280029784.X, filed Aug. 24, 2012. |
Application and File History for U.S. Appl. No. 14/127,879, filed May 9, 2014, inventors Egoyants et al. |
Application and File History for U.S. Appl. No. 14/127,144, filed Mar. 31, 2014, inventors Egoyants et al. |
Application and File History for U.S. Appl. No. 14/127,138, filed Feb. 10, 2014, inventors Egoyants et al. |
Application and File History for U.S. Appl. No. 14/127,133, filed Jul. 15, 2014, inventors Vasiliev et al. |
Office Action and Search Report (with English Translation) mailed Apr. 27, 2015, for CN201280030681.5. |
Office Action (with English Translation) mailed Apr. 7, 2015 for JP2014519586. |
International Search Report and Written Opinion, mailed Jan. 9, 2013, for International Apllication No. PCT/EP2012/066523 filed Aug. 24, 2012. |
International Preliminary Report on Patentability, mailed Nov. 4, 2013, for International Application No. PCT/EP2012/066523 filed Aug. 24, 2012. |
Search Report dated Mar. 24, 2015, for Chinese Patent Application No. 201280029767.6 filed Aug. 24, 2012 (including English Translation). |
International Search Report and Written Opinion, mailed Jan. 9, 2013 for International Application No. PCT/EP2012/066524, filed Aug. 24, 2012. |
International Preliminary Report On Patentability, mailed Oct. 17, 2013 for International Application No. PCT/EP2012/066524, filed Aug. 24, 2012. |
International Search Report and Written Opinion, mailed Dec. 10, 2012, for PCT/EP2012/066485, filed Aug. 24, 2012. |
Written Opinion, mailed Oct. 15, 2013, for PCT/EP2012/066485, filed Aug. 24, 2012. |
International Search Report and Written Opinion, mailed Jan. 9, 2013, for International Application No. PCT/EP2012/066484, filed Aug. 24, 2012, Nov. 4, 2015. |
Application and File History for U.S. Appl. No. 14/382,198, filed Aug. 29, 2014, inventors Saleem et al. |
International Search Report and Written Opinion, mailed Feb. 11, 2014 for PCT/EP2013/057539 filed Apr. 11, 2013. |
Warrier et al., “Effect on the Porous Structure of Graphite on Atomic Hydrogen Diffusion and Inventory”. Nucl. Fusion 47(2007) 1656-1663, DOI: 10.1088/0029-5515/47/12/003. |
Davies et al., (1983) Metallic Foams: Their Production, Properties and Applications, Journal of Materials Science, vol. 18 (7). p. 1899-1911. |
Application and File History for U.S. Appl. No. 13/583,381, filed Dec. 17, 2012, inventor Buchberger. |
International Search Report dated Jul. 18, 2011 issued in corresponding International Patent Application No. PCT/AT2011/000123. |
Application and File History for U.S. Appl. No. 14/927,537, filed Oct. 30, 2015, inventors Kaufman et al. |
Application and File History for U.S. Appl. No. 14/927,539, filed Oct. 30, 2015, inventors Blandino et al. |
Application and File History for U.S. Appl. No. 14/927,551, filed Oct. 30, 2015, inventors Blandino et al. |
Application and File History for U.S. Appl. No. 14/927,556, filed Oct. 30, 2015, inventors Blandino et al. |
Application and File History for U.S. Appl. No. 14/343,368, filed Jun. 24, 2014, inventors Abramov et al. |
International Search Report and Written Opinion mailed Jan. 9, 2013 for PCT/EP2012/066525 filed Aug. 24, 2012. |
Number | Date | Country | |
---|---|---|---|
20140182608 A1 | Jul 2014 | US |