Claims
- 1. A salt of a metal ion, complex ion or ammonium ion and a compound having the formula ##STR14## wherein R.sub.1 represents hydrogen atom or a lower alkyl group,
- R.sub.2 represents a lower alkyl group or a lower alkenyl group,
- n is an integer of 2 or 3,
- Z represents a halogen atom, nitro group or a lower alkyl group, and Z's may be the same or different, and
- Y represents an oxygen atom.
- 2. A salt of a metal ion, complex ion or ammonium ion and a compound having the formula ##STR15## wherein R.sub.1 represents a hydrogen atom or an alkyl group having from 1 to 3 carbon atoms,
- R.sub.2 represents an alkyl group having from 1 to 3 carbon atoms,
- X's are the same or different and each represents a halogen atom, an alkyl group having from 1 to 4 carbon atoms or a nitro group, and
- n is an integer of 2 or 3.
- 3. The salt of claim 1 wherein
- R.sub.1 is hydrogen atom or an alkyl group having 1 to 6 carbon atoms,
- R.sub.2 is an alkyl group having 1 to 6 carbon atoms or an alkenyl group having 3 to 6 carbon atoms,
- Z is a halogen atom, nitro group or an alkyl group having 1 to 4 carbon atoms.
- 4. The salt of claim 1 wherein
- R.sub.1 is hydrogen atom or an alkyl group having 1 to 3 carbon atoms,
- R.sub.2 is an alkyl group having 1 to 3 carbon atoms or an alkenyl group having 3 to 4 carbon atoms,
- Z is halogen atom, nitro group, an alkyl group having 1 to 4 carbon atoms.
- 5. The salt of claim 1 wherein
- R.sub.1 is methyl group,
- R.sub.2 is methyl group or allyl group,
- Z is chlorine atom, nitro group or methyl group.
- 6. The compound of claim 1 wherein the salt is a salt with a monovalent to trivalent metalic ion.
- 7. The salt of claim 6 wherein the salt is a calcium, magnesium, aluminum, copper, or sodium salt.
- 8. The salt of claim 1 selected from the group consisting of
- 1,3-dimethyl-4-(2,4-dichlorobenzoyl)-5-hydroxypyrazole calcium salt,
- 1,3-dimethyl-4-(2,4-dichlorobenzoyl)-5-hydroxypyrazole magnesium salt,
- 1,3-dimethyl-4-(2,4-dichlorobenzoyl)-5-hydroxypyrazle isopropylamine salt,
- 1,3-dimethyl-4-(2,4-dichlorobenzoyl)-5-hydroxypyrazole aluminum salt,
- 1,3-dimethyl-4-(2,4-dichlorobenzoyl)-5-hydroxypyrazole iron salt,
- 1,3-dimethyl-4-(2,4-dichlorobenzoyl)-5-hydroxypyrazole copper salt, or
- 1,3-dimethyl-4-(2,4-dichlorobenzoyl)-5-hydroxypyrazole sodium salt.
- 9. The salt of claim 2 wherein
- R.sub.1 represents a methyl group,
- R.sub.2 represents a methyl group,
- X's are the same or different and each represents a halogen atom, a methyl group or a nitro group, and
- n is an integer of 2 or 3.
- 10. The salt of claim 2 wherein
- R.sub.1 represents a methyl group,
- R.sub.2 represents a methyl group,
- X's are the same or different and each represents a chlorine atom, a methyl group, or a nitro group, and
- n is an integer of 2.
- 11. The salt of claim 2 wherein the metal ion is monovalent or trivalent.
- 12. The salt of claim 2 wherein the metallic ion is selected from the group consisting of sodium, potassium, calcium, magnesium, aluminum, iron, manganese, zinc, nickel, cobalt, and copper.
- 13. The salt of claim 2 wherein the metallic ion is selected from the group consisting of sodium, potassium, calcium, magnesium, aluminum, iron, manganese, zinc, nickel, cobalt, and copper, the complex ion is selected from the group consisting of [Cu(H.sub.2 O).sub.2 ].sup.++, [Mn(H.sub.2 O).sub.2 ].sup.++, [Ni(H.sub.2 O).sub.4 ].sup.++, [A(OH)].sup.++, [Zn(OH)].sup.+, [Cu(OH)].sup.+, [Cu(NH.sub.3).sub.2 ].sup.++ and [Co(NH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2)].sup.++ ; and the ammonium ion is selected from the group consisting of N.sup.+ H.sub.4, N.sup.+ H(CH.sub.3).sub.3, N.sup.+ H.sub.2 (C.sub.2 H.sub.5).sub.2, N.sup.+ H.sub.3 CH(CH.sub.3).sub.2, N.sup.+ H.sub.3 CH.sub.2 CH.sub.2 OH and N.sup.+ H.sub.3 CH.sub.2 CH.sub.2 OC.sub.2 H.sub.5.
Priority Claims (1)
Number |
Date |
Country |
Kind |
49-34939 |
Mar 1974 |
JPX |
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Parent Case Info
This is a division of application Ser. No. 953,357, filed Oct. 23, 1978, now abandoned, which, in turn, is a continuation of application Ser. No. 838,083, filed Sept. 30, 1977, now U.S. Pat. No. 4,146,726, which, in turn, is a division of application Ser. No. 558,682, filed on Mar. 17, 1975, now U.S. Pat. No. 4,063,925.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
4008200 |
Avar et al. |
Feb 1977 |
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4146540 |
Avar et al. |
Mar 1979 |
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Non-Patent Literature Citations (2)
Entry |
Sarenko et al., Khimiya Geterotsikl. Soedin. 1972 (6), pp. 799-808. |
Wamhoff et al., Chem. Abst. 1971, vol. 75, No. 20282v. |
Divisions (2)
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Number |
Date |
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Parent |
953357 |
Oct 1978 |
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Parent |
558682 |
Mar 1975 |
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Continuations (1)
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Number |
Date |
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Parent |
838083 |
Sep 1977 |
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