Claims
- 1. A herbicidal composition comprising an active thiocarbamate herbicide compound and a nonphytotoxic antidotally effective amount of a compound having the formula ##STR455## wherein each of R.sub.1 and R.sub.2 are alkenyl groups containing from 2 to 12 carbon atoms, inclusive; said compound being antidotally active with said thiocarbamate herbicide compound and wherein said compound is present in an amount ranging between about 0.0001 to 30 parts by weight for each part by weight of the active herbicidal compound.
- 2. A herbicidal composition comprising an active thiocarbamate herbicide compound and an antidotally effective amount of an antidote compound having the formula ##STR456## wherein said antidote compound is present in an amount ranging between about 0.0001 to 30 parts by weight for each part by weight of the active herbicidal compound.
- 3. The herbicidal composition as set forth in claim 1 wherein said active thiocarbamate is selected from the group consisting of EPTC, S-ethyl diisobutyl thiocarbamate, S-propyl dipropyl thiocarbamate, S-2,3,3-trichloroallyl-di-isopropyl thiocarbamate, S-4-chlorobenzyl diethyl thiocarbamate, S-ethyl cyclohexylethyl thiocarbamate or S-ethyl hexahydro-1H-azepine-1-carbothioate.
- 4. The herbicidal composition as set forth in claim 2 wherein said active thiocarbamate is selected from the group consisting of EPTC, S-ethyl diisobutyl thiocarbamate, S-propyl dipropyl thiocarbamate, S-2,3,3-trichloroallyl-di-isopropyl thiocarbamate, S-4-chlorobenzyl-diethyl thiocarbamate S-ethyl cyclohexylethyl thiocarbamate and S-ethyl hexahydro-1H-azepine-1-carbothioate.
- 5. The herbicidal composition as set forth in claim 2 wherein said active thiocarbamate is S-ethyl diisobutyl thiocarbamate.
- 6. The herbicidal composition as set forth in claim 2 wherein said active thiocarbamate is S-propyl dipropyl thiocarbamate.
- 7. The herbicidal composition as set forth in claim 2 wherein said active thiocarbamate is S-2,3,3-trichloroallyl-diisopropyl thiocarbamate.
- 8. The herbicidal composition as set forth in claim 2 wherein said active thiocarbamate is S-ethyl cyclohexylethyl thiocarbamate.
- 9. The herbicidal composition as set forth in claim 2 wherein said active thiocarbamate is S-ethyl hexahydro-1H-azepine-1-carbothioate.
- 10. The herbicidal composition as set forth in claim 2 wherein said active thiocarbamate is S-4-chlorobenzyl diethyl thiocarbamate.
- 11. The method of controlling weed pests and protecting crop plants comprising adding to the habitat thereof an herbicidally effective amount of the composition as set forth in claim 1.
- 12. The method of controlling weed pests and protecting crop plants comprising adding to the habitat thereof an herbicidally effective amount of the composition as set forth in claim 2.
- 13. The method of protecting a plant crop from injury due to an active thiocarbamate herbicidal compound, comprising applying to the soil, in which an herbicidally effective amount of said active thiocarbamate herbicidal compound is used, a non-phytotoxic antidotally effective amount of a compound corresponding to the formula ##STR457## wherein each R.sub.1 and R.sub.2 are alkenyl groups containing from 2 to 12 carbon atoms, inclusive; said compound being antidotally active with said thiocarbamate herbicide compound.
- 14. The method according to claim 13 wherein each of R.sub.1 and R.sub.2 are --CH.sub.2 --CH=CH.sub.2.
- 15. The method of protecting a plant crop from injury due to the herbicidally active thiocarbamate compound EPTC, comprising applying to the soil a herbicidal composition, comprising an herbicidally effective amount of EPTC and a non-phytotoxic antidotally effective amount of a compound having the formula ##STR458## wherein each of R.sub.1 and R.sub.2 are alkenyl groups containing from 2 to 12 carbon atoms, inclusive; said compound being antidotally active with said EPTC and wherein said compound is present in an amount ranging between about 0.0001 to 30 parts by weight for each part by weight of the herbicidally active thiocarbamate.
- 16. The method of protecting a plant crop from injury due to the herbicidally active thiocarbamate compound EPTC, comprising applying to the soil a herbicidal composition, comprising an herbicidally effective amount of EPTC and an antidotally effective amount of an antidote compound having the formula ##STR459## wherein said antidote compound is present in an amount ranging between about 0.0001 to 30 parts by weight for each part by weight of the active herbicidal thiocarbamate.
- 17. The method according to claim 13 in which said thiocarbamate herbicide compound is selected from EPTC, S-ethyl diisobutyl thiocarbamate, S-propyl dipropyl thiocarbamate S-2,3,3-trichloroalkyl-di-isopropyl thiocarbamate, S-4-chlorobenzyl diethyl thiocarbamate S-ethyl cyclohexylethyl thiocarbamate and S-ethyl hexahydro-1H-azepine-1-carbothioate.
- 18. The method of protecting corn plants from injury due to EPTC, comprising applying to the soil in which an herbicidally effective amount of said EPTC is used, a nonphytotoxic antidotally effective amount of a compound corresponding to the formula ##STR460##
- 19. The method of protecting corn plants from injury due to S-ethyl diisobutyl thiocarbamate comprising applying to the soil in which an herbicidally effecting amount of said S-ethyl diisobutyl thiocarbamate is used, a non-phytotoxic antidotally effective amount of a compound corresponding to the formula ##STR461##
- 20. The method of protecting corn plants from injury due to S-propyl dipropyl thiocarbamate, comprising applying to the soil in which an herbicidally effective amount of said S-propyl dipropyl thiocarbamate is used, a non-phytotoxic antidotally effective amount of a compound corresponding to the formula ##STR462##
- 21. The herbicide composition as set forth in claim 1 wherein said active thiocarbamate is EPTC (S-ethyl N,N-di-n-propyl thiocarbamate).
- 22. The herbicide composition as set forth in claim 2 wherein said active thiocarbamate is EPTC (S-ethyl N,N-di-n-propyl thiocarbamate).
- 23. The method according to claim 14 in which the thiocarbamate herbicide compound is selected from EPTC, S-ethyl diisobutyl thiocarbamate, S-propyl dipropyl thiocarbamate, S-2,3,3-trichloroallyl-di-isopropyl thiocarbamate, S-4-chlorobenzyl diethyl thiocarbamate, S-ethyl cyclohexylethyl thiocarbamate and S-ethyl hexahydro-1H-azepine-1-carbothioate.
CROSS REFERENCE TO RELATED APPLICATION
This is a division of application Ser. No. 208,041, filed Dec. 9, 1971, which application is a continuation-in-part of copending application, Ser. No. 134,868, filed Apr. 16, 1971, now abandoned.
US Referenced Citations (8)
Non-Patent Literature Citations (1)
Entry |
Hamm et al., "Effect of Variations in the Acyl, etc.," (1957) J. Ag. & Food Chem., 5, pp. 30-32 (1957). |
Divisions (1)
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Number |
Date |
Country |
Parent |
208041 |
Dec 1971 |
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Continuation in Parts (1)
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Number |
Date |
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134868 |
Apr 1971 |
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