Claims
- 1. A herbicide composition comprising an active thiocarbamate herbicide compound and an antidotally effective amount of an antidote compound having the formula ##STR352## wherein R is selected from the group consisting of --CH(CH.sub.3)Br, --C(CH.sub.3).sub.2 Br, --CCl.sub.2 --CH.sub.3, --CF.sub.2 C.sub.2 F.sub.5, --CH.sub.2 Cl, --CCl.sub.3, --CBr.sub.3, --(CH.sub.2).sub.4 --CH.sub.2 Br, --CH.sub.2 --CH.sub.2 Cl and --CH.sub.2 I; and R.sub.1 and R.sub.2 are alkenyl containing from 2 to about 12 carbon atoms, inclusive; said antidote compound being antidotally active with said thiolcarbamate herbicide and wherein said antidote compound is present in an amount varying between about 0.0001 to 30 parts by weight for each part by weight of active herbicidal compound.
- 2. The herbicidal composition as set forth in claim 1 wherein said active thiolcarbamate herbicide is selected from the group consisting of EPTC, S-ethyl diisobutyl thiolcarbamate, S-propyl dipropyl thiolcarbamate, S-2,3-3-trichloroallyl diisopropyl thiolcarbamate, S-4-chlorobenzyl diethyl thiolcarbamate, S-ethyl cyclohexylethyl thiolcarbamate or S-ethyl hexahydro-1H-azepine-1-carbothioate.
- 3. The composition as set forth in claim 1 wherein R is --CH(CH.sub.3)Br; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 4. The composition as set forth in claim 1 wherein R is --C(CH.sub.3).sub.2 Br; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 5. The composition as set forth in claim 1 wherein R is --CCl.sub.2 --CH.sub.3 ; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 6. The composition as set forth in claim 1 wherein R is --CF.sub.2 --C.sub.2 F.sub.5 ; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 7. The composition as set forth in claim 1 wherein R is --CH.sub.2 Cl; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 8. The composition as set forth in claim 1 wherein R is --CCl.sub.3 ; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 9. The composition as set forth in claim 1 wherein R is CBr.sub.3 ; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 10. The composition as set forth in claim 1 wherein R is --(CH.sub.2).sub.4 --CH.sub.2 Br; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 11. The composition as set forth in claim 1 wherein R is --CH.sub.2 --CH.sub.2 Cl; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 12. The composition as set forth in claim 1 wherein R is --CH.sub.2 I; R.sub.1 and R.sub.2 are --CH.sub.2 --CH.dbd.CH.sub.2.
- 13. A method of controlling weed pests comprising adding to the habitat thereof an herbicidally effective amount of the composition as set forth in claim 2.
- 14. A method of controlling weed pests comprising adding to the habitat thereof an herbicidally effective amount of the composition as set forth in claim 1.
- 15. The method of protecting a plant crop from injury due to an active herbicidal thiolcarbamate, comprising applying to the plant seed prior to planting a non-phytotoxic antidotally effective amount of a compound corresponding to the formula ##STR353## wherein R is selected from the group consisting of --CH(CH.sub.3)Br, --C(CH.sub.3).sub.2 Br, --CCl.sub.2 --CH.sub.3, --CF.sub.2 C.sub.2 F.sub.5, --CH.sub.2 Cl, --CCl.sub.3, --CBr.sub.3, --(CH.sub.2).sub.4 --CH.sub.2 Br, --CH.sub.2 --CH.sub.2 Cl and --CH.sub.2 I; and R.sub.1 and R.sub.2 are alkenyl containing from 2 to about 12 carbon atoms, inclusive; said antidote compound being antidotally active with said thiolcarbamate herbicide.
- 16. The method of controlling weed pests and protecting a plant crop from injury due to an active thiolcarbamate herbicide, comprising applying to the soil a herbicidally effective amount of said herbicide and a non-phytotoxic antidotally effective amount of a compound having the formula ##STR354## wherein R is selected from the group consisting of --CH(CH.sub.3)Br, --C(CH.sub.3).sub.2 Br, --CCl.sub.2 --CH.sub.3, --CF.sub.2 C.sub.2 F.sub.5, --CH.sub.2 Cl, --CCl.sub.3, --CBr.sub.3, --(CH.sub.2).sub.4 --CH.sub.2 Br, --CH.sub.2 --Cl and --CH.sub.2 I; and R.sub.1 and R.sub.2 are alkenyl containing from 2 to about 12 carbon atoms, inclusive; said antidote compound being antidotally effective with said thiolcarbamate herbicide.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a division of application Ser. No. 930,967, filed Aug. 4, 1978, which is a division of application Ser. No. 208,041, filed Dec. 9, 1971, now U.S. Pat. No. 4,137,070, which is a CIP of application Ser. No. 134,868, filed Apr. 16, 1971, now abandoned.
US Referenced Citations (7)
Non-Patent Literature Citations (2)
Entry |
Speziale et al., "Prep. of 2-Substituted Acetamides," (1956), JACS 78, pp. 5580-5584. |
Hamm et al., "Effect of Variations etc.," (1957), J. Ag. Food Chem. 5, pp. 30-32, (1975). |
Divisions (2)
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Number |
Date |
Country |
Parent |
930967 |
Aug 1978 |
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Parent |
208041 |
Dec 1971 |
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Continuation in Parts (1)
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Number |
Date |
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Parent |
134868 |
Apr 1971 |
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