Claims
- 1. A compound of the formula ##STR689## in which R.sup.1, R.sup.2, R.sup.5 and R.sup.6 independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R.sup.3 and R.sup.4 independently represent a hydrogen atom, a hydroxy group or an alkyl group having 1 to 4 carbon atoms,
- Y represents a nitrogen atom or ##STR690## R.sup.9 represents a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, a hydroxy group, an alkoxy group having 1 to 4 carbon atoms, a benzyloxy group, an alkyl group having 1 to 4 carbon atoms which may be substituted by at least one member selected from the class consisting of a fluorine atom, a chlorine atom, a hydroxy group, an alkoxy group having 1 to 2 carbon atoms, alkylthio groups having 1 to 2 carbon atoms, a cyano group, a dimethylamino group, alkylcarbonyl groups having an alkyl with 1 to 2 carbon atoms and alkoxycarbonyl groups having an alkyl with 1 to 2 carbon atoms,
- an alkenyl group having 2 to 3 carbon atoms, a phenyl group,
- an alkylcarbonyl group having an alkyl with 1 to 4 carbon atoms which may be substituted by at least one member selected from the class consisting of a methoxy group, a chlorine atom and a fluorine atom,
- an alkenylcarbonyl group having an alkenyl with 2 to 3 carbon atoms,
- a benzoyl group which may be substituted by at least one member selected from the class consisting of a fluorine atom, a chlorine atom, a bromine atom,
- a methoxy group and a methyl group,
- an alkoxycarbonyl group which may be substituted by a fluorine atom and/or a chlorine atom,
- an alkylthiocarbonyl group having an alkyl with 1 to 4 carbon atoms,
- a phenoxycarbonyl group which may be substituted by at least one member selected from the class consisting of a fluorine atom, a chlorine atom, a bromine atom, a methyl group, a methoxy group and a nitro group,
- a phenylthiocarbonyl group, a benzyloxycarbonyl group,
- a benzoylaminocarbonyl group which may be substituted by at least one member selected from the class consisting of a methyl group, a fluorine atom,
- a chlorine atom and a bromine atom,
- a phenylsulfonylaminocarbonyl group which may be substituted by at least one member selected from the class consisting of a methyl group, a fluorine atom,
- a chlorine atom and a bromine atom,
- an alkylsulfonylaminocarbonyl group having an alkyl with 1 to 4 carbon atoms,
- an alkylthio group having 1 to 4 carbon atoms,
- an alkylsulfonyl group which may be substituted by a fluorine atom and/or a chlorine atom,
- a phentylthio group which may be substituted by at least one member selected from the class consisting of a methyl group, a fluorine atom, a chlorine atom and a bromine atom, or
- a phenylsulfonyl group which may be substituted by at least one member selected from the class consisting of a methyl group, a fluorine atom, a chlorine atom and a bromine atom,
- in addition, R.sup.9 may form a bis-form of the formula (I), via a methylene group,
- R represents a hydrogen atom or a methyl group, and
- Z represents a 5 to 6 membered heterocyclic group, containing one to three hetero atoms selected from the class consisting of an oxygen atom, a sulfur atom and a nitrogen atom, at least one of which is a nitrogen atom, which may be substituted by at least one member selected from the class consisting of a fluorine atom, a chlorine atom, a bromine atom, alkyl groups having 1 to 4 carbon atoms which may be substituted by a fluorine atom and/or a chlorine atom,
- a nitro group, a cyano group,
- alkylsulfinyl groups having 1 to 4 carbon atoms,
- alkylsulfonyl groups having 1 to 4 carbon atoms,
- alkoxy groups having 1 to 4 carbon atoms which may be substituted by a fluorine atom and/or a chlorine atom,
- alkylthio groups having 1 to 4 carbon atoms which may be substituted by a fluorine atom and/or a chlorine atom;
- alkenyl groups having 2 to 3 carbon atoms which may be substituted by a chlorine atom,
- an acetamide group which may be substituted by a fluorine atom and/or a chlorine atom,
- alkoxycarbonyl groups having an alkyl with 1 to 4 carbon atoms, a thiocyanato group,
- alkynyl groups having 2 to 4 carbon atoms,
- an amino group, a methylamino group,
- a dimethylamino group, an acetyl group,
- a formyl group, a carboxy group, a hydroxy group,
- a mercapto group, cycloalkyl groups having 3 to 7 carbon atoms, an oxo group, a thioxo group,
- alkenylthio groups substituted by a fluorine atom, a chlorine atom and/or a bromine atom, alkoxyalkyl groups having 2 to 4 carbon atoms in total,
- alkylaminocarbonyl groups having an alkyl with 1 to 2 carbon atoms,
- dialkylaminocarbonyl groups having an alkyl with 1 to 2 carbon atoms,
- a phenyl group, a phenoxy group and a benzyl group.
- 2. A compound according to claim 1, in which
- R.sup.1, R.sup.2, R.sup.5 and R.sup.6 independently represent a hydrogen atom or a methyl group,
- Y represents a nitrogen atom or ##STR691## R.sup.9 represents a hydrogen atom, a chlorine atom, a bromine atom, a hydroxy group, a methoxy group,
- a benzyloxy group, an alkyl group which may be substituted by at least one member selected from the class consisting of a fluorine atom, a chlorine atom, a hydroxy group, a methoxy group, a cyano group,
- a dimethylamino group, an acetyl group and a methoxycarbonyl group,
- an allyl group, a phenyl group,
- an acetyl group which may be substituted by a chlorine atom, a vinylcarbonyl group,
- an allylcarbonyl group, a benzoyl group,
- an alkoxycarbonyl group having an alkyl with 1 to 2 carbon atoms which may be substituted by a fluorine atom,
- n-butylthiocarbonyl group, a phenoxycarbonyl group which may be substituted by a chlorine atom and/or a methyl group, a phenylthiocarbonyl group, a benzyloxycarbonyl group, a benzoylaminocarbonyl group which may be substituted by a chlorine atom,
- a phenylsulfonylaminocarbonyl group which may be substituted by a methyl group,
- a methylsulfonylaminocarbonyl group,
- a propylthio group, a methylsulfonyl group which may be substituted by a fluorine atom and/or a chlorine atom, a phenylthio group which may be substituted by a chlorine atom, or a phenylsulfonyl group,
- in addition, R.sup.9 may form a bis-form of the formula (I), via a methylene group,
- R represents a hydrogen or a methyl group, and
- Z represents a 5 to 6 membered heterocyclic group, containing one to three hetero atoms selected from the class consisting of an oxygen atom, a sulfur atom and a nitrogen atom, at least one of which is a nitrogen atom, which may be substituted by at least one member selected from the class consisting of a fluorine atom, a chlorine atom, a bromine atom, a methyl group, fluoroalkyl groups having 1 to 2 carbon atoms,
- a methoxy group, a methylthio group,
- a methylsulfinyl group, a methylsulfonyl group,
- a nitro group, a cyano group, a trifluoromethoxy group, a trifluoromethylthio group, an allyl group,
- an acetamide group, a methoxycarbonyl group,
- an acetyl group, a formyl group and a carboxyl group.
- 3. 3-(2-Chloro-5-pyridylmethyl)-2-(nitromethylene)thiazolidine according to claim 1 of the formula ##STR692##
- 4. 3-(2-Fluoro-5-pyridylmethyl)-2-(nitromethylene)thiazolidine according to claim 1 of the formula ##STR693##
- 5. 3-(2-Bromo-5-pyridylmethyl)-2-(nitromethylene)thiazolidine according to claim 1 of the formula ##STR694##
- 6. 3-[1-(2- hloro-5-pyridyl)ethyl]-2-(nitromethylene)thiazolidine according to claim 1 of the formula by the following formula: ##STR695##
- 7. 3-(2-Methyl-5-pyridylmethyl)-2-(nitromethylene)thiazolidine according to claim 1 of the formula ##STR696##
- 8. 3-(2-Trifluoromethyl-5-pyridylmethyl)-2-(nitromethylene)thiazolidine according to claim 1 of the formula ##STR697##
- 9. 3-(2-Ethyl-5-pyridylmethyl)-2-(nitromethylene)thiazolidine according to claim 1 of the formula ##STR698##
- 10. Ethyl nitro[3-(2-chloro-5-pyridylmethyl)thiazolidin-2-ylidene]acetate according to claim 1 of the formula ##STR699##
- 11. 3-(2-Chloro-5-pyridylmethyl)-2-(nitroimino)thiazolidine according to claim 1 of the formula: ##STR700##
- 12. An insecticidal composition comprising an insecticidally effective amount of a compound according to claim 1 in admixture with a diluent.
Priority Claims (6)
Number |
Date |
Country |
Kind |
60-18627 |
Feb 1985 |
JPX |
|
60-18628 |
Feb 1985 |
JPX |
|
60-23683 |
Feb 1985 |
JPX |
|
60-106853 |
May 1985 |
JPX |
|
60-106854 |
May 1985 |
JPX |
|
60-219082 |
Oct 1985 |
JPX |
|
Parent Case Info
This is a division of application Ser. No. 347,836, filed May 4, 1989, now U.S. Pat. No. 5,001,128, which is a division of application Ser. No. 068,991, filed Jul. 1, 1987, now U.S. Pat. No. 4,845,106, which is a division of Ser. No. 821,621 filed Jan. 21, 1986, now U.S. Pat. 4,742,060.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
4616025 |
Ezer |
Oct 1986 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
2140412 |
Nov 1984 |
GBX |
Divisions (3)
|
Number |
Date |
Country |
Parent |
347836 |
May 1989 |
|
Parent |
68991 |
Jul 1987 |
|
Parent |
821621 |
Jan 1986 |
|