The present application is related generally to wire-grid polarizers.
Wire-grid polarizers (WGPs or WGP for singular) can be used to divide light into two different polarization states. One polarization state can mostly pass through the WGP and the other can be mostly absorbed or reflected. The effectiveness or performance of WGPs is based on a high percent transmission of one polarization and minimal transmission of an opposite polarization. A percent transmission of the primarily-transmitted polarization divided by a percent transmission of the opposite polarization is called contrast. It can be difficult to manufacture WGPs that provide sufficiently-high contrast. High contrast can sometimes be obtained by reducing the pitch of the wires/ribs, but doing so can be a difficult manufacturing challenge, especially for smaller wavelengths. It would be beneficial to find a way to improve WGP performance by some way other than a reduction in pitch.
It has been recognized that it would be advantageous to improve wire-grid polarizer (WGP or WGPs for plural) performance by some way other than a reduction in pitch. The present invention is directed to various embodiments of embedded, inverse WGPs, methods of polarizing light, and methods of designing embedded, inverse WGPs, that satisfy these needs. Each embodiment may satisfy one, some, or all of these needs.
In one embodiment, an embedded, inverse wire-grid polarizer (WGP) can comprising ribs over a transparent substrate, gaps between the ribs, and a fill-layer substantially filling the gaps. The ribs can be metallic. At a wavelength of light incident upon the WGP in a range≥175 nm, E∥ transmission>E⊥ transmission, where E∥ is a polarization of the light with an electric field oscillation parallel to a length of the ribs and E⊥ is a polarization of the light with an electric field oscillation perpendicular to a length of the ribs. Also, at the wavelength of the light, the ribs can be reflective, the fill-layer can be transparent, and the fill-layer can have an index of refraction greater than 1.7.
In another embodiment, an embedded, inverse WGP can comprise ribs over a transparent substrate, gaps between the ribs, and a fill-layer substantially filling the gaps. The fill-layer can also extend from the gaps over the ribs such that the fill-layer in each gap extends continuously over adjacent ribs to the fill-layer in each adjacent gap. The fill-layer can be transparent and can have an index of refraction greater than 1.7. At a wavelength of light incident upon the WGP in a range≤175 nm, E∥ transmission>E⊥ transmission.
In another embodiment, an embedded, inverse WGP can comprise ribs over a transparent substrate, gaps between the ribs, and a fill-layer substantially filling the gaps. The fill-layer can comprise aluminum oxide.
As used herein, the term “elongated” means that a length L (see
As used herein, the values of the “index of refraction” mean the values of the real part of the index, not the values of the imaginary part of the index, also known as the extinction coefficient.
As used herein, the term “light” can mean light or electromagnetic radiation in the x-ray, ultraviolet, visible, and/or infrared, or other regions of the electromagnetic spectrum.
As used herein, the term “nm” means nanometer(s).
As used herein, the term “thin-film layer” means a continuous layer that is not divided into a grid.
As used herein, the term “width” of the rib means the maximum width of the rib, unless specified otherwise.
Many materials used in optical structures absorb some light, reflect some light, and transmit some light. The following definitions are intended to distinguish between materials or structures that are primarily absorptive, primarily reflective, or primarily transparent. Each material can be primarily absorptive, primarily reflective, or primarily transparent in a specific wavelength of interest (e.g. all or a portion of the ultraviolet, visible, or infrared spectrums of light) and can have a different property in a different wavelength of interest.
As illustrated in
For the following discussion, E∥ is a polarization of light with an electric field oscillation parallel to a length L of the ribs and E⊥ is a polarization of light with an electric field oscillation perpendicular to a length L of the ribs. In typical WGP use, E⊥ is primarily transmitted and E∥ is primarily reflected or absorbed. A WGP can be used as an inverse WGP in a wavelength range of light where E∥ is primarily transmitted and E⊥ is primarily reflected or absorbed (E∥ transmission>E⊥ transmission). Merely having E∥ transmission>E⊥ transmission is insufficient for many applications, and it can be important to optimize performance of the inverse WGP, meaning a high E∥ transmission and/or high contrast (E∥ transmission/E⊥ transmission). The WGP structure can be optimized for improved inverse WGP performance.
The WGPs 10, 20, and 30 can have gaps 16 between the ribs 13. The term “gap” means a space, opening, or divide, separating one rib from another rib. A fill-layer 15, substantially filling the gaps 16, and especially a fill-layer 15 with a relatively large index of refraction, can improve inverse WGP performance. For example, an index of refraction of the fill-layer 15 can be greater than 1.4 in one aspect, greater than 1.5 in another aspect, greater than 1.6 in another aspect, greater than 1.7 in another aspect, greater than 1.75 in another aspect, greater than 1.8 in another aspect, greater than 1.9 in another aspect, greater than 2.0 in another aspect, or greater than 2.1 in another aspect. The aforementioned index of refraction values are those at the light wavelength of intended use (e.g. ≥100 nm, ≥150 nm, ≥175 nm, ≥200 nm, ≥250 nm, ≥300 nm, ≥400 nm, or ≥700 nm; and ≤200 nm, ≤250 nm, ≤300 nm, ≤400 nm, ≤700 nm, or ≤1000 nm), where E∥ transmission>E⊥ transmission. The fill-layer 15 can be a solid material or liquid. The fill-layer 15 can be transparent. Examples of fill-layer materials, for polarization of ultraviolet light, include aluminum oxide (Al2O3, n=1.81 at λ=300 nm), zirconium oxide (ZrO2, n=2.25 at λ=361 nm), and hafnium oxide (HfO2, n=2.18 at λ=365 nm). Other examples of fill-layer materials include silicon nitride, tantalum oxide, tellurium oxide, germanium oxide, transition metal oxides, oxides of elements with an atomic number≥20, and rare earth oxides (atomic numbers 21, 39, and 57-71).
Use of a fill-layer 15 to improve WGP performance, and especially use of a fill-layer with a relatively large index of refraction, is contrary to conventional WGP design theory. For example, see U.S. Pat. No. 6,288,840, column 6, line 59 through column 7, line 15. A conventional WGP (E⊥ transmission>E∥ transmission) may include a fill-layer for protection of the ribs, accepting a reduction in WGP performance. For example, see U.S. Pat. No. 6,288,840, column 1, lines 18-54.
The fill-layer 15 of WGPs 20 and 30 in
Use of a substrate 11 and/or a thin-film layer 31 (see
Rib 13 pitch P can be selected to improve inverse WGP performance and to shift the wavelength range at which E∥ transmission>E⊥ transmission. In conventional WGPs, the pitch needed for high-performance polarization can be less than one-half of the smallest wavelength in the desired polarization wavelength range. Consequently, a pitch of less than 150 nanometers is typically used for polarization of visible light (λ/P≈150/400=2.67), and around 100 nanometers or less for polarization of ultraviolet light. Manufacture of such polarizers can be difficult and costly due to this small pitch. Fortunately, optimal pitch P, for inverse WGPs described herein, can be larger than a pitch needed for conventional polarizers, thus improving the manufacturability of these inverse WGPs.
For example, the wavelength of the light of desired inverse polarization divided by a pitch P of the ribs 13 can be less than 2.5 in one aspect, less than 2.0 in another aspect, less than 1.9 in another aspect, less than 1.8 in another aspect, or less than 1.7 in another aspect. As another example, for inverse polarization of light with a wavelength of less than 400 nanometers (e.g.
ultraviolet light), a pitch P of the ribs 13 can be greater than 140 nanometers. Pitch P of the ribs 13 and an index of refraction n of the fill-material 15 can be selected by the following equation: P*(n−0.2)<λ<P*(n+0.2), where λ is the wavelength of the light of desired inverse polarization.
Although pitch P for inverse polarization may be relatively large, for polarization of small wavelengths of light, such as less than 260 nanometer light in one aspect or less than 200 nanometer light in another aspect, small pitches P may be needed, such as for example less than 100 nanometers in one aspect, less than 80 nanometers in another aspect, or even less than 60 nanometers in another aspect.
A duty-cycle (W/P) of the ribs 13 can be selected to improve inverse WGP performance and to shift the wavelength range at which E∥ transmission>E⊥ transmission. For example, the following duty-cycles can improve contrast: greater than 0.45 in one aspect or greater than 0.55 in another aspect, and less than 0.60 in one aspect, less than 0.65 in another aspect, less than 0.70 in another aspect, or less than 0.80 in another aspect.
A lower duty-cycle can be selected to improve transmission of E∥, and can broaden the wavelength range of high E∥ transmission, but possibly by sacrificing contrast. Thus, a duty-cycle can be selected for improved transmission of E∥, such as for example less than 0.7 in one aspect, less than 0.6 in another aspect, less than 0.5 in another aspect, or less than 0.4 in another aspect. For example, for a wavelength range of light of at least 30 nanometers, E∥ transmission>E⊥ transmission and E∥ transmission can be greater than 80%. This wavelength range of light can be in a region of the electromagnetic spectrum of less than 400 nanometers, e.g. ultraviolet spectrum.
A smaller rib thickness Th13 can improve contrast. For example, rib thickness Th13 can be less than 70 nanometers in one aspect, less than 55 nanometers in another aspect, or less than 45 nanometers in another aspect.
Rib 13 shape can be selected to improve inverse WGP performance and to shift the wavelength range at which E∥ transmission>E⊥ transmission. Edges E (i.e. corners) of the ribs 13 can be approximately 90 degrees, thus forming rectangular-shaped ribs 13, as shown in
Ribs 13 with multiple widths WL and WH in each rib 13, as shown on WGP 30 in
WGPs described herein can be made with E∥ transmission>E⊥ transmission, with high contrast (E∥ transmission/E⊥ transmission), and with high E∥ transmission, even in the difficult to polarize regions of the electromagnetic spectrum. For example, the WGPs described herein can have E∥ transmission>E⊥ transmission and contrast of at least 10 in one aspect, at least 100 in another aspect, at least 300 in another aspect, at least 400 in another aspect, at least 1000 in another aspect, at least 5000 in another aspect, or at least 10,000 in another aspect, at a certain wavelength or wavelength range. As another example, the WGPs described herein can have E∥ transmission of at least 70&, at least 80%, or at least 90%, at a certain wavelength or wavelength range. These WGP performance numbers can even be achieved at a wavelength or a wavelength range of light in the electromagnetic spectrum of less than 400 nanometers in one aspect, less than 300 nanometers in another aspect, less than 270 nanometers in another aspect, or a wavelength in or across the ultraviolet spectrum in another aspect.
A method of polarizing light can comprise one or more of the following:
A method of designing an embedded, inverse WGP can comprise one or more of the following for matching or tuning the inverse WGP performance (E∥ transmission>E⊥ transmission) to a desired wavelength or wavelength range and/or for improving WGP performance (contrast and/or % E∥ transmission) at that wavelength or wavelength range:
Integrated circuits (ICs or IC) can be made of semiconductor material and can include nanometer-sized features. ICs can be used in various electronic devices (e.g. computer, motion sensor, etc.). Defects in the IC can cause the electronic device to fail. Thus, inspection of the IC can be important for avoiding failure of the electronic device, while in use by the consumer. Such inspection can be difficult due to the small feature-size of IC components. Light, with small wavelengths (e.g. ultraviolet), can be used to inspect small feature-size components. It can be difficult to have sufficient contrast between these small feature-size components and defects or their surroundings. Use of polarized light can improve integrated circuit (IC) inspection contrast. It can be difficult to polarize the small wavelengths of light (e.g. ultraviolet/UV) used for IC inspection. Polarizers that can polarize such small wavelengths, and that can withstand exposure to high-energy wavelengths of light, may be needed.
The WGPs described herein can polarize small wavelengths of light (e.g. UV) and can be made of materials sufficiently durable to withstand exposure to such light. The fill-material 15 can protect the ribs 13 from UV light damage. An IC inspection tool 40 is shown in
A detector 47 (e.g. CCD) can be located to receive an output light-beam 46 from the IC wafer 43. An electronic circuit 48 can be configured to receive and analyze a signal from the detector 47 (the signal based on the output light-beam 46 received by the detector 47). To improve inspection contrast, a WGP 44 (according to an embodiment described herein) can be located in, and can polarize, the output light-beam 46.
The WGPs described herein can be used in the manufacture of flat panel displays (FPDs for plural or FPD for singular). FPDs can include an aligned polymer film and liquid crystal. An FPD manufacturing tool 50 is shown in
This application is a continuation of U.S. patent application Ser. No. 15/631,164, filed on Jun. 23, 2017, which is a continuation-in-part of U.S. patent application Ser. No. 15/006,566, filed on Jan. 26, 2016, which claims priority to U.S. Provisional Patent Application No. 62/113,101, filed on Feb. 6, 2015, which are incorporated herein by reference in their entirety.
Number | Date | Country | |
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62113101 | Feb 2015 | US |
Number | Date | Country | |
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Parent | 15631164 | Jun 2017 | US |
Child | 16256514 | US |
Number | Date | Country | |
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Parent | 15006566 | Jan 2016 | US |
Child | 15631164 | US |