The present invention relates primarily to methods of improving the efficiency, reducing environmental issues, and operational and capital costs, of desalination systems. More particularly, to desalination systems that distill brackish or ocean water.
Fresh water is a scant 2.5% of the total global water supply and 69% of that is represented by permanent snow and glaciers. The remaining 97.5% is saltwater. Since 1940, the amount of fresh water used by humanity has roughly quadrupled as the world population doubled. Given the finite nature of the earth's fresh water resources, such a quadrupling of worldwide water use probably cannot occur again. In many of the regions where the world population is growing most rapidly, the needed fresh water is not available. Desalination of seawater represents the best source of fresh water to satisfy future requirements.
However, present day desalination systems are energy intensive. For example, the newly constructed system in Carlsbad, Calif. is said to be the most energy efficient of any large scale desalination system in the USA at 3.6 kilowatts per cubic meter of water. It also desalinates only fifty percent of intake water, returning the remaining concentrated brine to the ocean. Returning concentrated brine solution to the ocean presents a continually escalating environmental hazard to the ocean ecosystem.
For desalination to be the source of fresh water to meet future requirements, it must be cost competitive with ground water sources and environmentally friendly.
The true cost of household fresh water is difficult to assess due to government subsidies, transfer cost and variations in local energy and labor cost. However, it is estimated that energy requirements for desalination should be in the range of about 2 to 2.5 kilowatts per cubic meter of fresh water to be competitive.
Another environmental issue involves seawater intakes that can only be addressed in connection with site location of the desalination system. However, there are intake methods such as subsurface, sand filters, subterranean, and beach wells that can solve most environment intake problems.
Throughout the world today, all desalination facilities combined produce about 38 million cubic meters (approx. 10 billion gallons) of desalinated water per day. These facilities basically utilize two technologies, membrane filter processes and thermal distillation processes. Of these processes, reverse osmosis (membrane filter process) and multi-stage flash distillation (thermal distillation process), make up and share about 80% of the world market.
Reverse osmosis uses high pressure pumps to force fresh water through a semi-permeable membrane, leaving the dissolved solids behind. This process requires seawater pretreatment, an electrical power source, chemical post-treatment and annual membrane replacement.
Multi-stage flash (MSF) involves introducing heated seawater into multiple, reduced pressure chambers that cause a portion of the water to instantly flash (boil) into water vapor. The vapor is then condensed into distilled water. This process requires an energy source for heating the seawater as well as control functions.
Both technologies are energy intensive, and both convert about 50% of the input seawater into fresh drinkable water, discharging the remaining brine solution back into the ocean, which results in an ever increasing environmental problem.
The past decade has seen a huge increase in research and development in desalination projects around the world utilizing improved technologies, resulting in improved efficiency and reduced capital costs, such as low temperature flash desalination. Numerous patents have been granted disclosing designs that improve efficiency. A large number of these patents involve the “flash desalination” of water at low, near ambient temperatures in an effort to reduce energy requirements. Although seawater can be evaporated at low temperatures by decreasing pressure (partial vacuum), the decreasing temperature results in an exponential decrease in the Vapor Saturation Density. Therefore, large quantities of vapor must be transferred to recover significant quantities of distilled liquid, which places much higher energy and costs requirements upon the system.
For example, at 40° C. (104° F.), saturated vapor density is 51.1 grams per cubic meter (0.00319 pounds per cubic feet). At 110° C. (230° F.), saturated vapor density is 850 grams per cubic meter (0.05306 pounds per cubic feet). The result is that a system that is to produce 100 cubic meters (26,417 gal) of fresh water per day at a temperature of 40° C. must transfer vapor at a rate of more than 1359 cubic meters per min, whereas at 110° C. it would only need to transfer 81.7 cubic meters per min.
Despite the inventions, research, developments and improvements, present day seawater desalination processes continue to be an intensive fossil energy consumer that escalates desalination cost from to 5 times greater than ground water supplies.
The desalination industry has publicized that the minimum energy requirement to desalinate 3.5% seawater is 860 watts per cubic meter. A true statement, but somewhat misleading in that the process does require 860 watts per cubic meter to remove the dissolved solids. However, desalination is a reversible process; therefore, the energy used for removing the solids can, theoretically, be recovered.
In a thermal desalination system the “heat of vaporization” can be recovered in the condensation stage, referred to as the “heat of condensation.”
The first law of thermodynamics states that the total energy of an isolated system is constant; energy can be transformed from one form to another, but cannot be created or destroyed.
For a thermal process to be effective the system must be isolated (insulated) so that minimum heat energy escapes the system. The thermal process does not require energy form changes and can extract dry solids from seawater.
For a filtration process to recover and reuse the energy would require transforming from one form of energy to another (e.g., electrical to pressure) resulting in high entropy. The process cannot extract dry solids from seawater.
Therefore, there is still a need to create an efficient desalination that results in operational cost equal to, or less than, conventional ground water supplies.
In one embodiment, the present invention is directed towards a desalination system for substantially increasing the efficiency of the distillation of ocean and brackish water by continuously reusing heat energy to reduce the overall energy requirements, comprised of basic assemblies, including an evaporation chamber, a vapor transfer assembly, and a condensing chamber, that are surrounded by a, double wall assembly comprised of a first and second wall, wherein the space between the first and second wall is placed under low partial vacuum to maintain very low conductive and convection heat loss. An external water heater source feeds heated input sea water into the evaporation chamber through a plurality of spray nozzles, which transforms the sea water into droplet-mist that flash vaporize into a density-saturated vapor. The density-saturated vapor is drawn into the condenser by a vacuum pump assembly. The solids that remain from the flash vaporization fall to the bottom of the evaporation chamber. Any droplet-mist that does not vaporize is prevented from entering the vapor transfer assembly by a demister. The density-saturated vapor is discharged through the vacuum pump assembly and is forced into the condensing chamber located below the vacuum pump assembly. The condenser is then continuously cooled by intake sea water distributed by a ratio valve through an intake channel into a heat-exchanger port. This condenses the liquid-vapor into pure liquid distilled water. Concurrently, the intake sea water is heated by its contact with the heat exchanger. The heated intake sea water is then transferred to the external water heater source through a vacuum insulated channel to be fed back into the evaporation chamber.
The ratio valve also distributes intake sea water to the bottom of be evaporation chamber to cool the solids that fall and collect at the bottom. This is accomplished by distributing the intake sea water through a first chamber port into cooling coils to cool the solids. The intake sea water is heated in the process, and is transferred back to the external water heater source through a vacuum insulated channel. The preheated intake sea water is then fed into the evaporation chamber.
In another embodiment, the desalination system similarly uses a thermal process that converts saltwater, such as seawater or brackish water, into fresh distilled water. The system introduces methods for continually removing the dissolved solid byproducts that may be processed as sea-salt. The output is 100% potable and dry solids, with zero liquid discharge. This feature eliminates the environmental problem of discharging waste brine solution back into the ocean.
The desalination system efficiently vaporizes saltwater, thereby extracting the dry solids from the water and condensing the water vapor back into liquid form to create distilled water by reusing retained heat energy multiple times. The only energy input, after startup stabilization, is the energy required to compensate for the small heat energy loss to the atmosphere, through a vacuum insulation double wall, the drive motor of the vapor transfer assembly, and instrumentation.
The desalination system recovers the heat energy used in the vaporization process. Heat loss in the distillation system is essentially eliminated, reducing energy requirements to approximately 1.2 kWh/cubic meter (264 gallons) of fresh water, far below energy requirements used in current technologies.
Heat energy used to evaporate water (heat of vaporization) is recovered in the condensing phase (heat of condensation) and used to preheat the incoming seawater. This process is continuously repeated reusing the heat energy multiple times. The process requires that very little heat energy, above the input seawater ambient temperature, be allowed to exit the system.
In addition, the desalination system is designed with components that minimize the total outside system surface area so as to minimize heat loss to the atmosphere. Also, the system employs vacuum insulation via a double-wall assembly that surrounds the components of the desalination system to prevent heat energy, greater than a few degrees above ambient seawater temperature, from exiting the system. Insulation is provided by a deep partial vacuum created between the first and second walls of the double-wall assembly.
The system may be designed with spray nozzles that transform the fluid water into a fine mist of water droplets with droplet sizes below fifty microns. Droplet surface area and temperature are key issues in the vaporization stage. Evaporation occurs first at the liquid surface causing the remaining liquid to be more concentrated, which increases the boiling point and energy required to vaporize the remaining liquid. Therefore, it is important to increase surface area as much as possible.
Using spray nozzles to break the liquid into small droplets greatly increases the surface area. The large surface area decreases the time and energy for evaporation.
For example, a one-inch diameter (volume=0.523 cubic inches) drop of water has a surface area of 3.14 square inches.
If the same volume is parted into 10 micron (3.937E-04 inch) diameter droplets (volume=3.19E-11 cubic inch), the total number of droplets would be over 16 billion with a total liquid surface area of 7,980 square inches.
The condenser may be a specially designed spiral heat exchanger that uses the inside surface of the second wall of the double-wall assembly as part of the outside spiral of the condenser. Intake seawater ambient temperature is introduced to the outside spiral that lowers the temperature of the vacuum insulation second wall and transfers the heat energy back into a vaporizing chamber. This arrangement reduces the temperature of the vacuum insulated second wall, and the energy that would normally escape to the atmosphere through the vacuum insulation.
The primary objective of the present invention is to provide a means of increasing the overall efficiency of large scale desalination systems by significantly reducing the energy input requirement, and make desalination affordable. Another object of the invention is to provide a means for using the ambient temperatures of seawater and air to continually transfer
The heat energy, from the outer perimeters of the system, back into the, centrally located, evaporation chamber. Another object of the invention is to provide a means of using evacuated space (partial vacuum) insulation that prevents heat from escaping into the atmosphere. The invention also includes means for reusing the heat energy repeatedly to preheat the incoming saltwater. The invention also provides a method for evaporating the heated saltwater into a density-saturated vapor. It also provides a means for condensing the vapor into fresh distilled water and capturing and re-using the heat-of-condensation to preheat the input saltwater. A further object of the invention is to provide means for separating the dissolved solids from the liquid water and still further means for continually removing the solids from the system without interruption. A further object of the invention is to provide means for removing the heat energy from the hot solids and reusing it to preheat the air flow as it enters the air heater, which provides heat to vaporize the droplet mist as it falls within the evaporation chamber. A further object of the invention is to provide means for eliminating the heat loss through the structural feed through of the vacuum insulated double wall.
Additional objects of the present invention will become better understood with reference to the description and claims.
The detailed description set forth below in connection with the appended drawings is intended as a description of presently-preferred embodiments of the invention and is not intended to represent the only forms in which the present invention may be constructed or utilized. The description sets forth the functions and the sequence of steps for constructing and operating the invention in connection with the illustrated embodiment. It is to be understood, however, that the same or equivalent functions and sequences may be accomplished by different embodiments that are also intended to be encompassed within the spirit and scope of the invention.
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The following description describes another embodiment of the present invention. Components that are similarly named or perform similar functions may be interchangeable and share similar features in both embodiments regardless of the reference number designations. With references to
The double-wall assembly 101 comprises a first (outer) wall 102 and a second (inner) wall 103 that is surrounded by the first wall 102, thereby defining a space 104 between the first and second walls 102, 103. The space 104 may be under low partial vacuum to maintain very low conductive and convection heat energy loss. The first wall 102 is exposed to the environment. The second wall 103 may be substantially coextensive with the first wall 102 to create the space 104 in between the first and second walls 102, 103.
Preferably, a deep partial vacuum is provided within the space 104 between the first wall 102 and second wall 103. The double-wall assembly 101 surrounds the components of the desalination system 100. In some embodiments, the space 104 between the first and second walls 102, 103 may include an insulator 105. Preferably, the insulator 105 is a structural insulation. For clarity, the insulator 105 is shown in a small portion of the space 104. However, the insulator 105 can occupy up to the entire space 104. In the preferred embodiment, perlite is used for the insulator 105 as it exhibits a thermal conductivity of approximately 0.031 W/m*K that improves to 0.00137 W/m*K under low partial vacuum, and may provide structural support.
The first wall 102 and the second wall 103 of the double wall 101 are connected for structural support that also provides an opening 106.
A common problem with vacuum insulation is the thermally conductive path that is created by the necessary structural support connecting the double walls that maintain positioning of the two walls relative to each other, and to provide a passageway for accessibility to the internal cavity of the double wall.
The double wall assembly 101 has only one opening 106 at one end of the system 100, thereby creating a passageway from the outside of the system 100 to the internal cavity defined by the internal surface of the second wall 103. Preferably, the opening 106 is created at the bottom end of the system 100.
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As the droplet-mist 503 vaporizes into the density saturated vapor 501, that is drawn upward by the air stream 504 and the dry solids 902 are extracted from the mist 503 and fall towards the bottom of the evaporation chamber 500. Due to the toroid shape of the heater 600, the air stream 800 directs the falling dry solids 902 toward the center of the evaporation chamber 500.
The dry solids 902 continue to fall through the center opening of the heater 600 and into a finned funnel assembly 700 where the dry solids 908 are cooled by the ambient temperature air flow 800 flowing through the feed-through assembly 200. As the hot dry solids 908 fall towards the bottom of the evaporation chamber 500, the hot dry solids 908 transfers heat to the cool air flow 907 being drawn into the system 100 through the central channel 206 of feed-through assembly 200. The cool dry solids 908 continue to fall through the central channel 206 of the feedthrough assembly 200 where they are further cooled by the saltwater flowing through the intake port 202 of the feed-through assembly 200 before exiting the system 100.
In some embodiments, a transfer auger 903 may be provided to facilitate movement of the dry solids 908. Whether a transfer auger 903 is required will depend upon the components of the dry solids 908. In most environments the dry solids 908 will free flow without the need of the transfer auger 903.
The vapor 501 is drawn upward through a demister 904 by the vapor transfer assembly 400 and forced into the inner passageway 307 of the condenser 300 where the vapor is condensed into pure distilled liquid water 304 at near ambient temperature. The demister 904 prevents droplets that have not yet been vaporized from entering into the condenser 300. The distilled water 304 flows from the condenser 300 and enters the feed-through assembly 200 through receiver port 204 where it is further cooled by the inflowing seawater, and exits through the exit port 205 of the feed-through assembly 200.
A structural insulation assembly 905 is positioned between the heater 600 and the funnel 700 that provides a low thermally conductive path from the heater 600 to the dry solids 908 that have fallen into the funnel 700.
When it is desirable to use solar energy instead of or in combination with electrical power, the square toroid shaped air heater 600 may be replaced with a similar shaped heater that uses hot water or steam as an energy source.
Although particular embodiments of the present invention have been described in the foregoing description, it is to be understood that the present invention is not to be limited to just the embodiments disclosed, but that they are capable of numerous rearrangements, modifications and substitutions without departing from the description herein.
All features disclosed in this specification, including any accompanying claims, abstract, and drawings, may be replaced by alternative features serving the same, equivalent or similar purpose, unless expressly stated otherwise. Thus, unless expressly stated otherwise, each feature disclosed is one example only of a generic series of equivalent or similar features.
Although preferred embodiments of the present invention have been shown and described, various modifications and substitutions may be made thereto without departing from the spirit and scope of the invention. Accordingly, it is to be understood that the present invention has been described by way of illustration and not limitation.
This application is a continuation-in-part application of U.S. patent application Ser. No. 12/902,011, filed Oct. 11, 2010, entitled “Large Scale insulated Desalination System,” which application is incorporated here in its entirety by this reference.
Number | Name | Date | Kind |
---|---|---|---|
3163587 | Champe | Dec 1964 | A |
3960668 | Rush | Jun 1976 | A |
4671856 | Sears | Jun 1987 | A |
4869067 | Sears | Sep 1989 | A |
5053110 | Deutsch | Oct 1991 | A |
5181991 | Deutsch | Jan 1993 | A |
5207928 | Lemer | May 1993 | A |
5348622 | Deutsch et al. | Sep 1994 | A |
5729987 | Miller | Mar 1998 | A |
5772850 | Morris | Jun 1998 | A |
6254734 | Sephton | Jul 2001 | B1 |
6299735 | Lumbreras | Oct 2001 | B1 |
6355144 | Weinstein | Mar 2002 | B1 |
6699369 | Hartman et al. | Mar 2004 | B1 |
6932889 | Holcomb | Aug 2005 | B1 |
7381310 | Hernandez Hernandez | Jun 2008 | B2 |
7897019 | Akers | Mar 2011 | B2 |
8444830 | Davey | May 2013 | B2 |
8496787 | Lord | Jul 2013 | B2 |
8533972 | Hubbard, Jr. et al. | Sep 2013 | B2 |
8893496 | Ramamurthy | Nov 2014 | B2 |
9205349 | Kaminski | Dec 2015 | B2 |
9211482 | Kaminski | Dec 2015 | B2 |
9428403 | Haynes | Aug 2016 | B2 |
20080283199 | Hartman | Nov 2008 | A1 |
20100181185 | Davey | Jul 2010 | A1 |
20120085635 | Haynes | Apr 2012 | A1 |
Number | Date | Country | |
---|---|---|---|
20160368784 A1 | Dec 2016 | US |
Number | Date | Country | |
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Parent | 12902011 | Oct 2010 | US |
Child | 15252050 | US |