The invention relates to the field of photonic crystals, and in particular to a dielectric high omnidirectional reflector.
Low-loss periodic dielectrics, or “photonic crystals”, allow the propagation of electromagnetic energy, e.g., light, to be controlled in otherwise difficult or impossible ways. The existence of photonic bandgap in certain photonic crystals has given rise to the possibility that a photonic crystal can be a perfect mirror for light from any direction, with any polarization, within a specified frequency range. Within the frequency range of photonic bandgaps, there are no propagating solutions of Maxwell's equations inside a periodic medium. Consequently, a wave-front with a frequency within the gap which is incident upon the surface of such a crystal would be completely reflected.
It is natural to assume that a necessary condition for such omnidirectional reflection is that the photonic crystal exhibit a complete three-dimensional photonic band-gap, i.e., a frequency range within which there are no propagating solutions of Maxwell's equations. Such a photonic crystal would require periodic variations in dielectric constant in all three dimensions. These crystals, if designed for infrared or optical light, are difficult to fabricate, since the spatial periods must be comparable to the wavelength of operation. This is the reason why, despite heroic experiments involving advanced lithographic methods or self-assembling microstructures, most of the proposals for utilizing photonic crystals are in early stages of development.
It is therefore an object of the invention to provide a dielectric structure that acts as a perfect mirror by exhibiting high omnidirectional reflection of energy regardless of polarization and incident angle.
It is a further object of the invention to provide a one-dimensionally periodic photonic crystal structure, such as multi-layer films, that can exhibit complete reflection of radiation in a given frequency range for all incident angles and polarizations.
Accordingly, the invention provides a reflector, a of producing same and a method of creating high omnidirectional reflection for a predetermined range of frequencies of incident electromagnetic energy for any angle of incidence and any polarization. The reflector includes a structure with a surface and a refractive index variation along the direction perpendicular to the surface while remaining nearly uniform along the surface. The structure is configured such that i) a range of frequencies exists defining a photonic band gap for electromagnetic energy incident along the perpendicular direction of said surface, ii) a range of frequencies exists defining a photonic band gap for electromagnetic energy incident along a direction approximately 90° from the perpendicular direction of said surface, and iii) a range of frequencies exists which is common to both of said photonic band gaps. In one exemplary embodiment the reflector is configured as a photonic crystal.
Any one-dimensional photonic crystal, as defined by a varying index function n(y) that in the illustrated case is periodic will have a non-zero gap for kx=0. Within it there are no propagating modes, so a wave with its frequency falling in the range of the gap, if incident normal to the surface of such a crystal, will be reflected.
For kx>0 (an arbitrary direction of propagation) it is convenient to examine the projected band structure, which is shown in
The shape of the projected band structure for a multilayer film can be understood intuitively. At kx=0, the normal-incidence bandgap of
One obvious feature of
However, the absence of a complete band-gap does not preclude omnidirectional reflection. The criterion is not that there be no propagating states within the crystal; rather, the criterion is that there be no propagating states that may couple to an incident propagating wave. This is equivalent to the existence of a frequency range in which the projected band structures of the crystal and the ambient medium have no overlap.
The two diagonal black lines 302, 304 in
For a semi-infinite crystal occupying y<0 and an ambient medium occupying y>0, the system is no longer periodic in the y-direction (no translational symmetry) and the electromagnetic modes of the system can no longer be classified by a single value of ky. They must be written as a weighted sum of plane waves with all possible ky. However, kx is still a valid symmetry label. The angle of incidence θ upon the interface at y=0 is related to kx by ω sin θ=ckx.
For there to be any transmission through the semi-infinite crystal at a particular frequency, there must be an electromagnetic mode available at that frequency which is extended for both y>0 and y<0. Such a mode must be present in the projected photonic band structures of both the crystal and the ambient medium. The only states that could be present in the semi-infinite system that were not present in the bulk system are surface states, which decay exponentially in both directions away from the surface, and are therefore irrelevant to the transmission of an external wave. Therefore, the criterion for high omnidirectional reflection is that there are no states in common between the projected bands of the ambient medium and those of the crystal, i.e., there exists a frequency zone in which the projected bands of the crystal have no states with ω>ckx.
It can be seen from
The lowest two p-bands cross at a point above the line ω=ckx, preventing the existence of such a frequency zone. This crossing occurs at the Brewster angle θB=tan−1(n2/n1), at which there is no reflection of p-polarized waves at any interface. At this angle there is no coupling between waves with ky and −ky, a fact which permits the band-crossing to occur. As a result, the bands curve upwards more rapidly.
This difficulty vanishes when the bands of the crystal are lowered relative to those of the ambient medium, by raising the indices of refraction of the dielectric films. For example, by multiplying the index of refraction n(y) by a constant factor α>1, all of the frequencies of the electromagnetic modes are lowered by the same factor α.
Between the frequencies corresponding to the points 400 and 402, there will be total reflection from any incident angle for either polarization. For a finite number of films, the transmitted light will diminish exponentially with the number of films. The calculated transmission spectra, for a finite system of ten films (five periods), are plotted in
The criterion for high omnidirectional reflection (the non-overlap of the projected bands of both crystal and ambient medium) applies for a general function n(y) that is not necessarily periodic. For the special case of a multilayer film it is possible to derive an explicit form of the band structure function ωn(kx,ky) and use it to investigate systematically the frequency zone of directional reflection, if any, which results from a given choice of n1, n2, d1 and d2.
The graphical criterion for high omnidirectional reflection, as shown in
where ωpn(kx, ky) is the p-polarized band structure function for the multilayer film. It will be appreciated that the left side is a self-consistent solution for the frequency ωp1. The difference between these two frequencies is the range of high omnidirectional reflection.
For a multilayer film, the dispersion relation ωn(kx,ky) may be derived by computing the eigenvalues Λ of the transfer matrix associated with one period of the film at a particular frequency and incident angle. When θ=exp(ikya) with ky real, there is a propagating mode at that frequency and angle. The dispersion relation ω(kx,ky) is governed by the transcendental equation:
Here β1,2=(d1,2/c)√{square root over (n1,22−sin2 θ)} is defined for each film. The polarization-dependent constant A is defined by:
These results may be used to evaluate the criterion as expressed in equation (1). The roots of equation (2) may be found numerically, for a given ky and θ=a sin(ckx/ω). The frequency range (if any) of omidirectional reflection, according to equation (1), is between the first root of equation (2) for p-polarized waves with ky=π/a and θ=π/2 (point 400 of FIG. 4), and the second root for ky=π/a and θ=0 (point 402).
The frequency range has been calculated (when it exists) for a comprehensive set of film parameters. Since all the mode wavelengths scale linearly with d1+d2=a, only three parameters need to be considered for a multilayer film: n1, n2, and d1/a. To quantify the range of high omnidirectional reflection [ω1, ω2] in a scale-independent manner, the “range-midrange ratio” is defined as (ω2−ω1)/[(1/2)(ω1+ω2)].
For each choice of n1 and n2/n1, there is a value of d1/a that maximizes the range-midrange ratio. That choice may be computed numerically.
An approximate analytic expression for the optimal zone of high omnidirectional reflection may be derived:
Numerically this is found to be an excellent approximation for the entire range of parameters depicted in
It can be seen from
For example, for light with a wavelength of 1.5 μm, silicon dioxide has n1=1.44 and silicon has n2=3.48=2.42n1. From
In practice, the optimization of d1/a results in a gap size very close to the gap size that would result from a quarter-wave stacked with the same indices d1/a=n2/(n2+n1). The 0% contour for quarter-wave stacks is plotted in
With this in mind, an approximation to equation (2) may be derived for films which are nearly quarter-wave stacks. In that limit β2−β1≈0, so the second cosine in equation (2) is approximately 1. In this approximation the frequency of the band edge at ky=π/a is:
using the same notion as in equations (3) and (4). This frequency can be computed for the cases θ=0 and θ=π/2. If the difference between these two frequencies is positive, there will be omnidirectional reflection for any frequency between them.
The invention demonstrates that, even though it is not possible for a one-dimensional photonic crystal to have a complete bandgap, it is still possible to achieve reflection of ambient light regardless of incident angle or polarization. This happens whenever the projected bands of the crystal and ambient medium have overlap within some range of frequencies.
This constraint is not unrealistic, even for the most common sort of one-dimensional photonic crystal, the multilayer film. As can be seen in
The optical response of a particular dielectric multilayer film can be predicted using the characteristic matrix method. In this method, a 2×2 unitary matrix is constructed for each layer. This matrix represents a mapping of the field components from one side of the layer to the other. To successfully predict the optical response of a multilayer film the characteristic matrix for each layer needs to be calculated. The form of the characteristic matrix for the jth layer is
where nj is the index of refraction, and hj is the thickness of the jth layer, θ0 is the angle between the incident wave and the normal to the surface and no is the index of the initial medium (e.g. air).
The matrices are then multiplied to give the film's characteristic matrix
which in turn can be used to calculate the reflectivity for a given polarization and angle of incidence,
where pg0 contains information about the index of the medium and angle of incidence on one side of the multilayer film and pg1 contains information about the index of the medium and angle of incidence on the other.
To construct a reflector exhibiting a reflectivity R of a minimal prescribed value for all angles of incidence and both polarizations one needs to (1) satisfy the criteria for omnidirectional reflection, and (2) solve equation (10) for θ=89.9*, g=TM and R™(89.9)=R.
Although the invention has been illustrated by using multilayered films, the invention as described can apply generally to any periodic dielectric function n(y), or even an aperiodic dielectric function n(y). What is required is that n(y) leads to photonic bandgaps along various directions such that there exists a zone of frequencies in which the projected bands of the dielectric structure and ambient media do not overlap. Such a requirement can also be satisfied by a photonic crystal with two- or three-dimensionally periodic index contrasts, which have incomplete bandgaps.
However, the absence of a complete bandgap does have physical consequences. In the frequency range of high omnidirectional reflection, there exist propagating solutions of Maxwell's equations, but they are states with ω<ckx, and decrease exponentially away from the crystal boundary. If such a state were launched from within the crystal, it would propagate to the boundary and reflect, just as in total internal reflection.
Likewise, although it might be arranged that the propagating states of the ambient medium do not couple to the propagating states of the crystal, any evanescent states in the ambient medium will couple to them. For this reason, a point source of waves placed very close (d<λ) to the crystal surface could indeed couple to the propagating state of the crystal. Such restrictions, however, apply only to a point source and can be easily overcome by simply adding a low index cladding layer to separate the point source from the film surface.
Many potential applications are envisioned for such a high omnidirectional reflector or mirror. For example, in the infrared, visible, or ultraviolet regimes, high omnidirectional reflectors could serve as a frequency-selective mirrors for laser beams or highly-reflective coatings on focusing instruments. These would be effective for light that is incident from any angle, instead of just a finite range around a fixed design angle.
The invention can also be utilized in coatings with infrared mirrors to keep heat in or out of the items coated, e.g., walls, windows, clothes, etc. The mirrors can be cut into small flakes and mixed with paint or fabrics to allow for application to the desired items.
The reflector of the invention could be used in improving thermo-photovoltaic cells that trap waste heat and convert it into energy. The reflector of the invention can also be made to reflect radio waves and thus can be used to boost performance of radio devices such as cellular telephones.
Although the present invention has been shown and described with respect to several preferred embodiments thereof, various changes, omissions and additions to the form and detail thereof, may be made therein, without departing from the spirit and scope of the invention.
This application is a continuation of U.S. Ser. No. 09/253,379 filed Feb. 19, 1999, now U.S. Pat. No. 6,130,780, which claims priority from provisional application Ser. No. 60/075,223 filed Feb. 19, 1998.
This invention was made with government support under 9400334-DRM awarded by the National Science Foundation. The government has certain rights in the invention.
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Child | 09634099 | US |