Patent Application
20100264038
The present invention relates to a high-pressure electrolysis installation for decomposing water into hydrogen and oxygen. It relates more specifically to an installation of this type comprising an electrolysis stack consisting of a plurality of electrolytic cells, each comprising an anode and a cathode. The installation further comprises a water recirculation system supplying water to said anodes and cathodes. The recirculation system itself comprises a water recirculation circuit, a recirculation pump, a first separator for separating the water and the gaseous hydrogen produced in the electrolysis stack and a second separator for separating the water and the oxygen produced in the electrolysis stack, said installation further comprising hydraulic supply means for supplying the recirculation circuit with deionised water so as to compensate for the water consumed by the production of gaseous hydrogen and oxygen, and lastly comprising extinguishing means for inertising the first and second separators when the installation is shut down.
The present invention also relates to a process for inertising an installation of the type described above when it is shut down.
Electrolysis installations in accordance with the above preamble are already known. A prior art installation of this type is shown schematically in the appended
The hydrogen and oxygen accumulate in the respective upper parts of the two separators. The first separator 7 is provided with a pressure regulation valve 17 which determines the working pressure of the installation as a whole (generally between 5 and 30 bar). When the pressure inside the separator 7 reaches the limit value of the valve 17, said valve allows the hydrogen which has been produced to escape. Because oxygen continues to accumulate in the second separator 9 during this time, the water level in said separator decreases and, in accordance with the principle of communicating vessels, the water level inside the first separator 7 increases. The two separators are each provided with a level gauge (denoted as 19 and 20 respectively). The second separator 9 is further equipped with a pressure relief valve 23, and when the gauges indicate that the difference in level in the separators has exceeded a predetermined value, the valve 23 opens and allows oxygen to escape until the two levels become equal.
The operation of the electrolysis installation involves progressive destruction of the water which it contains. When the sum of the water levels in the two separators falls below a predetermined value, hydraulic supply means are triggered to supply cold water to the recirculation circuit 11, 13. As is shown in
The electrolysis installation is further provided with extinguishing means for inertising the first and second separators when the installation is shut down. The extinguishing means comprise a reserve of pressurised nitrogen 30 and a supply pipe 32 connecting the nitrogen reserve to the two separators 7, 9. When it is sought to shut down the installation, a valve 34 is opened, causing the nitrogen to flow into the separators, preferably in a large amount. Simultaneously, a relief valve 36 on the first separator 7 and the relief valve 23 on the second separator 9 are opened. Thus, the nitrogen exits the first separator through the valve 36, carrying along the hydrogen contained in the separator 7. Similarly, the nitrogen can escape via the valve 23, carrying with it the oxygen contained in the separator 9. This way of proceeding allows the two separators to be emptied and thus in particular allows any risk of explosions, in connection with the presence of hydrogen, to be avoided.
Electrolysis installations of the same type as those which have just been described exhibit some drawbacks. First, the extinguishing means make it necessary to have a large amount of pressurised nitrogen available. Furthermore, the hydrogen contained in the first separator 7 is lost during inertisation because it is mixed with a large amount of nitrogen and then released into the atmosphere.
The present invention aims in particular to overcome the above-mentioned drawbacks. This object is achieved by providing an electrolysis installation of the type described in the preamble, characterised in that the extinguishing means comprise a first and a second relief valve provided on the first and second separators respectively, said relief valves being provided to relieve the pressure in the two separators simultaneously while keeping the water level inside the two separators substantially constant, and in that the extinguishing means are provided to control said hydraulic supply means so as to completely fill the two separators with water once the two separators have been virtually relieved of pressure.
It will be understood that according to the present invention, the hydraulic supply means of the installation are used to supply the inertising fluid for the separators. This feature means that it is not necessary to provide a pressurised nitrogen reserve, and this greatly reduces the maintenance costs of the electrolysis installation.
Furthermore, the hydraulic supply means are the same ones as are provided to replenish the cold water of the recirculation circuit 11 in normal operation. The fact that the same equipment is used during the extinguishing phase and during the normal operating phases allows the design of the invention to be greatly simplified.
In an advantageous variant of the present invention, the hydrogen driven out of the first separator during the inertisation phase, when the two separators 7, 9 are completely filled with water, is recovered instead of being released into the atmosphere. In fact, since the hydrogen is not mixed with nitrogen, its quality is not affected by the inertisation process and it can thus be recovered.
Preferably, the extinguishing means are also provided to interrupt the electricity supply of the electrolysis stack before said pressure relief valves are opened. In another preferred feature, the extinguishing means can be provided to make the hydraulic supply means start filling the two separators when the hydrogen pressure in the first separator has fallen below two bars.
In another advantageous feature, the extinguishing means control the hydraulic supply means automatically. The two pressure relief valves may also advantageously be controlled automatically. In a preferred embodiment, the first pressure relief valve releases hydrogen into the atmosphere.
In another aspect, the present invention also aims to overcome the above drawbacks by providing an electrolysis installation of the type described in the preamble, characterised in that the hydraulic supply means comprise a reservoir of deionised water, connected to a pipe for placing the reservoir in communication with the recirculation circuit upstream from the entrance of the recirculation pump, and in that said pipe is provided with a valve provided to open when the amount of water in the recirculation system has fallen below a predefined level.
In a preferred feature of this second aspect, said pipe is provided with a backflow preventer. Furthermore, in an advantageous embodiment, the recirculation circuit is provided with a recirculation valve arranged upstream from the point where this pipe meets the recirculation circuit, said recirculation valve being provided to reduce the flow of water from the two exchangers so as to increase the proportion of the water coming from the hydraulic supply means.
In yet another aspect, the invention relates to a process for inertising a high-pressure electrolysis installation for decomposing water into hydrogen and oxygen when the installation is shut down, said installation comprising an electrolysis stack consisting of a plurality of electrolytic cells, each comprising an anode and a cathode, a water recirculation system supplying water to said anodes and cathodes, the recirculation system comprising a water recirculation circuit, a recirculation pump, a first separator for separating from the water the gaseous hydrogen produced in the electrolysis stack and a second separator for separating from the water the oxygen produced in the electrolysis stack, said installation further comprising hydraulic supply means for supplying the recirculation circuit with deionised water so as to compensate for the water consumed by the production of gaseous hydrogen and oxygen, and lastly comprising extinguishing means for inertising the first and second separators when the installation is shut down, and in which the extinguishing means comprise a first and a second pressure relief valve provided on the first and second separators respectively, the process being characterised in that it comprises the steps of:
In an advantageous embodiment of the process, the electrical supply of the electrolysis stack is interrupted before said pressure relief valves are opened, and the two separators are filled by the hydraulic supply means when the pressure of the hydrogen in the first separator has fallen below two bars.
Preferably, the hydraulic supply means and the two pressure relief valves are controlled automatically and the first pressure relief valve (36) releases hydrogen into the atmosphere.
Further features and advantages of the present invention will become clear upon reading the following description, given merely by way of non-limiting example and in reference to the appended drawings, in which:
Simply removing the nitrogen reserve 30, the supply pipe 32 and the valve 34 from the diagram of
Apart from the extinguishing phase, the electrolysis installation shown in
Once the pressure in the separators 7, 9 has fallen below approximately two bars, the hydraulic supply means are started up automatically and supply water to the recirculation circuit so as to increase the level of liquid in the two separators until they are filled completely and thus to expel all of the hydrogen and all of the oxygen contained in the separators. Once this operation is complete, the supply pump 27 and the recirculation pump 15 are stopped and all of the valves are closed.
The electrolysis installation shown in the drawing of
For this purpose, the pump 31 is placed downstream from the junction between the pipe 28 and the recirculation circuit 13. The drawing shows that a supply valve 35 is mounted on the circuit 28 in the position where the supply pump 27 was located in the first embodiment. Moreover, a second valve 37 and a non-return valve 38 are mounted on the recirculation circuit upstream from the junction between said circuit and the pipe 28. It will be noted that the anti-return valve can be omitted. It will be understood that by controlling the relative openness of the valves 35 and 37, it is possible to control the relative amount of the supply of cold water relative to the recirculation of electrolyte, without having to use two pumps. The main advantage of the variant of the present example is therefore that it makes it possible to save on one of the two pumps, thus simplifying the installation, limiting the risk of the installation breaking down and making it less expensive.
It will also be understood that various modifications and/or improvements which are obvious to a person skilled in the art can be applied to the embodiment of the present description, without departing from the scope of the present invention as defined in the appended claims. In particular, the subject-matter of the present invention is not limited to electrolysis installations which combine the feature of using the hydraulic supply means for inertisation with the feature of having just one single pump 31 which simultaneously takes on the functions of a recirculation pump and of a supply pump. An electrolysis installation according to the present invention need only comprise either one of these two features.
| Number | Date | Country | Kind |
|---|---|---|---|
| 07112288.1 | Jul 2007 | EP | regional |
This is a National Phase Application in the United States of International Patent Application No. PCT/EP2008/005583 filed Jul. 9, 2008 which claims priority on European Patent Application No. 07112288.1 filed Jul. 11, 2007. The entire disclosures of the above patent applications are hereby incorporated by reference.
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP08/05583 | 7/9/2008 | WO | 00 | 7/1/2010 |
