The present application claims priority 35 U.S.C. §119 to European Patent Publication No. EP 21193425.2 (filed on Aug. 27, 2021), which is hereby incorporated by reference in its entirety.
One or more embodiments relate to a high-pressure tank comprising a liner made of plastic and a shell of the liner, and at least one boss.
In a known design for high-pressure tanks, especially hydrogen tanks, an inner layer of the tank is formed from a plastic liner, for example from polyamide or polyethylene, and this liner is jacketed with a fibre material, for example with carbon fibres. A boss made of metal is typically inserted at the end of such a high-pressure tank, especially to receive a withdrawal apparatus, such as a withdrawal valve, for filling and withdrawal of the medium from the high-pressure tank.
A problem here is the binding of the boss to the liner, since reliable impermeability to counter escape of the medium, especially of hydrogen gas, has to be ensured between boss and liner. In order to achieve the high impermeability required, it is customary for multiple sealing elements, such as sealing rings, to be disposed between boss and liner. However, the use of additional mechanical sealing elements makes the production of the vessel more complicated and costly. The effect of the sealing elements can also decrease over the course of utilization of the high-pressure vessel.
It is an object of this disclosure to enhance a high-pressure tank of the type specified in this regard, and especially to specify a high-pressure tank that assures reliable impermeability between liner and boss and at the same time can be produced in a simple manner. It is a further object of this disclosure to specify a simple and inexpensive method of producing such a high-pressure tank having good impermeability between boss and liner.
The object is achieved by a high-pressure tank comprising a liner made of plastic and a shell of the liner, and at least one boss, wherein the boss makes contact with the liner at least at one contact surface, wherein the contact surface has a plastic coating, wherein the plastic coating constitutes the only seal between boss and liner, such that there are no other sealing elements between boss and liner.
In accordance with one or more embodiments, a boss is coated with a plastic in order to seal the boss with respect to the liner. The plastic of the plastic layer may especially be a plastic that is typically used as corrosion protection on metal parts, i.e. a corrosion protectant. The plastic may especially be nylon-11, also known by the name Rilsan®, or may be nylon-12. These plastics are known per se as corrosion protectant on metal parts.
In the context of this disclosure, it has been found that plastic corrosion protectants, especially nylon-11 and/or nylon-12, have excellent sealing properties at a contact surface between boss and plastic liner, such that such a coating of the boss can be used as a full replacement for otherwise customary sealing elements, such as sealing rings.
Developments of this disclosure are specified in the dependent claims, the description and the appended drawings.
The plastic coating is preferably a Rilsan® nylon-11 coating and/or has been applied to the boss in a Rilsan® coating method. Such a Rilsan® coating method is especially known from the company ARKEMA, for application of an anticorrosion layer to metal parts.
The plastic coating preferably has a thickness of 50-900 μm (micrometres), more preferably of 300-500 μm (micrometres).
The entire contact surface over which the boss comes into contact with the liner preferably has the plastic coating. The seal may then extend over the entire surface of the boss which is in contact with the liner. Alternatively, an only partial coating of the contact surface with the plastic is possible.
In accordance with one or more embodiments, a method of producing such a high-pressure tank comprises applying the plastic coating to the contact surface of the boss by powder coating, especially with nylon-11 or nylon-12, preferably by a sintering method such as fluidized bed sintering, or an electrostatic powder spraying method or flame spraying method.
The powder coating is preferably preceded by a chemical or mechanical pretreatment of the contact surface, more preferably a blasting operation, especially with white corundum.
The powder coating is preceded, and the chemical or mechanical pretreatment of the contact surface is preferably followed, preferably by application of a bonding primer to the contact surface, especially of a Primgreen® LAT 12035 bonding primer.
The powder coating of the boss preferably precedes the shaping production of the high-pressure tank. The coating can be bonded to the liner either by the rotomolding, thermoforming, blow molding or injection molding method.
Preferably, therefore, the powder coating of the boss creates a material bond to the liner of the high-pressure tank, either by the rotomolding, thermoforming, blow molding or injection molding method.
One or more embodiments will be illustrated by way of example in the drawings and explained in the description hereinbelow.
As illustrated in
The boss 2 also has grooves 6 on the contact surface 3 that may, for example, run circumferentially, especially in the form of a circular segment and/or circle, and/or extend radially. The grooves 6 likewise form part of the coated contact surface 3. Grooves, and additional mechanical securing by means of undercuts and segments 6 on the sealing surface in general, may also be dispensed with completely by virtue of the coating depending on the embodiment. The function of assurance against rotation by the grooves 6 can be replaced by the two-dimensional coating. In general, a partial region with coating of the side 3, 4 facing the liner 1 may in some cases already be sufficient for the sealing and bonding function.
The contact surface 3 has at least partially or completely a plastic coating 4 of Rilsan® nylon-11 or comparable materials. The plastic coating 4 constitutes the sole seal between boss 2 and liner 1. No other sealing elements are disposed between the boss 2 and the liner 1.
The plastic coating 4 has a thickness of about 50-500 μm. The plastic coating 4 has been applied by a coating method, for example by means of powder coating with nylon-11, to the contact surface 3 of the boss 2. For this purpose, first of all, a region 7 of the boss 2 that was not to be coated was masked.
The coating was preceded by a chemical or mechanical pretreatment of the contact surface 3, preferably a blasting operation with white corundum.
After the chemical or mechanical pretreatment of the contact surface 3, a bonding primer is applied to the contact surface 3, for example a Primgreen® LAT 12035 bonding primer.
The material bond between coated surface of the boss (2) and the high-pressure tank (liner) is effected either by the rotomolding, thermoforming, blow molding or injection molding method.
The terms “coupled,” “attached,” or “connected” may be used herein to refer to any type of relationship, direct or indirect, between the components in question, and may apply to electrical, mechanical, fluid, optical, electromagnetic, electromechanical or other connections. In addition, the terms “first,” “second,” etc. are used herein only to facilitate discussion, and carry no particular temporal or chronological significance unless otherwise indicated.
Those skilled in the art will appreciate from the foregoing description that the broad techniques of the embodiments can be implemented in a variety of forms. Therefore, while the embodiments have been described in connection with particular examples thereof, the true scope of the embodiments should not be so limited since other modifications will become apparent to the skilled practitioner upon a study of the drawings, specification, and following claims.
Number | Date | Country | Kind |
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EP21193425.2 | Aug 2021 | EP | regional |