The present application relates to crankcase ventilation systems.
During operation of an internal combustion engine, a fraction of combustion gases can flow out of the combustion cylinder and into the crankcase of the engine. These gases are often called “blowby” gases. The blowby gases include a mixture of aerosols, oils, and air. If vented directly to the ambient, the blowby gases can harm the environment. Accordingly, the blowby gases are typically routed out of the crankcase via a crankcase ventilation system. The crankcase ventilation system may pass the blowby gases through a coalescer (i.e., a coalescing filter element) to remove a majority of the aerosols and oils contained in the blowby gases. The coalescer includes filter media. The filtered blowby gases are then either vented to the ambient (in open crankcase ventilation systems) or routed back to the air intake for the internal combustion engine for further combustion (in closed crankcase ventilation systems).
Some crankcase ventilation systems utilize rotating coalescers that increase the filter efficiency of the coalescing filter elements by rotating the filter media during filtering. In rotating filter cartridges, the contaminants (e.g., oil droplets suspended and transported by blowby gases) are separated inside the filter media of the filter cartridge through the particle capture mechanisms, such as inertial impaction, interception, diffusion, and gravitational forces onto the fibers. By rotating the filter media, inertial impaction and gravitational forces are enhanced by the additional centrifugal force. Additionally, the rotation of the filter cartridge can create a pumping effect, which reduces the pressure drop through the filtration system. Rotating filter cartridges may include fibrous filters as well as centrifugal separation devices.
One example embodiment relates to filter media. The filter media includes fibers that have a geometric mean fiber diameter between 5 to 40 μm. The fibers have a solidity between 5% and 30%. The filter media has a compressibility of less than 25% at pressures greater than 20 kPa.
Another example embodiment relates to a high-speed rotating coalescer element. The high-speed rotating coalescer element includes a first endplate, a second endplate, and a filter media pack comprising filter media positioned between the first endplate and the second endplate. The filter media includes fibers that have a geometric mean fiber diameter between 5 to 40 μm. The fibers have a solidity between 5% and 30%. The filter media has a compressibility of less than 25% at pressures greater than 20 kPa.
A further example embodiment relates to a filter media pack for a high-speed rotating coalescer. The filter media pack includes filter media having fibers that have a geometric mean fiber diameter between 5 to 40 μm. The fibers have a solidity between 5% and 30%. The filter media has a compressibility of less than 25% at pressures greater than 20 kPa.
These and other features, together with the organization and manner of operation thereof, will become apparent from the following detailed description when taken in conjunction with the accompanying drawings, wherein like elements have like numerals throughout the several drawings described below.
Referring to the figures generally, filter media and media packs that provide robust performance in HSRC elements for crankcase ventilation systems are described. The filter media is HSRC filter media. As such, the filter media has a higher resistance to compressibility than traditional coalescer filter media, such as filter media used in low-speed rotating coalescer arrangements or stationary coalescer arrangements. The HSRC filter media may comprise a single layer of filter media, multiple layers of filter media with differing properties, or filter media whose properties vary as a function of depth designed to optimize performance (i.e., gradient filter media). As described in further detail below, the HSRC filter media structure has a higher resistance to compressibility than traditional coalescer filter media.
Referring to
The crankcase ventilation system 100 includes a coalescer 108. The coalescer 108 is a rotating coalescer. The coalescer 108 includes a first endplate 110 and a second endplate 112 axially spaced from the first endplate 110. A filter media pack 114 comprised of filter media is positioned between the first endplate 110 and the second endplate 112. The filter media pack 114 includes fibrous filter media as described in further detail below. The fibrous filter media may include any of meltblown polyester filter media, meltblown polyphenylene sulfide filter media, needle-punched spunbond polyphenylene sulfide filter media, microglass with acrylic binder filter media, microglass with phenolic binder filter media, meltblown nylon filter media, needlefelt polyethylene terephthalate filter media, or another suitable filter media. The filter media of the filter media pack 114 is described in further detail below.
The filter media pack 114 is sealed to the first and second endplates 110 and 112 such that blowby gases entering the inlet 104 pass through the filter media pack 114. The filter media pack 114 is cylindrical in shape. In some arrangements, the filter media pack 114 is an open-ended cylindrical media pack (e.g., as shown in
In some arrangements, the coalescer 108 includes a support cage 116 that extends between the first and second endplates 110 and 112 adjacent to the filter media pack 114. The support cage 116 provides a support surface for the filter media pack 114. The support cage 116 is positioned radially outward of the filter media pack 114 with respect to a central axis 118 of the coalescer 108.
During operation, the crankcase ventilation system 100 receives blowby gases from an internal combustion engine through the inlet 104. The blowby gases flow from an inner area of the coalescer element 108 through the filter media pack 114 and out of the outlet 106 (as designated by the arrows). The coalescer 108 is rotated about its central axis 118 at a rotational speed ω. The coalescer 108 is a HSRC element. As used herein, a HSRC element refers to a rotating coalescer element that generates centrifugal forces at the filter media in excess of 500 G (G is defined below in equation 1). In some arrangements, the rotational speed ω can exceed 10,000 RPM. The coalescer 108 may be rotated, for example, by an electric motor, an oil driven motor, a mechanical linkage between the coalescer 108 and the internal combustion engine, or the like. The contaminants (e.g., oil droplets, aerosol, etc.) transported by blowby gases are separated inside the filter media pack 114 through particle capture mechanisms, such as inertial impaction, interception, diffusion, and gravitational forces onto the fibers. By rotating the filter media pack 114, inertial impaction is enhanced by the additional centrifugal force. Additionally, the rotation of the coalescer 108 can create a pumping effect, which reduces the pressure drop through the crankcase ventilation system 100. In some arrangements, the support cage 116 includes fins or ribs to enhance the pumping effect. Separated contaminants, such as oil, fall to the bottom of the stationary housing 102 where the contaminants can exit the housing through the drain 120.
As discussed above, the crankcase ventilation system 100 removes contaminants, such as fine oil droplets from the blowby gas. This helps to reduce emissions from the internal combustion engine. In arrangements where the crankcase ventilation system 100 is part of a closed loop crankcase ventilation system, the removal of the contaminants also protects intake components of the internal combustion engine, such as a turbocharger. In some arrangements, the crankcase ventilation system 100 is configured for high contaminant removal efficiency. For example, the crankcase ventilation system 100 can be configured to remove greater than 99% of particles as small as 0.3 μm with a pressure drop of less than 0.8 kPa at full load on the internal combustion engine. In some arrangements, the life of the coalescer 108 is greater than 7000 operating hours without significant deterioration in performance. The coalescer can operate at temperatures up to 120 degrees Celsius. To achieve the above-noted design parameters, the coalescer 108 is a HSRC. As discussed below, the media pack 114 has different media characteristics than media packs used for stationary (i.e., non-rotating) coalescers and low speed rotating coalescers (LSRC). A LSRC is a coalescer that rotates and creates less than about 200 to 500 G of centrifugal force, while a HSRC rotates and creates more than 500 G of centrifugal force and can exceed 1000 G of centrifugal force. G is defined by Equation 1.
In Equation 1, ω is the rotational speed of a given rotating coalescer in radians per second and R is the radius of the rotating coalescer in meters.
HSRC elements, such as the coalescer 108, are designed to different system and operating parameters than conventional stationary (i.e., non-rotating) coalescer applications and conventional LSRC applications. The conventional stationary coalescer applications and the conventional LSRC applications are herein referred to as “conventional crankcase ventilation applications.” In these conventional crankcase ventilation applications, the geometric mean media fiber diameter, solidity, and thickness are controlled to meet the required removal efficiency, pressure drop, and life requirements. As used herein, the phrase “geometric mean” refers to a mean that indicates the central tendency or typical value of a set of numbers identified by taking the nth root of the product of n numbers (i.e., (Πi=1nxi)1/n for a set of numbers {xi}i=1n), as opposed to the arithmetic mean which relies on dividing the sum of n numbers by n. For internal combustion engine air intake filtration systems and conventional crankcase ventilation applications, low pressure drops may be required and media with low solidity, less than 15% is used. Table 1 summarizes some of the characteristics of filter media used in various crankcase ventilation applications.
Referring to Table 1, media A, C, D and E are conventional media used in conventional crankcase ventilation applications. Media B and F are examples of the media that is usable in HSRC applications, such as the media pack 114 of the coalescer 108. As used herein, media B and F may be referred to as “HSRC media.” A variety of materials, including polyester, glass, cellulose, metal fibers, and polyamide, have been used for conventional crankcase ventilation applications. However, in HSRC applications, the filter media is exposed to greater than 20 kPa pressure due to centrifugal forces caused by the high speed rotation. The centrifugal forces can compress the filter media, which negatively impacts the performance in HSRC applications. This is shown in graphs 400 and 500, which are discussed below.
Referring to
Coalescer media used in crankcase ventilation applications must exhibit both a high removal efficiency for fine droplets, as well as low pressure drop. Frazier permeability, as determined using ASTM D737 or similar test method, is a media property that is directly related to pressure drop under stationary conditions and indirectly related to removal efficiency. Frazier permeability is reported as the air flow rate, measured in cubic feet per minute (cfm), at 0.5 inches of water pressure drop. In general, lower values for Frazier permeability correspond to higher pressure drop and higher removal efficiency. For HSRC applications, it is desirable that the Frazier permeability be less than or equal to 250 cfm in order to meet these requirements. It is preferable that the Frazier permeability be between 10 and 100 cfm in order to meet both removal efficiency and pressure drop requirements for crankcase ventilation applications. In a more particular implementation, the Frazier permeability may be between 10 and 50 cfm.
The relatively poor performance of conventional media, such as media A as demonstrated in graphs 400 and 500, in HSRC applications is due to compression of the filter media and collapse of the media's structure. The filter media compresses and collapses under the high centrifugal forces experienced during high speed rotation. While it is known that media compression increases pressure drop, the media design challenge of reducing pressure drop while maintaining high removal efficiency is achieved by the HSRC media discussed herein. Accordingly, in HSRC applications, media that both (1) resists compression and structural collapse at high rotational speeds and (2) maintains high removal efficiency is needed. Such media is described in further detail below. The below-described specific values of compressibility are understood to be the limits (i.e., the maximum compressiblities) at room temperature (i.e., 20 degrees Celsius) unless otherwise stated (e.g., as done with respect to the description of
The media pack 114 of coalescer 108 includes HSRC filter media composed of fibers of a single polymeric material (e.g., PPS), a single copolymer (e.g., polyoxymethylene copolymer), or a single polymer blend (e.g., polybutylene terephthalate-polyethylene terephthalate blend) that possesses characteristics that provide functionality in terms of high oil droplet removal efficiency and low restriction at centrifugal forces in excess of about 200 G, and more specifically in excess of 1000 G. In other arrangements, the HSRC filter media may be comprised of more than one type of polymer, microglass, or metal fibers. In such arrangements, the HSRC filter media may be arranged as a composite media (e.g., a media having a plurality of different media fibers), a gradient (e.g., a media having a plurality of different media fibers arranged in a manner in which the filter element has a filtering efficiency that varies across a depth of the filter element), or a multilayer media (e.g., a media having different filter materials layered over one another) to achieve different filtering regions. Secondarily, the media of the media pack 114 exhibits chemical compatibility and thermal properties suitable for crankcase ventilation applications. Thus, the filter media should be chemically compatible with engine oil, glycol, and water and be able to withstand temperatures in the range of 80 to 120 degrees Celsius without loss of functionality. In general, HSRC filter media for these applications should have a geometric mean fiber diameter within the range of 5 to 40 μm, solidity between 5 and 30%, and a Frazier permeability of up to 250 cfm at 0.5 inches of water pressure drop. In some arrangements, the Frazier permeability is 10 to 100 cfm at 0.5 inches of water pressure drop. In some arrangements, the filter media has a geometric mean fiber diameter within the range of 10 to 20 μm, solidity between 15 and 30%, and a Frazier permeability of 10 to 20 cfm at 0.5 inches of water pressure drop. Further, the filter media has a compressibility of less than 20% at pressures greater than 20 kPa. In some arrangements, the filter media has a compressibility of less than 15% at pressures greater than 20 kPa. As used herein, “compressibility” is the relative change in filter media volume in response to pressure or force. Specific examples of compressibility discussed herein were determined by measuring the change in thickness of the filter media while increasing the amount of force applied to the surface of the media over the range of about 1 to 30 kPa. “Compressibility” is defined herein as the percent change in volume of the filter media at a specified pressure relative to the volume at 1 kPa. Thus, a filter media that has a thickness of 1 mm at 1 kPa and of 0.9 mm at 10 kPa, has a compressibility of 10% at 10 kPa. Media compressibility (at a given temperature) as a function of pressure or centrifugal force is governed by many factors, including, but not limited to, the fiber size distribution of the media, media solidity, the flexural modulus of the polymer (i.e., the fiber material), the strength and degree of fiber to fiber bonding in the media, and degree of entanglement of the fibers.
In
The compressibility of HSRC media and media packs (e.g., media pack 114) due to centrifugal forces is related to the media's resistance to compression due to pressure drop. However, compression due to centrifugal forces also takes into account other factors, such as media pack design and application factors (e.g., rotational speed, radius of the media pack, etc.). In some arrangements, the HSRC media of the media pack 114 has a compressibility of less than 20% at 200 G at room temperature (i.e., at 20 degrees Celsius). In further arrangements, the HSRC media of the media pack 114 has a compressibility of less than 20% at 1000 G at room temperature (i.e., at 20 degrees Celsius). In additional arrangements, the media of the media pack 114 has a compressibility of less than 15% at 200 G. In further arrangements, the media of the media pack 114 has a compressibility of less than 15% at 1000 G.
As previously discussed, the HSRC filter media and media packs (e.g., media pack 114) have a geometric mean fiber diameter within the range of 5 to 40 μm in order to provide the removal efficiency, pressure drop, and compressibility requirements of HSRC applications. Referring to
Although the geometric mean fiber diameter of HSRC media is within the range of 5 to 40 μm, the HSRC media includes some fibers having a diameter larger than 20 μm in some arrangements. For example, note the relative numbers of fibers larger than 20 μm in media B and larger than 30 μm in media F. These larger fibers help to reduce the compressibility of the given media. Accordingly, in particular embodiments, the HSRC media (e.g., media B and F) include at least some larger fibers, but with a predominance of smaller fibers in the smallest mode as shown in the histograms 800. The relative abundance of the fibers larger than about 30 μm relative to smaller fibers should be low in order to not adversely impact contaminant removal. Accordingly, the HSRC media may include between 1 and 5% of the fibers larger than about 40 μm to reduce compressibility. In some arrangements, the HSRC media includes about 3% of fibers that are larger than 30 μm. In another arrangement, the HSRC media includes between 1 and 5% of fibers larger than about 20 μm. In further arrangements, the HSRC media includes a layer of filter media having a geometric mean diameter within the range of 5 to 40 μm and one or more upstream and/or downstream layers with fibers having a diameter greater than 30 μm.
Another factor that affects media compressibility is the solidity of the filter media. Solidity refers to the relative volume of a filter media that is physically occupied by media fibers. Thus, a completely nonporous solid possessing no voids in its structure has a solidity of 100%, while a gas or a liquid sample containing no solid material has a solidity of 0%. Numerically, solidity is equal to 100% minus the porosity of a filter media sample. At low solidity, the media becomes excessively compressible in HSRC applications. At high solidity, the media may become too restrictive, which can cause a high pressure drop in the crankcase ventilation system 100. In some arrangements, the HSRC media has a solidity between 5 and 30% (and more specifically between 5 and 25%). In other arrangements, the HSRC media has a preferred solidity of 15-30%. In further arrangements, the HSRC media has a more preferred solidity between 18 and 25%. As a point of reference, the non-HSRC media in table 1 have solidities of 8-16%. The above-noted solidities of 15-30% for the HSRC media are undesirable for conventional crankcase ventilation applications and air intake applications, as the resultant pressure drop is excessive. However, for HSRC applications, the high solidity is both desirable and possible because, at high speeds, rotation of the filter creates a pumping action that offsets the increased restriction of the filter media (e.g., as discussed above with respect to
Material stiffness also affects media compressibility. For example, fibers with greater stiffness (i.e., a high flexural modulus) are more resistant to compression. Flexural modulus can be determined using the ASTM D790 test method or another test method. Conventional media A (PE—process 1), media D (nylon 6,6), and media E (PET), each have flexural moduli of approximately 2400 MPa to 2800 MPa. Media B (PPS) has a flexural modulus of approximately 4200 MPa. Media F (PE—process 2) has a flexural modulus between 2300 and 2800 MPa, but media F is expected to have a greater flexural modulus than media A as a result of its more crystalline polymer structure. Accordingly, media B and media F have a significantly higher stiffness than media A, media D, and media E. The flexural modulus does not depend exclusively on the specific polymer used, but also on the conditions under which the material was produced. For example, the stiffness of conventional media A may be significantly increased by slowing down the speed of the uptake mandrel during media production, which allows the polymer to cool more slowly and achieve a more crystalline and three-dimensional structure as observed with media F. For HSRC applications, the polymer from which the fibers are produced should have a flexural modulus of at least 2000 MPa at 23 degrees Celsius in order to resist collapse. In some arrangements, the polymer from which the fibers for the HSRC media are produced has a flexural modulus greater than 3000 MPa. In other arrangements, the polymer from which the fibers for the HSRC media are produced has a flexural modulus greater than 4000 MPa.
As previously described, the HSRC media and media packs (e.g., media pack 114) are made from fibers composed of a single polymer, a single copolymer, or a single polymer blend. In other arrangements, the HSRC filter media may be comprised of more than one type of polymer, microglass, or metal fibers. In such arrangements, the HSRC filter media may be arranged in a composite, a gradient, or a multilayer media that can have different material for different filtering regions. In contrast to conventional crankcase ventilation media, the desired properties, including resistance to compression, when obtained by means of a bi- or multi-component structure with scaffold fibers or particles, or through the use of binders or resins to hold the fibers in place, may result in less desirable performance tradeoffs. Compressibility of the resulting media may be strongly influenced by the strength and degree of fiber to fiber bonding. The use of a single polymer, a single copolymer, or a single polymer blend simplifies production and manufacturing and also enables the use of alternative manufacturing methods to achieve stronger fiber to fiber bonding when making the media pack 114. In some arrangements, the stronger fiber to fiber bonding is achieved by a thermal process. The nonwoven media is produced by a process, such as melt spinning, melt blowing, flash spinning, or spun laying, in which newly formed soft or molten fibers are laid down on top of one another, before they cool and stiffen, to form the web or mat. Upon cooling, the fibers are bonded to one another, without the need for additional binders or resins. The thermal production process ensures an abundance of strong fiber to fiber bonds within the HSRC media.
An increase in the three-dimensional structure of filter media also reduces media compression. Media produced by wet or dry laying processes, such as meltblowing and melt spinning, typically result in media whose individual fibers are largely oriented in a two-dimensional structure, approaching stacked X-Y planar structures in an X-Y-Z coordinate system where the X-Y plane is normal to the direction of flow through the filter media and where the Z axis is parallel to the direction of flow and defines a thickness of the media. Media A, media C, media D, and media E are examples of such media. To reduce compression, the HSRC media may be produced to have greater three-dimensional structure (e.g., by increasing fiber orientation in the Z direction). This can be achieved in a number of ways. In some arrangements, the three-dimensional character of the media B is enhanced by needle punching (i.e., needling). In other arrangements, the three-dimensional structure of the HSRC media is enhanced by other processes, such as the use of water jets (e.g., hydroentangling), air jets, and/or felting. In further arrangements, the three-dimensional structure of the HSRC media is enhanced by increasing the orientation of fibers in the Z direction during the media production process by, for example, by decreasing the line speed used to produce the media as in the case of media F.
The above-described HSRC media (e.g., media B and media F) and media packs (e.g., media pack 114) provide benefits over conventional crankcase ventilation media for HSRC applications. For example, the HSRC media is more efficient at contaminant removal for particles between 0.4 and 2.0 μm in diameter. In tests run at ambient temperatures, cumulative oil droplet removal efficiencies for particles between 0.4 and 2.0 μm in diameter of 99.94% and 99.97% were obtained, respectively, for conventional media A and media B. As shown in
It should be noted that any use of the term “example” herein to describe various embodiments is intended to indicate that such embodiments are possible examples, representations, and/or illustrations of possible embodiments (and such term is not intended to connote that such embodiments are necessarily extraordinary or superlative examples).
As used herein, the term “about” or “approximately” when coupled to a number or a range means plus or minus five percent of the modified number or range. When a range is described as being between two numbers, the range is intended to be inclusive of the two numbers that define the range.
The terms “coupled” and the like as used herein mean the joining of two members directly or indirectly to one another. Such joining may be stationary (e.g., permanent) or moveable (e.g., removable or releasable). Such joining may be achieved with the two members or the two members and any additional intermediate members being integrally formed as a single unitary body with one another or with the two members or the two members and any additional intermediate members being attached to one another.
References herein to the positions of elements (e.g., “top,” “bottom,” “above,” “below,” etc.) are merely used to describe the orientation of various elements in the FIGURES. It should be noted that the orientation of various elements may differ according to other example embodiments, and that such variations are intended to be encompassed by the present disclosure.
It is important to note that the construction and arrangement of the various example embodiments are illustrative only. Although only a few embodiments have been described in detail in this disclosure, those skilled in the art who review this disclosure will readily appreciate that many modifications are possible (e.g., variations in sizes, dimensions, structures, shapes and proportions of the various elements, values of parameters, mounting arrangements, use of materials, colors, orientations, etc.) without materially departing from the novel teachings and advantages of the subject matter described herein. For example, elements shown as integrally formed may be constructed of multiple parts or elements, the position of elements may be reversed or otherwise varied, and the nature or number of discrete elements or positions may be altered or varied. The order or sequence of any process or method steps may be varied or re-sequenced according to alternative embodiments. Additionally, features from particular embodiments may be combined with features from other embodiments as would be understood by one of ordinary skill in the art. Other substitutions, modifications, changes and omissions may also be made in the design, operating conditions and arrangement of the various example embodiments without departing from the scope of the present invention.
This application is a national stage of PCT Application No. PCT/US2016/047755, filed Aug. 19, 2016, which claims priority to U.S. Provisional Patent Application No. 62/208,284, entitled “HIGH SPEED ROTATING CRANKCASE VENTILATION FILTER MEDIA,” filed Aug. 21, 2015. The contents of both applications are hereby incorporated by reference in their entirety.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/US2016/047755 | 8/19/2016 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2017/034976 | 3/2/2017 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
2788125 | Webb | Apr 1957 | A |
2905327 | Phillips | Sep 1959 | A |
2937755 | Szwargulski | May 1960 | A |
3234716 | Sevin et al. | Feb 1966 | A |
3362155 | Driscoll | Jan 1968 | A |
3451551 | Downey | Jun 1969 | A |
3531897 | Weimar | Oct 1970 | A |
4189310 | Hotta | Feb 1980 | A |
4279630 | Nakamura | Jul 1981 | A |
4482365 | Roach | Nov 1984 | A |
4487618 | Mann | Dec 1984 | A |
4502956 | Wilson | Mar 1985 | A |
4514193 | Booth | Apr 1985 | A |
4516994 | Kocher | May 1985 | A |
4981502 | Gottschalk | Jan 1991 | A |
5056935 | Singh | Oct 1991 | A |
5401706 | Fischer | Mar 1995 | A |
5462658 | Sem | Oct 1995 | A |
5466385 | Rogers et al. | Nov 1995 | A |
5716423 | Krul et al. | Feb 1998 | A |
5863317 | Smith et al. | Jan 1999 | A |
6033450 | Krul et al. | Mar 2000 | A |
6123061 | Baker et al. | Sep 2000 | A |
6139595 | Herman et al. | Oct 2000 | A |
6183407 | Hallgren et al. | Feb 2001 | B1 |
6499285 | Snyder | Dec 2002 | B1 |
6517612 | Crouch et al. | Feb 2003 | B1 |
6640792 | Harvey et al. | Nov 2003 | B2 |
6652439 | Herman et al. | Nov 2003 | B2 |
6709477 | Haakansson et al. | Mar 2004 | B1 |
6876760 | Vaisberg | Apr 2005 | B1 |
7235177 | Herman et al. | Jun 2007 | B2 |
7811347 | Carlsson et al. | Oct 2010 | B2 |
7824458 | Borgstrom et al. | Nov 2010 | B2 |
7824459 | Borgstrom et al. | Nov 2010 | B2 |
8172917 | Kup et al. | May 2012 | B2 |
8231752 | Janikowski | Jul 2012 | B2 |
8268033 | Rogers et al. | Sep 2012 | B2 |
8794222 | Schwandt et al. | Aug 2014 | B2 |
8974567 | Verdegan et al. | Mar 2015 | B2 |
20030034016 | Harvey et al. | Feb 2003 | A1 |
20040016345 | Springett | Jan 2004 | A1 |
20040020839 | Kato | Feb 2004 | A1 |
20040071328 | Vaisberg | Apr 2004 | A1 |
20040214710 | Herman et al. | Oct 2004 | A1 |
20060096263 | Kahlbaugh et al. | May 2006 | A1 |
20060242933 | Webb et al. | Nov 2006 | A1 |
20070039300 | Kahlbaugh | Feb 2007 | A1 |
20070175191 | Ziebold et al. | Aug 2007 | A1 |
20070249479 | Eliasson et al. | Oct 2007 | A1 |
20070271884 | Pearson et al. | Nov 2007 | A1 |
20080280777 | Bittner | Nov 2008 | A1 |
20090000258 | Carlsson et al. | Jan 2009 | A1 |
20090020486 | Barnwell | Jan 2009 | A1 |
20090044702 | Adamek et al. | Feb 2009 | A1 |
20090056292 | Fornof et al. | Mar 2009 | A1 |
20090067986 | Mignano | Mar 2009 | A1 |
20090101013 | Moredock | Apr 2009 | A1 |
20090263238 | Jarrah | Oct 2009 | A1 |
20100126145 | He et al. | May 2010 | A1 |
20100180854 | Baumann et al. | Jul 2010 | A1 |
20100229511 | Steins et al. | Sep 2010 | A1 |
20100285101 | Moore | Nov 2010 | A1 |
20110180051 | Schwandt et al. | Jul 2011 | A1 |
20110198280 | Jones et al. | Aug 2011 | A1 |
20110247309 | Smith et al. | Oct 2011 | A1 |
20110252974 | Verdegan et al. | Oct 2011 | A1 |
20110263496 | Fineman | Oct 2011 | A1 |
20120034083 | Shoji et al. | Feb 2012 | A1 |
20120118200 | Howell et al. | May 2012 | A1 |
20120315225 | Porbeni et al. | Dec 2012 | A1 |
20130037481 | Lalouch et al. | Feb 2013 | A1 |
20130056407 | Parikh et al. | Mar 2013 | A1 |
20130167816 | Dawar et al. | Jul 2013 | A1 |
20140033668 | Kleynen | Feb 2014 | A1 |
20140069432 | Mebasser et al. | Mar 2014 | A1 |
20140096683 | Azwell et al. | Apr 2014 | A1 |
20140326661 | Madsen et al. | Nov 2014 | A1 |
20150047582 | Dawar et al. | Feb 2015 | A1 |
20150075377 | Gorbach et al. | Mar 2015 | A1 |
20150173577 | Kim et al. | Jun 2015 | A1 |
20160030875 | Parikh et al. | Feb 2016 | A1 |
20160245157 | Wilkins et al. | Aug 2016 | A1 |
20180030868 | Elsaesser et al. | Feb 2018 | A1 |
20180117512 | Janakiraman et al. | May 2018 | A1 |
20190153635 | Ikejiri | May 2019 | A1 |
Number | Date | Country |
---|---|---|
101491793 | Jul 2009 | CN |
101784325 | Jul 2010 | CN |
104334284 | Feb 2015 | CN |
100 44 615 | Apr 2002 | DE |
203 02 824 | Aug 2004 | DE |
10 2006 024 816 | Dec 2007 | DE |
1 532 352 | May 2005 | EP |
1 645 320 | Apr 2006 | EP |
2933626 | Jan 2010 | FR |
H11-141325 | May 1999 | JP |
WO 2011100712 | Aug 2011 | WO |
WO2012016659 | Aug 2012 | WO |
WO 2012106659 | Aug 2012 | WO |
WO2012106659 | Aug 2012 | WO |
WO 2013025445 | Feb 2013 | WO |
WO-2016046944 | Mar 2016 | WO |
WO 2016159951 | Oct 2016 | WO |
WO-2016159951 | Oct 2016 | WO |
WO 2017189516 | Nov 2017 | WO |
WO-2018002244 | Jan 2018 | WO |
Entry |
---|
Holdich, R.G., “Fundamentals of Particle Technology,” Chapter 8, Midland Information Technology and Publishing, Jan. 1, 2002, 15 pages. |
International Search Report and Written Opinion issued for PCT/U2017/029315, dated Aug. 1, 2017, 14 pages. |
International Search Report and Written Opinion issued for PCT/US2015/023290, dated Jun. 29, 2015, 10 pages. |
International Search Report and Written Opinion issued for PCT/US2016/036384, dated Aug. 25, 2016, 9 pages. |
International Search Report and Written Opinion issued for PCT/US2016/036432, dated Aug. 31, 2016, 24 pages. |
International Search Report and Written Opinion issued for PCT/US2016/048912, dated Nov. 10, 2016, 12 pages. |
Chinese Office Action from corresponding CN Application No. 2016800326319, dated Mar. 18, 2019, pp. 1-6. |
First Office Action for Chinese Patent App. No. 2015800784030 dated Mar. 1, 2019, 19 pages (with translation). |
Office Action for U.S. Appl. No. 15/561,170 dated Mar. 14, 2019, 11 pages. |
Office Action issued for U.S. Appl. No. 15/580,481 dated Feb. 14, 2020. |
First Examination Report for Indian Patent App. No. 201847007059 dated May 5, 2020, 6 pages. |
First Office Action for Chinese Patent App. No. 201780024820.6 dated Mar. 31, 2020, 22 pages (with translation). |
International Search Report and Written Opinion Issues for PCT Application No. PCT/US2016/047755, dated Nov. 4, 2016, 10 pages. |
Extended European Search Report for European Patent App. No. 17790235.0 dated Oct. 25, 2019, 9 pages. |
Office Action issued for U.S. Appl. No. 16/096,585, dated Oct. 16, 2019, 10 pages. |
Final Office Action issued for U.S. Appl. No. 15/580,481, dated Aug. 17, 2020, 27 pages. |
Number | Date | Country | |
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20180353882 A1 | Dec 2018 | US |
Number | Date | Country | |
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62208284 | Aug 2015 | US |