High strength reactive materials

Abstract

In this method for making a sintered reactive material, fuel particles are blended with a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material. The reactive material is dried and pressed to obtain a shaped pre-form, which is sintered in an inert atmosphere to form the sintered reactive material. By sintering in an inert atmosphere, the sintered reactive material may include reactive metals and/or metalloids in a non-oxidized state. The resulting sintered reactive material preferably has a tensile strength in excess of 1800 psi and an elongation at break in excess of 30%.

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention pertains to high strength reactive materials and methods for their production, especially high strength materials having maximum stresses and strains that exceed those heretofore obtained with conventionally fabricated energetic materials. The present invention also relates to warheads comprising the high strength energetic materials.

2. Description of the Related Art

Various military warheads are equipped with a liner or inner sheath comprised of a reactive material. In principle, upon impact these warheads are intended to deliver kinetic energy and chemical energy from the reactive material. The reactive material is intended to fragment, react and release energy (chemical) as a result of the high temperature and pressure (shear) when the warhead impacts its target. The reactive fragments provide additional means for threat destruction.

At present, however, there has been a need for a sufficiently robust reactive material that is inert during storage, but which has significantly improved strength characteristics. Reactive materials produced by conventional methods have been found to possess inadequate tensile strength and to be characterized by poor elongation at break.

It would be a significant advancement in the art to discover a reactive material comprised of a fluoropolymer and a particulate metal or metalloid which has a tensile strength greater than 1800 psi and a strain (elongation at break) of greater than 30%, and a method for its production.

Metallic particles such as aluminum, zirconium, titanium, and magnesium are energetic fuels that, if distributed in a fluoropolymer, would establish an excellent reactive material. However, known methods of distributing metal particles into fluoropolymers involve the oxidization of these particles, which significantly reduces their energetic capacities. For example, U.S. Pat. No. 2,961,712 to Davis discloses a method of making filled polytetrafluoroethylene products in which metallic filler, such as aluminum powder, is inter-dispersed and precipitated in a dispersion of the polytetrafluoroethylene, which is then dried and sintered. The sintered mixture is broken up into powder. The sintered powder is then mixed with another polytetrafluoroethylene dispersion, precipitated, and subjected to a second sintering process. Davis characterizes its fillers as substantially inert, most probably due to the use of an oxidizing atmosphere during preparation and sintering of its energetic particles. Other U.S. patents disclose the use of water or aqueous solutions for dispersing metal and metalloid particles in a fluoropolymer. However, water generally functions as an oxidizing agent, and in the presence of some metals, such as aluminum, can cause the release of hazardous amounts of hydrogen gas.

OBJECTS OF THE INVENTION

It is therefore one of the objects of this invention to provide a method of making a sintered reactive material comprising non-oxidized reactive fuel particles present in a sintered fluoropolymer matrix.

It is another object of the invention to provide a sintered reactive material comprising non-oxidized reactive fuel particles in a sintered fluoropolymer matrix.

Additional objects and advantages of the invention will be set forth in the description that follows, and in part will be apparent from the description, or may be learned by practice of the invention. The objects and advantages of the invention may be realized and obtained by means of the instrumentalities and combinations pointed out in the appended claims.

SUMMARY OF THE INVENTION

To achieve the foregoing objects, and in accordance with the purposes of the invention as embodied and broadly described herein, a method is provided for making a sintered reactive material. The method comprises blending fuel particles and a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material. Non-oxidized reactive metals and/or metalloids may be selected as the fuel particles. The reactive material is dried and pressed to obtain a shaped pre-form, which is sintered in an inert atmosphere to form the sintered reactive material. By sintering in an inert atmosphere, oxidation of the fuel particles is avoided.

In accordance with another aspect of this invention, there is provided a sintered reactive material comprising a matrix of one or more fluoropolymers and at least one metal or metalloid in fine particulate form dispersed in the matrix. The sintered reactive material has a tensile strength in excess of 1800 psi and an elongation at break in excess of 30%. It has been found that the sintered reactive material may exhibit tensile strengths in excess of 2700 psi and an elongation at break in excess of 100%.

The present invention also includes process embodiments which now enable the fabrication of reactive material having the sought after physical properties. The reactive materials can be shaped to form liners or inserts for warheads on various hardware, such as air-to-air, ground-to-air, or air-to-ground advanced tactical missiles. A warhead with such a liner and the missile carrying it is part of the invention.

The reactive materials can also be shaped in spheres or other selected form to generate reactive “grape” shot. When a warhead impacts or an explosive is set off, the reactive material may be fragged but is nonetheless dispersed following impact or in the explosion. The pre-shaped reactive material can thus form a non-continuous liner for warhead.

The present invention also contemplates a method of protecting aircraft, ships vehicles, missiles or the like, against threats, this method comprises deploying tactical munitions or tactical missiles with the reactive material as a warhead liner or reactive material as “grape” shot against the threat.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are incorporated in and constitute a part of the specification, illustrate presently preferred embodiments and methods of the invention and, together with the general description given above and the detailed description of the preferred embodiments and methods given below, serve to explain the principles of the invention. In such drawings:

FIG. 1 is a representative plot of a sintering cycle; and

FIG. 2 is a representative plot of another sintering cycle for 1 inch (2.54 cm) diameter spheres of shaped reactive material.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS AND METHODS OF THE INVENTION

Reference will now be made in detail to the presently preferred embodiments and methods of the invention as described below. It should be noted, however, that the invention in its broader aspects is not limited to the specific details, representative devices and methods, and examples described in this section in connection with the preferred embodiments and methods. The invention according to its various aspects is particularly pointed out and distinctly claimed in the attached claims read in view of this specification, and appropriate equivalents.

The reactive material of the present invention is characterized as having a high tensile strength and a high maximum strain. As used herein, a high tensile strength means greater than about 1800 psi and a high strain means greater than about 30% elongation at break.

Compositionally, the matrix phase is comprised of at least one fluoropolymer. Suitable fluoropolymers include thermoplastic and vulcanizable polymers, copolymers and terpolymers. The fluoropolymers include fluorothermoplastics and fluoroelastomers (including so-called fluoro-rubbers) such as polytetrafluoroethylene, tetrafluoroethylene/hexafluoropropylene/vinylidene fluoride terpolymers, and vinylidene fluoride and hexafluoropropylene di-polymers (copolymers) among others. These and other suitable matrix fluoropolymers are available from Dyneon LLC of Oakdale, Minn. (Dyneon™ Fluorothermoplastic THV×240A and THV×246; Fluorel™ Fluoroelastomer FC 2174 (a curable copolymer of vinylidene fluoride and hexafluoro propylene), and Dyneon™ THV Fluorothermoplastic 200P (terpolymer of TFE/VDF/HFP); DuPont (7 series fluoropolymer resins of which resins 7A and 7C are illustrative)). Other fluoropolymer resins available from DuPont include Teflon® NXT75 fluoropolymer resin (modified PTFE granular molding resin) and Viton® brand fluoroelastomers such as Viton® B and Vitron® E-60C. Exemplary, vulcanizable (curable) extrudable fluoropolymers are available from Zeus Int'l (Orangeburg, S.C.) and these include the “FEP” resin.

A fine particulate fuel is dispersed in the matrix. The fuel can be comprised of one or more metals or metalloids. Metals are preferred and include, by way of example, aluminum, zirconium, titanium, magnesium and a combination of any thereof.

The fuel, by present preference, has an average particle size greater than 1 μm to reduce the sensitivity (ESD, impact and friction) of the reactive material. In principle larger sized particles up to less than 500 μm in average particle size may be used. A practical maximum size will be dictated by the rate of reaction and rate at which sufficiently sized fragments form upon impact. A present more preferred upper value is about 250 μm. Satisfactory results have also been achieved with powdered fuels, such as powdered aluminum, having particle sizes in the range of approximately 1 μm to 10 μm such as 5 μm and 3 μm.

The relative amounts of the two essential constituents of the present reactive material can vary within relatively broad ranges. The fuel must be present in an amount greater than 0%, and up to approximately 35% by weight of the reactive material. In general, the fuel comprises approximately 15-35% by weight of the reactive material, and a present preference is for approximately 25 to 30% by weight. The matrix comprises the remainder of the two essential constituents.

The present reactive material can include various additives singly or in combination. Fibers, bonding agents and, depending on the fluoropolymer, cross linking agents, among others can be included in the reactive material. Suitable fibers include graphite fibers and aramid fibers.

The present sintered reactive material is at least shaped (consolidated) in an environment that at least essentially excludes oxygen. A selected powdered fuel and a selected fluoropolymer(s) are physically blended in an inert solvent organic media (if necessary). The blend can, if desired, be washed with an inert organic media. The blend is then dried at a selected temperature, and the solids blend is shaped under a selected high pressure while under a hard or sufficient vacuum to form an object (pellets, disk, wafer, cone, etc.) whereby air voids are at least minimized, and the density is maximized.

Preparing the blend, i.e., compounding, can be conducted using high or low shear mixing mixers, of which a Banbury mixer, Haake Rheocord mixer or twin screw extruder are typical. Other mixers such as a Hobart mixer or a Muller mixer can in principle be used. The Hobart mixer with a high-shear whip attachment is a mixer of present choice. The Haake Rheocord mixer and the twin screw extruders are also presently preferred. A solvent, such as heptane or ethanol, may be used during blending to facilitate homogeneous mixing. Generally, the amount of solvent used will depend upon the particular mixer selected, and can be determined by those skilled in the art. However, it has been found that solvent levels of 45 weight percent in Hobart mixers produce advantageous results.

A screening stage may be introduced at this time, in order to break up agglomerates and produce higher homogeneity in the pressing stage. Screening preferably involves the use of a 4 mesh screen, although other screen sizes may be used in the scope of this invention. Screening also preferably comprises pressing agglomerates through the screen, such as by hand.

The shaping stage can be a single pressing stage, or multi-staged, but under vacuum. A single pressing stage follows an optional pre-heat of the reactive material. A single stage shaping involves placing the selected amount of the solid blend (reactive material) in a die (may be a heated die), applying the selected pressure to the reactive material at the suitable temperature for a sufficient time to obtain a shaped pre-form, and then recovering the pre-form. The typical actual pressures can be from approximately from 3,000 psi to 10,000 psi, more particularly from 4000 psi to 8000 psi. The pressure can be applied for about 5 seconds to a few minutes (5 minutes), preferably 30 seconds to 90 seconds, and more particularly for about 30 to 60 seconds.

The shaping can also be conducted in stages to minimize induced stress and strain in the shaped object. For smaller-sized shaped objects, such as thin disks, or wafers shaping can be conducted using a die (such as vacuum, heated die) and a press, but under vacuum. The blend of the solid selected reactive material can, if desired, be first warmed, to the approximate temperature of the heated die. Pressure is initially applied at an actual pressure from 3,000 psi to 10,000 psi, typically 4,000 to 8,000 psi. The pressing is conducted for a sufficient time, typically from 5 seconds to a few minutes (e.g. about 5 seconds to about 5 minutes, more preferably 1 to 2 minutes), but the actual time will be based on the size of the object to be shaped. The pressure is next released and the object being shaped relaxes, still under vacuum, for a selected period of time which, for smaller objects, can be on the order of about 30 seconds to about 1 minute. Pressure is then re-applied again under vacuum, and the object being shaped is pressurized for 30 seconds to a few minutes. The pressure is then released and the pre-form (object) is recovered. The multi-staged shaping process may involve, for example, inverting of the sample between pressing stages so as to decrease gradient gradients inside the sample.

The total dwell time in the shaping is pre-selected, but can be on the order of a few second to a few minutes at 4,000 psi for a thin disk of reactive material being fabricated from powdered aluminum (26.5%) and PTFE (DuPont 7C resin, remainder).

As mentioned above, the reactive material to be shaped (consolidated) in either a single or multi-stage process can be heated to a temperature approximating that of the heated die in a pressing apparatus. The reactive material can, in general, be subjected to an initial thermal treatment in an approximate range of 170° F. (76.6° C.) to about 190° F. (87.7° C.) before (consolidating) shaping.

The objects obtained are then sintered. The sintering can proceed such as by adapting the time vs. temperature plot in FIG. 1 or FIG. 2 . The proper sinter cycle is, in general, essential to obtaining the desired physical properties, and to avoid creating cracks. Shaping (consolidating) under vacuum and following a specified sintering cycle are important to obtaining a product with the desired physical properties.

In the sintering process the pre-form, e.g. shaped object, is transformed into a sintered object having the desired increased tensile strength and decreased void fraction. The sintering generally involves a first stage in which the pre-form expands as its temperature rises above the melting point of the fluoropolymer. In the second phase, the particles in the pre-form coalesce and eliminate voids with the particles fusing together.

Sintering may slightly distort the pre-form shape. Thus, the sintered object can, if desired, be machined, such as by milling, to a final configuration or another shape after sintering.

In general, the fluoropolymer resins exhibit poor thermal conductivity, and therefore the pre-form of reactive material is heated to the sintering temperature at a rate sufficient to avoid cracking or the like. For instance with thick pre-forms there will be a temperature gradient within the pre-form during the warm-up, and raising the temperature too rapidly can result in cracks. It is therefore important to avoid excessive thermal gradient in the sintering oven (furnace) and in the pre-form. The warm-up can be staged so that an initial heat up rate is applied until a selected temperature is reached (typically below the melting point) and then the heat up rate is slowed down until the sinter temperature is reached. Other staging can, if desired, be used such as differing heat-up rates separated by a hold or dwell time at an intervening target temperature as the pre-form is heated up through the melting point to the sintering temperature. The sintering temperature is typically in a range of 350-385° C. and the dwell time is selected to avoid thermal degradation. The dwell time may depend on the thickness of the sintered part. Generally, dwell time may last up to about 6 hours or more, depending upon the thickness of the part. A lower sintering temperature in this range may be used for large objects such as billets or blocks.

After soaking at the sintering temperature, the molten object is cooled to ambient conditions. As the molten object cools through the melting point, the fluoropolymer chains may array themselves in more ordered alignment. The degree of alignment (crystallinity) is presently thought to be a function of the cooling rate. The cooling rate is sufficiently slow to avoid cracking due to thermal gradients. For a virgin fluoropolymer, a cooling rate in a range of 80° C./hour to 15° C./hour, more preferably 45° C./hour to 25° C./hour, may be considered. The cooling rate for the sintered reactive material is determined based on its thickness. Slow cooling is preferably conducted so that at least the mid-section of the sintered reactive material is below the melting point of the fluoropolymer, and the center has crystallized. This can initially be determined using a test sample provided with thermocouples to “bench mark” the cooling rate and temperatures to a rate sufficient to avoid cracking or the like for the object to be sintered.

For larger-sized sintered objects, an annealing stage can be included in the cooling period.

The exclusion of air (oxygen) can, if necessary, be extended to the sintering cycle. This may be desired with thicker pre-forms to be sintered, and is less important for thinner objects such as discs or wafers. This can be accomplished by conducting the sintering under an inert atmosphere (a Noble gas such as argon) and/or sealing the object within a bag to limit the product being exposed to air (oxygen) during the sintering. For example, an inert atmosphere sintering of aluminum/polytetrafluoro-ethylene pre-forms can be accomplished in a gas-tight high temperature oven using gases such as nitrogen, helium, neon and argon. The inert gas can be fed into the oven through an inert gas inlet valve. The inlet valve is pressure regulated to maintain a positive pressure inside the oven. The original air in the oven can be displaced by the inert gas using a positive pressure purge or a vacuum pump. A circulating air oven is preferred to produce uniform samples by minimizing temperature gradients inside the oven.

Various reactive material formulations are tabulated as follows:

Reactive Material Formulations
Ingredient	Mix 1 Baseline	Mix 2	Mix 3
PFTE 7C	74.0 wt %	74.0 wt %	69.5 wt %
Valimet, Aluminum H-5 (5 μm)	26.0 wt %	—	29.5 wt %
Valimet, Aluminum H-3 (3 μm)	—	26.0 wt %	—

The baseline material from Mix-1 was pressed under vacuum and sintered generally as in Example 1.The recovered sintered product had a tensile strength of 2200 psi and an elongation at break of 315%.

Mix-2 was prepared and treated under a non-oxidizing atmosphere during sintering. The sintering cycle was analogous to that in FIG. 1 . The bottom, middle and top of the sintered product (2″×2″ disk) were tested and the tensile strengths were in a range of 1990 psi to 2090 psi and the percent elongation at break was respectively 327%, 238% and 286%.

Mechanical Properties of Reactive Materials
Mix Number	Tensile Strength (psi)	Elongation
Mix 1	2200	315
2.0 inch diameter disc
0.10 inch thick
Mix 4	2320 bottom	328 bottom
2.0 inch diameter disc	1900 middle	276 middle
2.0 inch thick	2230 top	313 top
Mix 15	2920 bottom	333 bottom
2.0 inch diameter	2960 middle	307 middle
2.0 inch thick puck	1960 top	310 top
Mix 16	2000 end-1 oxidized	310 end-1 oxidized
3.5 inch diameter	2010 end-2 oxidized	298 end-2 oxidized
1.5 inch thick	3180 middle unoxidized	370 middle unoxidized
Mix 17	3370 bottom*	290 bottom*
3.5 inch diameter	3320 middle*	2785 middle*
1.5 inch thick P37	3420 top*	285 top*
*Samples had course machining marks; inert sintered atmosphere

The utility of spheres of sintered reactive material was confirmed in high velocity gun tests. The tests evaluated the mechanical strength of the spheres using high speed photography viewed as the sphere impacted and passed through a metal sheet. The degree of breakup was used to confirm the effectiveness of the article.

The present invention is now described further with reference to the following non-limiting examples.

EXAMPLE 1

A physical blend of powdered aluminum (Valimet, A1 H-5, 5 μ average particle size) and fluoropolymer (PTFE, DuPont Teflon™ 7C resin) was prepared. Powdered aluminum (78.0 gram) was mixed with PTFE (222.0 grams) in heptane for 5 minutes in a propeller mixer. The solids blend was dried at 135° F. (57.2° C.) on a conductive tray for approximately 24 to 72 hours.

An amount of dried solids blend (130 grams) was pressed into a 2 inch (approximately 5.0 cm) pellet in a pellet press under vacuum at a pressure of approximately 8,000 psi. The pressing cycle included pressing for about 1 minute under vacuum, releasing the pressure and allowing the pressed material to relax for about 30 seconds while still under vacuum, pressing again for about 1 minute under vacuum, releasing the pressure and allowing the pressed material to relax for about 30 seconds while still under vacuum, pressing for about another minute while under vacuum and releasing the pressure and recovering the pellet.

Two pellets were prepared using this procedure.

The die used in this pressing was heated to temperature of about 170° F. (76.6° C.) to about 190° F. (87.7° C.).

While still warm from the pressing, the two pressed pellets were then inserted into a sintering oven (tube furnace) and the oven temperature was ramped up to 700° F. (371.1° C.) at a rate of about 36.4° F./minute for five minutes and 71.0° F./minute for the next five minutes. The actual temperature peaked at about 724° F. (384° C.). The pressed pellets were held at 700° F. (371.1° C.) for about 1 hour, the temperature was ramped down to 600° F. for about 30 minutes, the pellets were held at 600° F. (371.1° C.) for about 60 minutes, and the pellets were thereafter cooled to ambient temperature at an average cooling rate of 3.1° F. (1.7° C.)/minute.

Before sintering the pellets were approximately 0.1 inch thick with a diameter of about 2 inches (5.0 cm).

EXAMPLE 2

A physical blend was prepared in a manner analogous to Example 1. The blend comprised powdered aluminum (Valimet, A1 H-5, 5μ; 24.5 wt. %), Fluorel™ 2174 (30.0 wt. %) and PTFE (DuPont Teflon™ 7C) (45.5 wt. %). The solids blend was made by initially combining acetone, the fluoropolymers (PTFE/Fluorenel™) and powdered aluminum, mixing in a propeller mixer for about 5 minutes, adding sufficient heptane to obtain a slurry, and drying the solids blend as in Example 1.

EXAMPLES 3-8

Blends are prepared in a manner analogous to Example 2. The compositions of these blends are as follows:

	Example**
Ingredient	3	4	5	6	7	8
PTFE 7-C					45.0	45.5
THV-220				76.0	30.0
Viton E60C	77.4					30.0
Fluorel 2174		77.4
Kel F 800			77.4
A1 H-5	22.6	22.6	22.6	24	25	24.5
**Amounts reported in weight percent

As in Example 2, a slurry is first prepared (acetone) and is washed with heptane or (hexanes).

Pellets are pressed from the blends. The pellets are about 2.0 inches in diameter and about 0.1 inches thick. The pellets are pressed and sintered as in Example 1 when using Teflon® or like fluoropolymer, whereas reactive materials using fluororubbers are molded/vulcanized at 250° C. for 18 hours.

EXAMPLE 9

A blend as in Example 1 was prepared but ethanol was used instead of heptane. The blend was prepared starting from 74 wt. % PTFE (1,110.0 grams) and 26.0 wt. % powdered aluminum (A1 H-5, 5 μm, 390 grams).

A series of pressed pellets are prepared. The pellets were each approximately 2.0 inches in diameter.

The thickness was 0.1 inches (3 pellets), 0.50 inch (thick (three pellets) 1.0 inch thick (three pellets), and 2.0 inches thick (three pellets). The pressing cycle was according to Example 1 with the pressure settings at 27,000 pounds load for an approximate applied actual pressure of about 8,000 psi to 13,800 psi.

The pellets are relaxed ambient pressure temperature prior to sintering. For pellets of 2 inches thickness a relaxation dwell time of about 2 to 3 hours is satisfactory. This relaxation or resting time between pressing and sintering permits the essentially complete, if not complete, removal of entrapped air and for stress relaxation in the pellets.

The pellets were thereafter sintered. The pellets were placed in a sintering oven and the temperature was increased at about 50° C./hour until a temperature of 380° C. was reached. The pellet samples were held at this temperature for about 6 hours. The temperature of the sintering oven is then reduced at a rate of 50° C./hour until a temperature of 310° C. is reached. The pellets are soaked at this temperature for about 4 hours. The temperature was then lowered at a rate of about 50° C./hour to ambient temperature.

The foregoing detailed description of the preferred embodiments of the invention has been provided for the purpose of explaining the principles of the invention and its practical application, thereby enabling others skilled in the art to understand the invention for various embodiments and with various modifications as are suited to the particular use contemplated. This description is not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Modifications and equivalents will be apparent to practitioners skilled in this art and are encompassed within the spirit and scope of the appended claims.

Claims

1. A method of making a sintered reactive material having a total weight, the method comprising:blending fuel particles and a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material, the fuel particles comprising at least one member selected from the group consisting of reactive nonoxidized metals and reactive nonoxidized metalloids; drying the reactive material; pressing the reactive material to obtain a shaped preform; and sintering the shaped preform in an inert atmosphere to form the sintered reactive material while avoiding oxidization of the fuel particles.

2. The method according to claim 1, further including selecting the fuel particles to comprise at least one member selected from the group consisting of aluminum, zirconium, titanium, and magnesium.

3. The method according to claim 1, further including providing the fuel particles at an average size less than about 500 microns.

4. The method according to claim 1, further including providing the fuel particles in an amount sufficient to account for up to approximately 35 weight percent of the total weight of the sintered reactive material.

5. The method according to claim 1, further including providing the fuel particles in an amount sufficient to account for approximately 15 weight percent to 35 weight percent of the total weight of the sintered reactive material.

6. The method according to claim 1, further including providing the fuel particles in an amount sufficient to account for approximately 25 weight percent to 30 weight percent of the total weight of the sintered reactive material.

7. The method according to claim 1, further including providing the fuel particles at an average size of not greater than about 250 microns.

8. The method according to claim 1, further including providing the fuel particles at an average size in a range of approximately 1 micron to 10 microns.

9. The method according to claim 1, further including selecting the fuel particles to comprise aluminum.

10. The method according to claim 1, wherein said pressing is conducted at approximately from 3000 psi to 10000 psi.

11. The method according to claim 1, wherein said sintering comprises heating the shaped preform to 350° C. to 385° C.

12. The method according to claim 1, wherein the sintered reactive material has a tensile strength greater than about 1800 psi and a strain greater than about 30% elongation at break.

13. A method of making a sintered reactive material having a total weight, the method comprising:blending fuel particles and a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material; drying the reactive material; pressing the reactive material to obtain a shaped preform; and sintering the shaped preform in an inert atmosphere to form the sintered reactive material, the sintered reactive material having a tensile strength greater than about 1800 psi and a strain greater than about 30% elongation at break, wherein the fuel particles in the sintered reactive material have an average size less than 500 microns and comprise at least one reactive nonoxidized metal selected from the group consisting of aluminum, zirconium, titanium, and magnesium, and wherein the fuel particles account for approximately 15 weight percent to 35 weight percent of the total weight of the sintered reactive material.

14. The method according to claim 13, wherein the fuel particles comprise aluminum.

15. A reactive material having a total weight and comprising:a polymeric matrix comprising at least one sintered fluoropolymer; and energetic fuel particles dispersed in the polymeric matrix, the energetic fuel particles having an average size less than about 500 microns and comprising at least one nonoxidized metal selected from the group consisting of aluminum, zirconium, titanium, and magnesium.

16. the reactive material according to claim 15, wherein the energetic fuel particles account for approximately 15 weight percent to 35 weight percent of the total weight of the reactive material.

17. The reactive material according to claim 15, wherein the average size of the energetic fuel particles is not greater than about 250 microns.

18. The reactive material according to claim 15, wherein the average size of the energetic fuel particles is in a range of approximately 1 micron to 10 microns.

19. The reactive material according to claim 15, wherein the energetic fuel particles comprise aluminum.

20. The reactive material according to claim 15, wherein the reactive material has a tensile strength greater than about 1800 psi and a strain greater than about 30% elongation at break.

21. The method according to claim 1, wherein said blending, drying and pressing are conducted in an environment that at least essentially excludes oxygen.

22. The method according to claim 2, wherein said blending, drying and pressing are conducted in an environment that at least essentially excludes oxygen.

23. The method according to claim 13, wherein said blending, drying, and pressing are conducted in an environment that at least essentially excludes oxygen.