Patent Application
20250197979
The present invention relates to a high strength steel sheet excellent in tensile strength, El, toughness, flatness in the width direction, and working embrittlement resistance, and to a method for manufacturing the same. The high strength steel sheet according to aspects of the present invention may be suitably used as structural members, such as automobile parts.
Steel sheets for automobiles are being increased in strength in order to reduce CO2 emissions by weight reduction of vehicles and to enhance crashworthiness by weight reduction of automobile bodies at the same time, with introduction of new laws and regulations one after another. To increase the strength of automobile bodies, high strength steel sheets having a tensile strength (TS) of 980 MPa or higher grade are increasingly applied to principal structural parts of automobiles.
High strength steel sheets used in automobiles require excellent press formability. For example, high strength steel sheets with high El are suitably applied to automobile frame parts, such as bumpers. From the point of view of crash safety, excellent toughness and working embrittlement resistance are required.
Furthermore, high strength steel sheets used in automobiles require high flatness. Patent Literature 1 describes that warpage of a steel sheet causes operational troubles in forming lines and adversely affects the dimensional accuracy of products. The present inventors carried out extensive studies and have found that the dimensional accuracy of products is affected not only by the warpage of steel sheets but also by the flatness in the width direction that is evaluated as steepness. For example, the steepness in the width direction is suitably 0.02 or less in order to achieve excellent dimensional accuracy.
To meet the above demands, for example, Patent Literature 2 provides a high strength steel sheet having a tensile strength of 1100 MPa or more and being excellent in YR, surface quality, and weldability, and a method for manufacturing the same. However, the technique described in Patent Literature 2 does not take into consideration El, toughness, flatness in the width direction, and working embrittlement resistance.
Patent Literature 3 provides a hot-dip galvanized steel sheet with excellent press formability and low-temperature toughness that has a tensile strength of 980 MPa or more, and a method for manufacturing the same. While the steel sheet of Patent Literature 3 is improved in embrittlement at low temperatures, the technique does not take into consideration the working embrittlement of the steel sheet or the flatness in the width direction.
Aspects of the present invention have been developed in view of the circumstances discussed above. Objects of aspects of the present invention are therefore to provide a high strength steel sheet having 980 MPa or higher TS and 10% or more El and being excellent in toughness, flatness in the width direction, and working embrittlement resistance; and to provide a method for manufacturing the same.
The present inventors carried out extensive studies directed to solving the problems described above and have consequently found the following facts.
Aspects of the present invention have been made based on the above findings. Specifically, a summary of aspects of the present invention is as follows.
wherein [% C], [% Mn], [% Cr], [% Mo], and [% Ni] indicate the contents (mass %) of C, Mn, Cr, Mo, and Ni, respectively, and are zero when the element is absent.
According to aspects of the present invention, a high strength steel sheet can be obtained that has 980 MPa or higher TS and 10% or more El and excels in toughness, flatness in the width direction, and working embrittlement resistance. Furthermore, for example, the high strength steel sheet according to aspects of the present invention may be applied to automobile structural members to reduce the weight of automobile bodies and thereby to enhance fuel efficiency. Thus, aspects of the present invention are highly valuable in industry.
Embodiments of the present invention will be described below.
First, appropriate ranges of the chemical composition of the high strength steel sheet and the reasons why the chemical composition is thus limited will be described. In the following description, “%” indicating the contents of constituent elements of steel means “mass %” unless otherwise specified.
Carbon is one of the important basic components of steel. Particularly in accordance with aspects of the present invention, carbon is an important element that affects the amount of martensite. When the C content is less than 0.030%, the amount of martensite is so small that realizing 980 MPa or higher TS is difficult. When, on the other hand, the C content is more than 0.500%, martensite becomes brittle to cause deterioration in toughness and working embrittlement resistance. Thus, the C content is limited to 0.030% or more and 0.500% or less. The lower limit of the C content is preferably 0.050% or more. The upper limit of the C content is preferably 0.400% or less. The lower limit of the C content is more preferably 0.100% or more. The upper limit of the C content is more preferably 0.350% or less.
Silicon is one of the important basic components of steel and is an important element that affects TS and the amount of retained austenite. When the Si content is less than 0.50%, the strength of martensite decreases to make it difficult to achieve 980 MPa or higher TS. When, on the other hand, the Si content is more than 2.50%, the amount of retained austenite is increased excessively, and toughness and working embrittlement resistance are lowered. Thus, the Si content is limited to 0.50% or more and 2.50% or less. The lower limit of the Si content is preferably 0.55% or more. The upper limit of the Si content is preferably 2.00% or less. The lower limit of the Si content is more preferably 0.60% or more. The upper limit of the Si content is more preferably 1.80% or less.
Manganese is one of the important basic components of steel and is an important element that affects the amount of martensite. When the Mn content is less than 1.00%, the amount of martensite is so small that realizing 980 MPa or higher TS is difficult. When, on the other hand, the Mn content is more than 5.00%, martensite becomes brittle to cause deterioration in toughness and working embrittlement resistance. Thus, the Mn content is limited to 1.00% or more and 5.00% or less. The lower limit of the Mn content is preferably 1.50% or more. The upper limit of the Mn content is preferably 4.50% or less. The lower limit of the Mn content is more preferably 2.00% or more. The upper limit of the Mn content is more preferably 4.00% or less.
Phosphorus is segregated at prior austenite grain boundaries and makes the grain boundaries brittle, thereby lowering the ultimate deformability of steel sheets and causing deterioration in toughness and working embrittlement resistance. Thus, the P content needs to be 0.100% or less. The lower limit of the P content is not particularly specified. In view of the fact that phosphorus is a solid solution strengthening element and can increase the strength of steel sheets, the lower limit is preferably 0.001% or more. For the reasons above, the P content is limited to 0.100% or less. The lower limit of the P content is preferably 0.001% or more. The upper limit of the P content is preferably 0.070% or less.
Sulfur forms sulfides and lowers the ultimate deformability of steel sheets to cause deterioration in toughness and working embrittlement resistance. Thus, the S content needs to be 0.0200% or less. The lower limit of the S content is not particularly specified but is preferably 0.0001% or more due to production technique limitations. For the reasons above, the S content is limited to 0.0200% or less. The lower limit of the S content is preferably 0.0001% or more. The upper limit of the S content is preferably 0.0050% or less.
Aluminum forms the oxide and lowers the ultimate deformability of steel sheets to cause deterioration in toughness and working embrittlement resistance. Thus, the Al content needs to be 1.000% or less. The lower limit of the Al content is not particularly specified. In view of the fact that aluminum suppresses the occurrence of carbides during continuous annealing and promotes the formation of retained austenite, the Al content is preferably 0.001% or more. For the reasons above, the Al content is limited to 1.000% or less. The lower limit of the Al content is preferably 0.001% or more. The upper limit of the Al content is preferably 0.500% or less.
Nitrogen forms nitrides and lowers the ultimate deformability of steel sheets to cause deterioration in toughness and working embrittlement resistance. Thus, the N content needs to be 0.0100% or less. The lower limit of the N content is not particularly specified but the N content is preferably 0.0001% or more due to production technique limitations. For the reasons above, the N content is limited to 0.0100% or less. The lower limit of the N content is preferably 0.0001% or more. The upper limit of the N content is preferably 0.0050% or less.
Oxygen forms oxides and lowers the ultimate deformability of steel sheets to cause deterioration in toughness and working embrittlement resistance. Thus, the O content needs to be 0.0100% or less. The lower limit of the O content is not particularly specified but the O content is preferably 0.0001% or more due to production technique limitations. For the reasons above, the O content is limited to 0.0100% or less. The lower limit of the O content is preferably 0.0001% or more. The upper limit of the O content is preferably 0.0050% or less.
The chemical composition of the high strength steel sheet according to an embodiment of the present invention includes the components described above, and the balance is Fe and incidental impurities. Here, the incidental impurities include Zn, Pb, As, Ge, Sr, and Cs. A total of 0.100% or less of these impurities is acceptable.
In addition to the components in the proportions described above, the high strength steel sheet according to aspects of the present invention may further include at least one element selected from, in mass %, Ti: 0.200% or less, Nb: 0.200% or less, V: 0.200% or less, Ta: 0.10% or less, W: 0.10% or less, B: 0.0100% or less, Cr: 1.00% or less, Mo: 1.00% or less, Ni: 1.00% or less, Co: 0.010% or less, Cu: 1.00% or less, Sn: 0.200% or less, Sb: 0.200% or less, Ca: 0.0100% or less, Mg: 0.0100% or less, REM: 0.0100% or less, Zr: 0.100% or less, Te: 0.100% or less, Hf: 0.10% or less, and Bi: 0.200% or less. These elements may be contained singly or in combination.
When the contents of Ti, Nb, and V are each 0.200% or less, coarse precipitates and inclusions will not occur in large amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the contents of Ti, Nb, and V are each preferably 0.200% or less. The lower limits of the contents of Ti, Nb, and V are not particularly specified. These elements form fine carbides, nitrides, or carbonitrides during hot rolling or continuous annealing to increase the strength of steel sheets. In view of this fact, the contents of Ti, Nb, and V are each more preferably 0.001% or more. When titanium, niobium, and vanadium are added, the contents thereof are each limited to 0.200% or less for the reasons above. The lower limits of the contents of Ti, Nb, and V, when added, are each more preferably 0.001% or more. The upper limits of the contents of Ti, Nb, and V, when added, are each more preferably 0.100% or less.
When the contents of Ta and W are each 0.10% or less, coarse precipitates and inclusions will not occur in large amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the contents of Ta and W are each preferably 0.10% or less. The lower limits of the contents of Ta and W are not particularly specified. These elements form fine carbides, nitrides, or carbonitrides during hot rolling or continuous annealing to increase the strength of steel sheets. In view of this fact, the contents of Ta and W are each more preferably 0.01% or more. When tantalum and tungsten are added, the contents thereof are each limited to 0.10% or less for the reasons above. The lower limits of the contents of Ta and W, when added, are each more preferably 0.01% or more. The upper limits of the contents of Ta and W, when added, are each more preferably 0.08% or less.
When the B content is 0.0100% or less, inner cracks that lower the ultimate deformability of steel sheets will not form during casting or hot rolling and thus there will be no deterioration in toughness or working embrittlement resistance. Thus, the B content is preferably 0.0100% or less. The lower limit of the B content is not particularly specified. The B content is more preferably 0.0003% or more in view of the fact that this element is segregated at austenite grain boundaries during annealing and enhances hardenability. When boron is added, the content thereof is limited to 0.0100% or less for the reasons above. The lower limit of the content of B, when added, is more preferably 0.0003% or more. The upper limit of the content of B, when added, is more preferably 0.0080% or less.
When the contents of Cr, Mo, and Ni are each 1.00% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the contents of Cr, Mo, and Ni are each preferably 1.00% or less. The lower limits of the contents of Cr, Mo, and Ni are not particularly specified. In view of the fact that these elements enhance hardenability, the contents of Cr, Mo, and Ni are each more preferably 0.01% or more. When chromium, molybdenum, and nickel are added, the contents thereof are each limited to 1.00% or less for the reasons above. The lower limits of the contents of Cr, Mo, and Ni, when added, are each more preferably 0.01% or more. The upper limits of the contents of Cr, Mo, and Ni, when added, are each more preferably 0.80% or less.
When the Co content is 0.010% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the Co content is preferably 0.010% or less. The lower limit of the Co content is not particularly specified. In view of the fact that this element enhances hardenability, the Co content is more preferably 0.001% or more. When cobalt is added, the content thereof is limited to 0.010% or less for the reasons above. The lower limit of the content of Co, when added, is more preferably 0.001% or more. The upper limit of the content of Co, when added, is more preferably 0.008% or less.
When the Cu content is 1.00% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the Cu content is preferably 1.00% or less. The lower limit of the Cu content is not particularly specified. In view of the fact that this element enhances hardenability, the Cu content is preferably 0.01% or more. When copper is added, the content thereof is limited to 1.00% or less for the reasons above. The lower limit of the content of Cu, when added, is more preferably 0.01% or more. The upper limit of the content of Cu, when added, is more preferably 0.80% or less.
When the Sn content is 0.200% or less, inner cracks that lower the ultimate deformability of steel sheets will not form during casting or hot rolling and thus there will be no deterioration in toughness or working embrittlement resistance. Thus, the Sn content is preferably 0.200% or less. The lower limit of the Sn content is not particularly specified. The Sn content is more preferably 0.001% or more in view of the fact that tin enhances hardenability (in general, is an element that enhances corrosion resistance). When tin is added, the content thereof is limited to 0.200% or less for the reasons above. The lower limit of the content of Sn, when added, is more preferably 0.001% or more. The upper limit of the content of Sn, when added, is more preferably 0.100% or less.
When the Sb content is 0.200% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the Sb content is preferably 0.200% or less. The lower limit of the Sb content is not particularly specified. In view of the fact that this element enables control of the thickness of surface layer softening and the strength, the Sb content is more preferably 0.001% or more. When antimony is added, the content thereof is limited to 0.200% or less for the reasons above. The lower limit of the content of Sb, when added, is more preferably 0.001% or more. The upper limit of the content of Sb, when added, is more preferably 0.100% or less.
When the contents of Ca, Mg, and REM are each 0.0100% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the contents of Ca, Mg, and REM are each preferably 0.0100% or less. The lower limits of the contents of Ca, Mg, and REM are not particularly specified. In view of the fact that these elements change the shapes of nitrides and sulfides into spheroidal and enhance the ultimate deformability of steel sheets, the contents of Ca, Mg, and REM are each more preferably 0.0005% or more. When calcium, magnesium, and rare earth metal(s) are added, the contents thereof are each limited to 0.0100% or less for the reasons above. The lower limits of the contents of Ca, Mg, and REM, when added, are each more preferably 0.0005% or more. The upper limits of the contents of Ca, Mg, and REM, when added, are each more preferably 0.0050% or less.
When the contents of Zr and Te are each 0.100% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the contents of Zr and Te are each preferably 0.100% or less. The lower limits of the contents of Zr and Te are not particularly specified. In view of the fact that these elements change the shapes of nitrides and sulfides into spheroidal and enhance the ultimate deformability of steel sheets, the contents of Zr and Te are each more preferably 0.001% or more. When zirconium and tellurium are added, the contents thereof are each limited to 0.100% or less for the reasons above. The lower limits of the contents of Zr and Te, when added, are each more preferably 0.001% or more. The upper limits of the contents of Zr and Te, when added, are each more preferably 0.080% or less.
When the Hf content is 0.10% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the Hf content is preferably 0.10% or less. The lower limit of the Hf content is not particularly specified. In view of the fact that this element changes the shapes of nitrides and sulfides into spheroidal and enhances the ultimate deformability of steel sheets, the Hf content is more preferably 0.01% or more. When hafnium is added, the content thereof is limited to 0.10% or less for the reasons above. The lower limit of the content of Hf, when added, is more preferably 0.01% or more. The upper limit of the content of Hf, when added, is more preferably 0.08% or less.
When the Bi content is 0.200% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in toughness or working embrittlement resistance. Thus, the Bi content is preferably 0.200% or less. The lower limit of the Bi content is not particularly specified. In view of the fact that this element reduces the occurrence of segregation, the Bi content is more preferably 0.001% or more. When bismuth is added, the content thereof is limited to 0.200% or less for the reasons above. The lower limit of the content of Bi, when added, is more preferably 0.001% or more. The upper limit of the content of Bi, when added, is more preferably 0.100% or less.
When the content of any of Ti, Nb, V, Ta, W, B, Cr, Mo, Ni, Co, Cu, Sn, Sb, Ca, Mg, REM, Zr, Te, Hf, and Bi is below the preferred lower limit, the element does not impair the advantageous effects according to aspects of the present invention and is regarded as an incidental impurity.
Next, the steel microstructure of the high strength steel sheet according to aspects of the present invention will be described.
This configuration is a very important requirement that constitutes an aspect of the present invention. 980 MPa or higher TS can be achieved when the area fraction of martensite is 60% or more. Thus, the area fraction of martensite is limited to 60% or more. The area fraction is preferably 62% or more, and more preferably 64% or more.
This configuration is a very important requirement that constitutes an aspect of the present invention. When the volume fraction of retained austenite is less than 3%, it is difficult to realize 10% or more El and it is also difficult to attain excellent toughness because the toughness enhancement effect by retained austenite cannot be obtained. When the amount of retained austenite is more than 15%, retained austenite is excessively transformed into hard martensite at the time of working and the steel sheet is lowered in ultimate deformability and will not attain excellent working embrittlement resistance. Thus, the retained austenite is limited to 3% or more and 15% or less. The lower limit of the amount of retained austenite is preferably 5% or more. The upper limit of the amount of retained austenite is preferably 14% or less. The lower limit of the amount of retained austenite is more preferably 7% or more. The upper limit of the amount of retained austenite is more preferably 13% or less.
Here, retained austenite is measured as follows. The steel sheet is polished to expose a face 0.1 mm below ¼ sheet thickness and is thereafter further chemically polished to expose a face 0.1 mm below the face exposed above. The face is analyzed with an X-ray diffractometer using CoKα radiation to determine the integral intensity ratios of the diffraction peaks of {200}, {220}, and {311} planes of fcc iron and {200}, {211}, and {220} planes of bcc iron. Nine integral intensity ratios thus obtained are averaged to determine retained austenite.
[Area Fraction of the Total of Ferrite and Bainitic Ferrite: More than 10%]
This configuration is a very important requirement that constitutes an aspect of the present invention. When the total amount of ferrite and bainitic ferrite is 10% or less, it is difficult to achieve 10% or more El. Thus, the total amount of ferrite and bainitic ferrite is limited to more than 10%. The total amount is preferably 12% or more, and more preferably 13% or more. The upper limit of the total amount of ferrite and bainitic ferrite is not particularly limited.
Here, the total amount of ferrite and bainitic ferrite is measured as follows. A longitudinal cross section of the steel sheet is polished and is etched with 3 vol % Nital. A portion at ¼ sheet thickness (a location corresponding to ¼ of the sheet thickness in the depth direction from the steel sheet surface) is observed using SEM in 10 fields of view at a magnification of ×2000. In the microstructure images, ferrite and bainitic ferrite are recessed structures having a flat interior and containing no inner carbides. The values thus obtained are averaged to determine the total amount of ferrite and bainitic ferrite.
The amount of martensite is measured as follows. The amount of martensite can be determined by measuring the amounts of retained austenite, ferrite, and bainitic ferrite based on the methods described above, and subtracting the total thereof from 100%. Thus, the amount of martensite in accordance with aspects of the present invention includes both quenched martensite and tempered martensite. Because the volume fraction of retained austenite is almost equal to the area fraction, the amount is subtracted as such from 100% together with the amounts of ferrite and bainitic ferrite expressed in area fraction.
This configuration is a very important requirement that constitutes an aspect of the present invention. The proportion of a packet having the largest area in a prior austenite grain affects the flatness in the width direction and the working embrittlement resistance. As illustrated in
The proportion of one packet in a prior austenite grain is determined by dividing the area of the packet of interest by the area of the whole prior austenite grain.
As a result of extensive studies, the present inventors have found that strain among the packets is reduced and the flatness in the width direction is improved by lowering the proportion of a packet having the largest area in a prior austenite grain. The present inventors have also found that lowering the proportion of a packet having the largest area in a prior austenite grain leads to a fine microstructure and suppresses crack propagation, thereby enhancing the working embrittlement resistance of the steel sheet. Thus, the average of the proportions of packets having the largest area in prior austenite grains is limited to 70% or less. The average proportion is preferably 60% or less. The lower limit of the average proportion of packets having the largest area in prior austenite grains is not particularly limited. The grains contain up to four kinds of packets. When four packets are evenly distributed, the proportion of a packet having the largest area in the prior austenite grain is 25%. Thus, the lower limit of the average proportion of packets having the largest area in prior austenite grains is preferably 25% or more. However, the lower limit of the average proportion is not necessarily limited thereto.
Here, the average proportion of packets having the largest area in prior austenite grains is measured as follows. First, a test specimen for microstructure observation is sampled from the cold rolled steel sheet. Next, the sampled test specimen is polished by vibration polishing with colloidal silica to expose a cross section in the rolling direction (a longitudinal cross section) for use as observation surface. The observation surface is specular. Next, electron backscatter diffraction (EBSD) measurement is performed with respect to a portion at ¼ sheet thickness (a location corresponding to ¼ of the sheet thickness in the depth direction from the steel sheet surface) to obtain local crystal orientation data. Here, the SEM magnification is ×1000, the step size is 0.2 μm, the measured region is 80 μm square, and the WD is 15 mm. The local orientation data obtained is analyzed with OIM Analysis 7 (OIM), and a map (a CP map) that shows close-packed plane groups (CP groups) with different colors is created using the method described in Non Patent Literature 1. In accordance with aspects of the present invention, a packet is defined as a region or regions belonging to the same CP group. From the CP map obtained, the area of the packet having the largest area is determined and is divided by the area of the whole prior austenite grain to give the proportion of the packet having the largest area in the prior austenite grain. This analysis is performed with respect to 10 or more adjacent prior austenite grains, and the results are averaged to give the average proportion of packets having the largest area in prior austenite grains.
Next, a manufacturing method according to aspects of the present invention will be described.
In accordance with aspects of the present invention, a steel material (a steel slab) may be obtained by any known steelmaking method without limitation, such as a converter or an electric arc furnace. To prevent macro-segregation, the steel slab (the slab) is preferably produced by a continuous casting method.
In accordance with aspects of the present invention, the slab heating temperature, the slab soaking holding time, and the coiling temperature in hot rolling are not particularly limited. For example, the steel slab may be hot rolled in such a manner that the slab is heated and is then rolled, that the slab is subjected to hot direct rolling after continuous casting without being heated, or that the slab is subjected to a short heat treatment after continuous casting and is then rolled. The slab heating temperature, the slab soaking holding time, the finish rolling temperature, and the coiling temperature in hot rolling are not particularly limited. The lower limit of the slab heating temperature is preferably 1100° C. or above. The upper limit of the slab heating temperature is preferably 1300° C. or below. The lower limit of the slab soaking holding time is preferably 30 minutes or more. The upper limit of the slab soaking holding time is preferably 250 minutes or less. The lower limit of the finish rolling temperature is preferably Ar3 transformation temperature or above. Furthermore, the lower limit of the coiling temperature is preferably 350° C. or above. The upper limit of the coiling temperature is preferably 650° C. or below.
The hot rolled steel sheet thus produced is pickled. Pickling can remove oxides on the steel sheet surface and is thus important to ensure good chemical convertibility and a high quality of coating in the final high strength steel sheet. Pickling may be performed at a time or several. The hot rolled sheet that has been pickled may be cold rolled directly or may be subjected to heat treatment before cold rolling.
The rolling reduction in cold rolling and the sheet thickness after rolling are not particularly limited. The lower limit of the rolling reduction is preferably 30% or more. The upper limit of the rolling reduction is preferably 80% or less. The advantageous effects according to aspects of the present invention may be obtained without any limitations on the number of rolling passes and the rolling reduction in each pass.
The cold rolled steel sheet obtained as described above is annealed. Annealing conditions are as follows.
When the annealing temperature Ta is below 700° C., the amount of martensite is so small that realizing 980 MPa or higher TS is difficult. When, on the other hand, the annealing temperature is above 900° C., the total amount of ferrite and bainitic ferrite decreases to make it difficult to achieve 10% or more El. Thus, the annealing temperature is limited to 700° C. or above and 900° C. or below. The lower limit of the annealing temperature is preferably 750° C. or above. The upper limit of the annealing temperature is preferably 870° C. or below.
When the holding time at the annealing temperature Ta is less than 10 seconds, the amount of martensite is so small that realizing 980 MPa or higher TS is difficult. When, on the other hand, the holding time at the annealing temperature Ta is more than 1000 seconds, the total amount of ferrite and bainitic ferrite decreases to make it difficult to achieve 10% or more El. Thus, the holding time at the annealing temperature Ta is limited to 10 seconds or more and 1000 seconds or less. The lower limit of the holding time at the annealing temperature Ta is preferably 50 seconds or more. The upper limit of the holding time at the annealing temperature Ta is preferably 500 seconds or less.
[During the Annealing, the Steel Sheet is Bent and Unbent 1 to 15 Times in Total with a Roll Having a Radius of 800 mm or Less.]
As a result of extensive studies, the present inventors have found that bending and unbending of the steel sheet during annealing affects the proportion of a packet having the largest area in a prior austenite grain. When the steel sheet being annealed is not subjected to bending and unbending with a roll having a radius of 800 mm or less, the amount of nucleation sites for martensite transformation is reduced. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. When, on the other hand, the steel sheet being annealed is subjected to bending and unbending 16 times or more with a roll having a radius of 800 mm or less, the steel sheet is deteriorated in ultimate deformability and also in working embrittlement resistance. Thus, in the annealing, the total count of bending and unbending with a roll having a radius of 800 mm or less is limited to 1 or more and 15 or less. The radius of the roll is preferably 600 mm or less. The lower limit of the total count of bending and unbending is preferably 3 or more. The upper limit of the total count of bending and unbending is preferably 10 or less. The lower limit of the radius of the roll is not necessarily limited but is preferably 50 mm or more.
Incidentally, “bending and unbending” is a treatment that bends the steel sheet with a roll in one direction according to a known technique and unbends the steel sheet in the opposite direction to cancel the bend. Bending and unbending are not counted in pairs. That is, each bending is counted one and each unbending is counted one.
[Average Cooling Rate in the Temperature Range from 700° C. to 600° C.: 20° C./s or More]
As a result of extensive studies, the present inventors have found that the average cooling rate in the temperature range from 700° C. to 600° C. affects the proportion of a packet having the largest area in a prior austenite grain. When the average cooling rate in the temperature range from 700° C. to 600° C. is less than 20° C./s, the effects imparted by bending and unbending of the steel sheet during annealing are lowered and the amount of nucleation sites for martensite transformation is reduced. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. Thus, the average cooling rate from 700° C. to 600° C. is limited to 20° C./s or more and is preferably 30° C./s or more. The upper limit is not necessarily limited but is preferably 100° C./s or less.
[Average Cooling Rate in the Temperature Range from 499° C. to Ms: Less than 20° C./s]
The average cooling rate in the temperature range from 499° C. to Ms affects the total area fraction of ferrite and bainitic ferrite. When the average cooling rate in the temperature range from 499° C. to Ms is 20° C./s or more, the total amount of ferrite and bainitic ferrite decreases to make it difficult to achieve 10% or more El. Thus, the average cooling rate in the temperature range from 499° C. to Ms is limited to less than 20° C./s. The average cooling rate is preferably 18° C./s or less. The lower limit is not necessarily limited but is preferably 5° C./s or more.
The martensite start temperature Ms (° C.) is defined by the following formula (1):
wherein [% C], [% Mn], [% Cr], [% Mo], and [% Ni] indicate the contents (mass %) of C, Mn, Cr, Mo, and Ni, respectively, and are zero when the element is absent.
[The Steel Sheet in the Temperature Range from 499° C. to Ms is Bent and Unbent 1 to 15 Times in Total with a Roll Having a Radius of 800 mm or Less.]
As a result of extensive studies, the present inventors have found that bending and unbending of the steel sheet in the temperature range from 499° C. to Ms affects the proportion of a packet having the largest area in a prior austenite grain. When the steel sheet in the temperature range from 499° C. to Ms is not subjected to bending and unbending with a roll having a radius of 800 mm or less, the amount of martensite nucleation sites is reduced. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. When, on the other hand, the steel sheet in the temperature range from 499° C. to Ms is subjected to bending and unbending 16 times or more with a roll having a radius of 800 mm or less, the steel sheet is deteriorated in ultimate deformability and also in working embrittlement resistance. Thus, the total count of bending and unbending in the temperature range from 499° C. to Ms with a roll having a radius of 800 mm or less is limited to 1 or more and 15 or less. The radius of the roll is preferably 600 mm or less. The lower limit of the total count of bending and unbending is preferably 3 or more. The upper limit of the total count of bending and unbending is preferably 10 or less. The lower limit of the radius of the roll is not necessarily limited but is preferably 50 mm or more.
[Average Cooling Rate in the Temperature Range from Ms to Cooling Stop Temperature Tb: 150° C./s or Less]
As a result of extensive studies, the present inventors have found that the average cooling rate in the temperature range from Ms to the cooling stop temperature Tb affects the proportion of a packet having the largest area in a prior austenite grain. When the average cooling rate in the temperature range from Ms to the cooling stop temperature Tb is more than 150° C./s, the martensite transformation rate is so fast that a packet grows fast easily. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. Thus, the average cooling rate in the temperature range from Ms to the cooling stop temperature Tb is limited to 150° C./s or less. The average cooling rate is preferably 120° C./s or less. The lower limit is not necessarily limited but is preferably 5° C./s or more.
[Tension Applied to the Steel Sheet in the Temperature Range from Ms to the Cooling Stop Temperature Tb: 5 MPa or More and 100 MPa or Less]
As a result of extensive studies, the present inventors have found that the application of tension to the steel sheet in the temperature range from Ms to the cooling stop temperature Tb affects the proportion of a packet having the largest area in a prior austenite grain. When the tension applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Tb is less than 5 MPa, the amount of martensite nucleation sites is reduced. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. When, on the other hand, more than 100 MPa tension is applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Tb, the total amount of ferrite and bainitic ferrite is excessively increased and thus the amount of martensite decreases to make it difficult to realize 980 MPa or higher TS. Thus, the tension applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Tb is limited to 5 MPa or more and 100 MPa or less. The lower limit of the tension applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Tb is preferably 6 MPa or more. The upper limit of the tension applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Tb is preferably 50 MPa or less. The tension is applied in a usual manner. As an example, the tension may be applied by controlling the roll speeds of the rolls in the furnace.
While the bending and unbending process increases the number of nucleation sites that are martensite start sites, the tension application process produces different effects by promoting martensite transformation itself.
When the cooling stop temperature Tb is below 100° C., the amount of retained austenite decreases and bendability is lowered. When, on the other hand, the cooling stop temperature Tb is above (Ms−80° C.), the amount of retained austenite is excessively increased and the prior austenite grain size is excessively enlarged to cause deterioration in working embrittlement resistance. Thus, the cooling stop temperature Tb is limited to 100° C. or above and (Ms−80° C.) or below. The lower limit of the cooling stop temperature Tb is preferably 120° C. or above. The upper limit of the cooling stop temperature Tb is preferably (Ms−100° C.) or below.
After the cooling is stopped at the cooling stop temperature Tb, the steel sheet is held at the temperature or is reheated and held at a temperature of 450° C. or below to stabilize retained austenite. When the tempering temperature is below Tb, retained austenite cannot be obtained as desired; consequently El is lowered and excellent toughness is hardly obtained. When the tempering temperature is above 450° C., martensite is excessively tempered to make it difficult to achieve 980 MPa or higher TS. Thus, the tempering temperature is limited to Tb or above and 450° C. or below. The lower limit of the tempering temperature is preferably (Tb+10° C.) or above. The upper limit of the tempering temperature is preferably 420° C. or below.
When the holding time at the tempering temperature is less than 10 seconds, austenite stabilization is insufficient and retained austenite cannot be obtained as desired; consequently El is lowered and excellent toughness is hardly obtained. When the holding time at the tempering temperature is more than 1000 seconds, martensite is excessively tempered to make it difficult to achieve 980 MPa or higher TS. Thus, the holding time at the tempering temperature is limited to 10 seconds or more and 1000 seconds or less. The lower limit of the holding time at the tempering temperature is preferably 50 seconds or more. The upper limit of the holding time at the tempering temperature is preferably 800 seconds or less.
Post-temper cooling is not particularly limited and the steel sheet may be cooled to a desired temperature in an appropriate manner. Incidentally, the desired temperature is preferably about room temperature.
Furthermore, the high strength steel sheet described above may be worked under conditions where the amount of equivalent plastic strain is 0.10% or more and 5.00% or less. The working may be followed by reheating at 100° C. or above and 400° C. or below.
When the high strength steel sheet is a product that is traded, the steel sheet is usually traded after being cooled to room temperature.
The high strength steel sheet may be subjected to coating treatment during annealing or after annealing.
For example, the coating treatment during annealing may be hot-dip galvanizing treatment performed when the annealed steel sheet is being cooled or has been cooled from 700° C. to 600° C. at an average cooling rate of 20° C./s or more. The hot-dip galvanizing treatment may be followed by alloying. For example, the coating treatment after annealing may be Zn—Ni electrical alloy coating treatment or pure Zn electroplated coating treatment performed after tempering. A coated layer may be formed by electroplated coating, or hot-dip zinc-aluminum-magnesium alloy coating may be applied. While the coating treatment has been described above focusing on zinc coating, the types of coating metals, such as Zn coating and Al coating, are not particularly limited. Other conditions in the manufacturing method are not particularly limited. From the point of view of productivity, the series of treatments including annealing, hot-dip galvanizing, and alloying treatment of the coated zinc layer is preferably performed on hot-dip galvanizing line CGL (continuous galvanizing line). To control the coating weight of the coated layer, the hot-dip galvanizing treatment may be followed by wiping. Conditions for operations, such as coating, other than those conditions described above may be determined in accordance with the usual hot-dip galvanizing technique.
After the coating treatment after annealing, the steel sheet may be worked again under conditions where the amount of equivalent plastic strain is 0.10% or more and 5.00% or less. The working may be followed by reheating at 100° C. or above and 400° C. or below.
Steels having a chemical composition described in Table 1 and 2, with the balance being Fe and incidental impurities, were smelted in a converter and were continuously cast into slabs. Next, the slabs obtained were heated, hot rolled, pickled, cold rolled, and subjected to annealing treatment described in Table 3 and 4. High strength cold rolled steel sheets having a sheet thickness of 0.6 to 2.2 mm were thus obtained. During annealing, the steel sheet was subjected to bending and unbending with a roll having a radius of 300 mm. In the temperature range from 499° C. to Ms, the steel sheet was subjected to bending and unbending with a roll having a radius of 300 mm. Incidentally, some of the steel sheets were subjected to coating treatment during or after annealing.
The high strength cold rolled steel sheets obtained as described above were used as test steels. Tensile characteristics, flatness in the width direction, toughness, and working embrittlement resistance were evaluated in accordance with the following test methods.
0.028
0.505
0.42
2.54
0.95
5.16
0.109
0.0204
1.049
0.204
0.0106
0.204
1.05
697
901
1020
12
28
272
155
104
The amount of martensite, the amount of retained austenite, and the total amount of ferrite and bainitic ferrite were determined by the methods described hereinabove.
The average proportion of packets having the largest area in prior austenite grains was determined by the method described hereinabove.
A JIS No. 5 test specimen (gauge length: 50 mm, parallel section width: 25 mm) was sampled so that the longitudinal direction of the test specimen would be perpendicular to the rolling direction. A tensile test was performed in accordance with JIS Z 2241 under conditions where the crosshead speed was 1.67×10−1 mm/sec. TS and El were thus measured. In accordance with aspects of the present invention, 980 MPa or higher TS was determined to be acceptable, and 10% or more El was determined to be acceptable.
Toughness was evaluated by Charpy test. A Charpy test specimen was a 2 mm deep V-notched test piece that was a stack of steel sheets fastened together with bolts to eliminate any gaps between the steel sheets. The number of steel sheets that were stacked was controlled so that the thickness of the stack as the test piece would be closer to 10 mm. When, for example, the sheet thickness was 1.2 mm, eight sheets were stacked to give a 9.6 mm thick test piece. The Charpy test specimen was evaluated as “excellent in toughness” when the stack had a strength of 40 J/cm2 or more. Conditions other than those described above conformed to JIS Z 2242:2018.
The cold rolled steel sheets obtained as described above were analyzed to measure the flatness in the width direction. The measurement is illustrated in
The working embrittlement resistance was evaluated by Charpy test. A Charpy test specimen was a 2 mm deep V-notched test piece that was a stack of steel sheets fastened together with bolts to eliminate any gaps between the steel sheets. The number of steel sheets that were stacked was controlled so that the thickness of the stack as the test piece would be closer to 10 mm. When, for example, the sheet thickness was 1.2 mm, eight sheets were stacked to give a 9.6 mm thick test piece. The sheets for stacking into the Charpy test specimen were sampled so that the width direction would be the longitudinal direction. As an index of the working embrittlement resistance, the ratio vE0%/vE10% of the absorbed impact energy at room temperature of the as-produced (unworked) steel sheet to that of the steel sheet after 10% rolling was measured. The working embrittlement resistance was rated as “×” when vE0%/vE10% was less than 0.6, as “∘” when vE0%/VE10% was 0.6 or more and less than 0.7, and as “⊚” when vE0%/vE10% was 0.7 or more. The Charpy test specimen was evaluated as “excellent in working embrittlement resistance” when vE0%/vE10% was 0.6 or more. Conditions other than those described above conformed to JIS Z 2242:2018.
The results are described in Tables 5 to 7. As shown in Tables 5 to 7, INVENTIVE EXAMPLES achieved 980 MPa or higher TS, 10% or more El, and excellent toughness, flatness in the width direction, and working embrittlement resistance. In contrast, COMPARATIVE EXAMPLES were unsatisfactory in one or more of TS, El, toughness, flatness in the width direction, and working embrittlement resistance.
53
49
80
X
X
88
X
X
92
X
X
33
16
X
81
X
X
89
X
X
54
30
48
26
X
16
X
52
33
X
28
X
28
X
30
X
31
X
26
X
27
X
29
X
26
X
28
X
| Number | Date | Country | Kind |
|---|---|---|---|
| 2022-049759 | Mar 2022 | JP | national |
This is the U.S. National Phase application of PCT/JP2023/002917, filed Jan. 30, 2023 which claims priority to Japanese Patent Application No. 2022-049759, filed Mar. 25, 2022, the disclosures of these applications being incorporated herein by reference in their entireties for all purposes.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2023/002917 | 1/30/2023 | WO |
