Claims
- 1. A high temperature stable catalyst, which comprises a support and a catalytically active component supported thereon, wherein at least part of said support consists essentially of a composite oxide of aluminum and at least one member selected from the group consisting of lanthanum, neodymium, praseodymium and mixtures thereof, said composite oxide having a specific surface area of at least 10 m.sup.2 /g, and said composite oxide being characterized in that it exhibits characteristic peaks of lanthanide-beta-alumina in X-ray diffraction analysis, and wherein said composite oxide is a calcination product of a mixture of an aluminum compound and a member selected from the group consisting of lanthanum compound, neodymium compound, praseodymium compound and mixtures thereof, calcined at of at least 800.degree. C. for a time sufficient to convert the mixture into said composite oxide.
- 2. A high temperature stable catalyst according to claim 1, wherein the composite oxide is represented by at least one of the formulae La.sub.2 O.sub.3.11-14Al.sub.2 O.sub.3, Pr.sub.2 O.sub.3.11-14Al.sub.2 .sub.3 and Nd.sub.2 O.sub.3.11-14Al.sub.2 O.sub.3.
- 3. A high temperature stable catalyst, which comprises a support and a catalytically active component supported on said support, wherein at least part of said support consists essentially of composite oxide of aluminum and at least one member selected from the group consisting of lanthanum, neodymium, praseodymium and mixtures thereof and has a specific surface area of at least 10 m.sup.2 /g, said composite oxide being characterized in that it exhibits characteristic peaks corresponding to those of lanthanide-beta-alumina in X-ray diffraction analysis, and said composite oxide containing less than 1% weight of chromium, strontium and cerium.
- 4. A high temperature stable catalyst according to claim 3, wherein the composite oxide is represented by at least one of the formulae La.sup.2 O.sup.3.11-14Al.sub.2 O.sub.3, Pr.sub.2 O.sub.3.11-14Al.sub.2 O.sub.3 and Nd.sub.2 O.sub.3.11-14Al.sub.2 O.sub.3.
- 5. A high temperature stable catalyst, which comprises a support and a catalystially active component supported on said support, wherein at least part of said support consists essentially of a composite oxide of aluminum, in an amount of 99 to 80 molar %, and at least one member, in an amount of 1 to 20 molar %, selected from the group consisting of lanthanum, neodymium, praseodymium, and mixtures thereof; said composite oxide having a specific surface area of at least 10 m.sup.2 /g, said composite oxide being characterized in that is exhibits characteristic peaks corresponding to those of lanthanide-beta-alumina in X-ray diffraction analysis, and said composite oxide containing less than 1% by weight of chromium, strontium and cerium.
- 6. A high temperature stable catalyst according to claim 5, wherein the composite oxide is represented by at least one of the formulae La.sub.2 O.sub.3.11-14Al.sub.2 O.sub.3 PR.sub.2 O.sub.3. 11-14Al.sub.2 O.sub.3 and Nd.sub.2 O.sub.3.11-14Al.sub.2 O.sub.3.
- 7. A high temperature stable catalyst, which comprises a support and a catalytically active component supported on said support, wherein at least part of said support consists essentially of a composite oxide of aluminum, in an amount of 99 to 80 molar %, and at least one member, in an amount of 1 to 20 molar %, selected from the group consisting of lanthanum, neodymium, praseodymium and mixtures thereof; said composite oxide having a specific surface area of at least 10 m2/g, said composite oxide being characterized in that it exhibits characteristic peaks corresponding to those of lanthanide-beta-alumina in X-ray diffraction analysis, and said composite oxide containing less than 1% by weight of chromium, strontium and cerium; said active component being at least one member selected from the group consisting of VIII group elements of the Periodic Table, manganese, chromium, zirconinum, rare earth metals, magnesium, barium, strontium and calcium.
- 8. A process for preparing a high temperature stable catalyst, which comprises the steps of:
- effecting coprecipitation of an aluminum salt and at least one member selected from the group consisting of salts of lanthanum, neodymium, praseodymium, and mixtures thereof, from an aqueous solution of the salts by adding an alkali to the solution, wherein an amount of lanthanum, neodymium, praseodymium or the mixtures in the solution is 1 to 20 molar % based on the total of the salts and a concentration of chromium, strontium and cerium is less than 1% by weight, based on the calcined support;
- separting the resulting coprecipitate from the solution;
- drying the coprecipitate;
- heating the coprecipitate to convert it into a composite oxide of aluminum and lanthanum, neodymium, praseodymium or a mixture thereof to a temperature of at least 800.degree. C. for a time sufficient to produce said composite oxide having a specific surface area of at least 10 m.sup.2 / g and exhibiting characteristic peaks corresponding to lanthanide-beta-alumina in X-ray diffraction analysis;
- applying a catalytically active component to said composite oxide; and
- calcining the support carrying the active component at a temperature sufficient to firmly support the active component on the support.
- 9. A process according to claim 8, wherein the composite oxide is represented by at least one of the formulae La.sub.2 O.sub.3.11-14Al.sub.2 O.sub.3, Pr.sub.2 O.sub.3.11-Al.sub.2 O.sub.3 and Nd.sub.2 O.sub.3.11-14Al.sub.2 O.sub.3.
- 10. A high temperature stable catalyst, which comprises a support and a catalytically active component supported on said support, wherein at least part of said support which supports said active components consists essentially of a composite oxide of aluminum and at least one member selected from the group consisting of lanthanum, neodymium, praseodymium and mixtures thereof and has a specific surface area of at least 10 m.sup.2 /g, said composite oxide being chracterized in that it exhibits characteristic peaks corresponding to those of lanthanide-beta-alumina in the X-ray diffraction analysis.
- 11. A high temperature stable catalyst, which comprises a support and a catalytically active component supported on said support, wherein said support consists essentially of a composite oxide of aluminum and at least one member selected from the group consisting of lanthanum, neodymium, praseodymium, and mixtures thereof and has a specific surface area of at least 10 m.sup.2 /g, said composite oxide being characterized in that it exhibits characteristic peaks corresponding to those of lanthanide-beta-alumina in the X-ray diffraction analysis.
- 12. A high temperature stable catalyst, which comprises a support and a catalytically active component supported on said support, wherein said support has a coating thereon which consists essentially of a composite oxide of aluminum and at least one member selected from the group consisting of lanthanum, neodymium, praseodymium and mixtures thereof and has a specific surface area of at least 10 m.sup.2 /g, said composite oxide being characterized in that it exhibits characteristic peaks corresponding to those of lanthanide-beta-alumina in the X-ray diffraction analysis.
Priority Claims (2)
Number |
Date |
Country |
Kind |
58-118207 |
Jul 1983 |
JPX |
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58-127947 |
Jul 1983 |
JPX |
|
Parent Case Info
This is a continuation of application Ser No. 627,104, filed July 2, 1984, now abandoned.
US Referenced Citations (6)
Continuations (1)
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Number |
Date |
Country |
Parent |
627104 |
Jul 1984 |
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