Claims
- 1. A process for conducting a catalytic oxidation reaction, which comprises contacting fluid fuel and an oxidant with a catalyst comprising a support and a catalytically active component supported on aid support, wherein at least the part of said support that predominantly supports said active component consists essentially of a composite oxide of aluminum and at least one member selected from the group consisting of lanthanum, neodymium, praseodymium and mixtures thereof, said composite oxide having a specific surface area of at least 10 m.sup.2 /g, and being characterized in that it exhibits characteristic peaks corresponding to those of lanthanide-beta -alumina in X-ray diffraction analysis.
- 2. A process for conducting a catalytic oxidation reaction according to claim 1, wherein the composite oxide has a composition of 1 to 20 molar % of the oxide of at least one member selected from the group consisting of lanthanum, neodymium and praseodymium and the balance being alumina.
- 3. A process for conducting a catalytic oxidation reaction according to claim 20, wherein the composite oxide has a composition of 3 to 10 molar % of the oxide of at least one member selected from the group consisting of lanthanum, neodymium, and praseodymium and the balance being alumina
- 4. A process for conducting a catalytic oxidation reaction according to claim 3, wherein the composite oxide has a specific surface area of 20 to 100 m.sup.2 /g.
- 5. A process for conducting a catalytic oxidation reaction according to claim 4, wherein the entire support is made of the composite oxide.
- 6. A process for conducting a catalytic oxidation reaction according to claim 4, wherein the shape of the support is a honeycomb structure.
- 7. A process for conducting a catalytic oxidation reaction according to claim 4, wherein a surface of a substrate is coated with the composite oxide on which said active component is supported.
- 8. A process for conducting a catalytic oxidation reaction according to claim 7, wherein the substrate is a member selected from a metallic plate, metallic mesh, and foamed metal.
- 9. A process for conducting a catalytic oxidation reaction according to claim 4, wherein the active component is at least one member selected from the group consisting of Group VIII elements of the Periodic Table, manganese, chromium, zirconium, rare earth elements, tin, zinc, copper, magnesium, barium, strontium and calcium.
- 10. A process for conducting a catalystic oxidation reaction according to claim 4, wherein said fluid fuel is methane and said catalytically active component is at least one of the Group VIII elements of Periodic Table.
- 11. A process for conducting a catalytic oxidation reaction according to claim 6, wherein said active component is at least one Group VIII element of the Periodic Table.
- 12. A process for conducting a catalytic oxidation reaction according to claim 4, wherein the active component is at least one member selected from the group consisting of Group VIII elements, manganese, chromium, zirconium, rare earth elements, tin, zinc, copper, silver, magnesium, barium, strontium and calcium and the catalyst is contacted with a gas containing the fluid fuel at a temperature of 1500.degree. C. or below to oxidize the fluid fuel.
- 13. A process according to claim 1, wherein said composite oxide contains less than 1% by weight of chromium, strontium and cerium.
- 14. A process for conducting a catalytic oxidation reaction, which comprises contacting fluid fuel and an oxidant with a catalyst comprising a support and a catalytically active component supported on said support, wherein at least the part of said support that predominantly supports said active component consists essentially of a composite oxide of alumina and at least one member consisting of the group consisting of lanthanum, neodymium, praseodymium and mixtures thereof, said composite oxide having a specific surface area of at least 10 m.sup.2 /g, said composite oxide containing less than 1% by weight of chromium, strontium and cerium, and said composite oxide being characterized in that it exhibits characteristic peaks corresponding to those of lanthanide-beta-alumina in the X-ray diffraction analysis and said composite oxide being a calcination product of a mixture of an aluminum compound and a member selected from the group consisting of lanthanum compound, neodymium compound, praseodymium compound and mixtures thereof calcined at a temperature of at least 800.degree. C. for time sufficient to convert the mixture into said composite oxide.
Priority Claims (2)
Number |
Date |
Country |
Kind |
58-118207 |
Jul 1983 |
JPX |
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58-127947 |
Jul 1983 |
JPX |
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Parent Case Info
This is a division of application Ser. No. 867,542, filed May 28, 1986, now U.S. Pat. No. 4,738,946, which is a continuation of application Ser. No. 627,104, filed July 2, 1984, now abandoned.
US Referenced Citations (18)
Non-Patent Literature Citations (1)
Entry |
Dexpert-Chys et al, Optical and Structural Investigation of the Lanthanum .beta.-Alumina Phase Doped with Europium, Journal of Solid State Chemistry, 19, 193-204 (1976). |
Divisions (1)
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Number |
Date |
Country |
Parent |
867542 |
May 1986 |
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Continuations (1)
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Number |
Date |
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Parent |
627104 |
Jul 1984 |
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