This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No. 2003-089776, filed on Mar. 28, 2003, the entire contents of which are incorporated herein by reference.
1. Field of the Invention
This invention relates to a high-temperature superconducting device and a manufacturing method thereof and, more particularly, to a high-temperature superconducting device characterized by a means to form the high-temperature superconducting device by a ramp-edge-type superconductor junction with various critical current densities Jc, and a manufacturing method thereof.
2. Description of the Related Art
In recent years, oxide high-temperature superconductors as typified by yttrium-type superconductors have been expected to be applied to various fields such as sensors and logic circuits, since their superconducting state is exhibited at a temperature higher than liquid nitrogen, suggesting that its cooling is simpler than those of the conventional metal-type superconductors which require cooling by liquid helium (refer to Japanese Patent Application Laid-open No. 2000-353831, for example).
Such oxide high-temperature superconductors have a characteristic that superconducting current thereof tends to take paths along a Cu—O plane formed of copper and oxygen in a crystal, so that it is preferable that the junction traverses along a parallel direction with respect to such a Cu—O plane. Accordingly, a ramp-edge-type junction is proposed as a superconductor junction used for a high-temperature superconducting device.
For such ramp-edge-type junctions, are known a type in which a barrier layer is formed of deposited films, and a type in which a barrier layer is formed by modifying its surface with ion implantation (refer to Japanese Patent Application Laid-open No. 2001-244511, and Supercond. Sci. Technol., Vol. 14, pp.1052–1055, 2001, for example).
Further, among superconducting circuits, a single flux quantum (SFQ) circuit has a characteristic that it is operated at an ultrahigh speed and with low energy, so that, where the SFQ circuit is designed and manufactured with the high-temperature superconductor, a superconducting loop having Josephson junction and included in a circuit has to be designed to fulfill a condition that the product of an inductance L and a critical current value Ic of the Josephson junction of the loop (product of L multiplied by Ic) is one quantum magnetic flux (Φo) or ½ Φo.
In such a case, the higher is the product of the critical current Ic and the normal conducting resistance Rn of the junction used in the SFQ circuit being the product of Ic×Rn, the narrower the width of an SFQ pulse becomes, so that a high-speed operation can be realized. An interface-modified or interface-engineered junction of the high-temperature superconductor can make the product of Ic×Rn higher by increasing an interface current density Jc, the state of which will be explained below with reference to
Ic×Rn=Jc0.2, or
Ic×Rn=Jc0.5
Hence, it is understood that the product of Ic×Rn can be made larger by increasing Jc.
Here, a superconductor junction element having the interface-engineered ramp-edge junction is explained with reference to
First, in
Next, in
Subsequently, in
As shown in
Subsequently, in
It is noted that
In the case described above, the ramp slopes are formed in four directions by processing the lower electrode layer, and ion is irradiated vertically with respect to the substrate surface, whereby a damage layer is formed uniformly over the ramp slopes. As a result, interface-engineered ramp-edge junctions with a uniform critical current density Jc can be formed in the four directions, so that Jc for the intra-circuit junctions can be made uniform, whereby an accurate circuit operation is realized.
As described above, in designing a SFQ circuit, the inductance L and the critical current Ic in the circuit have to be determined by fulfilling the condition for the product of L×Ic (which is L×Ic<Φo). However, in the ramp-edge structure, in which a barrier layer is sandwiched by the upper and lower electrodes through the bridge portion, parasitic inductance is generated in series with the junction.
The parasitic inductance exists in no small way, because the size of the Josephson junction or the minimum length of interval between the electrode and the wiring are determined based on a lithographic limit and constraints with respect to material processing. In such a circumstance, if Jc of the Josephson junction is made higher in order to make the product of Ic×Rn larger, the junction width, which is the bridge width, has to be narrowed so as to obtain a constant-value Ic.
In such a case, the length of the bridge which exists in series with the Josephson junction becomes longer than the width thereof, and the parasitic inductance becomes larger.
For example, in a state where the electrode thickness, bridge length, and sheet inductance respectively are constant, if a Josephson junction is fabricated in a manner that it has a constant-value critical current Ic, the critical current density Jc being made N times higher results in the junction width of 1/N times wider, and the parasitic inductance of N times larger.
Consequently, when Jc of the Josephson junction is made higher, a loop inductance of a superconducting loop containing the Josephson junction becomes larger.
Hence, the above-described condition for the product of L×Ic (L×Ic<Φo) can no longer be fulfilled, and the circuit cannot be operated.
In order to deal with such a state, in the circuit design prevailing at present, the inductance is determined in tune with a circuit whose restriction on L×Ic is the most strict among the elements in the circuit, and the junction width is widened in order to reduce the influence of the parasitic inductance as much as possible.
However, if the junction width is widened in order to reduce the parasitic inductance influence as much as possible, Jc of the Josephson junction cannot be made higher, so that the junction with relatively small-value product of Ic×Rn has to be used. Consequently, the SFQ pulse width becomes wider, and a problem is caused in which the circuit performance is deteriorated in such a manner that the operational speed of the SFQ circuit is restricted, or the operational uncertainty (jitter) becomes greater.
It is an object of the present invention to allow a stable high-speed operation of a superconductor circuit such as an SFQ circuit.
Note that in
As can be seen in
By separately fabricating at least the two ramp-edge Josephson junctions 9 and 10 whose critical current densities Jc differ to each other above the substrate 1, and by utilizing each performance of the junctions differently depending on each element circuit, both a high-speed operation and a stable operation of the superconducting circuit device such as a SFQ circuit can be realized. Consequently, the performance of the high-temperature superconducting device can be enhanced.
In the above case, a Josephson junction 9 having a relatively high critical current density is used so that Ic×Rn is made larger, allowing a high-speed operation, while a Josephson junction 10 having a relatively low critical current density is used so that the junction width is widened and the inductance L is reduced, allowing a stable operation in a manner which fulfills the condition of L×Ic<Φo in a circuit element having a strict L×Ic condition.
Circuit elements not having such a strict L×Ic condition as referred to above include a pulse generator and a comparator, and at least one of which should contain the Josephson junction 9 of the relatively high critical current density.
That is to say, the superconducting circuit device includes circuits whose restrictions on the product of L×Ic are not strict, and specifically, those falling in such a category include a pulse generator and a comparator determining performance and operational speed of the entire circuit.
In such an element circuit, in order to make the product of L×Ic higher, it is possible to narrow the junction width so that Jc can be made higher without being restricted by the L×Ic product condition.
That is to say, it is important that junctions with different performances are used separately, in such a manner that an element circuit requiring high speed and high precision should contain a high-Jc junction, while an element circuit requiring a strict condition on the product of L×Ic should include a relatively low Jc junction so that the parasitic inductance L can be reduced.
Further, the above-described Josephson junctions 9 and 10 having different critical current densities to each other should form interface-engineered barriers 5 and 6 having respectively different damages, or barriers 5 and 6 having deposited films of respectively different thicknesses.
Furthermore, in the Josephson junctions 9 and 10 having different critical current densities to each other, after forming the ramp-edge structure having plural slopes in the sane island regions 2 and 3, the ion irradiation should be performed under the condition that at least a damage to one of the slopes is different from damages to other slopes. For example, ion should be irradiated from a specific diagonal direction under the condition that the substrate 1 is not rotated with respect to the island regions 2 and 3.
Otherwise, in the Josephson junctions 9 and 10 having different critical current densities to each other, after forming the ramp-edge structure having plural slopes in the same island regions 2 and 3, the barrier layers 5 and 6 should be deposited under the condition that the deposited film thickness of at least one of the slopes is different from the deposited film thickness of other slopes. For example, a material forming the barrier layers 5 and 6 should be deposited by the sputtering method from a fixed diagonal direction under the condition that the substrate 1 is not rotated with respect to the island regions 2 and 3.
Hereinafter, a forming process of an interface-engineered ramp-edge junction according to a first embodiment of the present invention is explained with reference to
First, as shown in 2A, a laser deposition method (PLD: pulse laser deposition) is used to sequentially deposit a lower electrode layer 12 formed of YBCO (YBa2Cu3O7-x) having a thickness of 200 nm for example, and an insulating layer 13 formed of a LSAT having a thickness of 300 nm for example, on a LSAT substrate 11 formed of [LaAlO3]0.3[Sr(Al,Ta)O3]0.7.
Next, as shown in 2B, a photo-resist is coated on the insulating layer 13, which is then exposed and developed. After that, the photo-resist film is reflowed by baking, so that a photo-resist pattern 14 is formed. The photo-resist pattern 14 is then used as a mask, so as to irradiate argon ion 15 from a diagonal direction with the LSAT substrate 11 rotated such that the insulating layer 13 and the lower electrode layer 12 are etched, resulting in formation of a ramp slope 16.
Subsequently, as shown in
Next, as shown in
As shown in
In that case in the process shown in
Further in the process shown in
Next, with reference to
First, as shown in
Subsequently, a photo-resist is coated on the insulating layer 13, which is then exposed and developed. The photo-resist film is then reflowed by baking, so that a photo-resist pattern 14 is formed. The photo-resist pattern 14 is then used as a mask, so as to irradiate argon ion 15 from a diagonal direction with the LSAT substrate 11 rotated, such that the insulating layer 13 and the lower electrode layer 12 are etched, resulting in formation of a ramp slope 16.
As shown in
Subsequently, as shown in
In that case in the process shown in
Further in the process shown in
With the above-described conditions as premises, a superconducting circuit device according to a third embodiment of the present invention will be explained next.
The circuit applies normal electrical signal used in semiconductor circuits through an input Isgn, and an SFQ pulse is outputted from an output terminal when an input signal exceeds a certain threshold level, where, the larger is the product of Ic×Rn of a Josephson junction used in the circuit, the narrower the time width of the generated pulse becomes. This state will be explained with reference to
The half widths of the pulses are 5.8 ps (pico seconds), 2.6 ps, and 1.85 ps respectively for the Josephson junctions having the Ic×Rn product of 0.5 mV, 1.0 mV, and 1.5 mV, so that it is understood that by using a Josephson junction having a larger Ic×Rn product, a pulse having the narrower width can be generated.
Hence, the pulse interval can be reduced in a circuit using a junction of a high Ic×Rn product, whereby the operational speed can be enhanced. In order to do so, the DC/SFQ conversion circuit should include a high-Jc Josephson junction.
Additionally, as shown in
Here, whilst the time width of the pulse generated from the DC/SFQ conversion circuit is uniform regardless of the product of Ic×Rn of the junction used at the JTL, the pulse waveform is shaped at a subsequent JTL so that the pulse width can be modified. This process will be explained with reference to
It is noted that the Ic×Rn product of the junction of the DC/SFQ conversion circuit is 0.5 mV.
As shown in
If such a narrow-width-pulse is used as a sampling pulse of a comparator in a circuit containing the DC/SFQ conversion circuit, JTL, and comparator, as shown in
It is noted that the Ic×Rn product of the Josephson junctions J8 and J9 of the subsequent JTL of the comparator is 0.5 mV.
As can be seen in
However, when the Josephson junction having the Ic×Rn product of 0.5 mV is used, the delay varies in the range from 10 ps to 4 ps, whereby dependence of the comparing operation to the level of the compared signal is observed.
That is to say, if the circuit includes a junction having a low Ic×Rn product, jitter is increased so that the accuracy of the comparing operation is reduced.
As can be seen in
That is to say, if the product of Ic×Rn is higher, a higher-speed operation can be performed.
Additionally, for a comparison purpose,
As can be seen in the comparison between
Further, as can be seen in the graph of Ic×Rn=1.5 mV in
Furthermore, the delay is 1 ps or less, indicating that high-speed operation is performed which is almost identical to that of a circuit whose junctions are all Ic×Rn=1.5 mV.
From the above-described simulation results, it is understood that by applying Josephson junctions of different performances to each of different elemental circuits, the performance of the high-temperature superconducting device can be enhanced in its entirety.
Based on the above-described simulation results, a superconducting circuit device according to a third embodiment of the present invention is manufactured, which will be explained with reference of
Subsequently, a YBCO layer forming an upper electrode layer 39 is deposited, and thereafter patterning is performed so that bridges 40 and 41, and at the same time a lead-out wiring line 42 and so forth, are formed.
It is noted that the Josephson junction of the bridge 40 provided in the upper region in
Accordingly, the DC/SFQ converter and the JTL formed in the island region 32 are fabricated by the high-Jc Josephson junction, and the comparator formed in the island region 33 is also fabricated by the high-Jc Josephson junction.
On the other hand, the JTL formed in the island region 34, and a SQUID formed in the island region 35 are fabricated by the low-Jc Josephson junction.
Specifically, the condition on the product of L×Ic of the SQUID is strict, so that a low-Jc Josephson junction should be used therein, whereby the bridge width becomes wide and the inductance L becomes small.
As described above, by differentiating damages of the damage layer of the ramp slopes in an island region, Josephson junctions having different critical current densities can be formed in the one island region. Here, by separately using Josephson junctions with different performances depending on each element circuit, the performance of the entire high-temperature superconducting device can be enhanced without complicating the device configuration and with a simple configuration.
Specifically, two Josephson junctions J1 and J2 forming the DC/SFQ converter are low-Jc Josephson junctions, while the rest of the Josephson junction J3, as well as Josephson junction J4 forming the JTL portion, is a high-Jc Josephson junction.
Thus far each embodiment of the present invention has been described, but this invention is not limited to the configurations and conditions mentioned in the embodiments, and various modifications thereto are possible.
For example, in each of the above embodiments, LSAT, in other words, [LaAIO3]03[Sr(Al,Ta)O3]07, is used as a substrate, but it is also possible to use MgO, SrTiO3, or the like.
Further, in each of the above-described embodiments, the lower electrode layer and upper electrode layer are formed of YBCO, which is YBa2Cu3O7-x, but it is not a limitation, and REBa2Cu3O7-x can be also used.
It is noted that rhenium of REBa2Cu3O7-x is lanthanoid excluding praseodymium and cerium, and is blended singly or plurally to be included in a ratio of rhenium:barium:copper=1:2:3.
Furthermore, in each of the above-described embodiments, LSAT is used as the inter-layer insulating film, but the material is not limited to LSAT, but MgO, CeO2, SrTiO3, or the like can also be used.
Further, in the second embodiment described above, the barrier layer is formed of PBCO, which is PrBa2Cu3O7-x, but it is not a restriction, and CeBa2Cu3O7-x or the like may also be used.
Also in each of the above embodiments, the laser deposition method is used for deposition of the YBCO film and the PBCO film, but it is not a limited method, and the sputtering method can also be used.
Furthermore, in the above first and third embodiments, argon ion is irradiated to form a damage layer, but it is not a limitation, and other rare gas ion such as neon, krypton, and xenon may be irradiated.
Further, in the above third embodiment and the modified example thereof, the ion milling method is used to form Josephson junctions having different Jcs, but similarly to the above second embodiment, the thickness of the deposited barrier layer may be differed to one another depending on each ramp slope, so as to form the Josephson junctions having different Jcs to one another.
Also in the above third embodiment and the modified example thereof, in an island region, the bridge is provided in the same ramp slope, so that Josephson junction having the same Jcs are formed. But it is possible to provide the bridge in a different ramp slope in an island region, so that Josephson junctions having different Jcs can be obtained.
Hence, ramp-edge-type junctions formed of an oxide superconductor and having a respective critical current density Jc, which is different to one another, can be separately used, so that particular element circuits within the superconducting circuit can be made high-speed or highly precise, allowing the performance of the entire high-temperature superconducting device to be enhanced. This should considerably contribute to practical application of various types of high-temperature sueprconducting device.
The present embodiments are to be considered in all respects as illustrative and no restrictive, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. The invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof.
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