Patent Application
20210151701
The field of the currently claimed embodiments of this invention relates to photovoltaic cells, and more particularly to monolithic tandem photovoltaic cells and their method of production.
In the following paragraphs some technical terms are used. The technical terms are defined for clarity.
The term “CIGS light absorption material” stands for CuInxGa(1-x)Se2, where x is less than one (“1”) and greater than zero (“0”).
The term “perovskite (PVSK) light absorption material” refers to a light absorption material that has a structure of ABX3, where ‘A’ and ‘B’ are two cations of very different sizes, and X is an anion that bonds to both.
PTAA is an acronym for Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine, one of the family members of poly(triaryl)amine.
The abundance of solar radiation presents an enormous incentive to develop methods to harness its energy. Compared to current means of obtaining energy, the major challenge lies not in the availability but in the harvesting and storing of the sun's energy in a cost-effective and environmental-friendly manner. The key to achieving affordable photovoltaic (PV) technologies is to develop techniques that offer both high performance and low material and processing costs. Although silicon-based solar panels remain the dominant market share with steadily growing power conversion efficiencies (PCE) and reducing costs, their efficiencies and practicality remain inferior to other forms of power generation. On the other hand, thin film solar cells are becoming a promising alternative due to their low cost and low energy usage during manufacturing. To further improve the cost-effectiveness of thin film solar cells, it is necessary to improve efficiencies while simultaneously reducing costs.
In an effort to boost efficiencies, multi junction solar cells have been developed that connect multiple sub-cells in series to cover a broader range of the spectrum and combine attributes from each cell design. Reducing thermalization losses of hot carriers generated by photons with larger energies than the bandgap (Eg) can break the limit of the theoretical maximum efficiency for a single junction photovoltaic cell. Multi junction cells reduce this loss dramatically by combining several photovoltaic units with cascading Eg values in a tandem structure. However, the cost to fabricate efficient tandem solar cells is often quite high. To date, over 30% efficient epitaxial III-V solar cells have been achieved, however, high fabrication costs restrict the wide adoption of these technologies.
Therefore, an over 30% efficient, low-cost solar cell is a commercially unmet need. Therefore, there remains a need for improved photovoltaic cells.
An aspect of the present invention is to provide a monolithic tandem photovoltaic cell. The monolithic tandem photovoltaic cell includes a first electrode; a CIGS light absorption section on the first electrode; an interconnecting layer on the CIGS light absorption section; and a perovskite light absorption section on the inter-connecting layer. The interconnecting layer has a polished surface on which the perovskite light absorption section is formed. The interconnecting layer provides an electrically conducting and optically transparent connection between the CIGS light absorption section and the perovskite light absorption section.
Another aspect of the present invention is to provide a method of producing a monolithic tandem photovoltaic cell. The method includes providing a first electrode on a substrate; producing a CIGS light absorption section on the first electrode; depositing an interconnecting layer on the CIGS light absorption section; polishing the interconnecting layer; and producing a perovskite light absorption section on the inter-connecting layer. The interconnecting layer provides an electrically conducting and optically transparent connection between the CIGS light absorption section and the perovskite light absorption section.
The present disclosure, as well as the methods of operation and functions of the related elements of structure and the combination of parts and economies of manufacture, will become more apparent upon consideration of the following description and the appended claims with reference to the accompanying drawings, all of which form a part of this specification, wherein like reference numerals designate corresponding parts in the various figures. It is to be expressly understood, however, that the drawings are for the purpose of illustration and description only and are not intended as a definition of the limits of the invention.
Some embodiments of the current invention are discussed in detail below. In describing embodiments, specific terminology is employed for the sake of clarity. However, the invention is not intended to be limited to the specific terminology so selected. A person skilled in the relevant art will recognize that other equivalent components can be employed and other methods developed without departing from the broad concepts of the current invention. All references cited anywhere in this specification, including the Background and Detailed Description sections, are incorporated by reference as if each had been individually incorporated.
The combination of Cu(In,Ga)Se2 (CIGS) with perovskite (PVSK) to provide PVSK/CIGS tandem solar cells offers a promising solution for both high performance and low-cost. Both perovskite and CIGS are compelling in their cost-effectiveness and high performance, making them highly attractive candidates for double junction tandem solar cells.
Different from the III-V tandem solar cells, the PVSK/CIGS tandem solar cells do not need high vacuum facilities, such as molecular beam epitaxy (MBE), metal-organic chemical vapor deposition (MOCVD), etc. Therefore, this could reduce the fabrication cost for such solar cells.
Compared to Silicon/PVSK tandem solar cells which require high quality silicon rear cells, PVSK/CIGS solar cells only need the commercialized CIGS rear cell to achieve high efficiency. In addition, as this is a thin film tandem solar cell, flexible tandem solar cells could be fabricated by this method.
For PVSK/CIGS tandem solar cells, we first report using a chemical-mechanical polishing (CMP) method to polish the interconnection layer and this key technique makes the devices more reliable and less expensive. In addition, we use an optically transparent electrode to help light harvesting, which is different from other tandem solar cells which use opaque electrodes. Therefore, our device efficiency is 80% higher than the prior results. For example, the conventionally reported highest efficiency of a PVSK/CIGS tandem solar cell is only 10.9%, which is published in “Teodor Todorov et al., Adv. Energy Mater. 2015, 5, 1500799.” The term “optically transparent” or “optically semi-transparent” is used herein throughout to mean having a transmission of radiation or light in the visible wavelength range, the ultraviolet wavelength range, and/or infrared wavelength range of at least 50%, for example, between 70% and 100%.
The conventional Todorov's PVSK/CIGS have an inferior efficiency. This can be attributed to various reasons. The present inventors have determined that the limited efficiency in the conventional PVSK/CIGS can be due to 1) the optical losses caused by the top opaque metal electrodes; 2) the intrinsic ZnO (i-ZnO) and aluminum doped ZnO (AZO) layers pertaining to typical CIGS cells are removed as zinc oxides can cause deterioration of the perovskite layer and this compromises the CIGS device architecture; the elimination of ZnO layer inevitably sacrifices the CIGS device performance; 3) the fill factor (F.F.) is reduced to 60% due to a high series or shunt resistance (Rs) caused by poor contact between the two subcells (CIGS and PVSK). Furthermore, as will be explained in the following paragraphs, the smoothness of the inter-connecting layer (ICL) can play a role in creating a reliable contact between the two sub-cells, since the planar perovskite solar cell is composed of several functional layers with thicknesses from few tens to hundreds of nanometers, which are sensitive to substrate roughness.
Accordingly, some embodiments of the present invention relate to Perovskite/Cu(In, Ga)Se2 (PVSK/CIGS) tandem photovoltaic devices 10 and their fabrication techniques.
In some embodiments, the polished surface 16A of the interconnecting layer 16 has a maximum vertical distance (VD) less than 250 nm. In some embodiments, the polished surface 16A of the interconnecting layer (ICL) 16 has a maximum vertical distance (VD) less than 100 nm. In some embodiments, the polished surface 16A of the interconnecting layer 16 has a maximum vertical distance (VD) in the range of 100 nm to 5 nm. In some embodiments, the polished surface 16A of the interconnecting layer 16 has a maximum vertical distance (VD) in the range of 40 nm to 10 nm.
In some embodiments, the interconnecting layer (ICL) 16 is an ITO layer between 200 nm and 400 nm thick. In some embodiments, the interconnecting layer 16 is an ITO layer about 300 nm thick. In an embodiment, good performance was achieved with a 300 nm ITO layer. If the thickness is thinner than 200 nm, the polishing process could damage the CIGS solar cell, and if the thickness is higher than 400 nm, the optical loss will be more severe.
In some embodiments, the perovskite light absorption section 18 includes a hole transport layer (HTL) 18A formed on the interconnecting layer 16, the hole transport layer 18A including PTAA doped with at least one of F4-TCNQ and TPFB. (TPFB is 4-Isopropyl-4′-methyldiphenyliodonium Tetrakis(pentafluorophenyl)borate.) In some embodiments, the hole transport layer 18A includes PTAA doped with between 0.5 wt % to 2 wt % of F4-TCNQ and with between 5 wt % to 15 wt % of TPFB. In some embodiments, the hole transport layer 18A includes PTAA doped with about 1 wt % of F4-TCNQ and with about 10 wt % of TPFB.
In some embodiments, the first electrode 12 is formed on a substrate 20. In some embodiments, the substrate 20 is a flexible substrate. In some embodiments, the substrate 20 is a soda-lime glass substrate. In some embodiments, the first electrode 12 is Mo.
In some embodiments, the CIGS light absorption section 14 includes a CIGS absorber layer 14A and a CdS layer 14B deposited on the CIGS absorber layer 14A. In some embodiments, the CIGS light absorption section further includes an i-ZnO layer 14C formed on the CdS layer 14B and a BZO layer 14D formed on the i-ZnO layer 14C. In some embodiments, the perovskite light absorption section 18 includes a PCBM layer 18C formed on a perovskite absorber layer 18B, a layer of ZnO nanoparticles 18D formed on the PCBM layer 18C, and an ITO layer 18E formed on the layer of ZnO nanoparticles 18D, the ITO layer 18E being the second electrode. In some embodiments, the monolithic tandem photovoltaic device/cell 10 further includes an anti-reflection coating 19 formed on the second electrode 18E. In some embodiments, the anti-reflection coating 19 is a MgF2 anti-reflection coating.
In some embodiments, the interconnecting layer (ICL) 16 is substantially optically transparent to light within an absorption band of the CIGS light absorption section 14.
In an embodiment, the total light current is attenuated about 7.5% after adding ITO layer 16 on the CIGS solar cell 14 within the spectrum from 300 to 1250 nm. The additional ITO layer light absorption could be reduced by adding some further optical design. As the desire for voltage improvement is much higher than current loss, the final efficiency is enhanced.
A method of producing a monolithic tandem photovoltaic cell according to some embodiments of the current invention includes providing a first electrode 12 on a substrate 20, producing a CIGS light absorption section 14 on the first electrode 12, depositing an interconnecting layer (ICL) 16 on the CIGS light absorption section 14, polishing the interconnecting layer 16, and producing a perovskite light absorption section 18 on the interconnecting layer 16. The interconnecting layer 16 provides an electrically conducting and optically transparent connection between the CIGS light absorption section 14 and the perovskite light absorption section 18.
In some embodiments, the polishing of the interconnecting layer 16 provides a surface 16A of the interconnecting layer 16 that has a maximum vertical distance (VD) less than 250 nm. In some embodiments, the polishing of the interconnecting layer 16 provides a surface 16A of the interconnecting layer 16 that has a maximum VD less than 100 nm. In some embodiments, the polishing of the interconnecting layer 16 provides a surface 16A of the interconnecting layer 16 that has a maximum VD in the range of 100 nm to 5 nm. In some embodiments, the polishing of the interconnecting layer 16 provides a surface 16A of the interconnecting layer 16 that has a maximum VD in the range of 40 nm to 10 nm.
In some embodiments, the depositing of the interconnecting layer 16 deposits an ITO layer about 300 nm thick. In some embodiments, the depositing of the interconnecting layer 16 deposits an Indium Tin Oxide (ITO) layer of between 200 nm to 400 nm thick.
In some embodiments, the producing of the perovskite light absorption section 18 on the interconnecting layer 16 includes depositing a hole transport layer (HTL) 18A on the interconnecting layer 16 and doping the hole transport layer 18A to increase hole conduction thereof.
According to other embodiments of the invention, a tandem device 10 having a transport top electrode 18E, suitable interconnecting layer (ICL) 16 and hole transporting layer (HTL) 18A, and successfully present a high-performance monolithic perovskite/CIGS tandem solar cell without modification of the CIGS device structure 14, i.e., by preserving its transparent conductive oxide (TCO) layers (i-ZnO) 14C and Boron-doped ZnO (BZO) layers 14D is constructed. For the two subcells, we apply a semitransparent perovskite section 18 with a band gap of 1.59 eV as a front cell, and CIGS section 14 with a bandgap of 1.00 eV as a rear cell. The certified tandem device power conversion efficiency (PCE) achieves 22.43% that is the highest PCE for thin film tandem solar cells and has doubled the previous record for the perovskite/CIGS monolithic tandem device structure 10.
A tandem solar cell with minimized thermalization losses has been proven a successful approach to overcome the Shockley-Queisser limit of a single junction cell. The tandem solar cell can realize the superposition of the open circuit voltage (VOC) of both sub-cells and simultaneously preserve the high short circuit current density (JSC) by utilizing photoactive materials with complementary absorption characteristics to harvest broader spectrum of sunlight.
The latest promising organic-inorganic hybrid PVSK and the CIGS thin film photovoltaic technology have emerged as an absorber material. Because both of PVSK and CIGS are solar materials having widely tunable band gaps from 1.0 to 1.7 eV for CIGS and 1.5 to 2.3 eV for PVSK, the combination of CIGS and PVSK indeed possesses great potential to realize a high efficiency tandem solar cell. These characteristics provide the potential to achieve the highest efficiency of double junction tandem solar cells, where the rear and front cells ought to have band gaps of 1.1 eV and 1.7 eV, respectively.
In some embodiments of the current invention, we demonstrate a high performance monolithic PVSK/CIGS tandem solar cell which also maintains the CIGS device structure.
Firstly, a rear CIGS solar cell is fabricated. The submicron-thick CIGS absorbers are deposited on Mo-coated soda-lime glass substrates with 2 μm thickness. After the deposition of CIGS absorber, a 50 nm CdS layer was deposited by chemical bath deposition. A 50 nm thick i-ZnO was subsequently deposited by RF-sputtering followed by sputtering deposition of a 300 nm thick AZO layer.
Secondly, the interconnection layer (ICL) of the tandem solar cell is deposited on CIGS layer. Indium tin oxide (ITO) and AZO transparent layers could be used as the interconnection layer. Usually, a considerable average roughness of AZO at the top of the CIGS device is about 300 nm, as shown in
In order to flatten the CIGS device surface, we use chemical mechanical polishing (CMP) to realize planar transparent conducting oxide (TCO) layers. AZO and ITO layers were polished using SiO2 and Al2O3 slurry, respectively. Colloid Al2O3 slurry with PH value 4 was used for ITO polishing and colloid SiO2 slurry with PH value 8 was used for AZO polishing. The CIGS solar cell was polished with flatten rotation rate 40 rpm for 5 min. After polishing, we find that the roughness of the ITO and AZO layers were reduced to 5 nm and 20 nm, respectively.
Thirdly, a front semitransparent PVSK solar cell is fabricated.
The average transmittance of semi-transparent perovskite cell in the wavelength region between 770 nm and 1100 nm is over 85%, and gradually decreases from 770 to 525 nm. Below 525 nm, the light is entirely absorbed by the perovskite cell, which indicates that the perovskite cell with composition of (FAPbI3)0.85(MAPbBr3)0.15 is an ideal candidate to couple with CIGS for near-infrared harvesting.
In order to design a functional ICL, the CIGS device surface has to be taken carefully into consideration.
The maximum length of VD is comparable to the perovskite absorber layer that is usually around 300 to 600 nm, and even larger than the thickness of the perovskite charge transporting layers. With these perceivable VDs, it becomes challenging to stack the perovskite solar cell on top of the CIGS with a homogeneous layer-by-layer structure. The rough BZO surface can cause perovskite subcell failure as the BZO peaks/rods can easily entangle the functional layers in perovskite device to induce electrical shorting pathways between the top contact of perovskite subcell and the BZO layer. Being aware of this fact, we confirm that the nature of CIGS device surface can be problematic for building a smooth ICL on top of it, and hence the ICL roughness is pivotal in realizing high-performance perovskite/CIGS tandem solar cells. To address this issue, we provide a smooth ICL while retaining original CIGS device structure. First, we deposit an ITO layer, followed by chemical mechanical polishing (CMP) to smooth out the ITO surface. By adding a sufficiently thick ITO layer, it can serve as a buffer layer for the CMP process to level out the relatively large VD of the BZO layer. In an embodiment, the ITO layer is polished using commercialized SiO2 slurry. After polishing, the maximum VD of the ITO layers is reduced to 40 nm (
As shown in TABLE 1, it is found that the VOC is substantially constant, which further implies that CMP processing does not damage the CIGS device structure. The current density JSC decreases slightly from 37.10 to 34.34 mA/cm2 for the ITO-polished device. The current density JSC drop can be due to the additional light absorption by the ITO layer, as we observe with the smaller external quantum efficiency (EQE) intensity across the entire response region, as shown in
After polishing, the fill factor (F.F.) reduced from 74.74% to 72.36%. The F.F. reduction is mainly induced by the shunt resistance (Rs) increase rather than the shunt resistance decrease, as shown in
After polishing the ITO layer of the CIGS device, the PCE decreased slightly from 18.74% to 16.75%. If we exclude the F.F. deficit influence, there will be only a 1.386 mA/cm2 current loss in the wavelength region from 750 to 1250 nm. This result shows that the CMP process can effectively flatten the ICL without sacrificing the efficiency of the CIGS subcell. This flattening/polishing step can result in the production of high performance perovskite/CIGS tandem solar cells for two reasons: i) the CIGS solar cell structure is not modified in that its high efficiency is preserved, and ii) CMP is a common processing technique in the semiconductor industry that is reliable and compatible with conventional semiconductor manufacturing, which will facilitate wide spread commercialization.
While connecting a semitransparent perovskite subcell with a CIGS subcell via ICL, the thickness and coverage of the first layer on top of the ICL can play an important role for tandem device performance. This may be due to the planar perovskite device structure that has limited tolerance to the substrate roughness. As discussed in the above paragraphs, the polished ICL can still preserve about 40 nm for its VD, which may be considerable for the HTL of perovskite subcell. Given this concern, we conducted experiments to study the solar cell performance versus the HTL thickness. In this study, PTAA is selected as the HTL layer, and two different following molecules A) and B) are used as dopants to enhance the HTL conductivity.
A) 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ); and
B) 4-Isopropyl-4′-methyldiphenyliodoniumTetrakis(pentafluorophenyl)borate (TPFB)
It is worth noting that, in an embodiment, PTAA is deposited using a low-temperature annealing process (110° C.) which can successfully avoid damage to the rear CIGS solar cell since the PN junction in the CIGS solar cell cannot tolerate temperatures higher than 150° C.
With the same concentration of F4-TCNQ, the device performance with the application of 30 nm PTAA is similar to the device performance with the application of 20 nm PTAA. However, the shunt resistance Rs increased when the PTAA reached 40 nm, which leads to a device F.F. and efficiency reduction. In the above examples, the best device performance is achieved when using 20 nm F4-TCNQ-doped PTAA at a voltage VOC of 1.084 V, a current density JSC of 18.10 mA/cm2 and F. F. of 75.60%. This results in a device having an overall device efficiency of 14.83%. In an embodiment, the desired F4-TCNQ/PTAA ratio is 1 wt %. Increasing F4-TCNQ concentration does not appear to help decrease the shunt resistance Rs as F4-TCNQ aggregates within the PTAA film. Therefore, in these examples, the most suitable thickness for F4-TCNQ-doped PTAA is less than 30 nm (for example, 20 nm).
On the other hand, the J-V curves of the perovskite device using TPFB-doped PTAA (TPFB/PTAA equal to 10 wt %) exhibited less sensitivity to the HTL thickness. The device performances are similar when using 30 to 50 nm PTAA. Surprisingly, the devices applying thicker TPFB-doped PTAA present superior performance than the devices with thinner F4-TCNQ-doped PTAA. In an embodiment, the best device is obtained by using 50 nm PTAA, with a voltage VOC of 1.091 V, current density JSC of 18.15 mA/cm2, F.F. of 75.49%, and PCE of 14.95%. The higher F.F. in the device in this example can be explained by the shunt resistance Rs reduction from the HTL, wherein the TPFB-doped PTAA has a higher conductivity than F4-TCNQ-doped PTAA. Considering the maximum vertical distance VD of the polished CIGS surface is about 40 nm in this example, thick PTAA is expected to provide a better coverage on the surface. Therefore, we adopted the TPFB-doped PTAA as the HTL for the perovskite front cell in the tandem architecture.
In an embodiment, device performances may be closely correlated to charge carriers dynamics in perovskite solar cells. We analyzed the charge collection and transportation using steady-state photoluminescence (PL) and time-resolved PL (TRPL).
In addition to high PCE, the long-term stability is also another benchmark for industrialization of perovskite devices. Several aging methods can be used to estimate a stability of the device in which the ion migration effects are excluded. For example, we monitored the un-encapsulated tandem device performance by aging for 500 hours under continuous one-sun illumination and maximum power point tracking at 30° C. ambient environment. The device started with 22.0% PCE and retained above 88% of its initial efficiency with aging for over 500 hours. The device can recover 93% of its initial PCE after 12 hours being kept in dark without load.
In the CIGS-Perovskite tandem device, a CdS layer is provided between the CIGS layer and the PVSK layer. The CdS buffer layer can be replaced by other comparable or equivalent buffer material, such as Zn(O, S, OH), as CdS is known to be a relatively toxic substance. In addition to solving the problem of toxicity, the working period of the perovskite/CIGS tandem solar cell can also be extended. In an embodiment, when the PVSK front cell has shown some environmental degradation, the degraded PVSK front cell can be removed and the CIGS cell reused. The CIGS solar cells can be reused after washing out the degraded perovskite front cell. Indeed, because the PTAA is applied as the HTL material, the whole perovskite front cell can be removed from the CIGS rear cell by dissolving in chlorobenzene and N, N-dimethylformamide. The CIGS rear cell keeps the same performance when the front perovskite cell is removed, demonstrating that the fabrication and dissolving processes of the front PVSK cell does not damage the CIGS cell. Therefore, by taking advantage of this feature, the CIGS cell can be either used as a single junction cell or reused as a rear cell in tandem PVSK-CIGS devices. Similar PCEs can be achieved with the reused CIGS-PVSK tandem devices as the PCEs of the original PVSK-CIGS tandem devices. This result demonstrates that the CIGS device can be recycled over many cycles to improve the working period of perovskite/CIGS tandem solar cells and thus reduce cadmium pollution.
More generally and as it can appreciated from the above paragraphs, a monolithic tandem photovoltaic cell according to some embodiments of the current invention include a first electrode, a CIGS light absorption section on the first electrode, an interconnecting layer on the CIGS light absorption section, and a perovskite light absorption section on the inter-connecting layer. The interconnecting layer has a polished surface on which the perovskite light absorption section is formed and the interconnecting layer provides an electrically conducting and optically transparent connection between the CIGS light absorption section and the perovskite light absorption section.
In some embodiments, the polished surface of the interconnecting layer has a maximum vertical distance (VD) less than 250 nm. In some embodiments, the polished surface of the interconnecting layer (ICL) has a maximum vertical distance (VD) less than 100 nm. In some embodiments, the polished surface of the interconnecting layer has a maximum vertical distance (VD) in the range of 100 nm to 5 nm. In some embodiments, the polished surface of the interconnecting layer has a maximum vertical distance (VD) in the range of 40 nm to 10 nm.
In some embodiments, the interconnecting layer is an ITO layer between 200 nm and 400 nm thick. In some embodiments, the interconnecting layer is an ITO layer about 300 nm thick. In an embodiment, good performance was achieved with a 300 nm ITO layer. If the thickness is thinner than 200 nm, the polishing process could damage the CIGS solar cell, and if the thickness is higher than 400 nm, the optical loss will be more severe.
In some embodiments, the perovskite light absorption section includes a hole transport layer formed on the interconnecting layer, the hole transport layer including PTAA doped with at least one of F4-TCNQ and TPFB. (TPFB is 4-Isopropyl-4′-methyldiphenyliodonium Tetrakis(pentafluorophenyl)borate.) In some embodiments, the hole transport layer includes PTAA doped with between 0.5 wt % to 2 wt % of F4-TCNQ and with between 5 wt % to 15 wt % of TPFB. In some embodiments, the hole transport layer includes PTAA doped with about 1 wt % of F4-TCNQ and with about 10 wt % of TPFB.
In some embodiments, the first electrode is formed on a substrate. In some embodiments, the substrate is a flexible substrate. In some embodiments, the substrate is a soda-lime glass substrate. In some embodiments, the first electrode is Mo.
In some embodiments, the CIGS light absorption section includes a CIGS absorber layer and a CdS layer deposited on the CIGS absorber layer. In some embodiments, the CIGS light absorption section includes an i-ZnO layer formed on the CdS layer and a BZO layer formed on the i-ZnO layer. In some embodiments, the perovskite light absorption section includes a PCBM layer formed on a perovskite absorber layer, a layer of ZnO nanoparticles formed on the PCBM layer, and an ITO layer formed on the layer of ZnO nanoparticles, the ITO layer being the second electrode. In some embodiments, the monolithic tandem photovoltaic cell further includes an anti-reflection coating formed on the second electrode. In some embodiments, the anti-reflection coating is a MgF2 anti-reflection coating.
In some embodiments, the interconnecting layer is substantially optically transparent to light within an absorption band of the CIGS light absorption section.
In an embodiment, the total light current is attenuated about 7.5% after adding ITO layer on the CIGS solar cell within the spectrum from 300 to 1250 nm. The additional ITO layer light absorption could be reduced by adding some further optical design. As the desire for voltage improvement is much higher than current loss, the final efficiency is enhanced.
A method of producing a monolithic tandem photovoltaic cell according to some embodiments of the current invention includes providing a first electrode on a substrate, producing a CIGS light absorption section on the first electrode, depositing an interconnecting layer on the CIGS light absorption section, polishing the interconnecting layer, and producing a perovskite light absorption section on the inter-connecting layer. The interconnecting layer provides an electrically conducting and optically transparent connection between the CIGS light absorption section and the perovskite light absorption section.
In some embodiments, the polishing of the interconnecting layer provides a surface of the interconnecting layer that has a maximum vertical distance (VD) less than 250 nm. In some embodiments, the polishing of the interconnecting layer provides a surface of the interconnecting layer that has a maximum VD less than 100 nm. In some embodiments, the polishing of the interconnecting layer provides a surface of the interconnecting layer that has a maximum VD in the range of 100 nm to 5 nm. In some embodiments, the polishing of the interconnecting layer provides a surface of the interconnecting layer that has a maximum VD in the range of 40 nm to 10 nm.
In some embodiments, the depositing of the interconnecting layer deposits an ITO layer about 300 nm thick. In some embodiments, the depositing of the interconnecting layer deposits an Indium Tin Oxide (ITO) layer of between 200 nm to 400 nm thick.
In some embodiments, the producing of the perovskite light absorption section on the inter-connecting layer includes depositing a hole transport layer on the interconnecting layer and doping the hole transport layer to increase hole conduction thereof.
According to other embodiments of the invention, a tandem device having a transport top electrode, suitable inter-connecting layer (ICL) and hole transporting layer (HTL), and successfully present a high-performance monolithic perovskite/CIGS tandem solar cell without modification of the CIGS device structure, i.e., by preserving its transparent conductive oxide (TCO) layers (i-ZnO and Boron-doped ZnO (BZO) layers is constructed. For the two subcells, we apply a semitransparent perovskite with a band gap of 1.59 eV as a front cell, and CIGS with a bandgap of 1.00 eV as a rear cell. The certified tandem device power conversion efficiency (PCE) achieves 22.43% that is the highest PCE for thin film tandem solar cells and has doubled the previous record for the perovskite/CIGS monolithic tandem device structure.
The embodiments illustrated and discussed in this specification are intended only to teach those skilled in the art how to make and use the invention. In describing embodiments of the invention, specific terminology is employed for the sake of clarity. However, the invention is not intended to be limited to the specific terminology so selected. The above-described embodiments of the invention may be modified or varied, without departing from the invention, as appreciated by those skilled in the art in light of the above teachings. It is therefore to be understood that, within the scope of the claims and their equivalents, the invention may be practiced otherwise than as specifically described.
The present patent application claims priority benefit to U.S. Provisional Patent Application No. 62/656,703 filed on Apr. 12, 2018, the entire content of which is incorporated herein by reference. All references cited anywhere in this specification, including the Background and Detailed Description sections, are incorporated by reference as if each had been individually incorporated.
This invention was made with government support under Grant Number ECCS-1509955 awarded by the National Science Foundation. The government has certain rights in the invention.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/US19/27336 | 4/12/2019 | WO | 00 |
| Number | Date | Country | |
|---|---|---|---|
| 62656703 | Apr 2018 | US |
