Highly reinforced elastomer for use in downhole stators

Information

  • Patent Application
  • 20080050259
  • Publication Number
    20080050259
  • Date Filed
    August 25, 2006
    17 years ago
  • Date Published
    February 28, 2008
    16 years ago
Abstract
A Moineau stator for a downhole drilling motor and a method for fabricating the stator are disclosed. The stator includes an internal helical cavity component fabricated from an improved elastomeric material formulated to provide both high resilience and good processability. For example, in one exemplary embodiment the elastomer material includes rheological parameters ML in a range from about 1.0 to about 4.0 lb·in and MH in a range from about 75 to about 110 lb·in according to ASTM D2084 at 380 degrees F. Stators in accordance with this invention may exhibit improved efficiency (and may thus provide improved torque output) as compared with conventional stators without substantially increasing manufacturing costs.
Description

BRIEF DESCRIPTION OF THE DRAWINGS

For a more complete understanding of the present invention, and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:



FIG. 1 depicts a conventional drill bit coupled to a Moineau style drilling motor utilizing an exemplary stator embodiment of the present invention.



FIG. 2 is a circular cross sectional view of the Moineau style stator as shown on FIG. 1.



FIG. 3 plots RPM versus pressure drop for an exemplary embodiment of a downhole drilling motor in accordance with the invention. The exemplary drilling motor of this invention is compared with conventional drilling motors; one including an elastomeric helical cavity component and another including a rigid metal reinforced helical cavity component.





DETAILED DESCRIPTION

As described above, conventional Moineau drilling motors have used an elastomeric helical cavity component bonded to a steel housing. However, due to the behavior of the selected elastomer material in various competing conditions, there have been inevitable tradeoffs in the choice of a desired elastomer material. Such tradeoffs typically result in the selected elastomer having at least one less-than-optimal material property (e.g., lower-than-desired resilience, suboptimal processability, and/or inadequate dynamic properties) and as described above, these tradeoffs tend to compromise various stator fabrication and/or performance metrics.


Lower than desired elastomer resilience results in inadequate torque transmission. As described above, elastomeric materials with insufficient resilience undergo excessive deformation at high torque loads (due to the low rigidity of the elastomer), which allows drilling fluid to pass from one cavity to the next without producing any work. The result is a loss in rotor RPM (and therefore drill bit RPM). In severe conditions the rotor can stall in the stator. Several material properties may be measured to determine the resilience of an elastomeric material. Such properties include, elastic modulus (e.g., at tensile strains of 25 and 100%), compression modulus (e.g., at compressive strains 5, 10, and 15%), and hardness (Shore A).


While increased elastomer resilience is known to reduce RPM drop-off (thereby improving torque transmission), it is also known to degrade elastomer processability. As described above in the Background section, conventional wisdom in the downhole drilling industry suggests that resilient elastomer materials are not suitable for downhole stators due to inherently high viscosity (poor flowability of the pre-cured elastomer) at conventional injection molding temperatures. The processability of the elastomer is particularly important in longer and/or smaller diameter stators. Longer stators (e.g., greater than 20 feet) are often used in an attempt to minimize RPM drop off. Smaller diameter stators (e.g., less than four inch diameter) are commonly used in side tracking or other coiled tubing applications. It is known to those of skill in the art that increasing stator length and decreasing lobe diameter significantly increase the required pressure and time (and therefore expense) required to fabricate a stator via injection molding.


One measure of processability commonly used in the art is a property referred to as Mooney viscosity (e.g., measured according to ASTM D1646). Mooney viscosities in the range from about 20 to about 60 are sometimes considered to provide suitable processability. However, such measurements can be difficult and time consuming. Rheological properties can also be used to determine both the processability and the resilience (rigidity) of an elastomer. For example, the minimum torque, ML, as determined via ASTM D2040, tends to be a good indicator of elastomer processability, while the maximum torque, MH, tends to be a good indicator of elastomer resilience. An elastomer typically has good processability (suitable flowability at conventional injection molding temperatures) when ML is in the range from about 1.0 to about 4.0 lb·in when measured at 380 degrees F. with no preheat. High elastomer resilience (for reducing RPM drop-off) is typically indicated when MH is in the range from about 75 to about 110 lb·in as also measured at 380 degrees F. with no preheat. Conventional stators typically have an MH of about 55 lb·in or less.


Often increasing the resilience of an elastomer also degrades the dynamic properties of the elastomer. Such degradation of the dynamic properties is known to cause localized heating of the elastomer lobes due to the viscoelastic behavior of the elastomer (and its poor thermal conductivity). This in turn can result in thermal degradation of the elastomer and ultimately in failure of the stator (due to a phenomenon referred to in the art as “chunking” in which the stator lobes become embrittled and subsequently crack and tear apart). The dynamic properties are typically determined in the art by measuring a quantity referred to as tan δ, which is the ratio of the loss (or viscoelastic) modulus to the storage (or elastic) modulus. Increasing tan δ typically indicates increasing viscoelastic behavior and therefore degraded dynamic properties. While there is no universally agreed upon industry standard measurement technique for determining tan δ, the Applicant has found that a 250 degree F. tan δ value as determined in an RPA, after cure temperature sweep at a frequency of 10 Hz and a strain of 7% provides a suitable indication of the dynamic properties of a stator elastomer for use in a downhole stator. Tan δ values of less than about 0.25 typically indicate suitable dynamic properties; however, the Applicant has also found that stators employing highly resilient elastomers can accommodate somewhat compromised dynamic properties via reducing the strain in the interference fit between rotor and stator.


With reference now to FIGS. 1 and 2, one exemplary embodiment of a Moineau style power section 100 according to this invention is shown in use in a downhole drilling motor 60. Drilling motor 60 is coupled to a drill bit assembly 50 in a configuration suitable for drilling a subterranean borehole, such as in an oil and/or gas formation. Drilling motor 60 includes a helical rotor 150 deployed in the helical cavity of Moineau style stator 105. The rotor 150 it operatively positioned in the cavity to cooperate with the plurality of lobes. Applying fluid pressure to the cavity causes the rotor 150 to rotate in cooperation with the lobes in order to allow pressurized drilling fluid that is introduced at an upper end of the stator 105 to be expelled at the lower end and subsequently exhausted from the drill bit into a borehole. Rotation of rotor 150 causes drill bit 50 to rotate in the borehole.


With reference now to FIG. 2, power section 100 is shown in circular cross section, as shown by the section lines on FIG. 1. Moineau style stator 105 includes an outer stator tube 140 (e.g., a steel tube) retaining an elastomeric helical cavity portion 110. Helical cavity portion 110 is shaped to define a plurality of helical lobes 120 (and corresponding grooves) on an inner surface thereof. In the exemplary embodiment shown, the differing helical configurations on the rotor and the stator provide, in circular cross section, 4 lobes on the rotor and 5 lobes on the stator. It will be appreciated that this 4/5 design is depicted purely for illustrative purposes only, and that the present invention is in no way limited to any particular choice of helical configurations for the power section design.


With continued reference to FIGS. 1 and 2, helical cavity component 110 is fabricated from an improved elastomeric material that, despite the teachings and conventional wisdom in the art, is formulated to be both rigid and processable. In one exemplary embodiment the elastomer material includes rheological parameter ML in the range from about 1.0 to about 4.0 lb·in and parameter MH in the range from about 75 to about 110 lb·in as determined via ASTM D2040 at 380 degrees F. with no preheat. In other exemplary embodiments ML may be in the range from about 1.0 to about 3.5 lb·in or even 1.0 to 3.0 lb·in at 380 degrees F. with no preheat. Advantageous embodiments may also include one or more of the mechanical properties in one of the ranges shown in Table I.













TABLE I








Preferred
Most Preferred



Elastomeric Property
Range
Range




















 25% Tensile Modulus (psi)
>400
550–750



100% Tensile Modulus (psi)
>800
 900–1200



 5% Compression Modulus (psi)
>100
110–150



 10% Compression Modulus (psi)
>200
225–325



 15% Compression Modulus (psi)
>300
350–475



Hardness (Shore A)
>85
88–94










In one exemplary embodiment, elastomer formulations including Nysyn 33-3 nitrile butadiene rubber (having 33 percent acrylonitrile and a Mooney viscosity of 30), at least 15 parts of a phenolic resin plasticizer per 100 parts nitrile rubber, and at least 60 parts carbon black per 100 parts nitrile rubber have been found to have both desirable resilience and processability (e.g., ML in the range from about 1.0 to about 4.0 and MH in the range from about 75 to about 110). Such formulations have also been found to have desirable dynamic properties (e.g., a 250 degree F. tan δ value of less than about 0.25).


Table II lists exemplary formulations A, B, C, and D in accordance with the present invention as well as a prior art formulation STD. It will be appreciated that this invention is not limited by the precise formulations listed in Table II. The artisan of ordinary skill will readily recognize that the various components in those formulations may be substituted with suitable equivalents. In the exemplary embodiments shown, Akrochem P55 phenolic resin is utilized. It will be appreciated that the invention is not limited to any particular phenolic resin. It will also be understood that Akrochem P55 also includes from about 6.5 to about 8.5 percent of a hexa cross-linking agent.














TABLE II





Formulation
STD
A
B
C
D




















NYSYN 33-3
100.00
100.00
100.00
100.00
100.00


ASD 75 - 75% Sulfur
4.80
4.80
4.80
4.80
4.80


in NBR


911C - 85% ZnO in NBR
5.00
5.00
5.00
5.00
5.00


Stearic Acid
1.00
1.00
1.00
1.00
1.00


Agerite Resin D
3.00
3.00
3.00
3.00
3.00


DUSANTOX 6 PPD
2.00
2.00
2.00
2.00
2.00


N774 Ultra Carbon Black
60.00
60.00
60.00
80.00
100.00


Cumar - R13
15.00



15.00


Akrochem P55 Phenolic
10.00
15.00
25.00
25.00
10.00


Resin


Diisodecyl Phthalate
10.00
15.00
10.00
10.00
10.00


Paraplex G25
5.00
7.50
5.00
5.00
5.00


50% PVI in SBR
1.00
1.00
1.00
1.00
1.00


PB(OBTS)75
2.00
2.00
2.00
2.00
2.00


PB(TMTM)75
0.15
0.15
0.15
0.15
0.15


TOTAL
218.95
216.45
218.95
238.95
258.95









Table III lists characteristic properties measured for the formulations listed in Table II. These properties were determined in accordance with the test methodologies listed in Table IV.














TABLE III





Elastomeric Property
STD
A
B
C
D




















Tensile Strength (psi)
2294
2093
2120
1749
2209


Ultimate Elongation (psi)
381
303
252
259
294


25% Tensile Modulus
210
323
511
695
366


(psi)


100% Tensile Modulus
478
701
991
1093
873


(psi)


5% Compression
56
84
108
122



Modulus (psi)


10% Compression
111
170
224
276



Modulus (psi)


15% Compression
171
261
344
423



Modulus (psi)


Tear Strength (lb/in)
203
219
237
234
194


Hardness (Shore A)
75
84
88
91
88


Rheological Parameter
2.3
2.8
3.0
3.3
3.4


ML (lb · in)


Rheological Parameter
63
73
88
80
68


MH (lb · in)


Tanδ at 250° F.
0.15
0.18
0.20
0.23
0.24

















TABLE IV





Elastomeric Property
Test Method







Tensile Strength (psi)
ASTM D412, Die C


Ultimate Elongation (psi)
ASTM D412, Die C


 25% Tensile Modulus (psi)
ASTM D412, Die C


100% Tensile Modulus (psi)
ASTM D412, Die C


 5% Compression Modulus (psi)
ASTM D575


 10% Compression Modulus (psi)
ASTM D575


 15% Compression Modulus (psi)
ASTM D575


Tear Strength (lb/in)
ASTM D624 Die C


Hardness (Shore A)
ASTM D2240


Rheological Parameter ML
ASTM 2084, 380° F. no preheat


Rheological Parameter MH
ASTM 2084, 380° F. no preheat


Tanδ at 250° F.
RPA Aftercure, 10 Hz, 7% strain









With reference now to FIG. 3, the performance of three exemplary drilling motors is contrasted at a flow rate of 600 gallons per minute. The three drilling motors were each sized and shaped in accordance with Dyna-Drill Model No. DD675783.0 having a length of 125 inches, an outer diameter of 6.75 inches, and a ⅞ inch lobe. The drilling motors differed only in the materials used to fabricated the helical cavity component of the respective stators: (i) the conventional elastomer stator being fabricated with elastomer STD in Table II, (ii) the stator in accordance with this invention being fabricated with elastomer C shown in Table II, and (iii) a prior art stator having a Rigid, metallic helical cavity component with an elastomeric liner deployed on an inner surface thereof.



FIG. 3 plots RPM versus pressure drop (psi) from the top to the bottom of the stator. As shown, the drilling motor including elastomer C in accordance with this invention advantageously undergoes significantly reduced RPM drop off as compared to that of conventional drilling motor STD. For example, at a pressure drop of 1000 psi drilling motor C (including elastomer C) exhibits an RPM drop of only about 45 rpm versus an RPM drop off of about 105 rpm for the conventional stator (including elastomer STD). The performance of drilling motor C even compares favorably with prior art drilling motors including a stator with an elastomer lined, rigid metallic helical cavity component (an RPM drop off of 45 rpm versus 30 rpm at 1000 psi).


Exemplary embodiments of this invention advantageously obviate the need for the above described tradeoff in elastomer rigidity and processability. Moreover, exemplary embodiments of this invention may even obviate the need for stators having rigid, metallic helical cavity components (except perhaps in the most demanding applications).


Although the present invention and its advantages have been described in detail, it should be understood that various changes, substitutions and alternations can be made herein without departing from the spirit and scope of the invention as defined by the appended claims.

Claims
  • 1. A stator for use in a downhole drilling motor, the stator comprising: an outer tube;a helical cavity component deployed substantially coaxially in the outer tube, the helical cavity component providing an internal helical cavity and including a plurality of internal lobes; andthe helical cavity component including an elastomeric material, the elastomeric material including: 33-3 nitrile butadiene rubber having about 30 percent by weight acrylonitrile and a Mooney viscosity of about 30;at least 60 parts by weight carbon black per 100 parts by weight of the nitrile rubber; andat least 15 parts by weight phenolic resin plasticizer per 100 parts by weight of the nitrile rubber, said phenolic resin plasticizer further including a hexa cross linking agent.
  • 2. The stator of claim 1, wherein the phenolic resin plasticizer includes from about 6.5 to about 8.5 percent by weight of the hexa cross linking agent.
  • 3. The stator of claim 1, wherein the elastomeric material comprises about 25 parts by weight of the phenolic resin plasticizer per 100 parts by weight of the nitrile rubber.
  • 4. The stator of claim 1, wherein the elastomeric material comprises about 25 parts by weight of the phenolic resin plasticizer and about 80 parts by weight carbon black per 100 parts by weight of the nitrile rubber.
  • 5. The stator of claim 1, wherein the helical cavity component is fabricated substantially entirely from the elastomeric material.
  • 6. The stator of claim 1, wherein the elastomeric material includes the following tensile properties: a modulus at 25% elongation in a range from about 550 to about 750 psi; anda modulus at 100% elongation in a range from about 900 to about 1200 psi.
  • 7. The stator of claim 1, wherein the elastomeric material includes the following compressive properties: a modulus at 5% compression in a range from about 110 to about 150 psi;a modulus at 10% compression in a range from about 225 to about 325 psi; anda modulus at 15% compression in a range from about 350 to about 475 psi.
  • 8. The stator of claim 1, wherein the elastomeric material comprises a Shore A hardness in the range from about 88 to about 94.
  • 9. The stator of claim 1, wherein the elastomer material comprises rheological parameters ML in a range from about 1.0 to about 4.0 lb·in and MH in a range from about 75 to about 110 lb·in, said ML and said MH representative of a minimum and maximum torque as determined according to ASTM D2084 at 380 degrees F. with no preheat.
  • 10. The stator of claim 1, wherein the elastomer material comprises an aftercure tan δ at 250 degrees F. of less than about 0.25.
  • 11. A stator for a downhole drilling motor comprising: an outer tube;a helical cavity component deployed substantially coaxially in the outer tube, the helical cavity component providing an internal helical cavity and including a plurality of internal lobes; andthe helical cavity component being fabricated from an elastomeric material, the elastomeric material including a nitrile rubber having from about 30 to about 40 percent acrylonitrile, the elastomeric material further including rheological parameters ML in a range from about 1.0 to about 4.0 lb·in and MH in a range from about 75 to about 110 lb·in, said ML and said MH representative of a minimum and maximum torque as determined according to ASTM D2084 at 380 degrees F. with no preheat.
  • 12. The stator of claim 11, wherein the elastomeric material comprises at least 15 parts by weight phenolic resin plasticizer per 100 parts by weight of the nitrile rubber, the phenolic resin plasticizer including a hexa cross linking agent.
  • 13. The stator of claim 11, wherein the elastomeric material comprises about 80 parts by weight carbon black per 100 parts by weight of the nitrile rubber.
  • 14. The stator of claim 11, wherein the nitrile rubber comprises a 33-3 nitrile butadiene rubber having about 30 percent by weight acrylonitrile and a Mooney viscosity of about 30.
  • 15. The stator of claim 11, wherein the elastomeric material includes the following tensile properties: a modulus at 25% elongation in a range from about 550 to about 750 psi; anda modulus at 100% elongation in a range from about 900 to about 1200 psi.
  • 16. The stator of claim 11, wherein the elastomeric material includes the following compressive properties: a modulus at 5% compression in a range from about 110 to about 150 psi;a modulus at 10% compression in a range from about 225 to about 325 psi; anda modulus at 15% compression in a range from about 350 to about 475 psi.
  • 17. The stator of claim 11, wherein the elastomeric material comprises a Shore A hardness in the range from about 88 to about 94.
  • 18. The stator of claim 11, wherein the elastomer material comprises an aftercure tan δ at 250 degrees F. of less than about 0.25.
  • 19. The stator of claim 11, wherein ML is in a range from about 1.0 to about 3.5 lb·in.
  • 20. The stator of claim 11, wherein ML is in a range from about 1.0 to about 3.0 lb·in
  • 21. A method of manufacturing a stator for a downhole drilling motor, the method comprising: (a) providing an elastomeric compound including a nitrile rubber having from about 30 to about 40 percent acrylonitrile, the elastomeric compound further including rheological parameters ML in a range from about 1.0 to about 4.0 lb·in and MH in a range from about 75 to about 110 lb·in, said ML and said MH representative of a minimum and maximum torque as determined according to ASTM D2084 at 380 degrees F. with no preheat; and(b) injection molding the elastomeric compound into a tubular stator housing to form a helical cavity component, the helical cavity component providing an internal helical cavity and including a plurality of internal lobes.
  • 22. The method of claim 21, wherein the nitrile rubber comprises a Nysyn 333 nitrile butadiene rubber having about 33 percent acrylonitrile and a Mooney viscosity of about 30.
  • 23. The method of claim 21, wherein the elastomeric compound comprises about 25 parts by weight phenolic resin plasticizer per 100 parts by weight of the nitrile rubber, the phenolic resin plasticizer including a hexa cross linking agent.
  • 24. The method of claim 21, wherein the elastomeric compound comprises about 80 parts by weight carbon black per 100 parts by weight of the nitrile rubber.
  • 25. A subterranean drilling motor comprising: a rotor having a plurality of rotor lobes on a helical outer surface of the rotor;a stator including a helical cavity component, the helical cavity component providing an internal helical cavity and including a plurality of internal stator lobes;the rotor deployable in the helical cavity of the stator such that the rotor lobes are in a rotational interference fit with the stator lobes, rotation of the rotor in a predetermined direction causing the rotor lobes to (i) contact the stator lobes on a loaded side thereof as the interference fit is encountered, and (ii) pass by the stator lobes on a non-loaded side thereof as the interference fit is completed; andthe internal stator lobes fabricated from an elastomeric material including (i) a 33-3 nitrile butadiene rubber having about 30 percent by weight acrylonitrile and a Mooney viscosity of about 30, (ii) about 80 parts by weight carbon black per 100 parts by weight of the nitrile rubber, (iii) and about 25 parts by weight phenolic resin plasticizer per 100 parts by weight of the nitrile rubber, said phenolic resin plasticizer further including a hexa cross linking agent.
  • 26. A subterranean drilling motor comprising: a rotor having a plurality of rotor lobes on a helical outer surface of the rotor;a stator including a helical cavity component, the helical cavity component providing an internal helical cavity and including a plurality of internal stator lobes;the rotor deployable in the helical cavity of the stator such that the rotor lobes are in a rotational interference fit with the stator lobes, rotation of the rotor in a predetermined direction causing the rotor lobes to (i) contact the stator lobes on a loaded side thereof as the interference fit is encountered, and (ii) pass by the stator lobes on a non-loaded side thereof as the interference fit is completed; andthe internal stator lobes fabricated from an elastomeric material having the following properties:rheological parameter ML in a range from about 1.0 to about 4.0 lb·in;rheological parameter MH in a range from about 75 to about 110 lb·in;a tensile modulus at 25% elongation from about 550 to about 750 psi;a tensile modulus at 100% elongation from about 900 to about 1200 psi;a Shore A hardness in the range from about 88 to about 94; andwherein said ML and said MH are representative of minimum and maximum torque as determined according to ASTM D2084 at 380 degrees F. with no preheat.